DE2437093C2 - Verfahren zur Verhinderung der Vernetzung von Vinylchlorid-Vinyltrialkoxysilan-Copolymerisaten - Google Patents
Verfahren zur Verhinderung der Vernetzung von Vinylchlorid-Vinyltrialkoxysilan-CopolymerisatenInfo
- Publication number
- DE2437093C2 DE2437093C2 DE2437093A DE2437093A DE2437093C2 DE 2437093 C2 DE2437093 C2 DE 2437093C2 DE 2437093 A DE2437093 A DE 2437093A DE 2437093 A DE2437093 A DE 2437093A DE 2437093 C2 DE2437093 C2 DE 2437093C2
- Authority
- DE
- Germany
- Prior art keywords
- vinyl chloride
- copolymerization
- copolymers
- sample
- vinyltrialkoxysilane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 12
- 238000004132 cross linking Methods 0.000 title claims description 9
- 229920001577 copolymer Polymers 0.000 title description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title description 4
- 229920002554 vinyl polymer Polymers 0.000 title description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 26
- 238000007334 copolymerization reaction Methods 0.000 claims description 20
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 2
- 239000008346 aqueous phase Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 description 10
- 235000012424 soybean oil Nutrition 0.000 description 10
- 239000003549 soybean oil Substances 0.000 description 10
- 238000003860 storage Methods 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- PQXKWPLDPFFDJP-UHFFFAOYSA-N 2,3-dimethyloxirane Chemical compound CC1OC1C PQXKWPLDPFFDJP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 125000003700 epoxy group Chemical group 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000007717 exclusion Effects 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 230000006855 networking Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- UXCBMLGLQWBHGL-UHFFFAOYSA-N (2-cyclohexylsulfonylacetyl) 2-cyclohexylsulfonylethaneperoxoate Chemical compound C1CCCCC1S(=O)(=O)CC(=O)OOC(=O)CS(=O)(=O)C1CCCCC1 UXCBMLGLQWBHGL-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- OBALOCVLTHUBMB-UHFFFAOYSA-N benzene;oxirene Chemical compound O1C=C1.C1=CC=CC=C1 OBALOCVLTHUBMB-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- BLKQQTCUGZJWLN-VAWYXSNFSA-N dicyclohexyl (e)-but-2-enedioate Chemical compound C1CCCCC1OC(=O)/C=C/C(=O)OC1CCCCC1 BLKQQTCUGZJWLN-VAWYXSNFSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- BQRPSOKLSZSNAR-UHFFFAOYSA-N ethenyl-tris[(2-methylpropan-2-yl)oxy]silane Chemical compound CC(C)(C)O[Si](OC(C)(C)C)(OC(C)(C)C)C=C BQRPSOKLSZSNAR-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- -1 glycidyl ester Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001007 puffing effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
- C08F230/085—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2437093A DE2437093C2 (de) | 1974-08-01 | 1974-08-01 | Verfahren zur Verhinderung der Vernetzung von Vinylchlorid-Vinyltrialkoxysilan-Copolymerisaten |
| FR7523840A FR2280645A1 (fr) | 1974-08-01 | 1975-07-30 | Procede pour empecher la reticulation de copolymeres de chlorure de vinyle et de vinyltrialcoxy-silanes |
| IT50732/75A IT1041079B (it) | 1974-08-01 | 1975-07-30 | Procedimento per impedire la retticolazione di copolimeri di cloruro vinilico e vinil trialcossisilani |
| BE158757A BE831908A (fr) | 1974-08-01 | 1975-07-30 | Procede en vue d'empecher la reticulation de copolymeres de chlorure de vinyle et vinyltrialcoxysilanes |
| JP50094129A JPS5144194A (enrdf_load_stackoverflow) | 1974-08-01 | 1975-08-01 | |
| NL7509219A NL7509219A (nl) | 1974-08-01 | 1975-08-01 | Werkwijze voor het verhinderen van de verknoping van copolymeren van vinylchloride en vinyltri- alkoxysilanen. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2437093A DE2437093C2 (de) | 1974-08-01 | 1974-08-01 | Verfahren zur Verhinderung der Vernetzung von Vinylchlorid-Vinyltrialkoxysilan-Copolymerisaten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2437093A1 DE2437093A1 (de) | 1976-02-12 |
| DE2437093C2 true DE2437093C2 (de) | 1983-10-06 |
Family
ID=5922172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2437093A Expired DE2437093C2 (de) | 1974-08-01 | 1974-08-01 | Verfahren zur Verhinderung der Vernetzung von Vinylchlorid-Vinyltrialkoxysilan-Copolymerisaten |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5144194A (enrdf_load_stackoverflow) |
| BE (1) | BE831908A (enrdf_load_stackoverflow) |
| DE (1) | DE2437093C2 (enrdf_load_stackoverflow) |
| FR (1) | FR2280645A1 (enrdf_load_stackoverflow) |
| IT (1) | IT1041079B (enrdf_load_stackoverflow) |
| NL (1) | NL7509219A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4412038A (en) | 1981-08-05 | 1983-10-25 | Chemische Werke Huels Ag | Low molecular weight 1,3-butadiene polymers containing reactive silyl groups, which are stabilized against crosslinking |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5699793A (en) * | 1980-01-12 | 1981-08-11 | Agency Of Ind Science & Technol | Preparation of pristanol by microorganism |
| JPS6142519A (ja) * | 1984-08-06 | 1986-03-01 | Shin Etsu Chem Co Ltd | 塩化ビニル系共重合体の製造方法 |
| KR100837425B1 (ko) | 2006-01-11 | 2008-06-12 | 주식회사 엘지화학 | 염화비닐 공중합체 조성물 및 그의 제조방법 |
| JP5091771B2 (ja) * | 2007-10-01 | 2012-12-05 | 積水化学工業株式会社 | 塩化ビニル系樹脂成形体及びその製造方法 |
| JP5667477B2 (ja) * | 2011-03-09 | 2015-02-12 | 積水化学工業株式会社 | 塩化ビニル系樹脂、塩化ビニル系樹脂の製造方法及び塩化ビニル系樹脂成形体 |
-
1974
- 1974-08-01 DE DE2437093A patent/DE2437093C2/de not_active Expired
-
1975
- 1975-07-30 IT IT50732/75A patent/IT1041079B/it active
- 1975-07-30 FR FR7523840A patent/FR2280645A1/fr active Granted
- 1975-07-30 BE BE158757A patent/BE831908A/xx unknown
- 1975-08-01 NL NL7509219A patent/NL7509219A/xx unknown
- 1975-08-01 JP JP50094129A patent/JPS5144194A/ja active Pending
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4412038A (en) | 1981-08-05 | 1983-10-25 | Chemische Werke Huels Ag | Low molecular weight 1,3-butadiene polymers containing reactive silyl groups, which are stabilized against crosslinking |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2280645B3 (enrdf_load_stackoverflow) | 1978-03-17 |
| NL7509219A (nl) | 1976-02-03 |
| FR2280645A1 (fr) | 1976-02-27 |
| BE831908A (fr) | 1975-11-17 |
| JPS5144194A (enrdf_load_stackoverflow) | 1976-04-15 |
| DE2437093A1 (de) | 1976-02-12 |
| IT1041079B (it) | 1980-01-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |