DE2501396A1 - Verfahren zur entfernung von kupfer aus geringe mengen kupfer enthaltenden sauren loesungen - Google Patents
Verfahren zur entfernung von kupfer aus geringe mengen kupfer enthaltenden sauren loesungenInfo
- Publication number
- DE2501396A1 DE2501396A1 DE19752501396 DE2501396A DE2501396A1 DE 2501396 A1 DE2501396 A1 DE 2501396A1 DE 19752501396 DE19752501396 DE 19752501396 DE 2501396 A DE2501396 A DE 2501396A DE 2501396 A1 DE2501396 A1 DE 2501396A1
- Authority
- DE
- Germany
- Prior art keywords
- copper
- solutions
- column
- ppm
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims description 43
- 239000002253 acid Substances 0.000 title description 3
- 239000010949 copper Substances 0.000 claims description 104
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 86
- 229910052802 copper Inorganic materials 0.000 claims description 86
- 239000000243 solution Substances 0.000 claims description 73
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 39
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 32
- 239000003245 coal Substances 0.000 claims description 18
- 238000002386 leaching Methods 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 15
- 239000003929 acidic solution Substances 0.000 claims description 10
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 6
- 239000000908 ammonium hydroxide Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 2
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims 1
- 150000001879 copper Chemical class 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 41
- 238000001179 sorption measurement Methods 0.000 description 19
- 229910052759 nickel Inorganic materials 0.000 description 16
- 230000001186 cumulative effect Effects 0.000 description 8
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 5
- 235000013495 cobalt Nutrition 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000010626 work up procedure Methods 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229910017709 Ni Co Inorganic materials 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- POVGIDNLKNVCTJ-UHFFFAOYSA-J cobalt(2+);nickel(2+);disulfate Chemical compound [Co+2].[Ni+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O POVGIDNLKNVCTJ-UHFFFAOYSA-J 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- YFLLTMUVNFGTIW-UHFFFAOYSA-N nickel;sulfanylidenecopper Chemical compound [Ni].[Cu]=S YFLLTMUVNFGTIW-UHFFFAOYSA-N 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000000247 postprecipitation Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical class [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
- C22B3/24—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US440688A US3914374A (en) | 1974-02-08 | 1974-02-08 | Removal of residual copper from nickel solutions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2501396A1 true DE2501396A1 (de) | 1975-08-21 |
Family
ID=23749775
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752501396 Ceased DE2501396A1 (de) | 1974-02-08 | 1975-01-15 | Verfahren zur entfernung von kupfer aus geringe mengen kupfer enthaltenden sauren loesungen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3914374A (enExample) |
| JP (1) | JPS582254B2 (enExample) |
| CA (1) | CA1028504A (enExample) |
| CU (1) | CU34177A (enExample) |
| DE (1) | DE2501396A1 (enExample) |
| DO (1) | DOP1975002270A (enExample) |
| FR (1) | FR2260370B1 (enExample) |
| ZA (1) | ZA7527B (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4100043A (en) * | 1976-09-17 | 1978-07-11 | Amax Inc. | Atmospheric leach ion-exchange process for treating iron-containing nickel-copper matte |
| US4094754A (en) * | 1977-03-07 | 1978-06-13 | Amax Inc. | Leaching of Ni-Cu-Fe-S matte |
| US4261737A (en) * | 1979-10-31 | 1981-04-14 | Uop Inc. | Recovery of cobalt values |
| US6315906B1 (en) | 1998-07-10 | 2001-11-13 | United States Filter Corporation | Removing metal ions from wastewater |
| US6346195B1 (en) | 1998-07-10 | 2002-02-12 | U.S. Filter Corporation | Ion exchange removal of metal ions from wastewater |
| US7488423B2 (en) * | 2005-08-02 | 2009-02-10 | Siemens Water Technologies Holding Corp. | System and method of slurry treatment |
| US20100108609A1 (en) * | 2006-08-28 | 2010-05-06 | Wismer Michael W | System and method of slurry treatment |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2614029A (en) * | 1951-02-21 | 1952-10-14 | Du Pont | Purification of silver nitrate solutions |
-
1974
- 1974-02-08 US US440688A patent/US3914374A/en not_active Expired - Lifetime
- 1974-11-05 CA CA212,968A patent/CA1028504A/en not_active Expired
- 1974-12-16 CU CU34177A patent/CU34177A/es unknown
-
1975
- 1975-01-02 ZA ZA00750027A patent/ZA7527B/xx unknown
- 1975-01-15 DE DE19752501396 patent/DE2501396A1/de not_active Ceased
- 1975-01-24 DO DO1975002270A patent/DOP1975002270A/es unknown
- 1975-02-06 FR FR7503667A patent/FR2260370B1/fr not_active Expired
- 1975-02-08 JP JP50015916A patent/JPS582254B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS50115116A (enExample) | 1975-09-09 |
| DOP1975002270A (es) | 1980-11-15 |
| FR2260370B1 (enExample) | 1978-02-03 |
| US3914374A (en) | 1975-10-21 |
| CU34177A (es) | 1983-10-04 |
| JPS582254B2 (ja) | 1983-01-14 |
| AU7707475A (en) | 1976-07-08 |
| FR2260370A1 (enExample) | 1975-09-05 |
| CA1028504A (en) | 1978-03-28 |
| CU21031L (en) | 1975-06-30 |
| ZA7527B (en) | 1976-01-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8128 | New person/name/address of the agent |
Representative=s name: BARTELS, H. HELD, M., DIPL.-ING. DR.-ING., PAT.-AN |
|
| 8131 | Rejection |