DE1745220C3 - Verfahren zum Polymerisieren oder Mischpolymerisieren von Vinylchlorid in wässriger Phase in Suspension oder feiner Suspension - Google Patents
Verfahren zum Polymerisieren oder Mischpolymerisieren von Vinylchlorid in wässriger Phase in Suspension oder feiner SuspensionInfo
- Publication number
- DE1745220C3 DE1745220C3 DE1967P0041235 DEP0041235A DE1745220C3 DE 1745220 C3 DE1745220 C3 DE 1745220C3 DE 1967P0041235 DE1967P0041235 DE 1967P0041235 DE P0041235 A DEP0041235 A DE P0041235A DE 1745220 C3 DE1745220 C3 DE 1745220C3
- Authority
- DE
- Germany
- Prior art keywords
- suspension
- vinyl chloride
- polymerization
- weight
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000725 suspension Substances 0.000 title claims description 115
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 110
- 238000000034 method Methods 0.000 title claims description 16
- 230000008569 process Effects 0.000 title claims description 6
- 230000000379 polymerizing effect Effects 0.000 title claims 4
- 239000008346 aqueous phase Substances 0.000 title claims 2
- 238000006116 polymerization reaction Methods 0.000 claims description 60
- 239000000178 monomer Substances 0.000 claims description 54
- 239000003054 catalyst Substances 0.000 claims description 53
- 239000002245 particle Substances 0.000 claims description 46
- 229920000642 polymer Polymers 0.000 claims description 46
- 239000000203 mixture Substances 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 35
- 238000006243 chemical reaction Methods 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 206010039509 Scab Diseases 0.000 claims description 13
- 238000002474 experimental method Methods 0.000 claims description 13
- 239000006185 dispersion Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 8
- 230000000052 comparative effect Effects 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 239000000084 colloidal system Substances 0.000 claims description 5
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- 230000035784 germination Effects 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 241000270730 Alligator mississippiensis Species 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 206010052428 Wound Diseases 0.000 claims 1
- 208000027418 Wounds and injury Diseases 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- 238000009776 industrial production Methods 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- 150000001451 organic peroxides Chemical class 0.000 claims 1
- 238000009304 pastoral farming Methods 0.000 claims 1
- 239000012071 phase Substances 0.000 claims 1
- 230000000750 progressive effect Effects 0.000 claims 1
- 108090000623 proteins and genes Proteins 0.000 claims 1
- 239000012429 reaction media Substances 0.000 claims 1
- 230000008521 reorganization Effects 0.000 claims 1
- 230000000717 retained effect Effects 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 51
- 239000004800 polyvinyl chloride Substances 0.000 description 51
- 229920000126 latex Polymers 0.000 description 40
- 239000004816 latex Substances 0.000 description 39
- 238000002360 preparation method Methods 0.000 description 20
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 9
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 8
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 8
- 229920002554 vinyl polymer Polymers 0.000 description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000004815 dispersion polymer Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- -1 B. I.aurylpcroxyd Chemical class 0.000 description 2
- 229920001944 Plastisol Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 241000158147 Sator Species 0.000 description 1
