DE1520550B2 - Verfahren zur Herstellung von gelfreien Dienpolymerisaten - Google Patents
Verfahren zur Herstellung von gelfreien DienpolymerisatenInfo
- Publication number
- DE1520550B2 DE1520550B2 DE19631520550 DE1520550A DE1520550B2 DE 1520550 B2 DE1520550 B2 DE 1520550B2 DE 19631520550 DE19631520550 DE 19631520550 DE 1520550 A DE1520550 A DE 1520550A DE 1520550 B2 DE1520550 B2 DE 1520550B2
- Authority
- DE
- Germany
- Prior art keywords
- polymerization
- conjugated diene
- weight
- gel
- cold flow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229920000642 polymer Polymers 0.000 title claims description 23
- 150000001993 dienes Chemical class 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 16
- 230000008569 process Effects 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 19
- 229920006216 polyvinyl aromatic Polymers 0.000 claims description 17
- 239000003999 initiator Substances 0.000 claims description 15
- 150000001491 aromatic compounds Chemical class 0.000 claims description 14
- -1 diene hydrocarbons Chemical class 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 125000001979 organolithium group Chemical group 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical compound C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 claims 1
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 33
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000000047 product Substances 0.000 description 9
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 241001441571 Hiodontidae Species 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000013032 Hydrocarbon resin Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 229920006270 hydrocarbon resin Polymers 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002779 inactivation Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RCJMVGJKROQDCB-SNAWJCMRSA-N (3e)-2-methylpenta-1,3-diene Chemical compound C\C=C\C(C)=C RCJMVGJKROQDCB-SNAWJCMRSA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- DQFAIOJURQGXBT-UHFFFAOYSA-N 1,2,4-tris(ethenyl)benzene Chemical compound C=CC1=CC=C(C=C)C(C=C)=C1 DQFAIOJURQGXBT-UHFFFAOYSA-N 0.000 description 1
- ZJQIXGGEADDPQB-UHFFFAOYSA-N 1,2-bis(ethenyl)-3,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C=C)=C1C ZJQIXGGEADDPQB-UHFFFAOYSA-N 0.000 description 1
- FWFAJEYKHANIJP-UHFFFAOYSA-N 1,3,5-tris(ethenyl)naphthalene Chemical compound C1=CC=C(C=C)C2=CC(C=C)=CC(C=C)=C21 FWFAJEYKHANIJP-UHFFFAOYSA-N 0.000 description 1
- QTYUSOHYEPOHLV-FNORWQNLSA-N 1,3-Octadiene Chemical compound CCCC\C=C\C=C QTYUSOHYEPOHLV-FNORWQNLSA-N 0.000 description 1
- SZEZDFQBIICMNO-UHFFFAOYSA-N 1,3-bis(ethenyl)-5-(4-ethenylphenyl)benzene Chemical group C1=CC(C=C)=CC=C1C1=CC(C=C)=CC(C=C)=C1 SZEZDFQBIICMNO-UHFFFAOYSA-N 0.000 description 1
- TUDTVAXRTPHZAJ-UHFFFAOYSA-N 1,3-bis(ethenyl)naphthalene Chemical compound C1=CC=CC2=CC(C=C)=CC(C=C)=C21 TUDTVAXRTPHZAJ-UHFFFAOYSA-N 0.000 description 1
- RCJMVGJKROQDCB-UHFFFAOYSA-N 1,3-dimethyl-1,3-butadiene Natural products CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 description 1
- FTUDIUREWUBVKL-UHFFFAOYSA-N 1,8-bis(ethenyl)naphthalene Chemical compound C1=CC(C=C)=C2C(C=C)=CC=CC2=C1 FTUDIUREWUBVKL-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- JVXPEVSEOVECRV-UHFFFAOYSA-N 2,4-bis(ethenyl)-1-phenylbenzene Chemical group C=CC1=CC(C=C)=CC=C1C1=CC=CC=C1 JVXPEVSEOVECRV-UHFFFAOYSA-N 0.000 description 1
- WFAQEKGVNQWFTG-UHFFFAOYSA-N 2-ethenyl-1-(2-ethenyl-4-ethylphenyl)-4-propylbenzene Chemical group C=CC1=CC(CCC)=CC=C1C1=CC=C(CC)C=C1C=C WFAQEKGVNQWFTG-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- OCTVDLUSQOJZEK-UHFFFAOYSA-N 4,5-diethylocta-1,3-diene Chemical compound CCCC(CC)C(CC)=CC=C OCTVDLUSQOJZEK-UHFFFAOYSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- ZGRJUVFLVXXJAW-UHFFFAOYSA-N [Li]CC=C(C)C[Li] Chemical compound [Li]CC=C(C)C[Li] ZGRJUVFLVXXJAW-UHFFFAOYSA-N 0.000 description 1
- BZEZSORUWZUMNU-UHFFFAOYSA-N [Li]CCCC[Li] Chemical compound [Li]CCCC[Li] BZEZSORUWZUMNU-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- DLEDOFVPSDKWEF-UHFFFAOYSA-N lithium butane Chemical compound [Li+].CCC[CH2-] DLEDOFVPSDKWEF-UHFFFAOYSA-N 0.000 description 1
- WTTUTKBXMMXKBQ-UHFFFAOYSA-N lithium;stilbene Chemical compound C=1C=CC=CC=1C([Li])C([Li])C1=CC=CC=C1 WTTUTKBXMMXKBQ-UHFFFAOYSA-N 0.000 description 1
- DVSDBMFJEQPWNO-UHFFFAOYSA-N methyllithium Chemical compound C[Li] DVSDBMFJEQPWNO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- NHKJPPKXDNZFBJ-UHFFFAOYSA-N phenyllithium Chemical compound [Li]C1=CC=CC=C1 NHKJPPKXDNZFBJ-UHFFFAOYSA-N 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
- C08G81/022—Block or graft polymers containing only sequences of polymers of C08C or C08F containing sequences of polymers of conjugated dienes and of polymers of alkenyl aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US210210A US3280084A (en) | 1962-07-16 | 1962-07-16 | Reducing cold flow in conjugated diene polymers with a polyvinyl aromatic compound |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1520550A1 DE1520550A1 (de) | 1969-04-10 |
| DE1520550B2 true DE1520550B2 (de) | 1970-08-13 |
Family
ID=22782012
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19631520550 Ceased DE1520550B2 (de) | 1962-07-16 | 1963-07-16 | Verfahren zur Herstellung von gelfreien Dienpolymerisaten |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3280084A (instruction) |
| BE (1) | BE638995A (instruction) |
| BR (1) | BR6350780D0 (instruction) |
| DE (1) | DE1520550B2 (instruction) |
| ES (1) | ES289967A1 (instruction) |
| GB (1) | GB996251A (instruction) |
| SE (1) | SE323202B (instruction) |
Families Citing this family (77)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE621659A (instruction) * | 1961-08-25 | |||
| US3402159A (en) * | 1963-12-20 | 1968-09-17 | Phillips Petroleum Co | Process for polymerizing butadiene and styrene terminated in short blocks of polystyrene |
| GB1130770A (en) * | 1965-12-29 | 1968-10-16 | Asahi Chemical Ind | Process for producing thermoplastic elastomers |
| US3862251A (en) * | 1970-02-11 | 1975-01-21 | Us Navy | Organo-dilithium initiator for anionic polymerization, a novel polyisoprene, and processes for production thereof |
| US4004070A (en) * | 1970-09-28 | 1977-01-18 | Phillips Petroleum Company | Viscosity reduction of organopolylithium-initiated polymer solutions |
| US3725370A (en) * | 1971-01-06 | 1973-04-03 | Firestone Tire & Rubber Co | Process and product of treating live polymers with divinyl benzene and an active halogen compound |
| US3725369A (en) * | 1971-01-06 | 1973-04-03 | Firestone Tire & Rubber Co | Process for postreaction of alkali metal-active polymers with silicic compounds and dialkenyl compounds |
| US3755276A (en) * | 1971-02-17 | 1973-08-28 | Firestone Tire & Rubber Co | Process for polymerizing conjugated dienes |
| US3855189A (en) * | 1972-02-11 | 1974-12-17 | Phillips Petroleum Co | Polar compounds improve effectiveness of polyvinyl aromatic compounds |
