DE1545302A1 - Verfahren zum Vermindern des Mercaptangehaltes von Erdoelkohlenwasserstoffen - Google Patents
Verfahren zum Vermindern des Mercaptangehaltes von ErdoelkohlenwasserstoffenInfo
- Publication number
- DE1545302A1 DE1545302A1 DE19651545302 DE1545302A DE1545302A1 DE 1545302 A1 DE1545302 A1 DE 1545302A1 DE 19651545302 DE19651545302 DE 19651545302 DE 1545302 A DE1545302 A DE 1545302A DE 1545302 A1 DE1545302 A1 DE 1545302A1
- Authority
- DE
- Germany
- Prior art keywords
- hydrocarbons
- molecular oxygen
- treated
- petroleum hydrocarbons
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims description 45
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 45
- 238000000034 method Methods 0.000 title claims description 45
- 239000003208 petroleum Substances 0.000 title claims description 33
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 title claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 22
- 229910001882 dioxygen Inorganic materials 0.000 claims description 22
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- 239000011593 sulfur Substances 0.000 claims description 13
- 229910052717 sulfur Inorganic materials 0.000 claims description 13
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 12
- 239000003502 gasoline Substances 0.000 claims description 12
- 230000003197 catalytic effect Effects 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 235000015096 spirit Nutrition 0.000 claims 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 27
- 239000000047 product Substances 0.000 description 13
- 238000009835 boiling Methods 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 150000002019 disulfides Chemical class 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 9
- 239000003513 alkali Substances 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 235000009508 confectionery Nutrition 0.000 description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 150000003464 sulfur compounds Chemical class 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 239000003209 petroleum derivative Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 230000005484 gravity Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- -1 light gasoline Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
- C10G17/09—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acid salts
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Seasonings (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US361879A US3244618A (en) | 1964-04-22 | 1964-04-22 | Sweetening process using nitrogen oxide catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1545302A1 true DE1545302A1 (de) | 1969-06-19 |
Family
ID=23423781
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19651545302 Pending DE1545302A1 (de) | 1964-04-22 | 1965-04-02 | Verfahren zum Vermindern des Mercaptangehaltes von Erdoelkohlenwasserstoffen |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3244618A (enrdf_load_stackoverflow) |
| BE (1) | BE662845A (enrdf_load_stackoverflow) |
| DE (1) | DE1545302A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1051515A (enrdf_load_stackoverflow) |
| LU (1) | LU48413A1 (enrdf_load_stackoverflow) |
| NL (1) | NL6505129A (enrdf_load_stackoverflow) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3919402A (en) * | 1973-08-06 | 1975-11-11 | Kvb Inc | Petroleum oil desulfurization process |
| US3847800A (en) * | 1973-08-06 | 1974-11-12 | Kvb Eng Inc | Method for removing sulfur and nitrogen in petroleum oils |
| US4485007A (en) * | 1982-06-15 | 1984-11-27 | Environmental Research And Technology Inc. | Process for purifying hydrocarbonaceous oils |
| US4643820A (en) * | 1986-02-24 | 1987-02-17 | Oxiprocessing | Process for enhancing the cetane number of diesel fuel |
| RU2125586C1 (ru) * | 1997-01-16 | 1999-01-27 | Всероссийский научно-исследовательский институт углеводородного сырья | Способ получения углеводородных дистиллятов с низким содержанием серы |
| US7678263B2 (en) * | 2006-01-30 | 2010-03-16 | Conocophillips Company | Gas stripping process for removal of sulfur-containing components from crude oil |
| US7674444B2 (en) * | 2006-02-01 | 2010-03-09 | Fluor Technologies Corporation | Configurations and methods for removal of mercaptans from feed gases |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2828247A (en) * | 1955-11-18 | 1958-03-25 | Sun Oil Co | Treatment of petroleum hydrocarbons |
| US3073778A (en) * | 1959-11-09 | 1963-01-15 | Pure Oil Co | Method of preparing odorless naphthas |
| US3135680A (en) * | 1961-09-11 | 1964-06-02 | Pure Oil Co | Process of refining diesel fuel with nitrogen dioxide |
| US3159570A (en) * | 1962-12-19 | 1964-12-01 | Charles O Petty | Hydrazine sweetening |
-
0
- GB GB1051515D patent/GB1051515A/en active Active
-
1964
- 1964-04-22 US US361879A patent/US3244618A/en not_active Expired - Lifetime
-
1965
- 1965-04-02 DE DE19651545302 patent/DE1545302A1/de active Pending
- 1965-04-16 LU LU48413A patent/LU48413A1/xx unknown
- 1965-04-21 BE BE662845D patent/BE662845A/xx unknown
- 1965-04-22 NL NL6505129A patent/NL6505129A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US3244618A (en) | 1966-04-05 |
| BE662845A (enrdf_load_stackoverflow) | 1965-08-17 |
| NL6505129A (enrdf_load_stackoverflow) | 1965-10-25 |
| LU48413A1 (enrdf_load_stackoverflow) | 1965-06-16 |
| GB1051515A (enrdf_load_stackoverflow) |
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