DE2653290C2 - Beständige Lösung eines Gemisches von Aluminium-iso- und -n-butoxiden in den entsprechenden Alkoholen und Verfahren zu ihrer Herstellung - Google Patents
Beständige Lösung eines Gemisches von Aluminium-iso- und -n-butoxiden in den entsprechenden Alkoholen und Verfahren zu ihrer HerstellungInfo
- Publication number
- DE2653290C2 DE2653290C2 DE2653290A DE2653290A DE2653290C2 DE 2653290 C2 DE2653290 C2 DE 2653290C2 DE 2653290 A DE2653290 A DE 2653290A DE 2653290 A DE2653290 A DE 2653290A DE 2653290 C2 DE2653290 C2 DE 2653290C2
- Authority
- DE
- Germany
- Prior art keywords
- aluminum
- mixture
- butoxides
- alcohols
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 title claims description 48
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 42
- 239000000203 mixture Substances 0.000 title claims description 40
- 229910052782 aluminium Inorganic materials 0.000 title claims description 38
- 150000001298 alcohols Chemical class 0.000 title claims description 27
- 238000000034 method Methods 0.000 title claims description 16
- 239000004411 aluminium Substances 0.000 title claims 3
- 238000002360 preparation method Methods 0.000 title claims 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 25
- MYWQGROTKMBNKN-UHFFFAOYSA-N tributoxyalumane Chemical class [Al+3].CCCC[O-].CCCC[O-].CCCC[O-] MYWQGROTKMBNKN-UHFFFAOYSA-N 0.000 claims description 25
- 229940035429 isobutyl alcohol Drugs 0.000 claims description 11
- 238000010992 reflux Methods 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 claims description 4
- 239000012808 vapor phase Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 24
- 239000000243 solution Substances 0.000 description 21
- -1 aluminum alkoxides Chemical class 0.000 description 14
- 239000007788 liquid Substances 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000012190 activator Substances 0.000 description 7
- WOZZOSDBXABUFO-UHFFFAOYSA-N tri(butan-2-yloxy)alumane Chemical compound [Al+3].CCC(C)[O-].CCC(C)[O-].CCC(C)[O-] WOZZOSDBXABUFO-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 150000004703 alkoxides Chemical group 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 230000001476 alcoholic effect Effects 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000012047 saturated solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- DAOVYDBYKGXFOB-UHFFFAOYSA-N tris(2-methylpropoxy)alumane Chemical class [Al+3].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-] DAOVYDBYKGXFOB-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 238000006036 Oppenauer oxidation reaction Methods 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000006650 prototype reaction Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/28—Metal alcoholates
- C07C31/32—Aluminium alcoholates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/68—Preparation of metal alcoholates
- C07C29/70—Preparation of metal alcoholates by converting hydroxy groups to O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/640,502 US4052428A (en) | 1975-12-15 | 1975-12-15 | Stable aluminum alkoxide solutions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2653290A1 DE2653290A1 (de) | 1977-06-23 |
| DE2653290C2 true DE2653290C2 (de) | 1987-01-29 |
Family
ID=24568522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2653290A Expired DE2653290C2 (de) | 1975-12-15 | 1976-11-24 | Beständige Lösung eines Gemisches von Aluminium-iso- und -n-butoxiden in den entsprechenden Alkoholen und Verfahren zu ihrer Herstellung |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4052428A (enExample) |
| JP (1) | JPS6058734B2 (enExample) |
| BE (1) | BE849413A (enExample) |
| CA (1) | CA1064525A (enExample) |
| DE (1) | DE2653290C2 (enExample) |