| US3959412A (en) * | 1973-12-10 | 1976-05-25 | Phillips Petroleum Company | Block polymer preparation |
| DE2401629A1 (de) * | 1974-01-15 | 1975-07-24 | Basf Ag | Block- bzw. pfropfcopolymerisate |
| US3985830B1 (en) * | 1974-07-15 | 1998-03-03 | Univ Akron | Star polymers and process for the preparation thereof |
| US4010226A (en) * | 1975-07-17 | 1977-03-01 | Shell Oil Company | Block polymers and their preparation |
| US4111915A (en) * | 1975-10-24 | 1978-09-05 | Phillips Petroleum Company | Lithium alkenoxides in preparation of functional liquid conjugated diene polymers |
| US4237246A (en) * | 1976-07-15 | 1980-12-02 | Phillips Petroleum Company | Copolymers of 1,3-cyclodienes, monovinylaromatic compounds and polyvinylaromatic hydrocarbons |
| US4137391A (en) * | 1976-09-10 | 1979-01-30 | Phillips Petroleum Company | Continuous solution polymerization of a conjugated diene with a monovinylaromatic compound using alkoxysilicon treating agents in the first reactor means of a reactor series |
| US4091198A (en) * | 1976-09-10 | 1978-05-23 | Phillips Petroleum Company | Suppressing gel in the continuous solution polymerization of a conjugated diene with a monovinyl aromatic compound |
| US4408006A (en) * | 1979-09-07 | 1983-10-04 | Atlantic Richfield Company | Star elastomers in footwear compounds |
| JPS5919577B2 (ja) * | 1980-08-25 | 1984-05-07 | 日本エラストマ−株式会社 | 耐衝撃性ポリスチレンの製造方法 |
| US4332760A (en) * | 1981-03-30 | 1982-06-01 | Atlantic Richfield Company | Direct production of elastomer compound from reactor solution |
| US4346193A (en) * | 1981-05-04 | 1982-08-24 | Atlantic Richfield Company | Continuous process for making star-block copolymers |
| US4370433A (en) * | 1981-07-10 | 1983-01-25 | Phillips Petroleum Company | High strength diene/monovinyl aromatic copolymer-based adhesives |
| US4409368A (en) | 1981-07-13 | 1983-10-11 | The General Tire & Rubber Company | Preparation of star polymers |
| USRE31770E (en) * | 1981-08-03 | 1984-12-18 | Atlantic Richfield Company | Derivatization of star-block copolymers |
| US4417029A (en) * | 1981-08-03 | 1983-11-22 | Atlantic Richfield Company | Derivatization of star-block copolymers |
| US4503188A (en) * | 1983-06-20 | 1985-03-05 | Atlantic Richfield Company | Acrylates as coupling agents for star-block copolymers |
| US4530959A (en) * | 1984-03-08 | 1985-07-23 | The Goodyear Tire & Rubber Company | Pneumatic tire with tread of medium vinyl polybutadiene/rubber blend |
| US4522970A (en) * | 1984-06-25 | 1985-06-11 | The Goodyear Tire & Rubber Company | Tire with tread rubber containing medium vinyl polybutadiene with clay and carbon black |
| US4845165A (en) * | 1987-03-13 | 1989-07-04 | The Goodyear Tire & Rubber Company | Anionic diene polymerization process with branching |
| IT1246287B (it) * | 1990-07-25 | 1994-11-17 | Enichem Elastomers | Copolimero a blocchi ramificato e idrogenato e procedimenti per la sua preparazione |
| US5487951A (en) * | 1991-07-08 | 1996-01-30 | Minnesota Mining And Manufacturing Company | Magnetic recording medium with a binder resin of a starblock copolymer having at least six arms |
| JP2611717B2 (ja) * | 1992-06-10 | 1997-05-21 | 住友化学工業株式会社 | ブタジエン系共重合体 |
| US5296547A (en) * | 1993-01-28 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Block copolymer having mixed molecular weight endblocks |
| US5412031A (en) * | 1993-05-25 | 1995-05-02 | Minnesota Mining & Manufacturing Company | Multi-arm block copolymers, and pressure sensitive adhesive and tape employing a multi-arm elastomeric block copolymer |
| US5332613A (en) * | 1993-06-09 | 1994-07-26 | Kimberly-Clark Corporation | High performance elastomeric nonwoven fibrous webs |
| EP0632075A3 (en) * | 1993-06-30 | 1998-02-25 | Shell Internationale Researchmaatschappij B.V. | Liquid star polymers having terminal hydroxyl groups |
| US5395885A (en) * | 1993-12-17 | 1995-03-07 | The University Of Akron | Multi-arm cationic star-polymers |
| US6197891B1 (en) | 1994-05-13 | 2001-03-06 | Fmc Corporation | Functionalized chain extended initiators for anionic polymerization |
| US5821307A (en) * | 1994-05-13 | 1998-10-13 | Fmc Corporation | Functionalized chain extended initiators for anionic polymerization |
| WO1995034586A2 (de) * | 1994-06-16 | 1995-12-21 | Basf Aktiengesellschaft | Thermoplastische formmasse |
| US5798418A (en) * | 1995-07-31 | 1998-08-25 | Fmc Corporation | Star polymers from mixed initiators |
| US5919870A (en) * | 1995-07-31 | 1999-07-06 | Fmc Corporation | Functional telechelic star polymers |
| US5922810A (en) | 1995-07-31 | 1999-07-13 | Fmc Corporation | Deprotection of protected functional polymers |
| AU6643196A (en) * | 1995-08-04 | 1997-03-05 | Fmc Corporation | Telechelic polystyrene/polyethylene copolymers and processes for making same |
| US5780551A (en) * | 1995-11-02 | 1998-07-14 | Fmc Corporation | Telechelic polymers from mixed initiator |
| GB2307872A (en) * | 1995-12-04 | 1997-06-11 | Minnesota Mining & Mfg | Star polymer binder for magnetic recording materials |
| DE19621734A1 (de) | 1996-05-30 | 1997-12-04 | Basf Ag | Flammwidrige thermoplastische Formmassen auf Basis von Polyphenylenethern |
| DE19621732A1 (de) | 1996-05-30 | 1997-12-04 | Basf Ag | Flammwidrige thermoplastische Formmassen mit verbesserter Tropffestigkeit |
| US5965681A (en) * | 1996-06-18 | 1999-10-12 | Fmc Corporation | Protected functionalized telechelic polymers and processes for making the same |
| WO1998002465A1 (en) | 1996-07-17 | 1998-01-22 | Schwindeman James A | Protected functionalized heterotelechelic polymers and processes for preparing the same |
| DE19642491A1 (de) | 1996-10-15 | 1998-04-16 | Basf Ag | Flammwidrige thermoplastische Formmassen auf Basis von Polyphenylenethern und vinylaromatischen Polymeren |
| US6153706A (en) * | 1997-07-30 | 2000-11-28 | Fmc Corporation | Protected multi-functionalized star polymers and processes for making the same |
| US6107408A (en) * | 1998-02-26 | 2000-08-22 | Fmc Corporation | Processes for improving linking efficiencies in the synthesis of star polymers |
| US6380304B1 (en) | 1999-09-30 | 2002-04-30 | The Dow Chemical Company | Mass polymerized rubber-modified monovinylidene aromatic copolymer compositions |
| US6306962B1 (en) | 1999-09-30 | 2001-10-23 | The Dow Chemical Company | Flow carbonate polymer blends |
| US6579940B1 (en) | 1999-10-28 | 2003-06-17 | Edwards Lifesciences Corporation | Thermoplastic elastomeric material as a replacement for natural rubber latex |
| US6228945B1 (en) | 1999-12-20 | 2001-05-08 | The University Of Akron | Three arm star compositions of matter having diblock arms based on polyisobutylene and methods of preparation |
| US20030211308A1 (en) * | 2001-02-02 | 2003-11-13 | Khandpur Ashish K | Adhesive for bonding to low surface energy surfaces |
| US6630531B1 (en) | 2000-02-02 | 2003-10-07 | 3M Innovative Properties Company | Adhesive for bonding to low surface energy surfaces |
| US6380303B1 (en) | 2000-02-24 | 2002-04-30 | The Dow Chemical Company | Flow carbonate polymer blends |
| US6613838B1 (en) | 2000-08-30 | 2003-09-02 | Edwards Lifesciences Corporation | Synthetic rubber elastomers as replacements for natural rubber latex |
| US6462137B2 (en) | 2000-10-19 | 2002-10-08 | China Petroleum And Chemical Corporation | Star-block interpolymers and preparation of the same |
| US20030069366A1 (en) * | 2001-09-17 | 2003-04-10 | Letchford Robert J. | Urethane oligomers of heterotelechelic amine functional polyolefins |
| ATE458789T1 (de) | 2006-07-26 | 2010-03-15 | Basf Se | Thermoplastische formmassen mit hoher steifigkeit |
| US20080045656A1 (en) * | 2006-08-18 | 2008-02-21 | General Electric Company | Poly(arylene ether) composition, method, and article |
| US20080045655A1 (en) * | 2006-08-18 | 2008-02-21 | General Electric Company | Poly(arylene ether) composition, method, and article |
| JP5624464B2 (ja) * | 2007-07-10 | 2014-11-12 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 難燃性を有する弾性共重合体 |
| CN102088857A (zh) * | 2008-07-09 | 2011-06-08 | 巴斯夫欧洲公司 | 包含异噁唑啉化合物的杀虫活性混合物ⅱ |
| US20120208909A1 (en) | 2009-10-09 | 2012-08-16 | Basf Se | Polymer mixtures of polystyrene having styrene butadiene block copolymers |
| EP2511304B1 (en) | 2009-12-10 | 2017-09-27 | Dynasol Elastomeros, S.A. | Functionalised multiarm polymers comprising functionalised polymers synthesised through anionic polymerisation and applications thereof |
| CN107513142A (zh) | 2010-10-27 | 2017-12-26 | 英力士苯领欧洲股份公司 | 在星型分子结构的星中至少有两条不同臂的弹性嵌段共聚物 |
| ES2726660T3 (es) | 2013-12-18 | 2019-10-08 | Ineos Styrolution Group Gmbh | Uso de masas moldeables basadas en copolímeros de bloque de compuesto aromático de vinilo-dieno para la impresión en 3D |
| KR102273553B1 (ko) | 2016-04-21 | 2021-07-06 | 이네오스 스티롤루션 그룹 게엠베하 | 개선된 균열 및 화학적 내성을 갖는 ａｂｓ 몰딩 조성물 및 그의 사용 |
| EP3478765B1 (en) | 2016-06-29 | 2020-06-10 | INEOS Styrolution Group GmbH | Polymer composition comprising at least one vinyl aromatic diene block copolymer and specific amounts of oil |
| CN111989366B (zh) | 2018-02-16 | 2023-08-29 | 英力士苯领集团股份公司 | 高耐热性abs模塑组合物 |
| US20220332872A1 (en) | 2019-08-21 | 2022-10-20 | Ineos Styrolution Group Gmbh | Abs molding composition for sheet extrusion and thermoforming with high escr, high color and thermal stability and low tendency to delamination |
| CN110885412B (zh) * | 2019-12-17 | 2023-01-06 | 广东众和高新科技有限公司 | 一种sbs胶液的制备方法、由其制得的星型sbs及其应用 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2815335A (en) * | 1952-08-29 | 1957-12-03 | Exxon Research Engineering Co | Divinyl benzene modified polymers |
| US2847406A (en) * | 1954-03-15 | 1958-08-12 | American Synthetic Rubber Corp | Cross linked copolymer |
| BE637376A (instruction) * | 1958-05-23 |
-
0
- BE BE638995D patent/BE638995A/xx unknown
-
1962
- 1962-07-16 US US210210A patent/US3280084A/en not_active Expired - Lifetime
-
1963
- 1963-07-13 ES ES289967A patent/ES289967A1/es not_active Expired
- 1963-07-15 SE SE7829/63A patent/SE323202B/xx unknown
- 1963-07-15 BR BR150780/63A patent/BR6350780D0/pt unknown
- 1963-07-16 DE DE19631520550 patent/DE1520550B2/de not_active Ceased
- 1963-07-16 GB GB28078/63A patent/GB996251A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES289967A1 (es) | 1963-12-16 |
| US3280084A (en) | 1966-10-18 |
| BE638995A (instruction) | |
| DE1520550A1 (de) | 1969-04-10 |
| SE323202B (instruction) | 1970-04-27 |
| BR6350780D0 (pt) | 1973-08-09 |
| GB996251A (en) | 1965-06-23 |
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