DE1236778B - Mehrstufiges Verfahren zum Herstellen von verstaerkten Kunstharzplatten mittels Polyester-massen - Google Patents

Mehrstufiges Verfahren zum Herstellen von verstaerkten Kunstharzplatten mittels Polyester-massen

Info

Publication number
DE1236778B
DE1236778B DES91895A DES0091895A DE1236778B DE 1236778 B DE1236778 B DE 1236778B DE S91895 A DES91895 A DE S91895A DE S0091895 A DES0091895 A DE S0091895A DE 1236778 B DE1236778 B DE 1236778B
Authority
DE
Germany
Prior art keywords
synthetic resin
production
reinforced synthetic
stage process
resin panels
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DES91895A
Other languages
English (en)
Inventor
Pierre Paul William Varlet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chausson Usines SA
Original Assignee
Chausson Usines SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR780144A external-priority patent/FR1223346A/fr
Priority claimed from FR805633A external-priority patent/FR76338E/fr
Priority claimed from FR819600A external-priority patent/FR77236E/fr
Application filed by Chausson Usines SA filed Critical Chausson Usines SA
Publication of DE1236778B publication Critical patent/DE1236778B/de
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/12—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of short length, e.g. in the form of a mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/242—Applying crosslinking or accelerating agent onto compounding ingredients such as fillers, reinforcements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/06—Unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C15/00—Apparatus in which combustion takes place in pulses influenced by acoustic resonance in a gas mass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/12—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of short lengths, e.g. chopped filaments, staple fibres or bristles
    • B29K2105/128—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of short lengths, e.g. chopped filaments, staple fibres or bristles in the form of a mat
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/06—Unsaturated polyesters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2361—Coating or impregnation improves stiffness of the fabric other than specified as a size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/273—Coating or impregnation provides wear or abrasion resistance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Composite Materials (AREA)
  • Wood Science & Technology (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Description

BUNDESREPUBLIK DEUTSCHLAND Inta.:
CC8L 67/00 C08g
DEUTSCHES
PATENTAMT
AUSLEGESCHRIFT
Deutsche KL: 39 b-22/10
Nummei:
Aktenzeichen
Anmeldetag.
Auslegetag:
1236778
S91895IVc/39b
15 Februar 1961
16 März 1967
Gegenstand des Patents 1137 210 ist em mehrstufiges Verfahren zum Herstellen durch Hitzeharten von durch fasenges Material verstärkten Kunstharzplatten mit einer glatten, mchtklebrigen Haut auf emer Unterlage aus Fasern, die mit Metallverbindungen sowie Polyesterharzmassen, die bereits üblichen Polymerisationskatalysatoren, anpolymensierbare, ungesättigte Monomere und einen Inhibitor enthalten, imprägniert sind Das Hauptpatent ist dadurch gekennzeichnet, daß man zunächst fur sich allein die Faserunterlage mit einer Losung trankt, die mindestens em reduzierendes Metallsalz in Athylenglykol oder Abkömmlingen des Athylenglykols, gegebenenfalls zusammen mit einem leicht verdunstenden Alkohol, gelost enthält, und wobei man dann mit der Polyestermasse imprägniert, wobei diese Polyestermasse in äußerst feiner Verteilung m die vorbereitete Unterlage gebracht wird, und wobei man schließlich wenigstens eme Oberfläche der Platte emer Oberflachenbehandlung unterwirft und an- ao schließend in dei Hitze verpreßt
Es hat sich nua gezeigt, daß man die nichtklebrige Haut der Kunstharzplatten durch Oberflachenbehandlung mit Merkaptanen besonders gunstig bilden kann Bevorzugt wird Laurylmerkaptan verwendet
Außer der durch das Laurylmerkaptan erhaltenen Beschleunigung der Polymerisation, die zur Bildung emer glatten, mchtklebrigen Haut auf der Oberflache des Gels fuhrt, eihalt man so einen »fetten« Überzug, der die spatere Bearbeitung der Platten bzw Folien erheblich erleichtert Dadurch ist es spater insbesondere bei Verwendung bewahrter Harzfolien in Ziehwerkzeugen nicht mehr erforderlich, diese Werkzeuge derart fern zu bearbeiten bzw zu polieren, wie dies bisher zur Verhütung einer unerwünschten Haftung des Harzes an der Oberflache der Ziehwerkzeuge bei dei Verformung von Fohen aus getränktem Harz der Fall war

Claims (1)

  1. Patentanspruch
    Mehrstufiges Verfahren zum Herstellen durch Hitzeharten von durch faseriges Material verstärkten Kunstharzplatten mit einer glatten, nichtklebngen Haul auf emer Unterlage aus Fasern, die mit Metallverbindungen sowie Polyesterharzmassen, die bereits ubhchen Polymensations-Mehrstufiges Verfahren zum Herstellen von
    verstärkten Kunstharzplatten mittels Polyestermassen
    Zusatz zum Patent 1137 210
DES91895A 1958-11-26 1961-02-15 Mehrstufiges Verfahren zum Herstellen von verstaerkten Kunstharzplatten mittels Polyester-massen Pending DE1236778B (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR780144A FR1223346A (fr) 1958-11-26 1958-11-26 Procédé pour la fabrication de feuilles en résine synthétique et produit obtenu par ce procédé
FR805633A FR76338E (fr) 1959-09-21 1959-09-21 Procédé pour la fabrication de feuilles en résine synthétique et produit obtenu par ce procédé
FR819600A FR77236E (fr) 1960-02-25 1960-02-25 Procédé pour la fabrication de feuilles en résine synthétique et produit obtenu par ce procédé
FR845923 1960-12-05

Publications (1)

Publication Number Publication Date
DE1236778B true DE1236778B (de) 1967-03-16

Family

ID=27445107

Family Applications (2)

Application Number Title Priority Date Filing Date
DES91895A Pending DE1236778B (de) 1958-11-26 1961-02-15 Mehrstufiges Verfahren zum Herstellen von verstaerkten Kunstharzplatten mittels Polyester-massen
DES76686A Pending DE1187370B (de) 1958-11-26 1961-11-14 Verfahren zum Herstellen von faserverstaerkten Polyesterplatten

Family Applications After (1)

Application Number Title Priority Date Filing Date
DES76686A Pending DE1187370B (de) 1958-11-26 1961-11-14 Verfahren zum Herstellen von faserverstaerkten Polyesterplatten

Country Status (9)

Country Link
US (3) US3116160A (de)
BE (2) BE610330A (de)
CH (3) CH390540A (de)
DE (2) DE1236778B (de)
FR (1) FR78790E (de)
GB (2) GB938403A (de)
IT (1) IT699989A (de)
NL (5) NL128612C (de)
SE (2) SE307666B (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3411940A (en) * 1963-06-20 1968-11-19 Shell Oil Co Process for coating surfaces with polyepoxide compositions
US3457095A (en) * 1963-08-05 1969-07-22 Owens Illinois Inc Method of fabricating transparent reinforced glass pipe
US3546000A (en) * 1968-01-23 1970-12-08 Koppers Co Inc Method for impregnating glass filament reinforcement rovings
US3650802A (en) * 1969-03-07 1972-03-21 Grace W R & Co Process for coating a substrate with a polyene/polythiol composition
US3793130A (en) * 1971-03-09 1974-02-19 Owens Corning Fiberglass Corp Fiber reinforced elastomers
US4085180A (en) * 1973-01-19 1978-04-18 Stoffey Donald G Method for rigid enclosures and molded items
US4012542A (en) * 1973-04-23 1977-03-15 Ferro Corporation Rigid thermosetting load bearing compositions
US3988516A (en) * 1974-02-01 1976-10-26 Basf Aktiengesellschaft Manufacture of bonded textile sheet structures
US4012553A (en) * 1974-08-01 1977-03-15 Minnesota Mining And Manufacturing Company Resinous repair pad
US4123488A (en) * 1977-09-06 1978-10-31 Lawson David E Molded plastic article and method of making the same
US4242406A (en) * 1979-04-30 1980-12-30 Ppg Industries, Inc. Fiber reinforced composite structural laminate composed of two layers tied to one another by embedded fibers bridging both layers
FR2686874B1 (fr) * 1992-02-04 1994-09-23 Europ Propulsion Procede de fabrication de pieces en materiau composite a matrice ceramique.
CN101531875A (zh) * 2009-03-25 2009-09-16 武汉市科达云石护理材料有限公司 石材勾缝胶
WO2011124282A1 (en) * 2010-04-08 2011-10-13 Dsm Ip Assets B.V. Unsaturated polyester resin or vinyl ester resin compositions
CN104497812A (zh) * 2014-12-11 2015-04-08 三棵树涂料股份有限公司 应用于三聚氰胺底材免打磨的不饱和聚酯底漆及其制备方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2654717A (en) * 1948-10-29 1953-10-06 Chessie E Rehberg Curing polymers of monoethylenic ethers and ether-esters
US2967117A (en) * 1949-01-25 1961-01-03 Bayer Ag Process for coating a substrate with a mixture of a polyhydroxy polyester and a polyisocyanate
US2684305A (en) * 1951-01-09 1954-07-20 Celastic Corp Process of effecting polymerization
US2740764A (en) * 1951-12-01 1956-04-03 Bayer Ag Polymerization of ethylenically unsaturated polyesters with vinyl compounds
US2932598A (en) * 1954-08-12 1960-04-12 Bjorksten Res Lab Inc Glass fiber treatment
US3010929A (en) * 1954-10-20 1961-11-28 Celanese Corp Emulsion polymerization of vinyl acetate in the presence of additives
BE543914A (de) * 1954-12-23 1900-01-01
US2813751A (en) * 1955-04-18 1957-11-19 Sealzit Company Of America Plastic spraying apparatus
US2866722A (en) * 1955-05-20 1958-12-30 Bayer Ag Process for the production of foamed urethan coatings
US2931739A (en) * 1956-10-08 1960-04-05 Owens Corning Fiberglass Corp Plastics and laminates formed of glass fibers and epoxy resins
BE563462A (de) * 1956-12-27 1900-01-01
US3159500A (en) * 1957-06-05 1964-12-01 Glidden Co Method of converting a polyester coating
US2978354A (en) * 1958-03-18 1961-04-04 David K Lesser Method of applying a coating
NL245380A (de) * 1958-12-02
US3097963A (en) * 1959-03-30 1963-07-16 Owens Corning Fiberglass Corp Sized glass fibers and composition
US3009824A (en) * 1959-08-03 1961-11-21 California Research Corp Process for reinforcing a ferrous metal surface

Also Published As

Publication number Publication date
NL129041C (de) 1900-01-01
GB938403A (en) 1963-10-02
US3250640A (en) 1966-05-10
SE300509B (de) 1968-04-29
GB1012233A (en) 1965-12-08
BE610330A (de) 1900-01-01
CH390540A (fr) 1965-04-15
BE599957A (de) 1900-01-01
US3116160A (en) 1963-12-31
NL128612C (de) 1900-01-01
IT699989A (de) 1900-01-01
NL271434A (de) 1900-01-01
CH416080A (fr) 1966-06-30
NL245236A (de) 1900-01-01
NL128927C (de) 1900-01-01
FR78790E (fr) 1962-09-07
SE307666B (de) 1969-01-13
DE1187370B (de) 1965-02-18
US3271182A (en) 1966-09-06
CH409390A (fr) 1966-03-15

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