DE2748040A1 - Alpha-halogensubstituierte asymmetrische diacylperoxide in coinitiatorsystemen - Google Patents
Alpha-halogensubstituierte asymmetrische diacylperoxide in coinitiatorsystemenInfo
- Publication number
- DE2748040A1 DE2748040A1 DE19772748040 DE2748040A DE2748040A1 DE 2748040 A1 DE2748040 A1 DE 2748040A1 DE 19772748040 DE19772748040 DE 19772748040 DE 2748040 A DE2748040 A DE 2748040A DE 2748040 A1 DE2748040 A1 DE 2748040A1
- Authority
- DE
- Germany
- Prior art keywords
- peroxide
- organic peroxide
- coinitiator
- carbon atoms
- coinitiator system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000012933 diacyl peroxide Substances 0.000 title claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 32
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- 150000001451 organic peroxides Chemical class 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 17
- 239000000178 monomer Substances 0.000 claims description 12
- -1 neodecanoic acid ester Chemical class 0.000 claims description 8
- 238000007334 copolymerization reaction Methods 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 150000004651 carbonic acid esters Chemical class 0.000 claims description 2
- XYXGFHALMTXBQX-UHFFFAOYSA-N carboxyoxy hydrogen carbonate Chemical compound OC(=O)OOC(O)=O XYXGFHALMTXBQX-UHFFFAOYSA-N 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- 241000156978 Erebia Species 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 30
- 240000007817 Olea europaea Species 0.000 description 16
- 229920005989 resin Polymers 0.000 description 15
- 239000011347 resin Substances 0.000 description 15
- PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 description 12
- SBUYBNIDQXQZSZ-UHFFFAOYSA-N p-aminophenylphosphocholine Chemical compound C[N+](C)(C)CCOP([O-])(=O)OC1=CC=C(N)C=C1 SBUYBNIDQXQZSZ-UHFFFAOYSA-N 0.000 description 11
- 239000003999 initiator Substances 0.000 description 10
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
- 229920006026 co-polymeric resin Polymers 0.000 description 5
- 150000002976 peresters Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- JETQIUPBHQNHNZ-OAYJICASSA-N sulbenicillin Chemical compound N([C@H]1[C@H]2SC([C@@H](N2C1=O)C(O)=O)(C)C)C(=O)C(S(O)(=O)=O)C1=CC=CC=C1 JETQIUPBHQNHNZ-OAYJICASSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
- 230000001976 improved effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000005029 sieve analysis Methods 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- NVFRHTFJDGAFQS-UHFFFAOYSA-N 1-(3,4,5-trihydroxyphenyl)nonan-1-one Chemical compound CCCCCCCCC(=O)C1=CC(O)=C(O)C(O)=C1 NVFRHTFJDGAFQS-UHFFFAOYSA-N 0.000 description 1
- UKWUOTZGXIZAJC-UHFFFAOYSA-N 4-nitrosalicylic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1O UKWUOTZGXIZAJC-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 241000557769 Iodes Species 0.000 description 1
- 229920003091 Methocel™ Polymers 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000006179 pH buffering agent Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/38—Mixtures of peroxy-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/739,416 US4102815A (en) | 1976-11-08 | 1976-11-08 | Alpha halo substituted asymmetrical diacyl peroxides in co-initiator systems |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2748040A1 true DE2748040A1 (de) | 1978-05-18 |
Family
ID=24972205
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19772748040 Withdrawn DE2748040A1 (de) | 1976-11-08 | 1977-10-26 | Alpha-halogensubstituierte asymmetrische diacylperoxide in coinitiatorsystemen |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US4102815A (OSRAM) |
| JP (1) | JPS5358590A (OSRAM) |
| BE (1) | BE860568A (OSRAM) |
| CA (1) | CA1097607A (OSRAM) |
| DE (1) | DE2748040A1 (OSRAM) |
| FR (1) | FR2370060A1 (OSRAM) |
| GB (1) | GB1577169A (OSRAM) |
| IT (1) | IT1079903B (OSRAM) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4279831A (en) * | 1979-08-10 | 1981-07-21 | Argus Chemical Corporation | 2-Chloro-2-alkyl substituted asymmetrical diacyl peroxides |
| US4307217A (en) * | 1979-08-10 | 1981-12-22 | Argus Chemical Corporation | 2-Chloro-2-alkyl substituted asymmetrical diacyl peroxides and polymerization process using same |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3022282A (en) | 1959-08-25 | 1962-02-20 | Us Rubber Co | Polymerization catalyst for vinyl chloride |
| US3420807A (en) * | 1966-12-19 | 1969-01-07 | Wallace & Tiernan Inc | Vinyl chloride polymerization |
| US3652681A (en) * | 1967-10-16 | 1972-03-28 | Argus Chem | Alpha-halo substituted asymmetrical diacyl peroxides |
| US3652524A (en) * | 1967-12-26 | 1972-03-28 | Argus Chem | Process for polymerizing vinyl chloride with low molecular weight acyl peroxycarbonic esters |
| NL6717760A (OSRAM) * | 1967-12-28 | 1969-07-01 | ||
| US3558537A (en) * | 1968-01-02 | 1971-01-26 | Argus Chem | Imparting antifogging properties to polyvinyl chloride resins and compositions therefor |
| US3817965A (en) * | 1968-02-27 | 1974-06-18 | Aquitaine Petrole | Polymerization of vinyl compounds in suspension |
| BE754577A (OSRAM) * | 1969-08-08 | 1971-02-08 | Wacker Chemie Gmbh | |
| BE756426A (fr) * | 1969-09-23 | 1971-03-22 | Basf Ag | Procede de preparation d'homo- ou de copolymeres de l'ethylene |
| US3763128A (en) * | 1970-04-08 | 1973-10-02 | Argus Chem | Novel co initiator systems |
| US3687867A (en) * | 1970-04-08 | 1972-08-29 | Argus Chem | Novel co-initiator systems |
| US3932372A (en) * | 1970-07-20 | 1976-01-13 | Argus Chemical Corporation | Peroxide co-initiator system for polymerization |
| US3736306A (en) * | 1970-09-14 | 1973-05-29 | Pennwalt Corp | Polymerization of vinyl chloride with blends of peroxide initiators |
| US3778422A (en) * | 1971-05-17 | 1973-12-11 | Tenneco Chem | Process for the production of vinyl halide polymers |
-
1976
- 1976-11-08 US US05/739,416 patent/US4102815A/en not_active Expired - Lifetime
-
1977
- 1977-03-04 US US05/774,289 patent/US4107419A/en not_active Expired - Lifetime
- 1977-07-06 CA CA282,132A patent/CA1097607A/en not_active Expired
- 1977-07-29 IT IT50506/77A patent/IT1079903B/it active
- 1977-08-19 JP JP9943277A patent/JPS5358590A/ja active Pending
- 1977-09-02 FR FR7726766A patent/FR2370060A1/fr active Granted
- 1977-09-23 GB GB39785/77A patent/GB1577169A/en not_active Expired
- 1977-10-26 DE DE19772748040 patent/DE2748040A1/de not_active Withdrawn
- 1977-11-07 BE BE182423A patent/BE860568A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1577169A (en) | 1980-10-22 |
| IT1079903B (it) | 1985-05-13 |
| FR2370060B3 (OSRAM) | 1980-06-06 |
| US4107419A (en) | 1978-08-15 |
| US4102815A (en) | 1978-07-25 |
| CA1097607A (en) | 1981-03-17 |
| BE860568A (fr) | 1978-03-01 |
| FR2370060A1 (fr) | 1978-06-02 |
| JPS5358590A (en) | 1978-05-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1520119C3 (de) | Verfahren zur Herstellung einer stabilen Dispersion eines Additionspolymeren in einer organischen Flüssigkeit | |
| DE2256154C3 (de) | Verfahren zur Herstellung von wäßrigen Dispersionen von Polymerisaten monoolefinisch ungesättigter Carbonsäureester | |
| DE3420036C2 (OSRAM) | ||
| DE2946984A1 (de) | Herstellung modifizierter polypropylene | |
| DE1720376A1 (de) | Verfahren zur Polymerisation von Vinylverbindungen | |
| DE2748040A1 (de) | Alpha-halogensubstituierte asymmetrische diacylperoxide in coinitiatorsystemen | |
| DE883352C (de) | Verfahren zur Herstellung von Mischpolymerisaten aus monomerem Vinylidencyanid (1, 1-Dicyanaethylen) und anderen Monomeren | |
| DE1247021B (OSRAM) | ||
| DE2255999A1 (de) | Vinylacetat-aethylen-copolymerisate, verfahren zu deren herstellung und deren verwendung | |
| DE1904372A1 (de) | Verfahren zur Herstellung von Polymerisaten und Mischpolymerisaten auf der Basis von Vinylchlorid und die dabei enthaltenen Produkte | |
| DE1570995A1 (de) | Verfahren zur Herstellung von Pfropfpolymerisaten | |
| DE2714948C2 (de) | Verfahren zur kontinuierlichen Herstellung von Vinylchlorid-Polymerisaten | |
| DE1131407B (de) | Verfahren zur Polymerisation ungesaettigter Verbindungen | |
| DE1090861B (de) | Verfahren zur Herstellung von Polyvinylchlorid | |
| DE2141847C3 (de) | Verfahren zur Polymerisation von Vinylchlorid | |
| DE2364057A1 (de) | Vinylhalogenid-terpolymer und massenpolymerisationsverfahren zu seiner herstellung | |
| DE1445303C (de) | Verfahren zur Herstellung von Poly athylen | |
| DE942352C (de) | Verfahren zur Herstellung von Mischpolymerisaten | |
| DE2639171A1 (de) | Innerlich plastifiziertes vinylchlorid-copolymer-gemisch | |
| DE2806044A1 (de) | Vernetzte, mit wasser quellbare polymerisate aus inden und maleinsaeureanhydrid | |
| DE2931102B2 (de) | Verfahren zur Herstellung von Vinylhalogenidpolymeren oder -copolymeren | |
| DE1720433B1 (de) | Verfahren zur polymerisation von vinylverbindungen | |
| DE3750090T3 (de) | Fester Katalysatorbestandteil für Olefinpolymerisation und Olefinpolymerisationskatalysator. | |
| DE2503154C3 (de) | Verfahren zur Herstellung von in Lacklösungsmitteln klare Lösungen ergebenden Mischpolymerisaten des Vinylchlorids | |
| DD231363A5 (de) | Verfahren zur polymerisation von vinychlorid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |