DE2634541B2 - Nickel und Aluminiumoxid sowie Natrium und/oder Kalium enthaltender Katalysator zur Reformierung von Kohlenwasserstoffen mit Dampf bei hohen Drücken - Google Patents
Nickel und Aluminiumoxid sowie Natrium und/oder Kalium enthaltender Katalysator zur Reformierung von Kohlenwasserstoffen mit Dampf bei hohen DrückenInfo
- Publication number
- DE2634541B2 DE2634541B2 DE2634541A DE2634541A DE2634541B2 DE 2634541 B2 DE2634541 B2 DE 2634541B2 DE 2634541 A DE2634541 A DE 2634541A DE 2634541 A DE2634541 A DE 2634541A DE 2634541 B2 DE2634541 B2 DE 2634541B2
- Authority
- DE
- Germany
- Prior art keywords
- sodium
- catalyst
- potassium
- nickel
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000003054 catalyst Substances 0.000 title claims description 84
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 47
- 229910052700 potassium Inorganic materials 0.000 title claims description 39
- 239000011734 sodium Substances 0.000 title claims description 37
- 229910052708 sodium Inorganic materials 0.000 title claims description 36
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims description 34
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 title claims description 34
- 239000011591 potassium Substances 0.000 title claims description 32
- 229910052759 nickel Inorganic materials 0.000 title claims description 23
- 229930195733 hydrocarbon Natural products 0.000 title claims description 9
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 9
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 title claims description 6
- 238000002407 reforming Methods 0.000 title claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 238000001914 filtration Methods 0.000 claims description 27
- 239000010802 sludge Substances 0.000 claims description 24
- 239000000243 solution Substances 0.000 claims description 22
- 238000001556 precipitation Methods 0.000 claims description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 14
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 9
- 238000001354 calcination Methods 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 4
- 239000012065 filter cake Substances 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 150000003112 potassium compounds Chemical class 0.000 claims description 2
- 235000012970 cakes Nutrition 0.000 description 19
- 229910002651 NO3 Inorganic materials 0.000 description 12
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- 238000009835 boiling Methods 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
- 238000005245 sintering Methods 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 6
- 239000001099 ammonium carbonate Substances 0.000 description 6
- 235000012501 ammonium carbonate Nutrition 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 6
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052593 corundum Inorganic materials 0.000 description 4
- 239000010431 corundum Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 239000012018 catalyst precursor Substances 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- 235000021463 dry cake Nutrition 0.000 description 3
- DWAHIRJDCNGEDV-UHFFFAOYSA-N nickel(2+);dinitrate;hydrate Chemical compound O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DWAHIRJDCNGEDV-UHFFFAOYSA-N 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 239000004317 sodium nitrate Substances 0.000 description 3
- 235000010344 sodium nitrate Nutrition 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- ZZCONUBOESKGOK-UHFFFAOYSA-N aluminum;trinitrate;hydrate Chemical compound O.[Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O ZZCONUBOESKGOK-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000000710 polymer precipitation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000000629 steam reforming Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 238000010744 Boudouard reaction Methods 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910018590 Ni(NO3)2-6H2O Inorganic materials 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000005048 flame photometry Methods 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- -1 nickel-aluminum oxide compound Chemical class 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB39724/75A GB1525017A (en) | 1975-09-29 | 1975-09-29 | Steam reforming and methanation catalysts methods of making them and processes for the production of fuel gases |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2634541A1 DE2634541A1 (de) | 1977-03-31 |
| DE2634541B2 true DE2634541B2 (de) | 1980-09-25 |
Family
ID=10411127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2634541A Ceased DE2634541B2 (de) | 1975-09-29 | 1976-07-31 | Nickel und Aluminiumoxid sowie Natrium und/oder Kalium enthaltender Katalysator zur Reformierung von Kohlenwasserstoffen mit Dampf bei hohen Drücken |
Country Status (21)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2533915A1 (fr) * | 1982-10-01 | 1984-04-06 | Jgc Corp | Catalyseur pour la synthese du methane et son procede de preparation |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2411030A1 (fr) * | 1977-12-12 | 1979-07-06 | Azote & Prod Chim | Catalyseur et procede de fabrication d'amines a partir d'alcools |
| FR2430262A2 (fr) * | 1978-07-04 | 1980-02-01 | Azote & Prod Chim | Catalyseur et procede de fabrication d'amines a partir d'alcools |
| EP0002630B2 (fr) * | 1977-12-12 | 1986-04-16 | Societe Chimique De La Grande Paroisse, Azote Et Produits Chimiques | Catalyseur et procédé de fabrication d'amines à partir d'alcools |
| US4209424A (en) | 1977-12-12 | 1980-06-24 | Societe Chimique de la Grande Paroisse, Azote et Products Chimiques | Catalyst for manufacturing amines from alcohols |
| GB2139520B (en) * | 1983-05-12 | 1988-05-05 | British Gas Plc | Clay-containing catalysts for methanation, methanol synthesis and steam-cracking |
| NL190750C (nl) * | 1984-06-21 | 1994-08-01 | Unilever Nv | Nikkelaluminaat katalysator, de bereiding daarvan en het hydrogeneren van onverzadigde organische verbindingen daarmee. |
| GB2184367A (en) * | 1985-12-18 | 1987-06-24 | British Gas Plc | Methanation catalysts |
| GB2188061B (en) * | 1986-03-21 | 1989-11-15 | British Gas Plc | Production of methane-containing gases |
| GB2222963B (en) * | 1988-09-23 | 1992-01-02 | British Gas Plc | Catalysts |
| US5264202A (en) * | 1990-11-01 | 1993-11-23 | Air Products And Chemicals, Inc. | Combined prereformer and convective heat transfer reformer |
| US5354364A (en) * | 1993-06-23 | 1994-10-11 | The Babcock & Wilcox Company | High efficiency advanced dry scrubber |
| US5643344A (en) * | 1995-02-14 | 1997-07-01 | The Babcock & Wilcox Company | Dry scrubber with forced recirculation |
| US6537352B2 (en) | 1996-10-30 | 2003-03-25 | Idatech, Llc | Hydrogen purification membranes, components and fuel processing systems containing the same |
| US6783741B2 (en) | 1996-10-30 | 2004-08-31 | Idatech, Llc | Fuel processing system |
| US6221117B1 (en) * | 1996-10-30 | 2001-04-24 | Idatech, Llc | Hydrogen producing fuel processing system |
| US7195663B2 (en) | 1996-10-30 | 2007-03-27 | Idatech, Llc | Hydrogen purification membranes, components and fuel processing systems containing the same |
| JP2001190917A (ja) * | 2000-01-13 | 2001-07-17 | Ngk Insulators Ltd | 三角セルハニカム構造体 |
| US7128769B2 (en) * | 2002-06-27 | 2006-10-31 | Idatech, Llc | Methanol steam reforming catalysts, steam reformers, and fuel cell systems incorporating the same |
| US7427388B2 (en) * | 2004-03-19 | 2008-09-23 | Air Products And Chemicals, Inc. | Process for improving prereforming and reforming of natural gas containing higher hydrocarbons along with methane |
| US7449167B2 (en) * | 2004-07-08 | 2008-11-11 | Air Products And Chemicals, Inc. | Catalyst and process for improving the adiabatic steam-reforming of natural gas |
| US7601302B2 (en) | 2005-09-16 | 2009-10-13 | Idatech, Llc | Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same |
| TWI328898B (en) | 2005-09-16 | 2010-08-11 | Idatech L L C | Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same |
| US7972420B2 (en) | 2006-05-22 | 2011-07-05 | Idatech, Llc | Hydrogen-processing assemblies and hydrogen-producing systems and fuel cell systems including the same |
| US7939051B2 (en) | 2006-05-23 | 2011-05-10 | Idatech, Llc | Hydrogen-producing fuel processing assemblies, heating assemblies, and methods of operating the same |
| US7365102B1 (en) | 2007-02-26 | 2008-04-29 | Delphi Technologies, Inc. | Process for pre-reforming hydrocarbon fuels |
| US8262752B2 (en) | 2007-12-17 | 2012-09-11 | Idatech, Llc | Systems and methods for reliable feedstock delivery at variable delivery rates |
| EP2335824B1 (en) * | 2008-09-24 | 2018-03-28 | Nippon Steel & Sumitomo Metal Corporation | Method for producing catalyst for reforming tar-containing gas, method for reforming tar and method for regenerating catalyst for reforming tar-containing gas |
| KR100980591B1 (ko) | 2009-03-16 | 2010-09-06 | 서울대학교산학협력단 | 중형기공성 니켈-알루미나 공침촉매, 그 제조방법 및 상기 촉매를 이용한 액화천연가스의 수증기 개질반응에 의한 수소 제조방법 |
| US8137422B2 (en) | 2009-06-03 | 2012-03-20 | Air Products And Chemicals, Inc. | Steam-hydrocarbon reforming with reduced carbon dioxide emissions |
| FR2949020B1 (fr) | 2009-08-06 | 2012-01-13 | Franco Cell | Dispositif de production d'electricite et de chaleur, incluant une pile a combustible admettant au moins du methane comme combustible |
| EP3018095B1 (en) | 2014-11-10 | 2017-06-28 | Air Products And Chemicals, Inc. | Steam-hydrocarbon reforming process |
| US10476093B2 (en) | 2016-04-15 | 2019-11-12 | Chung-Hsin Electric & Machinery Mfg. Corp. | Membrane modules for hydrogen separation and fuel processors and fuel cell systems including the same |
| US11712655B2 (en) | 2020-11-30 | 2023-08-01 | H2 Powertech, Llc | Membrane-based hydrogen purifiers |
| GB202103659D0 (en) | 2021-03-17 | 2021-04-28 | Johnson Matthey Plc | Getter activation and use |
| GB202103658D0 (en) | 2021-03-17 | 2021-04-28 | Johnson Matthey Plc | Catalyst activation |
| CN119546547A (zh) | 2022-08-02 | 2025-02-28 | 气体产品与化学公司 | 二氧化碳排放减少的蒸汽烃重整 |
| US20240270573A1 (en) | 2023-02-15 | 2024-08-15 | Air Products And Chemicals, Inc. | Steam-Hydrocarbon Reforming with Low Steam Production |
| US20240279057A1 (en) | 2023-02-15 | 2024-08-22 | Air Products And Chemicals, Inc. | Steam-Hydrocarbon Reforming with Low Steam Production |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3320182A (en) * | 1963-10-21 | 1967-05-16 | Exxon Research Engineering Co | High activity nickel-alumina catalyst |
| NL6402670A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1964-03-13 | 1965-09-14 | ||
| BE663807A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1964-05-12 | |||
| GB1043377A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1964-06-08 | 1966-09-21 | ||
| GB1271721A (en) * | 1968-05-03 | 1972-04-26 | Gas Council | A process for the production of methane-containing gases |
| GB1265481A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1968-05-03 | 1972-03-01 | ||
| US3759678A (en) * | 1971-04-08 | 1973-09-18 | Du Pont | Reformer catalyst |
| DE2255956A1 (de) * | 1972-11-15 | 1974-05-22 | Basf Ag | Katalysator und dessen verwendung zur herstellung von methan |
| DE2314804C3 (de) * | 1973-03-24 | 1982-01-21 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Erzeugung methanhaltiger Gase aus Kohlenwasserstoffen |
| GB1432696A (en) * | 1973-04-30 | 1976-04-22 | Ici Ltd | Catalytic process |
| US4104201A (en) * | 1974-09-06 | 1978-08-01 | British Gas Corporation | Catalytic steam reforming and catalysts therefor |
| US3988263A (en) * | 1974-10-02 | 1976-10-26 | Union Oil Company Of California | Thermally stable coprecipitated catalysts useful for methanation and other reactions |
| US4005996A (en) * | 1975-09-04 | 1977-02-01 | El Paso Natural Gas Company | Methanation process for the production of an alternate fuel for natural gas |
-
1975
- 1975-09-29 GB GB39724/75A patent/GB1525017A/en not_active Expired
-
1976
- 1976-07-12 US US05/704,410 patent/US4105591A/en not_active Expired - Lifetime
- 1976-07-15 IE IE1565/76A patent/IE43491B1/en unknown
- 1976-07-19 CA CA257,271A patent/CA1097315A/en not_active Expired
- 1976-07-19 ZA ZA00764261A patent/ZA764261B/xx unknown
- 1976-07-20 SE SE7608261A patent/SE427425B/xx unknown
- 1976-07-21 DK DK329376A patent/DK329376A/da not_active Application Discontinuation
- 1976-07-29 PL PL1976191516A patent/PL101184B1/pl unknown
- 1976-07-31 DE DE2634541A patent/DE2634541B2/de not_active Ceased
- 1976-08-02 IN IN1375/CAL/76A patent/IN146365B/en unknown
- 1976-08-20 LU LU75631A patent/LU75631A1/xx unknown
- 1976-08-20 FR FR7625404A patent/FR2325427A1/fr active Granted
- 1976-08-25 BR BR7605606A patent/BR7605606A/pt unknown
- 1976-09-02 JP JP51105387A patent/JPS594183B2/ja not_active Expired
- 1976-09-20 AU AU17913/76A patent/AU497814B2/en not_active Expired
- 1976-09-24 DD DD7600194988A patent/DD128791A5/xx unknown
- 1976-09-28 IT IT69320/76A patent/IT1069115B/it active
- 1976-09-29 NL NL7610788A patent/NL7610788A/xx unknown
- 1976-09-29 ES ES451939A patent/ES451939A1/es not_active Expired
- 1976-09-29 CS CS766287A patent/CS205043B2/cs unknown
- 1976-09-29 BE BE171073A patent/BE846737A/xx not_active IP Right Cessation
-
1977
- 1977-10-17 ES ES463282A patent/ES463282A1/es not_active Expired
-
1979
- 1979-06-18 US US06/049,601 patent/US4250060A/en not_active Expired - Lifetime
-
1980
- 1980-07-30 US US06/173,718 patent/US4417905A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2533915A1 (fr) * | 1982-10-01 | 1984-04-06 | Jgc Corp | Catalyseur pour la synthese du methane et son procede de preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| IE43491B1 (en) | 1981-03-11 |
| CA1097315A (en) | 1981-03-10 |
| DE2634541A1 (de) | 1977-03-31 |
| ZA764261B (en) | 1978-03-29 |
| IN146365B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1979-05-12 |
| AU1791376A (en) | 1978-04-06 |
| BR7605606A (pt) | 1977-08-09 |
| BE846737A (fr) | 1977-01-17 |
| FR2325427A1 (fr) | 1977-04-22 |
| AU497814B2 (en) | 1979-01-11 |
| DK329376A (da) | 1977-03-30 |
| ES451939A1 (es) | 1977-12-16 |
| US4250060A (en) | 1981-02-10 |
| IT1069115B (it) | 1985-03-25 |
| ES463282A1 (es) | 1978-07-16 |
| CS205043B2 (en) | 1981-04-30 |
| PL101184B1 (pl) | 1978-12-30 |
| IE43491L (en) | 1977-03-29 |
| SE7608261L (sv) | 1977-03-30 |
| FR2325427B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1978-11-03 |
| SE427425B (sv) | 1983-04-11 |
| NL7610788A (nl) | 1977-03-31 |
| JPS594183B2 (ja) | 1984-01-28 |
| DD128791A5 (de) | 1977-12-07 |
| US4417905A (en) | 1983-11-29 |
| LU75631A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1977-03-29 |
| JPS5242488A (en) | 1977-04-02 |
| GB1525017A (en) | 1978-09-20 |
| US4105591A (en) | 1978-08-08 |
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| 8263 | Opposition against grant of a patent | ||
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| 8227 | New person/name/address of the applicant |
Free format text: BRITISH GAS PLC, LONDON, GB |