DE2233941C3 - Verwendung von Perfluoralkylphosphorverbindungen als schaumdämpfende Mittel - Google Patents
Verwendung von Perfluoralkylphosphorverbindungen als schaumdämpfende MittelInfo
- Publication number
- DE2233941C3 DE2233941C3 DE2233941A DE2233941A DE2233941C3 DE 2233941 C3 DE2233941 C3 DE 2233941C3 DE 2233941 A DE2233941 A DE 2233941A DE 2233941 A DE2233941 A DE 2233941A DE 2233941 C3 DE2233941 C3 DE 2233941C3
- Authority
- DE
- Germany
- Prior art keywords
- foam
- compounds
- general formula
- substance
- see
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title claims description 33
- 239000006260 foam Substances 0.000 title description 43
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 description 31
- 239000000203 mixture Substances 0.000 description 18
- 238000000034 method Methods 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- -1 aliphatic alcohols Chemical class 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
- 150000003009 phosphonic acids Chemical class 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- PTIVACHGVHIMMK-UHFFFAOYSA-N 4-[[2-methoxy-4-[(4-nitrophenyl)diazenyl]phenyl]diazenyl]phenol Chemical compound COC1=CC(N=NC=2C=CC(=CC=2)[N+]([O-])=O)=CC=C1N=NC1=CC=C(O)C=C1 PTIVACHGVHIMMK-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- HRKAMJBPFPHCSD-UHFFFAOYSA-N Tri-isobutylphosphate Chemical compound CC(C)COP(=O)(OCC(C)C)OCC(C)C HRKAMJBPFPHCSD-UHFFFAOYSA-N 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- YXXQTQYRRHHWFL-UHFFFAOYSA-N diiodophosphanyl(diiodo)phosphane Chemical compound IP(I)P(I)I YXXQTQYRRHHWFL-UHFFFAOYSA-N 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000003197 gene knockdown Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000988 sulfur dye Substances 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0418—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing P-atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Detergent Compositions (AREA)
- Coloring (AREA)
- Beans For Foods Or Fodder (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Degasification And Air Bubble Elimination (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Paper (AREA)
- Printing Plates And Materials Therefor (AREA)
Priority Applications (18)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2233941A DE2233941C3 (de) | 1972-07-11 | 1972-07-11 | Verwendung von Perfluoralkylphosphorverbindungen als schaumdämpfende Mittel |
| NL7309145A NL7309145A (US07993877-20110809-P00003.png) | 1972-07-11 | 1973-06-29 | |
| SU1944632A SU492062A3 (ru) | 1972-07-11 | 1973-07-09 | Противовспениватели |
| US377561A US3912654A (en) | 1972-07-11 | 1973-07-09 | Use of perfluoralkylphosphorus compounds as foam-dampening agents |
| JP7717073A JPS5618241B2 (US07993877-20110809-P00003.png) | 1972-07-11 | 1973-07-10 | |
| GB3284473A GB1426339A (en) | 1972-07-11 | 1973-07-10 | Use of perfluoralkyl-phosphorus compounds as foam-dampening agents |
| AU57905/73A AU484459B2 (en) | 1972-07-11 | 1973-07-10 | Use of perfluoralkylphosphorus compounds as foam-dampening agents |
| CH1003273A CH552401A (de) | 1972-07-11 | 1973-07-10 | Verwendung von perfluoralkyl-phosphorverbindungen als schaumdaempfende mittel ausserhalb der textilindustrie. |
| DD172190A DD105130A5 (US07993877-20110809-P00003.png) | 1972-07-11 | 1973-07-10 | |
