DE2553094B2 - Die Verwendung bestimmter Perverbindungen zur Erhöhung der Beständigkeit von Äthylenpolymerisaten gegen ein Verschmoren und Erhöhung der Aushärtungsgeschwindigkeit - Google Patents
Die Verwendung bestimmter Perverbindungen zur Erhöhung der Beständigkeit von Äthylenpolymerisaten gegen ein Verschmoren und Erhöhung der AushärtungsgeschwindigkeitInfo
- Publication number
- DE2553094B2 DE2553094B2 DE2553094A DE2553094A DE2553094B2 DE 2553094 B2 DE2553094 B2 DE 2553094B2 DE 2553094 A DE2553094 A DE 2553094A DE 2553094 A DE2553094 A DE 2553094A DE 2553094 B2 DE2553094 B2 DE 2553094B2
- Authority
- DE
- Germany
- Prior art keywords
- increase
- weight
- masses
- hydroperoxide
- charring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920000573 polyethylene Polymers 0.000 title claims description 23
- 150000001875 compounds Chemical class 0.000 title description 11
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 21
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 13
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 11
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 description 36
- 238000012360 testing method Methods 0.000 description 27
- 238000001125 extrusion Methods 0.000 description 19
- 239000003963 antioxidant agent Substances 0.000 description 13
- 150000002978 peroxides Chemical class 0.000 description 11
- -1 organic peroxide compounds Chemical class 0.000 description 10
- 239000005977 Ethylene Substances 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000009413 insulation Methods 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- 239000004020 conductor Substances 0.000 description 5
- 150000002432 hydroperoxides Chemical class 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 238000009795 derivation Methods 0.000 description 3
- 230000002028 premature Effects 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- KSNRDYQOHXQKAB-UHFFFAOYSA-N 2,2,4-trimethyl-3,4-dihydro-1h-quinoline Chemical compound C1=CC=C2C(C)CC(C)(C)NC2=C1 KSNRDYQOHXQKAB-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000011872 intimate mixture Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- QYCGBAJADAGLLK-UHFFFAOYSA-N 1-(cyclohepten-1-yl)cycloheptene Chemical compound C1CCCCC=C1C1=CCCCCC1 QYCGBAJADAGLLK-UHFFFAOYSA-N 0.000 description 1
- KAJRUHJCBCZULP-UHFFFAOYSA-N 1-cyclohepta-1,3-dien-1-ylcyclohepta-1,3-diene Chemical compound C1CCC=CC=C1C1=CC=CCCC1 KAJRUHJCBCZULP-UHFFFAOYSA-N 0.000 description 1
- 125000003143 4-hydroxybenzyl group Chemical group [H]C([*])([H])C1=C([H])C([H])=C(O[H])C([H])=C1[H] 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 101100060894 Schizosaccharomyces pombe (strain 972 / ATCC 24843) ctp1 gene Proteins 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- OSPDFFCOJRYDNX-UHFFFAOYSA-N cumene;hydrogen peroxide;2-hydroperoxy-2-methylpropane Chemical compound OO.CC(C)(C)OO.CC(C)C1=CC=CC=C1 OSPDFFCOJRYDNX-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000007863 gel particle Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 101150033934 nip1 gene Proteins 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 125000002081 peroxide group Chemical group 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000004297 potassium metabisulphite Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52785274A | 1974-11-27 | 1974-11-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2553094A1 DE2553094A1 (de) | 1976-08-12 |
| DE2553094B2 true DE2553094B2 (de) | 1979-05-03 |
Family
ID=24103190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2553094A Withdrawn DE2553094B2 (de) | 1974-11-27 | 1975-11-26 | Die Verwendung bestimmter Perverbindungen zur Erhöhung der Beständigkeit von Äthylenpolymerisaten gegen ein Verschmoren und Erhöhung der Aushärtungsgeschwindigkeit |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS5177644A (enExample) |
| AU (1) | AU508623B2 (enExample) |
| BE (1) | BE835962A (enExample) |
| BR (1) | BR7507820A (enExample) |
| CA (1) | CA1047696A (enExample) |
| DE (1) | DE2553094B2 (enExample) |
| FR (1) | FR2292735A1 (enExample) |
| GB (1) | GB1535039A (enExample) |
| IN (1) | IN143890B (enExample) |
| IT (1) | IT1054913B (enExample) |
| NL (1) | NL7513803A (enExample) |
| SE (1) | SE408906B (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2063478A1 (en) | 1991-03-22 | 1992-09-23 | Michael F. Novits | Scorch extending curing/crosslinking compositions |
| ITMI960029U1 (it) * | 1996-01-18 | 1997-07-18 | Atochem Elf Italia | Composizioni perossidiche con resistenza allo scorch |
