DE1767006C3 - Kristallines Zinkborat mit geringem Hydratwassergehalt, Verfahren zu seiner Herstellung und seine Verwendung - Google Patents
Kristallines Zinkborat mit geringem Hydratwassergehalt, Verfahren zu seiner Herstellung und seine VerwendungInfo
- Publication number
- DE1767006C3 DE1767006C3 DE1767006A DE1767006A DE1767006C3 DE 1767006 C3 DE1767006 C3 DE 1767006C3 DE 1767006 A DE1767006 A DE 1767006A DE 1767006 A DE1767006 A DE 1767006A DE 1767006 C3 DE1767006 C3 DE 1767006C3
- Authority
- DE
- Germany
- Prior art keywords
- zinc
- zinc borate
- zno
- water
- boric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 title claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 13
- 230000036571 hydration Effects 0.000 title claims description 6
- 238000006703 hydration reaction Methods 0.000 title claims description 6
- 238000002360 preparation method Methods 0.000 title claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 58
- 239000011787 zinc oxide Substances 0.000 claims description 29
- 239000013078 crystal Substances 0.000 claims description 22
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 13
- 239000004327 boric acid Substances 0.000 claims description 13
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 9
- 229910021538 borax Inorganic materials 0.000 claims description 8
- 239000004328 sodium tetraborate Substances 0.000 claims description 8
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 8
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 8
- 239000011541 reaction mixture Substances 0.000 claims description 7
- 229960001763 zinc sulfate Drugs 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 150000003752 zinc compounds Chemical class 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011686 zinc sulphate Substances 0.000 claims description 2
- 235000009529 zinc sulphate Nutrition 0.000 claims description 2
- 239000000047 product Substances 0.000 description 33
- 239000000243 solution Substances 0.000 description 17
- 238000002425 crystallisation Methods 0.000 description 9
- 230000008025 crystallization Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000004800 polyvinyl chloride Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- WGKLIJDVPACLGG-UHFFFAOYSA-N trizinc diborate hydrate Chemical class O.[Zn++].[Zn++].[Zn++].[O-]B([O-])[O-].[O-]B([O-])[O-] WGKLIJDVPACLGG-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- 238000005684 Liebig rearrangement reaction Methods 0.000 description 1
- 229920001944 Plastisol Polymers 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- MGFRKBRDZIMZGO-UHFFFAOYSA-N barium cadmium Chemical compound [Cd].[Ba] MGFRKBRDZIMZGO-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007706 flame test Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004999 plastisol Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/06—Boron halogen compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C01B35/12—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64896867A | 1967-06-26 | 1967-06-26 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1767006A1 DE1767006A1 (de) | 1971-08-19 |
| DE1767006B2 DE1767006B2 (de) | 1981-07-23 |
| DE1767006C3 true DE1767006C3 (de) | 1982-04-29 |
Family
ID=24602960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1767006A Expired DE1767006C3 (de) | 1967-06-26 | 1968-03-20 | Kristallines Zinkborat mit geringem Hydratwassergehalt, Verfahren zu seiner Herstellung und seine Verwendung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3549316A (https=) |
| BE (1) | BE717110A (https=) |
| CA (1) | CA944928A (https=) |
| DE (1) | DE1767006C3 (https=) |
| FR (1) | FR1560173A (https=) |
| GB (1) | GB1184967A (https=) |
| NL (1) | NL155519B (https=) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3718615A (en) * | 1971-03-05 | 1973-02-27 | United States Borax Chem | Halogenated polymeric compositions containing zinc borate |
| US5342553A (en) * | 1991-11-22 | 1994-08-30 | U. S. Borax Inc. | Process of making zinc borate and fire-retarding compositions thereof |
| US6077984A (en) * | 1998-09-01 | 2000-06-20 | Phillips Petroleum Company | Process for making zeolite containing zinc borate composition, the composition and the use thereof in hydrocarbon conversion |
| JP4669098B2 (ja) * | 2000-01-11 | 2011-04-13 | 水澤化学工業株式会社 | ホウ酸亜鉛、その製法及び用途 |
| JP4610110B2 (ja) * | 2001-03-15 | 2011-01-12 | 水澤化学工業株式会社 | ホウ酸亜鉛及びその用途 |
| US20050039781A1 (en) * | 2002-11-01 | 2005-02-24 | The Procter & Gamble Company | Dispensing device for liquid detergent compositions |
| US20040180807A1 (en) * | 2002-12-30 | 2004-09-16 | The Procter & Gamble Company | Rinse aid composition containing water-soluble metal salt for use in automatic dishwashing for metal corrosion and rust formation protection |
| US6992052B2 (en) * | 2002-12-30 | 2006-01-31 | The Procter & Gamble Company | Process of preparing in-situ water-soluble zinc salt for use in automatic dishwashing compositions |
| US20040176264A1 (en) * | 2002-12-30 | 2004-09-09 | The Procter & Gamble Company | Rinse aid composition containing water-soluble metal salt for use in automatic dishwashing for glassware corrosion protection |
| CN1321060C (zh) * | 2004-09-30 | 2007-06-13 | 武汉大学 | 硼酸锌的制备方法 |
| US20100249292A1 (en) * | 2009-03-30 | 2010-09-30 | E. I. Du Pont De Nemours And Company | Flame resistant semicaromatic polyamide resin composition and articles therefrom |
| CN102633277A (zh) * | 2012-05-02 | 2012-08-15 | 天津大学 | 一种协效阻燃剂纳米硼酸锌的制备方法 |
| CN103964455B (zh) * | 2014-05-30 | 2016-01-20 | 山东川君化工股份有限公司 | 3.5水硼酸锌的制备方法 |
| CN105504346B (zh) * | 2015-12-16 | 2017-11-14 | 安徽壹石通材料科技股份有限公司 | 一种硼酸锌阻燃材料的制备方法 |
| WO2020106250A1 (en) * | 2018-09-25 | 2020-05-28 | Akdeniz Kimya Sanayi Ve Ticaret A.S. | A process for synthesis of zinc borate |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR695274A (fr) * | 1930-05-07 | 1930-12-13 | Procédé de traitement des minerais de borax | |
| US2405366A (en) * | 1943-10-12 | 1946-08-06 | New Jersey Zinc Co | Manufacture of zinc borate |
| US3126352A (en) * | 1958-12-31 | 1964-03-24 | Certificate of correction |
-
1967
- 1967-06-26 US US648968A patent/US3549316A/en not_active Expired - Lifetime
-
1968
- 1968-03-18 NL NL6803792.A patent/NL155519B/xx not_active IP Right Cessation
- 1968-03-20 DE DE1767006A patent/DE1767006C3/de not_active Expired
- 1968-04-23 FR FR1560173D patent/FR1560173A/fr not_active Expired
- 1968-06-25 BE BE717110D patent/BE717110A/xx not_active IP Right Cessation
- 1968-06-26 GB GB30460/68A patent/GB1184967A/en not_active Expired
-
1973
- 1973-08-22 CA CA179,404A patent/CA944928A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL155519B (nl) | 1978-01-16 |
| US3549316A (en) | 1970-12-22 |
| CA944928A (en) | 1974-04-09 |
| DE1767006B2 (de) | 1981-07-23 |
| GB1184967A (en) | 1970-03-18 |
| FR1560173A (https=) | 1969-03-14 |
| BE717110A (https=) | 1968-12-27 |
| DE1767006A1 (de) | 1971-08-19 |
| NL6803792A (https=) | 1968-12-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: REDIES, B., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 4000 DUESSELDORF |