DE19852219C1 - Wäßrige Lösung zur elektrolytischen Abscheidung von Zinn-Zink-Legierungen und Verwendung der Lösung - Google Patents
Wäßrige Lösung zur elektrolytischen Abscheidung von Zinn-Zink-Legierungen und Verwendung der LösungInfo
- Publication number
- DE19852219C1 DE19852219C1 DE19852219A DE19852219A DE19852219C1 DE 19852219 C1 DE19852219 C1 DE 19852219C1 DE 19852219 A DE19852219 A DE 19852219A DE 19852219 A DE19852219 A DE 19852219A DE 19852219 C1 DE19852219 C1 DE 19852219C1
- Authority
- DE
- Germany
- Prior art keywords
- solution according
- alkyl
- tin
- carboxylic acids
- ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000243 solution Substances 0.000 title claims abstract description 20
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical group [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229910001297 Zn alloy Inorganic materials 0.000 title claims abstract description 12
- 239000007864 aqueous solution Substances 0.000 title claims abstract description 12
- 230000008021 deposition Effects 0.000 title claims description 15
- -1 Zn(II) ions Chemical class 0.000 claims abstract description 17
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 6
- 150000003934 aromatic aldehydes Chemical class 0.000 claims abstract description 6
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims abstract description 5
- 150000008365 aromatic ketones Chemical class 0.000 claims abstract description 5
- 150000003839 salts Chemical class 0.000 claims abstract description 4
- 150000002500 ions Chemical class 0.000 claims abstract 2
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 150000001447 alkali salts Chemical class 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 125000001624 naphthyl group Chemical group 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 102220047090 rs6152 Human genes 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 150000003841 chloride salts Chemical class 0.000 claims 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract description 6
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- 159000000011 group IA salts Chemical class 0.000 abstract 2
- 238000009713 electroplating Methods 0.000 description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 3
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- FPYUJUBAXZAQNL-UHFFFAOYSA-N 2-chlorobenzaldehyde Chemical compound ClC1=CC=CC=C1C=O FPYUJUBAXZAQNL-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- OMBBWWNNSCAQJY-UHFFFAOYSA-N zinc tin(2+) Chemical compound [Zn++][Sn++] OMBBWWNNSCAQJY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/60—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of tin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19852219A DE19852219C1 (de) | 1998-11-12 | 1998-11-12 | Wäßrige Lösung zur elektrolytischen Abscheidung von Zinn-Zink-Legierungen und Verwendung der Lösung |
| KR1020017005925A KR20010086017A (ko) | 1998-11-12 | 1999-11-12 | 주석-아연 합금의 전기도금용 수용액 |
| AT99960973T ATE223979T1 (de) | 1998-11-12 | 1999-11-12 | Wässrige lösung zur elektrolytischen abscheidung von zinn-zink-legierungen |
| CZ20011633A CZ296310B6 (cs) | 1998-11-12 | 1999-11-12 | Vodný roztok pro elektrolytické pokovování slitinami cínu a zinku |
| PCT/EP1999/008724 WO2000029645A2 (de) | 1998-11-12 | 1999-11-12 | Wässrige lösung zur elektrolytischen abscheidung von zinn-zink-legierungen |