| IT1305324B1 (it) * | 1998-04-21 | 2001-05-04 | Atochem Elf Italia | Composizioni perossidiche con migliorata resistenza allo scorch per lareticolazione di elastomeri e poliolefine. |
| IT1305321B1 (it) * | 1998-04-21 | 2001-05-04 | Atochem Elf Italia | Composizioni perossidiche con migliorata resistenza allo scorch per lareticolazione di elastomeri e poliolefine |
| IT1305320B1 (it) | 1998-04-21 | 2001-05-04 | Atochem Elf Italia | Composizioni perossidiche con migliorata resistenza allo scorch perla reticolazione di elastomeri e poliolefine |
| IT1304174B1 (it) | 1998-12-17 | 2001-03-08 | Atochem Elf Italia | Composizioni perossidiche |
| US20040198920A1 (en) | 2003-04-03 | 2004-10-07 | Atofina | Scorch-retardant composition |
| FR2875502B1 (fr) | 2004-09-22 | 2007-01-05 | Arkema Sa | Composition retardant le grillage |
| US8581094B2 (en) | 2006-09-20 | 2013-11-12 | Dow Global Technologies, Llc | Electronic device module comprising polyolefin copolymer |
| US20080115825A1 (en) | 2006-09-20 | 2008-05-22 | Patel Rajen M | Electronic Device Module Comprising an Ethylene Multi-Block Copolymer |
| EP2070127B2 (en) | 2006-09-20 | 2015-09-02 | Dow Global Technologies LLC | Electronic device module comprising an ethylene multi-block copolymer |
| US7465769B2 (en) | 2006-10-09 | 2008-12-16 | Dow Global Technologies Inc. | Nitroxide compounds for minimizing scorch in crosslinkable compositions |
| JP5407877B2 (ja) * | 2010-01-08 | 2014-02-05 | 日油株式会社 | エチレン−酢酸ビニル共重合体組成物及び架橋物 |
| US20110290317A1 (en) | 2010-05-26 | 2011-12-01 | John Naumovitz | Electronic device module comprising polyolefin copolymer with low unsaturation and optional vinyl silane |
| EP2576639A1 (en) | 2010-06-04 | 2013-04-10 | Dow Global Technologies LLC | Electronic device module comprising film of homogeneous polyolefin copolymer and grafted silane |
| EP2576686A1 (en) | 2010-06-04 | 2013-04-10 | Dow Global Technologies LLC | Electronic device module comprising film of homogeneous polyolefin copolymer and adhesive property enhancing graft polymer |
| WO2011163025A1 (en) | 2010-06-24 | 2011-12-29 | Dow Global Technologies Llc | Electronic device module comprising heterogeneous polyolefin copolymer and optionally silane |
| JP2013539596A (ja) | 2010-06-24 | 2013-10-24 | ダウ グローバル テクノロジーズ エルエルシー | エチレンの長鎖分岐した（ｌｃｂ）、ブロック、または相互接続されたコポリマー、および場合によってはシランを含む電子素子モジュール |
| CN108384033B (zh) | 2012-02-03 | 2021-11-12 | 陶氏环球技术有限责任公司 | 包括含硅烷乙烯互聚物配方的膜和包括其的电子设备模块 |
| US9388296B2 (en) | 2012-06-04 | 2016-07-12 | National Institute Of Clean-And-Low-Carbon Energy | Crosslinked polyethylene composition having improved processability |
| WO2013185302A1 (zh) | 2012-06-13 | 2013-12-19 | 北京低碳清洁能源研究所 | 一种交联聚乙烯组合物 |
| EP3048649A1 (en) | 2015-01-23 | 2016-07-27 | Yparex B.V. | Electronic device module |
| JP2022142499A (ja) * | 2021-03-16 | 2022-09-30 | Ｍｃｐｐイノベーション合同会社 | 熱可塑性エラストマー組成物、成形体及びエアバック収納カバー |
| CN116891601B (zh) * | 2023-07-12 | 2025-07-08 | 浙江瑞堂塑料科技有限公司 | 一种滚塑成型哑铃片用聚烯烃复合材料及其应用 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT585379A (enExample) * | 1957-04-29 | |||
| US3661877A (en) * | 1970-05-21 | 1972-05-09 | Reichhold Chemicals Inc | Polymeric compositions and method of preparation |
-
1975
- 1975-10-21 CA CA238,088A patent/CA1047696A/en not_active Expired
- 1975-11-26 IT IT29672/75A patent/IT1054913B/it active
- 1975-11-26 IN IN2260/CAL/75A patent/IN143890B/en unknown
- 1975-11-26 BR BR7507820*A patent/BR7507820A/pt unknown
- 1975-11-26 GB GB48550/75A patent/GB1535039A/en not_active Expired
- 1975-11-26 NL NL7513803A patent/NL7513803A/xx not_active Application Discontinuation
- 1975-11-26 BE BE162190A patent/BE835962A/xx not_active IP Right Cessation
- 1975-11-26 AU AU86952/75A patent/AU508623B2/en not_active Expired
- 1975-11-26 DE DE2553094A patent/DE2553094B2/de not_active Withdrawn
- 1975-11-26 SE SE7513320A patent/SE408906B/xx not_active IP Right Cessation
- 1975-11-26 JP JP50140867A patent/JPS5177644A/ja active Pending
- 1975-11-26 FR FR7536196A patent/FR2292735A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE2553094A1 (de) | 1976-08-12 |
| SE7513320L (sv) | 1976-05-28 |
| JPS5177644A (enExample) | 1976-07-06 |
| GB1535039A (en) | 1978-12-06 |
| IN143890B (enExample) | 1978-02-18 |
| BE835962A (fr) | 1976-05-26 |
| FR2292735A1 (fr) | 1976-06-25 |
| BR7507820A (pt) | 1976-08-10 |
| SE408906B (sv) | 1979-07-16 |
| AU508623B2 (en) | 1980-03-27 |
| CA1047696A (en) | 1979-01-30 |
| AU8695275A (en) | 1977-06-02 |
| NL7513803A (nl) | 1976-05-31 |
| FR2292735B1 (enExample) | 1980-02-08 |
| IT1054913B (it) | 1981-11-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8239 | Disposal/non-payment of the annual fee |