DE19733017A1 - Chemische Verbindung - Google Patents

Chemische Verbindung

Info

Publication number
DE19733017A1
DE19733017A1 DE19733017A DE19733017A DE19733017A1 DE 19733017 A1 DE19733017 A1 DE 19733017A1 DE 19733017 A DE19733017 A DE 19733017A DE 19733017 A DE19733017 A DE 19733017A DE 19733017 A1 DE19733017 A1 DE 19733017A1
Authority
DE
Germany
Prior art keywords
group
alkyl
aryl
alkylaryl
hydrogen atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19733017A
Other languages
German (de)
English (en)
Inventor
Hans Bohnen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to DE19733017A priority Critical patent/DE19733017A1/de
Priority to CNB988077671A priority patent/CN100369921C/zh
Priority to DE59807400T priority patent/DE59807400D1/de
Priority to CNA2007101103429A priority patent/CN101092424A/zh
Priority to JP2000505172A priority patent/JP4334136B2/ja
Priority to AT98942608T priority patent/ATE233771T1/de
Priority to KR1020007001021A priority patent/KR20010022437A/ko
Priority to EP98942608A priority patent/EP1003753B1/de
Priority to US09/463,436 priority patent/US6417302B1/en
Priority to PCT/EP1998/004628 priority patent/WO1999006414A1/de
Priority to BRPI9810857-3A priority patent/BR9810857B1/pt
Priority to ES98942608T priority patent/ES2194346T3/es
Priority to ZA9806801A priority patent/ZA986801B/xx
Publication of DE19733017A1 publication Critical patent/DE19733017A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/062—Al linked exclusively to C
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
DE19733017A 1997-07-31 1997-07-31 Chemische Verbindung Withdrawn DE19733017A1 (de)

Priority Applications (13)

Application Number Priority Date Filing Date Title
DE19733017A DE19733017A1 (de) 1997-07-31 1997-07-31 Chemische Verbindung
CNB988077671A CN100369921C (zh) 1997-07-31 1998-07-23 含硼和铝的化合物
DE59807400T DE59807400D1 (de) 1997-07-31 1998-07-23 Bor und aluminium enthaltende verbindungen
CNA2007101103429A CN101092424A (zh) 1997-07-31 1998-07-23 含硼和铝的化合物
JP2000505172A JP4334136B2 (ja) 1997-07-31 1998-07-23 化合物
AT98942608T ATE233771T1 (de) 1997-07-31 1998-07-23 Bor und aluminium enthaltende verbindungen
KR1020007001021A KR20010022437A (ko) 1997-07-31 1998-07-23 붕소 및 알루미늄을 함유하는 화합물
EP98942608A EP1003753B1 (de) 1997-07-31 1998-07-23 Bor und aluminium enthaltende verbindungen
US09/463,436 US6417302B1 (en) 1997-07-31 1998-07-23 Compounds containing boron and aluminium
PCT/EP1998/004628 WO1999006414A1 (de) 1997-07-31 1998-07-23 Bor und aluminium enthaltende verbindungen
BRPI9810857-3A BR9810857B1 (pt) 1997-07-31 1998-07-23 composto quìmico, processos para a preparação do mesmo, para a preparação de um composto organoboro-alumìnio cocataliticamenteativo, e para a preparação de uma poliolefina na presença de um sistema catalisador, composto organoboro-alumìnio, sistema catalisador, e, uso do mesmo.
ES98942608T ES2194346T3 (es) 1997-07-31 1998-07-23 Compuestos que contienen boro y aluminio.
ZA9806801A ZA986801B (en) 1997-07-31 1998-07-30 Chemical compound.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19733017A DE19733017A1 (de) 1997-07-31 1997-07-31 Chemische Verbindung

Publications (1)

Publication Number Publication Date
DE19733017A1 true DE19733017A1 (de) 1999-02-04

Family

ID=7837499

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19733017A Withdrawn DE19733017A1 (de) 1997-07-31 1997-07-31 Chemische Verbindung
DE59807400T Expired - Lifetime DE59807400D1 (de) 1997-07-31 1998-07-23 Bor und aluminium enthaltende verbindungen

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE59807400T Expired - Lifetime DE59807400D1 (de) 1997-07-31 1998-07-23 Bor und aluminium enthaltende verbindungen

Country Status (11)

Country Link
US (1) US6417302B1 (https=)
EP (1) EP1003753B1 (https=)
JP (1) JP4334136B2 (https=)
KR (1) KR20010022437A (https=)
CN (2) CN100369921C (https=)
AT (1) ATE233771T1 (https=)
BR (1) BR9810857B1 (https=)
DE (2) DE19733017A1 (https=)
ES (1) ES2194346T3 (https=)
WO (1) WO1999006414A1 (https=)
ZA (1) ZA986801B (https=)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999040129A1 (de) * 1998-02-07 1999-08-12 Targor Gmbh Katalysatorsystem
WO1999061487A1 (de) * 1998-05-23 1999-12-02 Targor Gmbh Katalysatorsystem und seine verwendung zur polymerisation von propylen
WO2000017208A1 (de) * 1998-09-19 2000-03-30 Basell Polyolefine Gmbh Verfahren zur herstellung von mono- oder di-organo-boranen
WO2000018773A1 (de) * 1998-09-26 2000-04-06 Targor Gmbh Chemische verbindung
WO2000020466A1 (de) * 1998-10-01 2000-04-13 Targor Gmbh Katalysatorsystem

Families Citing this family (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19917985A1 (de) * 1999-04-21 2000-10-26 Targor Gmbh Katalysatorsystem
DE19962129A1 (de) 1999-12-21 2001-06-28 Targor Gmbh Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
CN1222550C (zh) 1999-12-21 2005-10-12 巴塞尔聚烯烃有限公司 用于制备双轴拉伸聚丙烯膜的半结晶丙烯聚合物组合物
BRPI0016723B1 (pt) 1999-12-23 2018-02-27 Basell Polyolefine Gmbh. Metaloceno, sistema catalisador, e, processo para a copolimerização de propileno com etileno
DE10028432A1 (de) 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
US6495484B1 (en) 2000-08-28 2002-12-17 Univation Technologies, Llc Catalyst system and its use in a polymerization process
ATE412016T1 (de) * 2001-09-14 2008-11-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von olefinen
DE10145453A1 (de) * 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
DE10158656A1 (de) 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE10163154A1 (de) * 2001-12-20 2003-07-03 Basell Polyolefine Gmbh Pyrogene Kieselsäuren enthaltender Katalysatorfeststoff zur Olefinpolymerisation
US20050182266A1 (en) * 2002-06-12 2005-08-18 Schulte Jorg L. Transition metal componds their preparation and their use in catalyst systems for the polymerization and copolymerization of olefins
AU2003245926B2 (en) * 2002-06-12 2007-11-29 Basell Polyolefine Gmbh Propylene copolymer compositions having a good low-temperature impact toughness and a high transparency
BR0311862B1 (pt) 2002-06-12 2013-08-06 composição copolimérica de propileno, processo para preparar composições copoliméricas de propileno, uso da composição copolimérica de propileno,fibras, filmes, ou artigos moldados.
AU2003257456A1 (en) 2002-07-15 2004-02-02 Basell Polyolefine Gmbh Preparation of supported catalyst systems
US20060089253A1 (en) * 2002-08-13 2006-04-27 Shahram Mihan Monocyclopentadienyl complexes
JP2005536566A (ja) 2002-08-22 2005-12-02 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノシクロペンタジエニル錯体
US7414005B2 (en) 2002-11-04 2008-08-19 Basell Polyolefine Gmbh Preparation of catalyst compositions having improved activity
JP2006512410A (ja) * 2002-12-06 2006-04-13 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 有機金属遷移金属化合物、ビスシクロペンタジエニル配位子を有する化合物、触媒組成物、及びこれらを用いたポリオレフィンの製造法
ATE503776T1 (de) * 2002-12-20 2011-04-15 Basell Polyolefine Gmbh Copolymere mit alpha-olefinen
JP2006511607A (ja) 2002-12-20 2006-04-06 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノシクロペンタジエニル錯体
EP1590377B1 (en) 2003-02-07 2007-06-13 Basell Polyolefine GmbH Polymerization catalysts, organic transition metal compounds, process for preparing polyolefins
JP2006522189A (ja) 2003-04-03 2006-09-28 バーゼル・ポリオレフィン・ゲーエムベーハー 気相流動床反応器内における有機遷移金属化合物存在下での高分子量ポリオレフィンの製造
US7507782B2 (en) 2003-05-21 2009-03-24 Basell Polyolefine Gmbh Transition-metal complexes with tridentate, nitrogen-containing ligands
ATE423784T1 (de) * 2003-05-28 2009-03-15 Basell Polyolefine Gmbh Bisindenyl-zirconium-komplexe zur olefinpolymerisation
JP2007506820A (ja) 2003-09-25 2007-03-22 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 重合触媒、ポリオレフィンの製造方法、有機遷移金属化合物及びリガンド
DE10352139A1 (de) 2003-11-04 2005-06-09 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem und Verfahren zur Herstellung von Polyolefinen
DE10358082A1 (de) * 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
US7544826B2 (en) * 2003-12-16 2009-06-09 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
WO2005058983A2 (en) 2003-12-19 2005-06-30 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
DE102004009426A1 (de) * 2004-02-24 2005-09-08 Cognis Deutschland Gmbh & Co. Kg Konditionierende Reinigungszubereitung auf Basis von Silikonen und bestimmten Wachsen
CN100558807C (zh) * 2004-03-24 2009-11-11 巴塞尔聚烯烃股份有限公司 具有高透明度的柔性丙烯共聚物组合物
US7285608B2 (en) 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
DE102004027332A1 (de) 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE102004032581A1 (de) * 2004-07-05 2006-02-09 Basell Polyolefine Gmbh Polymerisationskatalysatoren, Hauptgruppenkoordinationsverbindungen, Verfahren zur Herstellung von Polyolefinen und Polyolefine
DE102004039877A1 (de) 2004-08-17 2006-02-23 Basell Polyolefine Gmbh Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
DE102004061618A1 (de) * 2004-12-17 2006-06-22 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
DE102005014395A1 (de) 2005-03-24 2006-09-28 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
KR100698308B1 (ko) * 2005-04-06 2007-03-22 엘지전자 주식회사 식기세척기
US7985300B2 (en) 2005-04-04 2011-07-26 Lg Electronics Inc. Dishwasher and assembly method thereof
WO2006111448A1 (en) * 2005-04-21 2006-10-26 Basell Poliolefine Italia S.R.L. Biaxially oriented propylene polymer films
DE102005019395A1 (de) * 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators
DE102005019393A1 (de) 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Polyethylenformmassen für Spritzgussanwendungen
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
US20090227748A1 (en) * 2005-09-06 2009-09-10 Basell Polyolefine Gmbh Process for Preparing Olff in Polymers in the Presence of Catalyst Systems Having Photochromic Groups
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
DE102005056775A1 (de) * 2005-11-28 2007-05-31 Basell Polyolefine Gmbh Verfahren für den Katalysatorwechsel in einem Gasphasenwirbelschichtreaktor
DE102005057559A1 (de) * 2005-11-30 2007-05-31 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
EP1847555A1 (en) * 2006-04-18 2007-10-24 Borealis Technology Oy Multi-branched Polypropylene
WO2008076632A2 (en) * 2006-12-14 2008-06-26 Albemarle Corporation Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
CN101652178B (zh) 2007-03-06 2014-08-27 巴塞尔聚烯烃股份有限公司 铁络合物及其在聚合方法中的用途
DE102007017903A1 (de) * 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
US20100093953A1 (en) * 2007-05-04 2010-04-15 Basell Polyolefine Gmbh Polyethylene, process and catalyst composition for the preparation thereof
BRPI0722162A2 (pt) * 2007-10-25 2014-03-18 Lummus Novolen Technology Gmbh Compostos de metaloceno, catalisadores compreendendo os mesmos, processo para produzir um polímero de olefina pelo uso de catalisadores, e homo-e copolímeros de olefina.
WO2009054833A2 (en) 2007-10-25 2009-04-30 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
ATE547439T1 (de) 2007-10-25 2012-03-15 Lummus Novolen Technology Gmbh Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere
US8207281B2 (en) * 2007-12-18 2012-06-26 Basell Polyolefine Gmbh Process for preparing transition metal compounds for olefins polymerization
US8247587B2 (en) 2007-12-19 2012-08-21 Basell Polyolefine Gmbh Mono-hydroindacenyl complexes
BRPI0821085A2 (pt) 2007-12-19 2015-06-16 Basell Polyolefine Gmbh Terpolímeros de etileno
EP2222722B1 (en) * 2007-12-21 2011-11-30 Basell Polyolefine GmbH Phenantroline-comprising complexes
FR2926816B1 (fr) * 2008-01-25 2010-05-14 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
WO2009103516A2 (en) * 2008-02-18 2009-08-27 Basell Polyolefine Gmbh Adhesive polymer composition
JP5346088B2 (ja) 2008-09-25 2013-11-20 バーゼル・ポリオレフィン・ゲーエムベーハー 耐衝撃性ｌｌｄｐｅ組成物及びそれから製造されるフィルム
US8957158B2 (en) 2008-09-25 2015-02-17 Basell Polyolefine Gmbh Impact resistant LLDPE composition and films made thereof
US8435911B2 (en) 2008-10-16 2013-05-07 Basell Polyolefine Gmbh Hybrid catalyst composition for polymerization of olefins
EP2367854B1 (en) 2008-12-17 2012-11-28 Basell Polyolefine GmbH Catalyst system for olefin polymerization, its production and use
CN102471400B (zh) 2009-07-27 2013-12-11 巴塞尔聚烯烃股份有限公司 有机金属过渡金属化合物、催化剂体系以及聚烯烃的制备
WO2011147573A2 (en) 2010-05-28 2011-12-01 Basell Polyolefine Gmbh Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use
WO2011160828A1 (en) 2010-06-25 2011-12-29 Basell Polyolefine Gmbh Process for the production of high-strength polyolefin compositions and polyolefin compositions produced by this process
KR101702701B1 (ko) 2010-12-21 2017-02-06 바젤 폴리올레핀 게엠베하 높은 탄성 및 투명도를 갖는 폴리프로필렌 조성물

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999040129A1 (de) * 1998-02-07 1999-08-12 Targor Gmbh Katalysatorsystem
WO1999061487A1 (de) * 1998-05-23 1999-12-02 Targor Gmbh Katalysatorsystem und seine verwendung zur polymerisation von propylen
US6576723B1 (en) 1998-05-23 2003-06-10 Basell Polyolefine Gmbh Catalyst system and its use for the polymerization of propylene
WO2000017208A1 (de) * 1998-09-19 2000-03-30 Basell Polyolefine Gmbh Verfahren zur herstellung von mono- oder di-organo-boranen
WO2000018773A1 (de) * 1998-09-26 2000-04-06 Targor Gmbh Chemische verbindung
WO2000020466A1 (de) * 1998-10-01 2000-04-13 Targor Gmbh Katalysatorsystem

Also Published As

Publication number Publication date
CN101092424A (zh) 2007-12-26
DE59807400D1 (de) 2003-04-10
EP1003753A1 (de) 2000-05-31
ES2194346T3 (es) 2003-11-16
ZA986801B (en) 2000-01-31
KR20010022437A (ko) 2001-03-15
JP4334136B2 (ja) 2009-09-30
EP1003753B1 (de) 2003-03-05
CN100369921C (zh) 2008-02-20
JP2001512128A (ja) 2001-08-21
BR9810857A (pt) 2000-07-25
US6417302B1 (en) 2002-07-09
ATE233771T1 (de) 2003-03-15
BR9810857B1 (pt) 2010-06-01
CN1265663A (zh) 2000-09-06
WO1999006414A1 (de) 1999-02-11

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