| FR (1) | FR2335480A1 (enExample) |
| GB (1) | GB1507419A (enExample) |
| IT (1) | IT1069064B (enExample) |
| NL (1) | NL7612832A (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4525307A (en) * | 1983-08-02 | 1985-06-25 | Joseph Ayers, Inc. | Modified aluminum tri-alkoxide compounds |
| US4596881A (en) * | 1984-10-01 | 1986-06-24 | Stauffer Chemical Company | Stabilized liquid aluminum alkoxides and process |
| US4745204A (en) * | 1986-06-05 | 1988-05-17 | International Business Machines Corporation | Process for producing aluminum alkoxide or aluminum aryloxide |
| US4835298A (en) * | 1986-09-24 | 1989-05-30 | Union Carbide Corporation | Method for producing liquid alkoxides of mixed metals |
| US5139976A (en) * | 1986-09-24 | 1992-08-18 | Union Carbide Coatings Service Technology Corporation | Cordierite composition and method of production |
| US4946976A (en) * | 1986-09-24 | 1990-08-07 | Union Carbide Corporation | Cordierite composition and method of production |
| JP2007268118A (ja) * | 2006-03-31 | 2007-10-18 | Takara Belmont Co Ltd | 座部が揺動可能なスツール |
| US20090134369A1 (en) * | 2007-11-26 | 2009-05-28 | Applied Nanoworks, Inc. | Metal alkoxides, apparatus for manufacturing metal alkoxides, related methods and uses thereof |
| CN102153447B (zh) * | 2011-01-26 | 2013-08-28 | 连云港连连化学有限公司 | 低级烷醇铝的制备和固化方法 |
| CN102153448B (zh) * | 2011-01-26 | 2014-04-30 | 连云港连连化学有限公司 | 气固相反应制备低级烷醇铝的方法 |
| KR101341182B1 (ko) | 2011-11-28 | 2013-12-13 | 재단법인 포항산업과학연구원 | 고순도 알루미늄 알콕사이드의 제조방법 |
| CN103204763A (zh) * | 2013-04-28 | 2013-07-17 | 江苏双乐化工颜料有限公司 | 一种有机醇钠的合成方法 |
| CN113735687B (zh) * | 2020-05-28 | 2024-07-09 | 中国石油化工股份有限公司 | 一种高纯度烷氧基铝的制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2666076A (en) * | 1954-01-12 | Preparation of aluminum alcqhoi | ||
| US2579251A (en) * | 1948-01-27 | 1951-12-18 | British Aluminum Company Ltd | Manufacture of aluminum alkoxides |
| US2687423A (en) * | 1952-07-18 | 1954-08-24 | Mesirow Raymond | Preparation of liquid aluminum alkoxides |
| US2845447A (en) * | 1954-04-08 | 1958-07-29 | Shell Dev | Production of aluminum alcoholates |
| US2965663A (en) * | 1957-11-25 | 1960-12-20 | Anderson Chemical Company | Processes for preparing metal alkyls and alkoxides |
| US3068263A (en) * | 1959-12-23 | 1962-12-11 | Stauffer Chemical Co | Processes for preparing liquid stable aluminum alkoxide materials |
| US3094546A (en) * | 1960-07-14 | 1963-06-18 | Stauffer Chemical Co | Processes for preparing organometallic compounds |
| US3717666A (en) * | 1971-02-16 | 1973-02-20 | Ethyl Corp | Process for producing aluminum alkoxides |
| JPS5313002Y2 (enExample) * | 1972-10-24 | 1978-04-08 |
-
1975
- 1975-12-15 US US05/640,502 patent/US4052428A/en not_active Expired - Lifetime
-
1976
- 1976-11-18 NL NL7612832A patent/NL7612832A/xx not_active Application Discontinuation
- 1976-11-24 DE DE2653290A patent/DE2653290C2/de not_active Expired
- 1976-11-30 GB GB49936/76A patent/GB1507419A/en not_active Expired
- 1976-12-10 JP JP51147918A patent/JPS6058734B2/ja not_active Expired
- 1976-12-10 CA CA267,613A patent/CA1064525A/en not_active Expired
- 1976-12-13 IT IT52574/76A patent/IT1069064B/it active
- 1976-12-14 FR FR7637614A patent/FR2335480A1/fr active Granted
- 1976-12-15 BE BE2055532A patent/BE849413A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE2653290A1 (de) | 1977-06-23 |
| FR2335480A1 (fr) | 1977-07-15 |
| FR2335480B1 (enExample) | 1980-04-04 |
| BE849413A (nl) | 1977-06-15 |
| CA1064525A (en) | 1979-10-16 |
| NL7612832A (nl) | 1977-06-17 |
| JPS5273805A (en) | 1977-06-21 |
| US4052428A (en) | 1977-10-04 |
| IT1069064B (it) | 1985-03-25 |
| JPS6058734B2 (ja) | 1985-12-21 |
| GB1507419A (en) | 1978-04-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |