DE1617430C3 - Schäumende lagerstabile Zahnpaste - Google Patents
Schäumende lagerstabile ZahnpasteInfo
- Publication number
- DE1617430C3 DE1617430C3 DE1617430A DED0050712A DE1617430C3 DE 1617430 C3 DE1617430 C3 DE 1617430C3 DE 1617430 A DE1617430 A DE 1617430A DE D0050712 A DED0050712 A DE D0050712A DE 1617430 C3 DE1617430 C3 DE 1617430C3
- Authority
- DE
- Germany
- Prior art keywords
- weight
- paste
- percent
- acidic
- salts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000606 toothpaste Substances 0.000 title claims description 31
- 229940034610 toothpaste Drugs 0.000 title claims description 27
- 238000005187 foaming Methods 0.000 title claims description 6
- 239000006072 paste Substances 0.000 claims description 60
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 52
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 21
- 230000002378 acidificating effect Effects 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 19
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 16
- 150000008043 acidic salts Chemical class 0.000 claims description 16
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 13
- 239000001630 malic acid Substances 0.000 claims description 13
- 150000002978 peroxides Chemical class 0.000 claims description 13
- 235000011090 malic acid Nutrition 0.000 claims description 12
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 10
- 239000008119 colloidal silica Substances 0.000 claims description 10
- 239000000499 gel Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 150000007524 organic acids Chemical class 0.000 claims description 10
- 150000007513 acids Chemical class 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 235000019820 disodium diphosphate Nutrition 0.000 claims description 7
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 claims description 7
- 229940038485 disodium pyrophosphate Drugs 0.000 claims description 7
- 235000005985 organic acids Nutrition 0.000 claims description 7
- 239000011575 calcium Substances 0.000 claims description 6
- 150000007522 mineralic acids Chemical class 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Substances OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 5
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 5
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- 235000011007 phosphoric acid Nutrition 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 229940078916 carbamide peroxide Drugs 0.000 claims description 3
- 150000003016 phosphoric acids Chemical class 0.000 claims description 3
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 159000000003 magnesium salts Chemical class 0.000 claims description 2
- -1 peroxide compounds Chemical class 0.000 claims description 2
- 229960001922 sodium perborate Drugs 0.000 claims description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 claims 1
- 235000019441 ethanol Nutrition 0.000 description 26
- 235000011187 glycerol Nutrition 0.000 description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
- 229940099690 malic acid Drugs 0.000 description 11
- 239000001301 oxygen Substances 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- 238000000354 decomposition reaction Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- RBLGLDWTCZMLRW-UHFFFAOYSA-K dicalcium;phosphate;dihydrate Chemical compound O.O.[Ca+2].[Ca+2].[O-]P([O-])([O-])=O RBLGLDWTCZMLRW-UHFFFAOYSA-K 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 description 5
- 229960004995 magnesium peroxide Drugs 0.000 description 5
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 229960005069 calcium Drugs 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 235000003599 food sweetener Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000003765 sweetening agent Substances 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 241000220225 Malus Species 0.000 description 3
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 239000010692 aromatic oil Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 3
- 239000002324 mouth wash Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 210000003296 saliva Anatomy 0.000 description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 208000006558 Dental Calculus Diseases 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 229940051866 mouthwash Drugs 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 239000004343 Calcium peroxide Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 235000019739 Dicalciumphosphate Nutrition 0.000 description 1
- 241000023066 Pitane Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229910004116 SrO 2 Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004974 alkaline earth metal peroxides Chemical class 0.000 description 1
- 235000021016 apples Nutrition 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 description 1
- 235000019402 calcium peroxide Nutrition 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 description 1
- 229940038472 dicalcium phosphate Drugs 0.000 description 1
- 229910000390 dicalcium phosphate Inorganic materials 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000007983 food acid Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229940005740 hexametaphosphate Drugs 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- 210000002200 mouth mucosa Anatomy 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- CKRORYDHXIRZCH-UHFFFAOYSA-N phosphoric acid;dihydrate Chemical compound O.O.OP(O)(O)=O CKRORYDHXIRZCH-UHFFFAOYSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229940048084 pyrophosphate Drugs 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012619 stoichiometric conversion Methods 0.000 description 1
- UHCGLDSRFKGERO-UHFFFAOYSA-N strontium peroxide Chemical compound [Sr+2].[O-][O-] UHCGLDSRFKGERO-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Cosmetics (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1617430A DE1617430C3 (de) | 1966-07-29 | 1966-07-29 | Schäumende lagerstabile Zahnpaste |
| CH909167A CH492454A (de) | 1966-07-29 | 1967-06-27 | Schäumende lagerstabile Zahnpaste |
| AT633967A AT285050B (de) | 1966-07-29 | 1967-07-06 | Schäumende, lagerstabile Zahnpaste und Verfahren zu ihrer Herstellung |
| NL6709563.A NL161058C (nl) | 1966-07-29 | 1967-07-10 | Werkwijze voor de bereiding van een schuimende opslagbe- stendige tandpasta op basis van een tot pastaconsisten- tie door middel van colloidaal kiezelzuur verdikte, een alcohol bevattende gel. |
| US653315A US3577521A (en) | 1966-07-29 | 1967-07-14 | Storage-stable frothing toothpaste |
| BE701768D BE701768A (enExample) | 1966-07-29 | 1967-07-24 | |
| FR1559617D FR1559617A (enExample) | 1966-07-29 | 1967-07-28 | |
| IT18959/67A IT998007B (it) | 1966-07-29 | 1967-07-28 | Pasta dentrificia a sviluppo di schiuma conservabile per lunghis simo tempo |
| FR123870A FR7175M (enExample) | 1966-07-29 | 1967-10-10 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1617430A DE1617430C3 (de) | 1966-07-29 | 1966-07-29 | Schäumende lagerstabile Zahnpaste |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1617430A1 DE1617430A1 (de) | 1972-04-13 |
| DE1617430B2 DE1617430B2 (de) | 1974-01-10 |
| DE1617430C3 true DE1617430C3 (de) | 1980-07-10 |
Family
ID=7052862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1617430A Expired DE1617430C3 (de) | 1966-07-29 | 1966-07-29 | Schäumende lagerstabile Zahnpaste |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3577521A (enExample) |
| AT (1) | AT285050B (enExample) |
| BE (1) | BE701768A (enExample) |
| CH (1) | CH492454A (enExample) |
| DE (1) | DE1617430C3 (enExample) |
| FR (2) | FR1559617A (enExample) |
| IT (1) | IT998007B (enExample) |
| NL (1) | NL161058C (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4302441A (en) | 1979-04-19 | 1981-11-24 | Hans R. Muhlemann | Solid oral preparations of urea hydrogen peroxide without glycerol |
Families Citing this family (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1397248A (en) * | 1971-10-20 | 1975-06-11 | Beecham Inc | Dental compositions |
| US4108981A (en) * | 1976-08-02 | 1978-08-22 | Indiana University Foundation | Alkaline oral compositions comprising aluminum and a carboxylic acid |
| US4117120A (en) * | 1977-02-11 | 1978-09-26 | Elderbaum Gilbert J | Medication for herpes simplex and canker sores |
| US4292306A (en) * | 1978-12-28 | 1981-09-29 | Faunce Frank R | Dentifrice with topical and systemic phosphate fluoride system |
| WO1981002102A1 (en) * | 1980-01-21 | 1981-08-06 | F Powell | Denture decalcifying and cleansing preparations |
| US4607101A (en) * | 1981-08-27 | 1986-08-19 | Jaye-Boern Laboratories, Inc. | Method of treating acne vulgaris with a composition containing carbamide peroxide |
| US4487757A (en) * | 1981-12-28 | 1984-12-11 | Colgate-Palmolive Company | Dispensing container of toothpaste which effervesces during toothbrushing |
| US4528180A (en) * | 1983-03-01 | 1985-07-09 | Schaeffer Hans A | Dental preparation, article and method for storage and delivery thereof |
| US4849213A (en) * | 1983-03-01 | 1989-07-18 | Schaeffer Hans A | Dental preparation, article and method for storage and delivery therof |
| US5348734A (en) * | 1990-11-20 | 1994-09-20 | Micropure Inc. | Oral health preparation and method |
| US5200171A (en) * | 1990-11-20 | 1993-04-06 | Micropure, Inc. | Oral health preparation and method |
| JP2711393B2 (ja) * | 1988-05-31 | 1998-02-10 | 日本ゼオラ株式会社 | 口腔用組成物 |
| US5000942A (en) * | 1989-11-20 | 1991-03-19 | Libin Barry M | Oral hygiene composition |
| US4976955A (en) * | 1989-11-20 | 1990-12-11 | Libin Barry M | Oral hygiene composition |
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| US5817294A (en) * | 1990-11-02 | 1998-10-06 | Arnold; Michael J. | Plaque adsorbent oral composition and method |
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| AU660691B2 (en) * | 1991-09-13 | 1995-07-06 | Colgate-Palmolive Company, The | Abrasive tooth whitening dentifrice of improved stability |
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| US5658553A (en) * | 1995-05-02 | 1997-08-19 | The Procter & Gamble Company | Dentifrice compositions |
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| WO1997007777A1 (en) * | 1995-08-15 | 1997-03-06 | Robert Eric Montgomery | Peroxidase-activating oral compositions |
| AU7245596A (en) * | 1995-09-25 | 1997-04-17 | Robert Eric Montgomery | Tooth bleaching compositions |
| EP1314419B1 (en) * | 1995-09-25 | 2009-08-05 | Discus Dental, LLC | Tooth bleaching compositions |
| US20060171907A1 (en) * | 1996-11-21 | 2006-08-03 | The Procter & Gamble Company | Oral care compositions providing enhanced whitening and stain prevention |
| US20060002865A1 (en) * | 2004-06-30 | 2006-01-05 | Adonis Buelo | Stable baking soda/peroxide with calcium and phosphate whitening product |
| EP1814509A2 (en) * | 2004-11-09 | 2007-08-08 | Discus Dental Impressions, Inc. | Dental whitening systems comprising transition metal salt activator |
| US7670593B2 (en) * | 2004-11-24 | 2010-03-02 | J.M. Huber Corporation | High-cleaning silica materials and dentifrice containing such |
| US7267814B2 (en) | 2004-11-24 | 2007-09-11 | J.M. Huber Corporation | High-cleaning/low abrasive silica and materials and dentifrice containing such materials |
| US20060110307A1 (en) * | 2004-11-24 | 2006-05-25 | Mcgill Patrick D | High-cleaning silica materials made via product morphology control and dentifrice containing such |
| US7303742B2 (en) * | 2004-11-24 | 2007-12-04 | J.M. Huber Corporation | Viscosity-modifying silica materials that exhibit low cleaning and abrasive levels and dentifrices thereof |
| US7306788B2 (en) * | 2004-11-24 | 2007-12-11 | J.M. Huber Corporation | High-cleaning/moderate abrasive silica materials and dentifrice containing such materials |
| US20070071695A1 (en) * | 2005-09-27 | 2007-03-29 | Colgate-Palmolive Company | Single phase whitening dentifrice |
| US20070154412A1 (en) * | 2005-12-30 | 2007-07-05 | Nolan Lee Phillips | Dentifrices comprising biogenic silica materials |
| US20070154413A1 (en) * | 2005-12-30 | 2007-07-05 | Nolan Lee Phillips | Dentifrices comprising biogenic silica materials |
| US20070224133A1 (en) * | 2006-03-23 | 2007-09-27 | Mcgill Patrick D | High-cleaning silica materials made via product morphology control under high shear conditions |
| US7270803B1 (en) | 2006-03-23 | 2007-09-18 | J.M. Huber Corporation | High-cleaning, low abrasion, high brightness silica materials for dentrifices |
| US20080159968A1 (en) * | 2006-12-27 | 2008-07-03 | Fultz William C | Dentifrices comprising biogenic silica materials and calcium carbonate |
| US20080159967A1 (en) * | 2006-12-27 | 2008-07-03 | Fultz William C | Dentifrices comprising biogenic silica materials and at least one calcium phosphate |
| US20090297459A1 (en) * | 2008-06-03 | 2009-12-03 | Duen-Wu Hua | Transparent silica gel/precipitated silica composite materials for dentifrices |
| CN104780929A (zh) | 2012-09-11 | 2015-07-15 | Slh最佳保健有限责任公司 | 牙齿清洁组合物 |
| FR3049423B1 (fr) | 2016-03-24 | 2018-04-27 | Easii Ic | Circuit optoelectronique comprenant des diodes electroluminescentes |
| FR3049422A1 (fr) | 2016-03-24 | 2017-09-29 | Easii Ic | Circuit optoelectronique comprenant des diodes electroluminescentes |
| WO2019108205A1 (en) * | 2017-11-30 | 2019-06-06 | Colgate-Palmolive Company | Oral care compositions and methods for increasing stability of the same |
| US10925818B2 (en) | 2017-11-30 | 2021-02-23 | Colgate-Palmolive Company | Oral care compositions and methods for increasing stability of the same |
| MX2021005301A (es) * | 2018-11-07 | 2021-06-23 | Procter & Gamble | Composiciones para el cuidado bucal que comprenden polifosfatos de longitud media. |
| WO2024123555A2 (en) * | 2022-12-05 | 2024-06-13 | Isp Investments Llc | Anhydrous oral care compositions of adducts of alkali metal pyrophosphates and peroxides |
| FR3143342B1 (fr) * | 2022-12-16 | 2025-10-24 | Oreal | Composition comprenant de l’uree ou l’un de ses derives, un acide polycarboxylique et un sel de cation multivalent |
-
1966
- 1966-07-29 DE DE1617430A patent/DE1617430C3/de not_active Expired
-
1967
- 1967-06-27 CH CH909167A patent/CH492454A/de not_active IP Right Cessation
- 1967-07-06 AT AT633967A patent/AT285050B/de not_active IP Right Cessation
- 1967-07-10 NL NL6709563.A patent/NL161058C/xx not_active IP Right Cessation
- 1967-07-14 US US653315A patent/US3577521A/en not_active Expired - Lifetime
- 1967-07-24 BE BE701768D patent/BE701768A/xx unknown
- 1967-07-28 FR FR1559617D patent/FR1559617A/fr not_active Expired
- 1967-07-28 IT IT18959/67A patent/IT998007B/it active
- 1967-10-10 FR FR123870A patent/FR7175M/fr not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4302441A (en) | 1979-04-19 | 1981-11-24 | Hans R. Muhlemann | Solid oral preparations of urea hydrogen peroxide without glycerol |
Also Published As
| Publication number | Publication date |
|---|---|
| US3577521A (en) | 1971-05-04 |
| FR7175M (enExample) | 1969-08-11 |
| DE1617430B2 (de) | 1974-01-10 |
| NL161058B (nl) | 1979-08-15 |
| CH492454A (de) | 1970-06-30 |
| AT285050B (de) | 1970-10-12 |
| NL6709563A (enExample) | 1968-01-30 |
| FR1559617A (enExample) | 1969-03-14 |
| IT998007B (it) | 1976-01-20 |
| BE701768A (enExample) | 1968-01-02 |
| NL161058C (nl) | 1980-01-15 |
| DE1617430A1 (de) | 1972-04-13 |
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| BGA | New person/name/address of the applicant | ||
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |