DE1301057B - Verfahren zur Polymerisation von Butadien zu einem Polymerisat mit 1, 4-cis-Struktur in Gegenwart eines jodhaltigen metallorganischen Mischkatalysators - Google Patents
Verfahren zur Polymerisation von Butadien zu einem Polymerisat mit 1, 4-cis-Struktur in Gegenwart eines jodhaltigen metallorganischen MischkatalysatorsInfo
- Publication number
- DE1301057B DE1301057B DE1963S0087510 DES0087510A DE1301057B DE 1301057 B DE1301057 B DE 1301057B DE 1963S0087510 DE1963S0087510 DE 1963S0087510 DE S0087510 A DES0087510 A DE S0087510A DE 1301057 B DE1301057 B DE 1301057B
- Authority
- DE
- Germany
- Prior art keywords
- iodine
- polymerization
- butadiene
- polymer
- give
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims description 16
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title claims description 14
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title claims description 11
- 229910052740 iodine Inorganic materials 0.000 title claims description 11
- 239000011630 iodine Substances 0.000 title claims description 11
- 229920000642 polymer Polymers 0.000 title claims description 9
- 238000006116 polymerization reaction Methods 0.000 title claims description 7
- 238000000034 method Methods 0.000 title claims description 5
- 230000008569 process Effects 0.000 title claims description 5
- 125000002524 organometallic group Chemical group 0.000 title claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- 239000010936 titanium Substances 0.000 claims description 10
- CECABOMBVQNBEC-UHFFFAOYSA-K aluminium iodide Chemical compound I[Al](I)I CECABOMBVQNBEC-UHFFFAOYSA-K 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000001603 reducing effect Effects 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- -1 aluminum halides Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- 241001517013 Calidris pugnax Species 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229910010062 TiCl3 Inorganic materials 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- SPRIOUNJHPCKPV-UHFFFAOYSA-N hydridoaluminium Chemical compound [AlH] SPRIOUNJHPCKPV-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910001505 inorganic iodide Inorganic materials 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 150000002497 iodine compounds Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1907562 | 1962-09-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1301057B true DE1301057B (de) | 1969-08-14 |
Family
ID=11154322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1963S0087510 Pending DE1301057B (de) | 1962-09-27 | 1963-09-25 | Verfahren zur Polymerisation von Butadien zu einem Polymerisat mit 1, 4-cis-Struktur in Gegenwart eines jodhaltigen metallorganischen Mischkatalysators |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE637870A (enrdf_load_stackoverflow) |
| DE (1) | DE1301057B (enrdf_load_stackoverflow) |
| GB (1) | GB1008606A (enrdf_load_stackoverflow) |
| LU (1) | LU44511A1 (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100344230B1 (ko) * | 1999-10-13 | 2002-07-24 | 금호석유화학 주식회사 | 산소분자를 이용한 하이드록시 고 1,4-시스 폴리부타디엔의 제조방법 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1134202B (de) * | 1959-06-19 | 1962-08-02 | Polymer Corp | Verfahren zur Herstellung von Butadienpolymerisaten mit cis-1, 4-Struktur |
| FR1301021A (fr) * | 1960-08-08 | 1962-08-10 | Phillips Petroleum Co | Procédé de polymérisation du butadiène en vue d'obtenir un polymère contenant un pourcentage élevé d'addition du type cis-1, 4. |
-
0
- BE BE637870D patent/BE637870A/xx unknown
-
1963
- 1963-09-25 DE DE1963S0087510 patent/DE1301057B/de active Pending
- 1963-09-25 GB GB3769763A patent/GB1008606A/en not_active Expired
- 1963-09-26 LU LU44511D patent/LU44511A1/xx unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1134202B (de) * | 1959-06-19 | 1962-08-02 | Polymer Corp | Verfahren zur Herstellung von Butadienpolymerisaten mit cis-1, 4-Struktur |
| FR1301021A (fr) * | 1960-08-08 | 1962-08-10 | Phillips Petroleum Co | Procédé de polymérisation du butadiène en vue d'obtenir un polymère contenant un pourcentage élevé d'addition du type cis-1, 4. |
Also Published As
| Publication number | Publication date |
|---|---|
| LU44511A1 (enrdf_load_stackoverflow) | 1965-03-26 |
| GB1008606A (en) | 1965-10-27 |
| BE637870A (enrdf_load_stackoverflow) |
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