DE2133466A1 - Verfahren zur Herstellung von kristallinem Zinkborat mit geringem Hydratwassergehalt - Google Patents
Verfahren zur Herstellung von kristallinem Zinkborat mit geringem HydratwassergehaltInfo
- Publication number
- DE2133466A1 DE2133466A1 DE19712133466 DE2133466A DE2133466A1 DE 2133466 A1 DE2133466 A1 DE 2133466A1 DE 19712133466 DE19712133466 DE 19712133466 DE 2133466 A DE2133466 A DE 2133466A DE 2133466 A1 DE2133466 A1 DE 2133466A1
- Authority
- DE
- Germany
- Prior art keywords
- zinc
- product
- borate
- sodium
- zinc borate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 title claims description 31
- 238000000034 method Methods 0.000 title claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 27
- 230000036571 hydration Effects 0.000 title description 9
- 238000006703 hydration reaction Methods 0.000 title description 9
- 238000004519 manufacturing process Methods 0.000 title description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 38
- 239000011787 zinc oxide Substances 0.000 claims description 19
- 150000003751 zinc Chemical class 0.000 claims description 13
- 239000011541 reaction mixture Substances 0.000 claims description 12
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 12
- 229910021538 borax Inorganic materials 0.000 claims description 11
- 239000004328 sodium tetraborate Substances 0.000 claims description 10
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims description 7
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 6
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical group [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 4
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 claims description 4
- 235000005074 zinc chloride Nutrition 0.000 claims description 4
- 239000011592 zinc chloride Substances 0.000 claims description 4
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 229940102001 zinc bromide Drugs 0.000 claims description 2
- 229960001939 zinc chloride Drugs 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- RBUOVFCQLHVYOQ-UHFFFAOYSA-J dizinc disulfate Chemical compound [Zn+2].[Zn+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RBUOVFCQLHVYOQ-UHFFFAOYSA-J 0.000 claims 1
- 230000001376 precipitating effect Effects 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims 1
- 239000000047 product Substances 0.000 description 43
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000002441 X-ray diffraction Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 9
- 229960001763 zinc sulfate Drugs 0.000 description 9
- 229910000368 zinc sulfate Inorganic materials 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 238000002425 crystallisation Methods 0.000 description 6
- 230000008025 crystallization Effects 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 239000012736 aqueous medium Substances 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 4
- STNGULMWFPMOCE-UHFFFAOYSA-N ethyl 4-butyl-3,5-dimethyl-1h-pyrrole-2-carboxylate Chemical compound CCCCC1=C(C)NC(C(=O)OCC)=C1C STNGULMWFPMOCE-UHFFFAOYSA-N 0.000 description 4
- GJTUOBWRJOLPGS-UHFFFAOYSA-N 2-(4-pentylbenzoyl)-1-benzofuran-5-carbaldehyde Chemical compound C1=CC(CCCCC)=CC=C1C(=O)C1=CC2=CC(C=O)=CC=C2O1 GJTUOBWRJOLPGS-UHFFFAOYSA-N 0.000 description 3
- 239000003570 air Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FZQSLXQPHPOTHG-UHFFFAOYSA-N [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 Chemical compound [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 FZQSLXQPHPOTHG-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- CDMADVZSLOHIFP-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 CDMADVZSLOHIFP-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/06—Boron halogen compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C01B35/12—Borates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10052670A | 1970-12-21 | 1970-12-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2133466A1 true DE2133466A1 (de) | 1972-06-22 |
Family
ID=22280213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712133466 Withdrawn DE2133466A1 (de) | 1970-12-21 | 1971-07-06 | Verfahren zur Herstellung von kristallinem Zinkborat mit geringem Hydratwassergehalt |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3649172A (https=) |
| JP (1) | JPS5327240B1 (https=) |
| BE (1) | BE769799R (https=) |
| CA (1) | CA956779A (https=) |
| DE (1) | DE2133466A1 (https=) |
| FR (1) | FR2119407A6 (https=) |
| GB (1) | GB1348900A (https=) |
| IT (1) | IT966515B (https=) |
| NL (1) | NL7113283A (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2706827A1 (de) * | 1976-02-20 | 1977-09-01 | Ici Ltd | Verstaerkte polyamidmasse |
| CN112441593A (zh) * | 2020-12-15 | 2021-03-05 | 山东海螺型材有限责任公司 | 表面疏水改性无水纳米硼酸锌的制备方法 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3860692A (en) * | 1972-03-27 | 1975-01-14 | United States Borax Chem | Sodium aluminum borate |
| US5342553A (en) * | 1991-11-22 | 1994-08-30 | U. S. Borax Inc. | Process of making zinc borate and fire-retarding compositions thereof |
| US6077984A (en) * | 1998-09-01 | 2000-06-20 | Phillips Petroleum Company | Process for making zeolite containing zinc borate composition, the composition and the use thereof in hydrocarbon conversion |
| DE69913343D1 (de) | 1999-09-22 | 2004-01-15 | Gebroeders Cappelle N V | Hitzebeständiges Bismuthvanadat-Pigment und Verfahren zu seiner Herstellung |
| JP4669098B2 (ja) * | 2000-01-11 | 2011-04-13 | 水澤化学工業株式会社 | ホウ酸亜鉛、その製法及び用途 |
| CN102417189B (zh) * | 2011-08-24 | 2013-04-24 | 中国科学院青海盐湖研究所 | 柱状硼酸锌的合成方法 |
| CN105504346B (zh) * | 2015-12-16 | 2017-11-14 | 安徽壹石通材料科技股份有限公司 | 一种硼酸锌阻燃材料的制备方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2405366A (en) * | 1943-10-12 | 1946-08-06 | New Jersey Zinc Co | Manufacture of zinc borate |
| US3126352A (en) * | 1958-12-31 | 1964-03-24 | Certificate of correction |
-
1970
- 1970-12-21 US US100526A patent/US3649172A/en not_active Expired - Lifetime
-
1971
- 1971-02-05 JP JP465471A patent/JPS5327240B1/ja active Pending
- 1971-07-06 DE DE19712133466 patent/DE2133466A1/de not_active Withdrawn
- 1971-07-09 BE BE769799A patent/BE769799R/xx active
- 1971-09-15 CA CA122,959A patent/CA956779A/en not_active Expired
- 1971-09-28 NL NL7113283A patent/NL7113283A/xx unknown
- 1971-11-12 IT IT31017/71A patent/IT966515B/it active
- 1971-12-08 GB GB5702971A patent/GB1348900A/en not_active Expired
- 1971-12-14 FR FR7144801A patent/FR2119407A6/fr not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2706827A1 (de) * | 1976-02-20 | 1977-09-01 | Ici Ltd | Verstaerkte polyamidmasse |
| DE2706827C2 (de) | 1976-02-20 | 1987-03-19 | Imperial Chemical Industries Ltd., London | Verstärkte Polyamidmasse |
| CN112441593A (zh) * | 2020-12-15 | 2021-03-05 | 山东海螺型材有限责任公司 | 表面疏水改性无水纳米硼酸锌的制备方法 |
| CN112441593B (zh) * | 2020-12-15 | 2022-07-12 | 山东海螺型材有限责任公司 | 表面疏水改性无水纳米硼酸锌的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| IT966515B (it) | 1974-02-20 |
| US3649172A (en) | 1972-03-14 |
| FR2119407A6 (https=) | 1972-08-04 |
| GB1348900A (en) | 1974-03-27 |
| BE769799R (fr) | 1972-01-10 |
| NL7113283A (https=) | 1972-06-23 |
| CA956779A (en) | 1974-10-29 |
| JPS5327240B1 (https=) | 1978-08-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| 8130 | Withdrawal |