| AU17752/00A AU1775200A (en) | 1998-11-12 | 1999-11-12 | Aqueous solution for electrodepositing tin-zinc alloys |
| PL99348755A PL194304B1 (pl) | 1998-11-12 | 1999-11-12 | Roztwór wodny do elektrolitycznego strącania stopów cyna-cynk i zastosowanie tego roztworu |
| DE59902696T DE59902696D1 (de) | 1998-11-12 | 1999-11-12 | Wässrige lösung zur elektrolytischen abscheidung von zinn-zink-legierungen |
| EP99960973A EP1137825B1 (de) | 1998-11-12 | 1999-11-12 | Wässrige lösung zur elektrolytischen abscheidung von zinn-zink-legierungen |
| JP2000582620A JP4355987B2 (ja) | 1998-11-12 | 1999-11-12 | スズ−亜鉛合金を電着するための水溶液 |
| CNB998097950A CN1195904C (zh) | 1998-11-12 | 1999-11-12 | 电镀锡-锌合金的水溶液及其在沉积锡-锌涂层中的应用 |
| US09/854,131 US6770185B2 (en) | 1998-11-12 | 2001-05-11 | Aqueous solution for electrodepositing tin-zinc alloys |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19852219A DE19852219C1 (de) | 1998-11-12 | 1998-11-12 | Wäßrige Lösung zur elektrolytischen Abscheidung von Zinn-Zink-Legierungen und Verwendung der Lösung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19852219C1 true DE19852219C1 (de) | 2000-05-11 |
Family
ID=7887579
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19852219A Expired - Fee Related DE19852219C1 (de) | 1998-11-12 | 1998-11-12 | Wäßrige Lösung zur elektrolytischen Abscheidung von Zinn-Zink-Legierungen und Verwendung der Lösung |
| DE59902696T Expired - Lifetime DE59902696D1 (de) | 1998-11-12 | 1999-11-12 | Wässrige lösung zur elektrolytischen abscheidung von zinn-zink-legierungen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59902696T Expired - Lifetime DE59902696D1 (de) | 1998-11-12 | 1999-11-12 | Wässrige lösung zur elektrolytischen abscheidung von zinn-zink-legierungen |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6770185B2 (https=) |
| EP (1) | EP1137825B1 (https=) |
| JP (1) | JP4355987B2 (https=) |
| KR (1) | KR20010086017A (https=) |
| CN (1) | CN1195904C (https=) |
| AT (1) | ATE223979T1 (https=) |
| AU (1) | AU1775200A (https=) |
| CZ (1) | CZ296310B6 (https=) |
| DE (2) | DE19852219C1 (https=) |
| PL (1) | PL194304B1 (https=) |
| WO (1) | WO2000029645A2 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002024979A1 (de) * | 2000-09-20 | 2002-03-28 | Dr.-Ing. Max Schlötter Gmbh & Co. Kg | Elektrolyt und verfahren zur abscheidung von zinn-kupfer-legierungsschichten |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101809200A (zh) * | 2007-09-27 | 2010-08-18 | 日本油漆株式会社 | 表面处理金属材料和金属涂装物的制造方法 |
| CN102443827A (zh) * | 2011-12-19 | 2012-05-09 | 张家港舒马克电梯安装维修服务有限公司镀锌分公司 | 一种Sn-Zn合金电镀液 |
| CN102634827B (zh) * | 2012-05-07 | 2015-04-08 | 东莞市闻誉实业有限公司 | 一种锡-锌合金电镀方法 |
| CN106498453B (zh) * | 2016-09-14 | 2018-08-28 | 湖北大学 | 一种镀锡、锡合金的光亮剂及其制备方法和应用 |
| JP2021116473A (ja) * | 2020-01-27 | 2021-08-10 | 三菱マテリアル株式会社 | 錫又は錫合金電解めっき液、バンプの形成方法、及び回路基板の製造方法 |
| US20230038219A1 (en) * | 2020-01-27 | 2023-02-09 | Mitsubishi Materials Corporation | Tin or tin alloy electroplating solution, method for forming bumps, and method for producing circuit board |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5378346A (en) * | 1990-08-31 | 1995-01-03 | Ashiru; Oluwatoyin A. | Electroplating |
| EP0663460A1 (en) * | 1992-09-25 | 1995-07-19 | Dipsol Chemical Co., Ltd | Tin-zinc alloy electroplating bath and method for electroplating using the same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE415577B (sv) * | 1977-09-15 | 1980-10-13 | Magnusson H H Produkter | Sett och elektrolyt for att fobereda en stalyta for lackering |
| GB2013241B (en) * | 1977-11-16 | 1982-03-24 | Dipsol Chem | Electroplating bath for depositing tin or tin alloy with brightness |
| DE4034304A1 (de) * | 1990-10-29 | 1992-04-30 | Henkel Kgaa | Elektrolytzusatzmittel fuer ein faerbebad zur aluminiumeinfaerbung und verfahren zur einfaerbung von aluminium |
| GB2266894A (en) * | 1992-05-15 | 1993-11-17 | Zinex Corp | Modified tin brightener for tin-zinc alloy electroplating bath |
| DE4446329A1 (de) * | 1994-12-23 | 1996-06-27 | Basf Ag | Salze aromatischer Hydroxylverbindungen und deren Verwendung als Glanzbildner |
| JP3609565B2 (ja) * | 1996-12-09 | 2005-01-12 | 株式会社大和化成研究所 | 錫−亜鉛合金めっき浴 |
| JP3816241B2 (ja) * | 1998-07-14 | 2006-08-30 | 株式会社大和化成研究所 | 金属を還元析出させるための水溶液 |
-
1998
- 1998-11-12 DE DE19852219A patent/DE19852219C1/de not_active Expired - Fee Related
-
1999
- 1999-11-12 JP JP2000582620A patent/JP4355987B2/ja not_active Expired - Fee Related
- 1999-11-12 EP EP99960973A patent/EP1137825B1/de not_active Expired - Lifetime
- 1999-11-12 PL PL99348755A patent/PL194304B1/pl not_active IP Right Cessation
- 1999-11-12 CN CNB998097950A patent/CN1195904C/zh not_active Expired - Fee Related
- 1999-11-12 AU AU17752/00A patent/AU1775200A/en not_active Abandoned
- 1999-11-12 WO PCT/EP1999/008724 patent/WO2000029645A2/de not_active Ceased
- 1999-11-12 CZ CZ20011633A patent/CZ296310B6/cs not_active IP Right Cessation
- 1999-11-12 DE DE59902696T patent/DE59902696D1/de not_active Expired - Lifetime
- 1999-11-12 KR KR1020017005925A patent/KR20010086017A/ko not_active Withdrawn
- 1999-11-12 AT AT99960973T patent/ATE223979T1/de not_active IP Right Cessation
-
2001
- 2001-05-11 US US09/854,131 patent/US6770185B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5378346A (en) * | 1990-08-31 | 1995-01-03 | Ashiru; Oluwatoyin A. | Electroplating |
| EP0663460A1 (en) * | 1992-09-25 | 1995-07-19 | Dipsol Chemical Co., Ltd | Tin-zinc alloy electroplating bath and method for electroplating using the same |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002024979A1 (de) * | 2000-09-20 | 2002-03-28 | Dr.-Ing. Max Schlötter Gmbh & Co. Kg | Elektrolyt und verfahren zur abscheidung von zinn-kupfer-legierungsschichten |
| US7179362B2 (en) | 2000-09-20 | 2007-02-20 | Dr.-Ing. Max Schlotter Gmbh & Co.Kg | Electrolyte and method for depositing tin-copper alloy layers |
Also Published As
| Publication number | Publication date |
|---|---|
| CZ20011633A3 (cs) | 2001-12-12 |
| PL194304B1 (pl) | 2007-05-31 |
| CN1195904C (zh) | 2005-04-06 |
| PL348755A1 (en) | 2002-06-03 |
| WO2000029645A2 (de) | 2000-05-25 |
| KR20010086017A (ko) | 2001-09-07 |
| DE59902696D1 (de) | 2002-10-17 |
| JP4355987B2 (ja) | 2009-11-04 |
| CN1321205A (zh) | 2001-11-07 |
| EP1137825B1 (de) | 2002-09-11 |
| ATE223979T1 (de) | 2002-09-15 |
| US20020046954A1 (en) | 2002-04-25 |
| CZ296310B6 (cs) | 2006-02-15 |
| EP1137825A2 (de) | 2001-10-04 |
| JP2002530528A (ja) | 2002-09-17 |
| US6770185B2 (en) | 2004-08-03 |
| WO2000029645A3 (de) | 2000-09-14 |
| AU1775200A (en) | 2000-06-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8100 | Publication of patent without earlier publication of application | ||
| D1 | Grant (no unexamined application published) patent law 81 | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |