DE2822725A1 - Verfahren zur herstellung von kristallinen aluminosilicat-zeolithen - Google Patents
Verfahren zur herstellung von kristallinen aluminosilicat-zeolithenInfo
- Publication number
- DE2822725A1 DE2822725A1 DE19782822725 DE2822725A DE2822725A1 DE 2822725 A1 DE2822725 A1 DE 2822725A1 DE 19782822725 DE19782822725 DE 19782822725 DE 2822725 A DE2822725 A DE 2822725A DE 2822725 A1 DE2822725 A1 DE 2822725A1
- Authority
- DE
- Germany
- Prior art keywords
- crystallization
- temperature
- compound
- stirring
- rpm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 18
- 229910000323 aluminium silicate Inorganic materials 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000013078 crystal Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 30
- 238000002425 crystallisation Methods 0.000 claims description 25
- 230000008025 crystallization Effects 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 23
- 239000002243 precursor Substances 0.000 claims description 15
- 239000010457 zeolite Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 9
- BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229910021536 Zeolite Inorganic materials 0.000 claims description 6
- -1 alkylammonium compound Chemical class 0.000 claims description 5
- CYNYIHKIEHGYOZ-UHFFFAOYSA-N 1-bromopropane Chemical compound CCCBr CYNYIHKIEHGYOZ-UHFFFAOYSA-N 0.000 claims description 4
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 claims description 2
- 150000003868 ammonium compounds Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 13
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- RULRTQRLYQBEHV-UHFFFAOYSA-N CC(=O)CC.C(CC)Br.C(CC)N(CCC)CCC Chemical compound CC(=O)CC.C(CC)Br.C(CC)N(CCC)CCC RULRTQRLYQBEHV-UHFFFAOYSA-N 0.000 description 4
- 238000010899 nucleation Methods 0.000 description 3
- 230000006911 nucleation Effects 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000007323 disproportionation reaction Methods 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910018516 Al—O Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 101100230509 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) hat-1 gene Proteins 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2876—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures from a reacting mixture containing an amine or an organic cation, e.g. a quaternary onium cation-ammonium, phosphonium, stibonium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US80025977A | 1977-05-25 | 1977-05-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2822725A1 true DE2822725A1 (de) | 1978-12-07 |
| DE2822725C2 DE2822725C2 (https=) | 1988-04-21 |
Family
ID=25177919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19782822725 Granted DE2822725A1 (de) | 1977-05-25 | 1978-05-24 | Verfahren zur herstellung von kristallinen aluminosilicat-zeolithen |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS53147699A (https=) |
| DE (1) | DE2822725A1 (https=) |
| FR (1) | FR2391958A1 (https=) |
| GB (1) | GB1601915A (https=) |
| IT (1) | IT1096322B (https=) |
| NL (1) | NL7805627A (https=) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0011362A1 (en) * | 1978-11-13 | 1980-05-28 | Mobil Oil Corporation | Method for synthesis of zeolite ZSM-5 |
| EP0014546A1 (en) * | 1979-02-01 | 1980-08-20 | Mobil Oil Corporation | Preparation of nitrogenous zeolites and zeolites so prepared |
| EP0021674A1 (en) * | 1979-06-11 | 1981-01-07 | Mobil Oil Corporation | Synthesis of large crystal zeolite ZSM-5 and zeolite so made |
| EP0026962A1 (en) * | 1979-10-09 | 1981-04-15 | Mobil Oil Corporation | Method of synthesing large crystal zeolite ZSM-5 with controlled production of small crystals, and zeolite produced by this method |
| US4650656A (en) * | 1977-05-25 | 1987-03-17 | Mobil Oil Corporation | Large crystal ZSM-5 from template addition to the gel |
| EP1424128A1 (de) | 2002-12-01 | 2004-06-02 | Süd-Chemie Ag | Katalysator auf der Basis von kristallinem Alumosilicat |
| WO2011061196A1 (de) | 2009-11-19 | 2011-05-26 | Süd-Chemie AG | Kugelförmiger, zeolithischer katalysator zur umsetzung von methanol zu olefinen |
| DE102010026880A1 (de) | 2010-07-12 | 2012-01-12 | Süd-Chemie AG | Verfahren zur Herstellung von Katalysatoren auf Zeolithbasis zur Umsetzung von Oxygenaten zu niederen Olefinen |
| DE102010052258A1 (de) | 2010-11-23 | 2012-05-24 | Süd-Chemie AG | Verfahren zur Herstellung geträgerter ZSM-5-Zeolithe |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4908342A (en) * | 1985-09-04 | 1990-03-13 | Mobil Oil Corporation | ZSM-5 zeolites having uniformly large crystals |
| US4957320A (en) * | 1988-08-31 | 1990-09-18 | Trustees Of The University Of Pennsylvania | Methods and apparatus for mechanically intelligent grasping |
| CN104192859B (zh) * | 2014-08-21 | 2018-02-06 | 陕西延长石油(集团)有限责任公司研究院 | 一种小晶粒zsm‑5分子筛的快速合成法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3642434A (en) * | 1969-01-10 | 1972-02-15 | Mobil Oil Corp | Production of synthetic faujasite |
| DE1767235B2 (de) * | 1967-04-14 | 1979-10-04 | Mobil Oil Corp., New York, N.Y. (V.St.A.) | Verfahren zur Herstellung eines Zeolithen |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1117568A (en) * | 1965-11-24 | 1968-06-19 | Mobil Oil Corp | Synthetic crystalline aluminosilicate |
| FR2228721A1 (en) * | 1973-05-07 | 1974-12-06 | Mobil Oil | ZSM-21 synthetic crystalline aluminosilicate zeolites - for use as hydrocarbon conversion catalysts |
-
1978
- 1978-05-11 GB GB18959/78A patent/GB1601915A/en not_active Expired
- 1978-05-17 JP JP5772878A patent/JPS53147699A/ja active Granted
- 1978-05-24 FR FR7815399A patent/FR2391958A1/fr active Granted
- 1978-05-24 IT IT23765/78A patent/IT1096322B/it active
- 1978-05-24 NL NL7805627A patent/NL7805627A/xx not_active Application Discontinuation
- 1978-05-24 DE DE19782822725 patent/DE2822725A1/de active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1767235B2 (de) * | 1967-04-14 | 1979-10-04 | Mobil Oil Corp., New York, N.Y. (V.St.A.) | Verfahren zur Herstellung eines Zeolithen |
| US3642434A (en) * | 1969-01-10 | 1972-02-15 | Mobil Oil Corp | Production of synthetic faujasite |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4650656A (en) * | 1977-05-25 | 1987-03-17 | Mobil Oil Corporation | Large crystal ZSM-5 from template addition to the gel |
| EP0011362A1 (en) * | 1978-11-13 | 1980-05-28 | Mobil Oil Corporation | Method for synthesis of zeolite ZSM-5 |
| EP0014546A1 (en) * | 1979-02-01 | 1980-08-20 | Mobil Oil Corporation | Preparation of nitrogenous zeolites and zeolites so prepared |
| EP0021674A1 (en) * | 1979-06-11 | 1981-01-07 | Mobil Oil Corporation | Synthesis of large crystal zeolite ZSM-5 and zeolite so made |
| EP0026962A1 (en) * | 1979-10-09 | 1981-04-15 | Mobil Oil Corporation | Method of synthesing large crystal zeolite ZSM-5 with controlled production of small crystals, and zeolite produced by this method |
| EP1424128A1 (de) | 2002-12-01 | 2004-06-02 | Süd-Chemie Ag | Katalysator auf der Basis von kristallinem Alumosilicat |
| WO2011061196A1 (de) | 2009-11-19 | 2011-05-26 | Süd-Chemie AG | Kugelförmiger, zeolithischer katalysator zur umsetzung von methanol zu olefinen |
| DE102009053922A1 (de) | 2009-11-19 | 2011-05-26 | Lurgi Gmbh | Kugelförmiger, zeolithischer Katalysator zur Umsetzung von Methanol zu Olefinen |
| DE102010026880A1 (de) | 2010-07-12 | 2012-01-12 | Süd-Chemie AG | Verfahren zur Herstellung von Katalysatoren auf Zeolithbasis zur Umsetzung von Oxygenaten zu niederen Olefinen |
| WO2012007398A1 (de) | 2010-07-12 | 2012-01-19 | Süd-Chemie AG | Verfahren zur herstellung von katalysatoren auf zeolithbasis zur umsetzung von oxygenaten zu niederen olefinen |
| DE102010052258A1 (de) | 2010-11-23 | 2012-05-24 | Süd-Chemie AG | Verfahren zur Herstellung geträgerter ZSM-5-Zeolithe |
| WO2012069526A1 (de) | 2010-11-23 | 2012-05-31 | Süd-Chemie AG | Verfahren zur herstellung geträgerter zsm-5-zeolithe |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2822725C2 (https=) | 1988-04-21 |
| IT7823765A0 (it) | 1978-05-24 |
| FR2391958A1 (fr) | 1978-12-22 |
| JPS6215487B2 (https=) | 1987-04-08 |
| NL7805627A (nl) | 1978-11-28 |
| GB1601915A (en) | 1981-11-04 |
| JPS53147699A (en) | 1978-12-22 |
| FR2391958B1 (https=) | 1982-08-20 |
| IT1096322B (it) | 1985-08-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8128 | New person/name/address of the agent |
Representative=s name: KADOR, U., DIPL.-CHEM. DR.RER.NAT. KLUNKER, H., DI |
|
| 8110 | Request for examination paragraph 44 | ||
| 8128 | New person/name/address of the agent |
Representative=s name: KADOR, U., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 800 |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |