DE1496848A1 - Verfahren zum galvanischen Niederschlagen von Nickel aus Nickelsulfamatbaedern - Google Patents
Verfahren zum galvanischen Niederschlagen von Nickel aus NickelsulfamatbaedernInfo
- Publication number
- DE1496848A1 DE1496848A1 DE19661496848 DE1496848A DE1496848A1 DE 1496848 A1 DE1496848 A1 DE 1496848A1 DE 19661496848 DE19661496848 DE 19661496848 DE 1496848 A DE1496848 A DE 1496848A DE 1496848 A1 DE1496848 A1 DE 1496848A1
- Authority
- DE
- Germany
- Prior art keywords
- electrolyte
- nickel
- anode
- galvanic
- auxiliary anode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 25
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 20
- 229910052759 nickel Inorganic materials 0.000 title claims description 10
- 230000008569 process Effects 0.000 title claims description 9
- 238000009713 electroplating Methods 0.000 title description 5
- KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical compound [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 title description 5
- 239000003792 electrolyte Substances 0.000 claims description 30
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 20
- 229910052697 platinum Inorganic materials 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 5
- 150000002815 nickel Chemical class 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000872 buffer Substances 0.000 claims description 3
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 description 9
- 238000001556 precipitation Methods 0.000 description 7
- 238000000151 deposition Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- -1 sulfamate ions Chemical class 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229940075397 calomel Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 238000005323 electroforming Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Reciprocating Pumps (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US471431A US3374154A (en) | 1965-07-12 | 1965-07-12 | Electroforming and electrodeposition of stress-free nickel from the sulfamate bath |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1496848A1 true DE1496848A1 (de) | 1969-04-17 |
Family
ID=23871608
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19661496848 Pending DE1496848A1 (de) | 1965-07-12 | 1966-07-09 | Verfahren zum galvanischen Niederschlagen von Nickel aus Nickelsulfamatbaedern |
Country Status (11)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3498890A (en) * | 1967-03-27 | 1970-03-03 | Melpar Inc | Preparation of fiber-metal composites by electrodeposition |
| US3876510A (en) * | 1972-05-08 | 1975-04-08 | Xerox Corp | Process for electroforming a flexible belt |
| FR2363643A1 (fr) * | 1976-09-01 | 1978-03-31 | Duchenaud Alain | Procede et dispositif pour la fabrication d'un cylindre a paroi epaisse perforee et cylindre obtenu |
| CA2053342A1 (en) * | 1990-10-22 | 1992-04-23 | Robert A. Tremmel | Nickel electroplating process with reduced nickel ion build up |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB526968A (en) * | 1938-12-19 | 1940-09-30 | Houdaille Hershey Corp | Improvements in or relating to methods of nickel plating and nickel plating solutions therefor |
| US2625507A (en) * | 1945-10-16 | 1953-01-13 | Stuart A Mayper | Method of electrodepositing nickel |
| US2706170A (en) * | 1951-11-15 | 1955-04-12 | Sperry Corp | Electroforming low stress nickel |
| DE1250712B (de) * | 1963-05-22 | 1967-09-21 | International Nickel Limited, London | Galvanisches Nickelsulfamatbad und Verfahren zum Abscheiden von Nickeluberzugen |
-
1965
- 1965-07-12 US US471431A patent/US3374154A/en not_active Expired - Lifetime
-
1966
- 1966-06-30 GB GB29480/66A patent/GB1081308A/en not_active Expired
- 1966-07-01 NO NO163746A patent/NO115237B/no unknown
- 1966-07-08 AT AT655966A patent/AT267273B/de active
- 1966-07-08 CH CH992666A patent/CH463903A/fr unknown
- 1966-07-09 DE DE19661496848 patent/DE1496848A1/de active Pending
- 1966-07-09 ES ES0328935A patent/ES328935A1/es not_active Expired
- 1966-07-11 FR FR69013A patent/FR1486350A/fr not_active Expired
- 1966-07-11 NL NL6609687A patent/NL6609687A/xx unknown
- 1966-07-12 LU LU51541A patent/LU51541A1/xx unknown
- 1966-07-12 BE BE683980D patent/BE683980A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES328935A1 (es) | 1967-04-16 |
| AT267273B (de) | 1968-12-27 |
| BE683980A (enrdf_load_stackoverflow) | 1967-01-12 |
| GB1081308A (en) | 1967-08-31 |
| LU51541A1 (enrdf_load_stackoverflow) | 1966-09-12 |
| US3374154A (en) | 1968-03-19 |
| CH463903A (fr) | 1968-10-15 |
| NL6609687A (enrdf_load_stackoverflow) | 1967-01-13 |
| NO115237B (enrdf_load_stackoverflow) | 1968-09-02 |
| FR1486350A (fr) | 1967-06-23 |
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