| AT607673A AT330133B (de) | 1972-07-11 | 1973-07-10 | Schaumdampfung, insbesondere in flotten oder losungen von textilveredlungsmitteln bzw. in losungen von anionaktiven oder nichtionogenen tensiden |
| CH336274D CH336274A4 (US07993877-20110809-P00003.png) | 1972-07-11 | 1973-07-10 | |
| FR7325235A FR2191921B1 (US07993877-20110809-P00003.png) | 1972-07-11 | 1973-07-10 | |
| CA176,047A CA1014446A (en) | 1972-07-11 | 1973-07-10 | Perfluoralkylphosphorus compounds as foam-dampening agents |
| CH336274A CH568434B5 (US07993877-20110809-P00003.png) | 1972-07-11 | 1973-07-10 | |
| IT26421/73A IT994936B (it) | 1972-07-11 | 1973-07-10 | Impiego di composti del fosforo perfluoro alchilici come prodotti che limitano la formazione di schiuma |
| ZA734676A ZA734676B (en) | 1972-07-11 | 1973-07-11 | Use of perfluoralkyl phosphorus compounds as foam-dampening agents |
| ES416797A ES416797A1 (es) | 1972-07-11 | 1973-07-11 | Procedimiento para inhibir la formacion de espuma en proce-sos industriales. |
| BE133371A BE802214A (fr) | 1972-07-11 | 1973-07-11 | Utilisation de composes perfludralkyl-phosphores comme agents anti-mousses |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2233941A DE2233941C3 (de) | 1972-07-11 | 1972-07-11 | Verwendung von Perfluoralkylphosphorverbindungen als schaumdämpfende Mittel |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2233941A1 DE2233941A1 (de) | 1974-01-31 |
| DE2233941B2 DE2233941B2 (de) | 1977-07-14 |
| DE2233941C3 true DE2233941C3 (de) | 1978-03-02 |
Family
ID=5850270
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2233941A Expired DE2233941C3 (de) | 1972-07-11 | 1972-07-11 | Verwendung von Perfluoralkylphosphorverbindungen als schaumdämpfende Mittel |
Country Status (15)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0407874A1 (de) * | 1989-07-08 | 1991-01-16 | Hoechst Schering AgrEvo GmbH | Entschäumer für flüssige Netzmittel und schaumarme flüssige Pflanzenschutzmittel |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2742853C2 (de) * | 1977-09-23 | 1982-09-23 | Hoechst Ag, 6000 Frankfurt | Verwendung von fluorierten Alkoholen zur Unterdrückung des Schäumens flüssiger Medien |
| US4270915A (en) * | 1978-09-19 | 1981-06-02 | United Merchants And Manufacturers, Inc. | Fabric printing process |
| US4293441A (en) * | 1979-03-12 | 1981-10-06 | Minnesota Mining And Manufacturing Company | Corrosion inhibiting heat transfer liquid |
| US4202706A (en) * | 1979-03-12 | 1980-05-13 | Minnesota Mining And Manufacturing Company | Corrosion resistance treatment of aluminum with N-alkyl-fluoroaliphaticsulfonamidophosphonic acids and salts thereof |
| DE3723198A1 (de) * | 1987-07-14 | 1989-02-16 | Bayer Ag | Schaumhemmender zusatz in sauren beizen und galvanischen baedern |
| US5679618A (en) * | 1990-07-06 | 1997-10-21 | Hoechst Aktiengesellschaft | Antifoams for solid crop protection agents |
| DK0561265T3 (da) * | 1992-03-17 | 1996-10-14 | Hoechst Schering Agrevo Gmbh | Skumdæmpere til faste plantebeskyttelsesmidler |
| BR9815058A (pt) | 1997-11-28 | 2000-10-03 | Clariant Gmbh | Processo para a preparação de ácidos dialquilfosfìnicos |
| EP0919560B1 (de) | 1997-11-28 | 2004-02-25 | Clariant GmbH | Verfahren zur Herstellung von Metallsalzen von Aryl-alkylphosphinsäuren |
| EP0919561B1 (de) | 1997-11-28 | 2004-02-18 | Clariant GmbH | Verfahren zur Herstellung von Aryl-alkylphosphinsäuren |
| ES2209246T3 (es) | 1997-11-28 | 2004-06-16 | Clariant Gmbh | Procedimiento para la fabricacion de sales de acidos dialquilfosfinicos. |
| US6444618B1 (en) * | 1999-01-29 | 2002-09-03 | Basf Aktiengesellschaft | Crop protection emulsifiable concentrate containing defoaming agents |
| DE19927787C2 (de) | 1999-06-18 | 2003-12-11 | Clariant Gmbh | Verfahren zur Herstellung von Alkylphosphonsäuren |
| DE10220547A1 (de) * | 2002-04-16 | 2003-11-06 | Merck Patent Gmbh | Verfahren zur Herstellung von Monohydro-Pefluoralkanen, Perfluoralkylphosphinaten und Perfluoralkylphosphonaten |
| DE102006025847A1 (de) | 2006-06-02 | 2007-12-06 | Merck Patent Gmbh | Verwendung von Phosphinsäure in der Galvanotechnik |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2394596A (en) * | 1943-12-31 | 1946-02-12 | Standard Oil Dev Co | Nonfoaming compositions and methods of making same |
| US2792374A (en) * | 1953-01-14 | 1957-05-14 | Socony Mobil Oil Co Inc | Aqueous defoamants |
| NL130594C (US07993877-20110809-P00003.png) * | 1968-07-22 |
-
1972
- 1972-07-11 DE DE2233941A patent/DE2233941C3/de not_active Expired
-
1973
- 1973-06-29 NL NL7309145A patent/NL7309145A/xx unknown
- 1973-07-09 SU SU1944632A patent/SU492062A3/ru active
- 1973-07-09 US US377561A patent/US3912654A/en not_active Expired - Lifetime
- 1973-07-10 AT AT607673A patent/AT330133B/de not_active IP Right Cessation
- 1973-07-10 CH CH336274D patent/CH336274A4/xx unknown
- 1973-07-10 CH CH1003273A patent/CH552401A/xx not_active IP Right Cessation
- 1973-07-10 JP JP7717073A patent/JPS5618241B2/ja not_active Expired
- 1973-07-10 GB GB3284473A patent/GB1426339A/en not_active Expired
- 1973-07-10 FR FR7325235A patent/FR2191921B1/fr not_active Expired
- 1973-07-10 CH CH336274A patent/CH568434B5/xx not_active IP Right Cessation
- 1973-07-10 CA CA176,047A patent/CA1014446A/en not_active Expired
- 1973-07-10 DD DD172190A patent/DD105130A5/xx unknown
- 1973-07-10 IT IT26421/73A patent/IT994936B/it active
- 1973-07-11 ES ES416797A patent/ES416797A1/es not_active Expired
- 1973-07-11 BE BE133371A patent/BE802214A/xx unknown
- 1973-07-11 ZA ZA734676A patent/ZA734676B/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0407874A1 (de) * | 1989-07-08 | 1991-01-16 | Hoechst Schering AgrEvo GmbH | Entschäumer für flüssige Netzmittel und schaumarme flüssige Pflanzenschutzmittel |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA734676B (en) | 1974-07-31 |
| US3912654A (en) | 1975-10-14 |
| NL7309145A (US07993877-20110809-P00003.png) | 1974-01-15 |
| IT994936B (it) | 1975-10-20 |
| FR2191921B1 (US07993877-20110809-P00003.png) | 1976-09-17 |
| CH568434B5 (US07993877-20110809-P00003.png) | 1975-10-31 |
| DE2233941A1 (de) | 1974-01-31 |
| ATA607673A (de) | 1975-09-15 |
| CH552401A (de) | 1974-08-15 |
| AT330133B (de) | 1976-06-10 |
| JPS5618241B2 (US07993877-20110809-P00003.png) | 1981-04-27 |
| ES416797A1 (es) | 1976-06-16 |
| SU492062A3 (ru) | 1975-11-15 |
| GB1426339A (en) | 1976-02-25 |
| BE802214A (fr) | 1974-01-11 |
| DD105130A5 (US07993877-20110809-P00003.png) | 1974-04-12 |
| CA1014446A (en) | 1977-07-26 |
| AU5790573A (en) | 1975-01-09 |
| DE2233941B2 (de) | 1977-07-14 |
| JPS4953183A (US07993877-20110809-P00003.png) | 1974-05-23 |
| CH336274A4 (US07993877-20110809-P00003.png) | 1975-05-30 |
| FR2191921A1 (US07993877-20110809-P00003.png) | 1974-02-08 |
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