DE1568429A1 - Herstellung von Organochlorsilanen - Google Patents
Herstellung von OrganochlorsilanenInfo
- Publication number
- DE1568429A1 DE1568429A1 DE19661568429 DE1568429A DE1568429A1 DE 1568429 A1 DE1568429 A1 DE 1568429A1 DE 19661568429 DE19661568429 DE 19661568429 DE 1568429 A DE1568429 A DE 1568429A DE 1568429 A1 DE1568429 A1 DE 1568429A1
- Authority
- DE
- Germany
- Prior art keywords
- silicon
- slurry
- reaction
- temperature
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001367 organochlorosilanes Chemical class 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 18
- 239000010703 silicon Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000012442 inert solvent Substances 0.000 claims description 9
- 239000002480 mineral oil Substances 0.000 claims description 8
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 claims description 7
- 235000010446 mineral oil Nutrition 0.000 claims description 7
- OHXAOPZTJOUYKM-UHFFFAOYSA-N 3-Chloro-2-methylpropene Chemical compound CC(=C)CCl OHXAOPZTJOUYKM-UHFFFAOYSA-N 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 16
- 239000000203 mixture Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- VTEHVUWHCBXMPI-UHFFFAOYSA-N dichloro-bis(prop-2-enyl)silane Chemical compound C=CC[Si](Cl)(Cl)CC=C VTEHVUWHCBXMPI-UHFFFAOYSA-N 0.000 description 7
- 150000004820 halides Chemical class 0.000 description 6
- 229910000676 Si alloy Inorganic materials 0.000 description 5
- -1 alkene chlorides Chemical class 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000010574 gas phase reaction Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 4
- 239000005046 Chlorosilane Substances 0.000 description 4
- MJVFSDBAXDCTOC-UHFFFAOYSA-N dichloro(prop-2-enyl)silicon Chemical compound Cl[Si](Cl)CC=C MJVFSDBAXDCTOC-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 4
- 239000005047 Allyltrichlorosilane Substances 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- HKFSBKQQYCMCKO-UHFFFAOYSA-N trichloro(prop-2-enyl)silane Chemical compound Cl[Si](Cl)(Cl)CC=C HKFSBKQQYCMCKO-UHFFFAOYSA-N 0.000 description 3
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 3
- 239000005052 trichlorosilane Substances 0.000 description 3
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 150000001348 alkyl chlorides Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical class Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 2
- 239000011863 silicon-based powder Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- WCCJDBZJUYKDBF-UHFFFAOYSA-N copper silicon Chemical compound [Si].[Cu] WCCJDBZJUYKDBF-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 125000001844 prenyl group Chemical group [H]C([*])([H])C([H])=C(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- UIDUKLCLJMXFEO-UHFFFAOYSA-N propylsilane Chemical compound CCC[SiH3] UIDUKLCLJMXFEO-UHFFFAOYSA-N 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/16—Preparation thereof from silicon and halogenated hydrocarbons direct synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US51747265A | 1965-12-29 | 1965-12-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1568429A1 true DE1568429A1 (de) | 1970-03-26 |
Family
ID=24059946
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19661568429 Pending DE1568429A1 (de) | 1965-12-29 | 1966-12-23 | Herstellung von Organochlorsilanen |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3440267A (enExample) |
| AT (1) | AT263027B (enExample) |
| DE (1) | DE1568429A1 (enExample) |
| FR (1) | FR1506224A (enExample) |
| GB (1) | GB1137289A (enExample) |
| NL (1) | NL6618250A (enExample) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE469151A (enExample) * | 1945-06-11 |
-
1965
- 1965-12-29 US US517472A patent/US3440267A/en not_active Expired - Lifetime
-
1966
- 1966-12-08 GB GB54989/66A patent/GB1137289A/en not_active Expired
- 1966-12-23 DE DE19661568429 patent/DE1568429A1/de active Pending
- 1966-12-28 FR FR89213A patent/FR1506224A/fr not_active Expired
- 1966-12-28 NL NL6618250A patent/NL6618250A/xx unknown
- 1966-12-28 AT AT1192866A patent/AT263027B/de active
Also Published As
| Publication number | Publication date |
|---|---|
| NL6618250A (enExample) | 1967-06-30 |
| US3440267A (en) | 1969-04-22 |
| AT263027B (de) | 1968-07-10 |
| GB1137289A (en) | 1968-12-18 |
| FR1506224A (fr) | 1967-12-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0032377B1 (de) | Verfahren zum Anlagern von Si-gebundenem Wasserstoff an aliphatische Mehrfachbindung | |
| DE842059C (de) | Verfahren zur Herstellung von Organosiliziumhalogeniden | |
| DE3689307T2 (de) | Verfahren zur Beförderung von Hydrosilierungsreaktionen durch Verwendung eines zweiten Hydrosilans. | |
| EP0600266A2 (de) | Verfahren zur Herstellung von SiH-Gruppen aufweisenden Organopolysiloxanen | |
| DE829892C (de) | Verfahren zur Herstellung von alkenylsubstituierten, endstaendig ungesaettigten Chlorsilanen | |
| DE2851456A1 (de) | Verfahren zum herstellen von organosiliciumverbindungen | |
| DE2365272C2 (enExample) | ||
| DE69909208T2 (de) | Verfahren zur Herstellung von Alkylhalogensilanen | |
| DE855851C (de) | Verfahren zur Herstellung von Dimethyldichlorsilan | |
| DE1232580B (de) | Verfahren zur Herstellung von Vinylhalogensilanen | |
| DE921566C (de) | Verfahren zur Herstellung von Alkyl- bzw. Arylhalogensilanen | |
| DE1127898B (de) | Verfahren zur Herstellung von ª‰-Cyanaethylphenyldichlorsilan | |
| DE2351258A1 (de) | Verfahren zum umlagern von alkylsilanen und alkylhydrogensilanen | |
| DE936445C (de) | Verfahren zur Herstellung von Vinylchlorsilanen | |
| DE3303707C2 (enExample) | ||
| DE947475C (de) | Verfahren zur Herstellung von neuen Hexaorganoaethinyldisilanen | |
| DE1231240B (de) | Verfahren zur Herstellung von Silylacylmetallocenen | |
| DE1568429A1 (de) | Herstellung von Organochlorsilanen | |
| DE870555C (de) | Verfahren zur Herstellung von phenylenbrueckenhaltigen chlorierten Polyorganosilanen | |
| DE1161430B (de) | Verfahren zur Herstellung von Alkylchlor-polysilanen und/oder Alkylchlormonosilanen | |
| DE69400951T2 (de) | Verfahren zur Herstellung von Dicyclopentyldichlorosilan | |
| DE854950C (de) | Verfahren zur Herstellung von Trichlorsilylderivaten von aromatischen Chlorkohlenwasserstoffen | |
| CH620222A5 (enExample) | ||
| DE896045C (de) | Verfahren zur Herstellung von Organohalogensilanen | |
| DE1266301B (de) | Verfahren zur Herstellung von Alkylhalogensilanen |