DE1567536B2 - Verfahren zur herstellung eines als crackkatalysator geeigneten zeolithen - Google Patents
Verfahren zur herstellung eines als crackkatalysator geeigneten zeolithenInfo
- Publication number
- DE1567536B2 DE1567536B2 DE1965G0043070 DEG0043070A DE1567536B2 DE 1567536 B2 DE1567536 B2 DE 1567536B2 DE 1965G0043070 DE1965G0043070 DE 1965G0043070 DE G0043070 A DEG0043070 A DE G0043070A DE 1567536 B2 DE1567536 B2 DE 1567536B2
- Authority
- DE
- Germany
- Prior art keywords
- zeolite
- base exchange
- alkali
- ions
- exchange
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims 8
- 239000003054 catalyst Substances 0.000 title claims 3
- 238000005336 cracking Methods 0.000 title claims 3
- 239000010457 zeolite Substances 0.000 claims description 22
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 21
- 229910021536 Zeolite Inorganic materials 0.000 claims description 20
- 238000001354 calcination Methods 0.000 claims description 11
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 9
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 2
- 239000002585 base Substances 0.000 claims 20
- 239000003513 alkali Substances 0.000 claims 13
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims 6
- 150000002500 ions Chemical class 0.000 claims 6
- 150000001450 anions Chemical class 0.000 claims 4
- -1 hydrogen ions Chemical class 0.000 claims 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 4
- 238000001035 drying Methods 0.000 claims 3
- 238000005406 washing Methods 0.000 claims 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 229910052593 corundum Inorganic materials 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 2
- 241000282326 Felis catus Species 0.000 claims 1
- 241000158147 Sator Species 0.000 claims 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 235000019270 ammonium chloride Nutrition 0.000 claims 1
- FROZIYRKKUFAOC-UHFFFAOYSA-N amobam Chemical compound N.N.SC(=S)NCCNC(S)=S FROZIYRKKUFAOC-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 229910052681 coesite Inorganic materials 0.000 claims 1
- 229910052906 cristobalite Inorganic materials 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 239000012013 faujasite Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 238000009938 salting Methods 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 230000006641 stabilisation Effects 0.000 claims 1
- 238000011105 stabilization Methods 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 229910052682 stishovite Inorganic materials 0.000 claims 1
- YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 claims 1
- TXBULBYASDPNNC-UHFFFAOYSA-L tetraethylazanium;sulfate Chemical compound [O-]S([O-])(=O)=O.CC[N+](CC)(CC)CC.CC[N+](CC)(CC)CC TXBULBYASDPNNC-UHFFFAOYSA-L 0.000 claims 1
- 229910052905 tridymite Inorganic materials 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 1
- 239000000047 product Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26029863A | 1963-02-21 | 1963-02-21 | |
| US31824963A | 1963-10-23 | 1963-10-23 | |
| US35328864A | 1964-03-19 | 1964-03-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1567536A1 DE1567536A1 (de) | 1970-09-10 |
| DE1567536B2 true DE1567536B2 (de) | 1976-09-23 |
Family
ID=27401307
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1965G0043070 Granted DE1567536B2 (de) | 1963-02-21 | 1965-03-13 | Verfahren zur herstellung eines als crackkatalysator geeigneten zeolithen |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1567536B2 (enrdf_load_stackoverflow) |
| FR (2) | FR1554554A (enrdf_load_stackoverflow) |
| GB (2) | GB1060436A (enrdf_load_stackoverflow) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1162969A (en) * | 1968-08-19 | 1969-09-04 | Shell Int Research | A Process for Converting Hydrocarbons |
| NL7018221A (enrdf_load_stackoverflow) * | 1969-12-18 | 1971-06-22 |
-
1964
- 1964-02-20 FR FR964459A patent/FR1554554A/fr not_active Expired
- 1964-02-20 GB GB722364A patent/GB1060436A/en not_active Expired
-
1965
- 1965-03-10 GB GB1023665A patent/GB1102799A/en not_active Expired
- 1965-03-13 DE DE1965G0043070 patent/DE1567536B2/de active Granted
- 1965-03-18 FR FR9691A patent/FR94301E/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1554554A (enrdf_load_stackoverflow) | 1969-01-24 |
| FR94301E (fr) | 1969-08-01 |
| GB1102799A (en) | 1968-02-07 |
| DE1792787B1 (de) | 1977-02-24 |
| DE1567536A1 (de) | 1970-09-10 |
| GB1060436A (en) | 1967-03-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 |