DE2148774A1 - Stabilisatoren fuer Vinylchloridharze - Google Patents
Stabilisatoren fuer VinylchloridharzeInfo
- Publication number
- DE2148774A1 DE2148774A1 DE19712148774 DE2148774A DE2148774A1 DE 2148774 A1 DE2148774 A1 DE 2148774A1 DE 19712148774 DE19712148774 DE 19712148774 DE 2148774 A DE2148774 A DE 2148774A DE 2148774 A1 DE2148774 A1 DE 2148774A1
- Authority
- DE
- Germany
- Prior art keywords
- composition according
- compound
- monoalkyltin
- vinyl chloride
- stabilizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011347 resin Substances 0.000 title claims description 11
- 229920005989 resin Polymers 0.000 title claims description 11
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 6
- 239000003381 stabilizer Substances 0.000 title description 8
- 150000001875 compounds Chemical class 0.000 claims description 19
- -1 isooctyl- Chemical group 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- IUNVCWLKOOCPIT-UHFFFAOYSA-N 6-methylheptylsulfanyl 2-hydroxyacetate Chemical compound CC(C)CCCCCSOC(=O)CO IUNVCWLKOOCPIT-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 230000000087 stabilizing effect Effects 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 230000006641 stabilisation Effects 0.000 claims description 3
- 238000011105 stabilization Methods 0.000 claims description 3
- 150000003606 tin compounds Chemical class 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 2
- IQBLWPLYPNOTJC-FPLPWBNLSA-N (z)-4-(2-ethylhexoxy)-4-oxobut-2-enoic acid Chemical compound CCCCC(CC)COC(=O)\C=C/C(O)=O IQBLWPLYPNOTJC-FPLPWBNLSA-N 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims 1
- 229940070765 laurate Drugs 0.000 claims 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 9
- LUZSPGQEISANPO-UHFFFAOYSA-N butyltin Chemical class CCCC[Sn] LUZSPGQEISANPO-UHFFFAOYSA-N 0.000 description 6
- ZMHZSHHZIKJFIR-UHFFFAOYSA-N octyltin Chemical class CCCCCCCC[Sn] ZMHZSHHZIKJFIR-UHFFFAOYSA-N 0.000 description 6
- NPAIMXWXWPJRES-UHFFFAOYSA-N butyltin(3+) Chemical compound CCCC[Sn+3] NPAIMXWXWPJRES-UHFFFAOYSA-N 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 230000001976 improved effect Effects 0.000 description 4
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZHUWXKIPGGZNJW-UHFFFAOYSA-N 6-methylheptyl 3-sulfanylpropanoate Chemical compound CC(C)CCCCCOC(=O)CCS ZHUWXKIPGGZNJW-UHFFFAOYSA-N 0.000 description 1
- MKRJRMUQMAJPTL-UHFFFAOYSA-N 8-methyl-2-(6-methylheptyl)-2-(6-methylheptylsulfanyl)nonanoic acid Chemical compound CC(C)CCCCCSC(CCCCCC(C)C)(CCCCCC(C)C)C(O)=O MKRJRMUQMAJPTL-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- ZURNRTGXPYFPMR-ZBACLAMISA-H butyltin(3+) (Z)-2-(2-ethylhexyl)but-2-enedioate Chemical compound C(C)C(C/C(/C(=O)[O-])=C/C(=O)[O-])CCCC.C(C)C(C/C(/C(=O)[O-])=C/C(=O)[O-])CCCC.C(C)C(C/C(/C(=O)[O-])=C/C(=O)[O-])CCCC.C(CCC)[Sn+3].C(CCC)[Sn+3] ZURNRTGXPYFPMR-ZBACLAMISA-H 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- IESWIBSMHJCJAG-UHFFFAOYSA-L dibutyltin(2+);8-methyl-2-(6-methylheptyl)-2-sulfanylnonanoate Chemical compound CCCC[Sn+2]CCCC.CC(C)CCCCCC(S)(C([O-])=O)CCCCCC(C)C.CC(C)CCCCCC(S)(C([O-])=O)CCCCCC(C)C IESWIBSMHJCJAG-UHFFFAOYSA-L 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical group O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJAOYSPHSNGHNC-UHFFFAOYSA-N octadecane-1-thiol Chemical compound CCCCCCCCCCCCCCCCCCS QJAOYSPHSNGHNC-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- JQTFPHLEQLLQOT-UHFFFAOYSA-N octadecyl 2-sulfanylacetate Chemical class CCCCCCCCCCCCCCCCCCOC(=O)CS JQTFPHLEQLLQOT-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229940071127 thioglycolate Drugs 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4692270 | 1970-10-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2148774A1 true DE2148774A1 (de) | 1972-04-06 |
Family
ID=10443078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712148774 Pending DE2148774A1 (de) | 1970-10-02 | 1971-09-30 | Stabilisatoren fuer Vinylchloridharze |
Country Status (9)
| Country | Link |
|---|---|
| AU (1) | AU3409071A (OSRAM) |
| BE (1) | BE773416A (OSRAM) |
| DE (1) | DE2148774A1 (OSRAM) |
| ES (1) | ES395592A1 (OSRAM) |
| FR (1) | FR2109945A5 (OSRAM) |
| GB (1) | GB1346999A (OSRAM) |
| IT (1) | IT938868B (OSRAM) |
| NL (1) | NL7113390A (OSRAM) |
| ZA (1) | ZA716501B (OSRAM) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4988750A (en) * | 1981-07-17 | 1991-01-29 | Schering Ag | Non-toxic stabilizer for halogenated polymer |
| EP2123659A1 (en) * | 2008-05-15 | 2009-11-25 | Arkema France | High purity monoalkyltin compounds and uses thereof |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH588980A5 (OSRAM) | 1974-01-17 | 1977-06-30 | Ciba Geigy Ag | |
| EP0032106B1 (de) * | 1979-12-07 | 1983-06-01 | Ciba-Geigy Ag | Gemische von n-Octylzinn-Verbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Stabilisatoren für halogenhaltige Thermoplaste |
| NL8202252A (nl) * | 1981-07-17 | 1983-02-16 | Schering Ag | Niet-giftig stabilisatormengsel voor halogeen bevattende polymeren. |
| EP0111829B1 (en) * | 1982-12-10 | 1987-04-08 | Hoechst Celanese Corporation | Radiation-resistant vinyl chloride resin compositions |
| FR2599373B1 (fr) * | 1986-05-30 | 1989-06-16 | Ciba Geigy Ag | Compositions a base de poly-(chlorure de vinyle) stabilisees par des composes laurylstanniques, application de ces compositions et procede pour stabiliser des matieres a mouler |
| PL3145937T3 (pl) * | 2015-06-05 | 2018-11-30 | Galata Chemicals Llc | Stabilizatory zawierające związki monooktylocyny i dimetylocyny o wysokiej czystości |
-
1971
- 1971-09-27 GB GB4692270A patent/GB1346999A/en not_active Expired
- 1971-09-28 ZA ZA716501A patent/ZA716501B/xx unknown
- 1971-09-29 IT IT29272/71A patent/IT938868B/it active
- 1971-09-30 NL NL7113390A patent/NL7113390A/xx unknown
- 1971-09-30 ES ES395592A patent/ES395592A1/es not_active Expired
- 1971-09-30 AU AU34090/71A patent/AU3409071A/en not_active Expired
- 1971-09-30 DE DE19712148774 patent/DE2148774A1/de active Pending
- 1971-10-01 FR FR7135461A patent/FR2109945A5/fr not_active Expired
- 1971-10-01 BE BE773416A patent/BE773416A/nl unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4988750A (en) * | 1981-07-17 | 1991-01-29 | Schering Ag | Non-toxic stabilizer for halogenated polymer |
| EP2123659A1 (en) * | 2008-05-15 | 2009-11-25 | Arkema France | High purity monoalkyltin compounds and uses thereof |
| EP2300487B1 (en) * | 2008-05-15 | 2019-03-13 | PMC Organometallix, Inc. | High purity monoalkyltin compounds and uses thereof |
| EP3498720A1 (en) * | 2008-05-15 | 2019-06-19 | PMC Organometallix, Inc. | High purity monoalkyltin compounds and uses thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| BE773416A (nl) | 1972-01-31 |
| NL7113390A (OSRAM) | 1972-04-05 |
| IT938868B (it) | 1973-02-10 |
| ZA716501B (en) | 1972-10-25 |
| FR2109945A5 (OSRAM) | 1972-05-26 |
| GB1346999A (en) | 1974-02-13 |
| AU3409071A (en) | 1973-04-05 |
| ES395592A1 (es) | 1974-10-16 |
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