DE2527488A1 - Verfahren zur umwandlung von silbersalzen in metallisches silber - Google Patents
Verfahren zur umwandlung von silbersalzen in metallisches silberInfo
- Publication number
- DE2527488A1 DE2527488A1 DE19752527488 DE2527488A DE2527488A1 DE 2527488 A1 DE2527488 A1 DE 2527488A1 DE 19752527488 DE19752527488 DE 19752527488 DE 2527488 A DE2527488 A DE 2527488A DE 2527488 A1 DE2527488 A1 DE 2527488A1
- Authority
- DE
- Germany
- Prior art keywords
- silver
- temperature
- metallic
- alkali metal
- waste material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910052709 silver Inorganic materials 0.000 title claims description 118
- 239000004332 silver Substances 0.000 title claims description 118
- 238000000034 method Methods 0.000 title claims description 40
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 title claims description 27
- 230000008569 process Effects 0.000 title claims description 12
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 111
- 238000006243 chemical reaction Methods 0.000 claims description 63
- 238000002844 melting Methods 0.000 claims description 24
- 230000008018 melting Effects 0.000 claims description 24
- 239000007787 solid Substances 0.000 claims description 24
- 239000002699 waste material Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 11
- 239000000839 emulsion Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000011368 organic material Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 8
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 8
- 150000001339 alkali metal compounds Chemical class 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229920000159 gelatin Polymers 0.000 claims description 6
- 235000019322 gelatine Nutrition 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- -1 silver halide Chemical class 0.000 claims description 6
- 108010010803 Gelatin Proteins 0.000 claims description 5
- 239000008273 gelatin Substances 0.000 claims description 5
- 235000011852 gelatine desserts Nutrition 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 230000009466 transformation Effects 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 229910001963 alkali metal nitrate Inorganic materials 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- 239000001828 Gelatine Substances 0.000 claims 1
- 229910002651 NO3 Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 claims 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 20
- 150000003378 silver Chemical class 0.000 description 18
- 239000011734 sodium Substances 0.000 description 10
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000011084 recovery Methods 0.000 description 7
- 239000012535 impurity Substances 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 230000004907 flux Effects 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 4
- 239000000779 smoke Substances 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000003915 air pollution Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000010344 sodium nitrate Nutrition 0.000 description 3
- 239000004317 sodium nitrate Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 102000035195 Peptidases Human genes 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 229910001923 silver oxide Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000000184 acid digestion Methods 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US484349A US3929466A (en) | 1974-06-28 | 1974-06-28 | Recovery of silver from silver salts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2527488A1 true DE2527488A1 (de) | 1976-01-15 |
Family
ID=23923791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752527488 Withdrawn DE2527488A1 (de) | 1974-06-28 | 1975-06-20 | Verfahren zur umwandlung von silbersalzen in metallisches silber |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3929466A (en, 2012) |
| JP (1) | JPS519023A (en, 2012) |
| BE (1) | BE830519A (en, 2012) |
| CA (1) | CA1038170A (en, 2012) |
| CH (1) | CH614235A5 (en, 2012) |
| DE (1) | DE2527488A1 (en, 2012) |
| FR (1) | FR2276391A1 (en, 2012) |
| GB (1) | GB1454708A (en, 2012) |
| IT (1) | IT1039016B (en, 2012) |
| NL (1) | NL7507663A (en, 2012) |