- 208000003028 Stuttering Diseases 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- QGEOKXWFGANCJL-UHFFFAOYSA-N ethenyl acetate;hydrochloride Chemical compound Cl.CC(=O)OC=C QGEOKXWFGANCJL-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003102 growth factor Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229940099990 ogen Drugs 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000004999 plastisol Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR46461A FR1485547A (fr) | 1966-01-19 | 1966-01-19 | Procédé continu de polymérisation du chlorure de vinyle |
| FR85628A FR91709E (fr) | 1966-01-19 | 1966-11-30 | Procédé continu de polymérisation du chlorure de vinyle |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1745220A1 DE1745220A1 (de) | 1972-07-27 |
| DE1745220B2 DE1745220B2 (de) | 1975-06-26 |
| DE1745220C3 true DE1745220C3 (de) | 1980-05-08 |
Family
ID=26168066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1967P0041235 Expired DE1745220C3 (de) | 1966-01-19 | 1967-01-18 | Verfahren zum Polymerisieren oder Mischpolymerisieren von Vinylchlorid in wässriger Phase in Suspension oder feiner Suspension |
Country Status (13)
| Country | Link |
|---|---|
| AT (1) | AT277574B (enExample) |
| BE (1) | BE692903A (enExample) |
| CH (1) | CH488752A (enExample) |
| DE (1) | DE1745220C3 (enExample) |
| DK (1) | DK128499B (enExample) |
| ES (1) | ES335797A1 (enExample) |
| FI (1) | FI46074C (enExample) |
| FR (2) | FR1485547A (enExample) |
| GB (1) | GB1170963A (enExample) |
| LU (1) | LU52837A1 (enExample) |
| NL (1) | NL140533B (enExample) |
| NO (1) | NO124210B (enExample) |
| SE (1) | SE358402B (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2234321B1 (enExample) * | 1973-06-08 | 1976-06-11 | Rhone Progil | |
| HU173513B (hu) * | 1975-04-30 | 1979-05-28 | Rhone Poulenc Ind | Sposob polimerizacii vinilkhlorida v sshitojj mikrosuspensii |
| FR2587031B1 (fr) * | 1985-09-06 | 1987-12-11 | Atochem | Procede de preparation en microsuspension de latex d'homo- et copolymeres du chlorure de vinyle utilisables comme produits d'ensemencement |
| FR2596763B1 (fr) * | 1986-04-03 | 1988-06-03 | Atochem | Procede de preparation en microsuspension de latex d'homo- et copolymeres du chlorure de vinyle utilisables comme produits d'ensemencement |
| FR2607138B1 (fr) * | 1986-11-24 | 1990-05-04 | Atochem | Procede de preparation en microsuspension ensemencee d'homo- et copolymeres du chlorure de vinyle |
| DE69318322T3 (de) | 1992-02-13 | 2001-11-22 | European Vinyls Corp. Technology Ag, Zug | Polymerisationsverfahren |
-
1966
- 1966-01-19 FR FR46461A patent/FR1485547A/fr not_active Expired
- 1966-11-30 FR FR85628A patent/FR91709E/fr not_active Expired
-
1967
- 1967-01-13 FI FI9367A patent/FI46074C/fi active
- 1967-01-16 GB GB222467A patent/GB1170963A/en not_active Expired
- 1967-01-18 DE DE1967P0041235 patent/DE1745220C3/de not_active Expired
- 1967-01-18 NO NO16643767A patent/NO124210B/no unknown
- 1967-01-18 ES ES0335797A patent/ES335797A1/es not_active Expired
- 1967-01-18 DK DK29167A patent/DK128499B/da unknown
- 1967-01-18 LU LU52837D patent/LU52837A1/xx unknown
- 1967-01-18 CH CH73967A patent/CH488752A/fr not_active IP Right Cessation
- 1967-01-19 SE SE81667A patent/SE358402B/xx unknown
- 1967-01-19 BE BE692903D patent/BE692903A/xx not_active IP Right Cessation
- 1967-01-19 AT AT58467A patent/AT277574B/de not_active IP Right Cessation
- 1967-01-19 NL NL6700851A patent/NL140533B/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| FI46074C (fi) | 1972-12-11 |
| BE692903A (enExample) | 1967-07-19 |
| FI46074B (enExample) | 1972-08-31 |
| SE358402B (enExample) | 1973-07-30 |
| DE1745220B2 (de) | 1975-06-26 |
| DE1745220A1 (de) | 1972-07-27 |
| GB1170963A (en) | 1969-11-19 |
| AT277574B (de) | 1969-12-29 |
| NO124210B (enExample) | 1972-03-20 |
| DK128499B (da) | 1974-05-13 |
| NL140533B (nl) | 1973-12-17 |
| FR1485547A (fr) | 1967-06-23 |
| ES335797A1 (es) | 1967-12-01 |
| FR91709E (fr) | 1968-08-02 |
| NL6700851A (enExample) | 1967-07-20 |
| LU52837A1 (enExample) | 1967-07-18 |
| CH488752A (fr) | 1970-04-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2618761C2 (de) | Verfahren zum Polymerisieren oder Copolymerisieren von Vinylchlorid in Mikrosuspension | |
| DE2542283C2 (de) | Polymerisation von Vinylchlorid in Emulsion | |
| DE1520133B2 (de) | Verfahren zur herstellung von vinylchloridpolymerisaten | |
| DE2610021C3 (de) | Verfahren zur Herstellung von Vinylchloridpolymerisaten | |
| DE2461083C2 (enExample) | ||
| DE1745220C3 (de) | Verfahren zum Polymerisieren oder Mischpolymerisieren von Vinylchlorid in wässriger Phase in Suspension oder feiner Suspension | |
| DE1917090C3 (de) | Verfahren zur Herstellung von Styrolpolymerteilchen mit einheitlichen Größen | |
| DE3783930T2 (de) | Verfahren zur herstellung poroeser kugelfoermiger polyvinylchloridteilchen. | |
| DE2427385B2 (de) | Verfahren zur Herstellung von Vinylchloridhomo- oder -copolymeren | |
| EP0025561A1 (de) | Verfahren zur diskontinuierlichen Polymerisation von Vinylchlorid in Emulsion | |
| DE69702923T2 (de) | Verfahren zur Herstellung einer Initiatorzusammensetzung auf Basis von Polyvinylalkohol und Emulgator | |
| DE883351C (de) | Verfahren zur Herstellung perlfoermiger oder koerniger Polymerisationsprodukte | |
| DE2244279B2 (de) | Verfahren zur Polymerisation von Tetrafluoräthylen in wässriger Suspension und Verwendung des Verfahrensproduktes zum direkten Extrudieren und zum automatischen Beschicken der Pressformen | |
| DE1050062B (de) | Verfahren zur Herstellung von zur Plastisolbildung geeigneten Polyvinylchloridharzen | |
| DE1745283A1 (de) | Verfahren zur industriellen Herstellung von Polymerisationsprodukten von Zusammensetzungen auf der Grundlage von Vinylchlorid,die wenigstens teilweise durch Vinylchlorid gepfropfte Copolymere auf der Grundlage von Vinylacetat und AEthylen enthalten,und nach diesem Verfahren hergestellte Erzeugnisse | |
| DE3242088A1 (de) | Verfahren zur herstellung von verpastbaren polymeren des vinylchlorids | |
| DE2023971C3 (de) | Verfahren zur Polymerisation von Vinylchlorid und dessen Gemischen mit Verbindungen des Vinyltyps in Masse und so erhaltende Homo- bzw. Mischpolymerisate | |
| DE2220477C3 (de) | Verfahren zur Herstellung von Vinylchlorid-Polymerisaten | |
| DE1595421A1 (de) | Verfahren zur Herstellung von Emulsionen | |
| DE1495687A1 (de) | Polymerisationsverfahren fuer Vinylaromaten | |
| DE2839435A1 (de) | Zweistufiges verfahren zur herstellung von vinylchloridpolymerisaten oder -copolymerisaten mittels polymerisation in masse | |
| DE2629613A1 (de) | Verfahren zur herstellung von vinylchlorid-polymerisaten | |
| DE965445C (de) | Verfahren zur Herstellung von Polyvinylchlorid | |
| DE2640887A1 (de) | Verfahren zum herstellen von vinylchloridpolymeren | |
| DE1938911C (de) | Verfahren zur Herstellung eines Vinyl chloridpfropfpolymeren |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: CHLOE CHIMIE, 92800 PUTEAUX, FR |
|
| 8328 | Change in the person/name/address of the agent |
Free format text: WUESTHOFF, F., DR.-ING. FRHR. VON PECHMANN, E., DIPL.-CHEM. DR.RER.NAT. BEHRENS, D., DR.-ING. GOETZ, R., DIPL.-ING. DIPL.-WIRTSCH.-ING., PAT.-ANW., 8000 MUENCHEN |
|
| 8339 | Ceased/non-payment of the annual fee |