| ZA (1) | ZA753209B (en, 2012) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4028998A1 (de) * | 1989-09-28 | 1991-04-11 | Canadian Mint | Verfahren zur rueckgewinnung des silberanteils aus einem silberchloridhaltigen rueckstand |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1061947A (en) * | 1975-06-11 | 1979-09-04 | Horizons Research Incorporated | Solvent recovery of thermoplastic polyesters |
| CA1150061A (en) * | 1980-05-30 | 1983-07-19 | Wasyl Kunda | Process for the production of elemental silver from silver chloride or silver sulphate |
| US4388109A (en) * | 1980-05-30 | 1983-06-14 | Sherritt Gordon Mines Limited | Process for the production of silver powder from silver chloride, sulphate or sulphide |
| CA1150931A (en) * | 1980-05-30 | 1983-08-02 | Wasyl Kunda | Process for the recovery of silver values from silver-containing material which also contains iron and arsenic |
| US4437889A (en) | 1981-08-06 | 1984-03-20 | Palacios Mendoza Eliodoro | Method of recovering silver from solid and liquid photographic waste |
| JPS61270754A (ja) * | 1985-05-25 | 1986-12-01 | Konishiroku Photo Ind Co Ltd | 写真処理液の脱銀方法及び写真処理機 |
| JPS61270752A (ja) * | 1985-05-25 | 1986-12-01 | Konishiroku Photo Ind Co Ltd | 写真処理液の脱銀方法及び写真処理機 |
| JPS63259032A (ja) * | 1987-04-14 | 1988-10-26 | Tanaka Kikinzoku Kogyo Kk | 貴金属化合物の焼成方法 |
| US5064466A (en) * | 1989-01-19 | 1991-11-12 | Hilton Davis B | Non-toxic process for recovery of photographic silver |
| US5008017A (en) * | 1989-12-08 | 1991-04-16 | Eastman Kodak Company | Method for recovering metals from waste liquors |
| US5169682A (en) * | 1990-03-28 | 1992-12-08 | Coral Biotech Co., Ltd. | Method of providing silver on calcium carbonate material such as coral sand |
| JPH06340933A (ja) * | 1992-08-21 | 1994-12-13 | Panatsuku Kogyo Kk | 銀精錬方法および写真材料、写真処理液または写真乳剤からの銀回収方法 |
| CN106244815A (zh) * | 2016-08-31 | 2016-12-21 | 无锡中天固废处置有限公司 | 一种从感光胶片中分离回收银的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1545032A (en) * | 1925-07-07 | Process op secoveeing silver | ||
| US2131072A (en) * | 1937-04-09 | 1938-09-27 | Eastman Kodak Co | Silver recovery |
| US2131045A (en) * | 1937-04-09 | 1938-09-27 | Eastman Kodak Co | Silver recovery |
| US2218250A (en) * | 1938-08-19 | 1940-10-15 | Eastman Kodak Co | Silver recovery |
| US3632336A (en) * | 1969-07-25 | 1972-01-04 | Battelle Development Corp | Silver recovery process |
| US3594157A (en) * | 1969-08-19 | 1971-07-20 | Eastman Kodak Co | Alkaline chlorination of waste photographic processing solutions containing silver |
| US3671222A (en) * | 1969-11-24 | 1972-06-20 | Edward B Johnson | Silver recovery from photographic wastes |
| US3660079A (en) * | 1971-01-28 | 1972-05-02 | Midland Processing Inc | Precious metals recovery method |
| US3748123A (en) * | 1971-07-14 | 1973-07-24 | Bakker Dev Corp | Process for metal recovery |
| JPS548443B2 (en, 2012) * | 1974-05-11 | 1979-04-16 |
-
1974
- 1974-06-28 US US484349A patent/US3929466A/en not_active Expired - Lifetime
-
1975
- 1975-05-16 CA CA227,249A patent/CA1038170A/en not_active Expired
- 1975-05-19 ZA ZA00753209A patent/ZA753209B/xx unknown
- 1975-05-22 GB GB2228375A patent/GB1454708A/en not_active Expired
- 1975-06-09 JP JP50069462A patent/JPS519023A/ja active Pending
- 1975-06-16 IT IT24408/75A patent/IT1039016B/it active
- 1975-06-20 DE DE19752527488 patent/DE2527488A1/de not_active Withdrawn
- 1975-06-23 CH CH814775A patent/CH614235A5/xx not_active IP Right Cessation
- 1975-06-23 FR FR7519542A patent/FR2276391A1/fr active Granted
- 1975-06-23 BE BE157574A patent/BE830519A/xx unknown
- 1975-06-27 NL NL7507663A patent/NL7507663A/xx not_active Application Discontinuation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4028998A1 (de) * | 1989-09-28 | 1991-04-11 | Canadian Mint | Verfahren zur rueckgewinnung des silberanteils aus einem silberchloridhaltigen rueckstand |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1038170A (en) | 1978-09-12 |
| IT1039016B (it) | 1979-12-10 |
| GB1454708A (en) | 1976-11-03 |
| JPS519023A (en) | 1976-01-24 |
| CH614235A5 (en, 2012) | 1979-11-15 |
| AU8132375A (en) | 1976-11-25 |
| FR2276391A1 (fr) | 1976-01-23 |
| FR2276391B1 (en, 2012) | 1978-02-03 |
| NL7507663A (nl) | 1975-12-30 |
| ZA753209B (en) | 1976-04-28 |
| US3929466A (en) | 1975-12-30 |
| BE830519A (fr) | 1975-12-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8141 | Disposal/no request for examination |