DE1236302B - Verfahren zur Aktivierung der Oberflaechen von Metallen - Google Patents
Verfahren zur Aktivierung der Oberflaechen von MetallenInfo
- Publication number
- DE1236302B DE1236302B DEJ23773A DEJ0023773A DE1236302B DE 1236302 B DE1236302 B DE 1236302B DE J23773 A DEJ23773 A DE J23773A DE J0023773 A DEJ0023773 A DE J0023773A DE 1236302 B DE1236302 B DE 1236302B
- Authority
- DE
- Germany
- Prior art keywords
- platinum
- mercury
- amalgam
- metals
- heated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 17
- 239000002184 metal Substances 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 14
- 150000002739 metals Chemical class 0.000 title claims description 9
- 230000003213 activating effect Effects 0.000 title claims description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 58
- 229910052697 platinum Inorganic materials 0.000 claims description 25
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 19
- 229910052753 mercury Inorganic materials 0.000 claims description 17
- 239000000956 alloy Substances 0.000 claims description 9
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- 238000005868 electrolysis reaction Methods 0.000 claims description 7
- 229910000497 Amalgam Inorganic materials 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- MJGFBOZCAJSGQW-UHFFFAOYSA-N mercury sodium Chemical compound [Na].[Hg] MJGFBOZCAJSGQW-UHFFFAOYSA-N 0.000 claims description 6
- 229910001023 sodium amalgam Inorganic materials 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000012670 alkaline solution Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 229910000629 Rh alloy Inorganic materials 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- -1 platinum group metals Chemical class 0.000 claims description 3
- 229910001316 Ag alloy Inorganic materials 0.000 claims description 2
- 230000004913 activation Effects 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- SWELZOZIOHGSPA-UHFFFAOYSA-N palladium silver Chemical compound [Pd].[Ag] SWELZOZIOHGSPA-UHFFFAOYSA-N 0.000 claims description 2
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000005267 amalgamation Methods 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910000567 Amalgam (chemistry) Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8892—Impregnation or coating of the catalyst layer, e.g. by an ionomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US197938A US3202594A (en) | 1962-05-28 | 1962-05-28 | Process for activating platinum electrodes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1236302B true DE1236302B (de) | 1967-03-09 |
Family
ID=22731352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEJ23773A Pending DE1236302B (de) | 1962-05-28 | 1963-05-25 | Verfahren zur Aktivierung der Oberflaechen von Metallen |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3202594A (en:Method) |
| BE (1) | BE632894A (en:Method) |
| DE (1) | DE1236302B (en:Method) |
| GB (1) | GB957703A (en:Method) |
| MC (1) | MC407A1 (en:Method) |
| NL (2) | NL293258A (en:Method) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3444003A (en) * | 1965-09-30 | 1969-05-13 | Leesona Corp | Multilayer catalytic electrode having a layer of noble metal and lead and a surface layer free of lead and method of constructing same |
| BE756437A (fr) * | 1969-09-22 | 1971-03-01 | Progil | Bac d'electrolyse avec nouvel ensemble anodique |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1427171A (en) * | 1920-11-08 | 1922-08-29 | Albert W Smith | Electrolytic apparatus |
| US1940934A (en) * | 1931-03-16 | 1933-12-26 | Catalyst Research Corp | Method of making supported catalysts |
| US2760912A (en) * | 1951-09-26 | 1956-08-28 | Kellogg M W Co | Platinum and palladium catalysts in catalyzed reactions |
| US3055811A (en) * | 1961-05-08 | 1962-09-25 | Universal Oil Prod Co | Electrolysis with improved platinum plated titanium anode and manufacture thereof |
-
0
- NL NL125889D patent/NL125889C/xx active
- BE BE632894D patent/BE632894A/xx unknown
- NL NL293258D patent/NL293258A/xx unknown
-
1962
- 1962-05-28 US US197938A patent/US3202594A/en not_active Expired - Lifetime
-
1963
- 1963-01-30 GB GB3795/63A patent/GB957703A/en not_active Expired
- 1963-05-25 DE DEJ23773A patent/DE1236302B/de active Pending
- 1963-05-27 MC MC438A patent/MC407A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE632894A (en:Method) | |
| MC407A1 (fr) | 1964-01-28 |
| US3202594A (en) | 1965-08-24 |
| NL125889C (en:Method) | |
| NL293258A (en:Method) | |
| GB957703A (en) | 1964-05-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2810308C2 (de) | Verfahren zum elektrolytischen Körnen von Aluminium | |
| DE1115721B (de) | Verfahren zur Herstellung einer Elektrode mit einem Titankern und einer poroesen Deckschicht aus Edelmetall | |
| DE1796220B2 (de) | Verfahren zur Herstellung einer Elektrode zur Verwendung bei elektrolytischen Verfahren | |
| DE2063238A1 (de) | Verfahren zur Herstellung einer Elektrode zur Verwendung bei elektrolytischen Prozessen | |
| DE2157511B2 (de) | Verfahren zum erneuten Aufbringen von Überzügen aufgebrauchte, dimensionsstabile Elektroden | |
| DE1281232B (de) | Anode fuer den kathodischen Korrosionsschutz | |
| DE1421370B2 (de) | Verfahren zur Herstellung von Aufbauten aus einem Titangrundkörper mit einer Oberfläche aus einem Platinmetall zur Anwendung als Anoden in Elektrolysezellen | |
| DE1496937A1 (de) | Verfahren zum UEberziehen von Metalloberflaechen mit Aluminium durch Elektrolyse in Salzschmelzbaedern | |
| DE1170378B (de) | Verfahren zur Herstellung einer aktivierten, mit Platin plattierten Titananode | |
| DE592130C (de) | Verfahren zur Herstellung von Elektroden mit fein gerauhter Oberflaeche fuer elektrolytische Apparate | |
| DE1671426A1 (de) | Elektrode und Verfahren zu ihrer Herstellung | |
| DE3447733A1 (de) | Verfahren zur elektrolytischen behandlung von metall durch energiezufuhr mittels fluessigkeit | |
| DE3815585A1 (de) | Verfahren zum elektrolytischen behandeln von metallen | |
| DE715515C (de) | Verfahren zur anodischen Vorbehandlung zuvor in ueblicher Weise entfetteter Metalloberflaechen | |
| DE1909757B2 (de) | Verfahren zur reinigung von anoden fuer elektrolytische prozesse, die aus einer unterlage eines filmbildenden metalls und einem ueberzug aus edelmetallen, edelmetalloiden oder edelmetalloxide enthaltenden mischoxiden bestehen | |
| DE2008335A1 (de) | Verfahren zum Entfernen von leitenden Schichten auf formbeständigen Elektroden | |
| DE2232903C3 (de) | Verfahren zur elektrolytischen Raffination von Kupfer unter Verwendung von Titanelektroden | |
| DE1236302B (de) | Verfahren zur Aktivierung der Oberflaechen von Metallen | |
| DE1256504B (de) | Verfahren zur galvanischen Herstellung unloeslicher Anoden fuer elektrochemische Prozesse | |
| DE483948C (de) | Verfahren zur Herstellung von Oxydkathoden fuer Gluehkathodenroehren | |
| DE1521875A1 (de) | Verfahren zum Schuetzen von Titan gegen das AEtzen | |
| DE1944388B2 (de) | Verfahren zum elektrolytischen beizen und entzundern von zinnhaltigen titanlegierungen | |
| DE2114543A1 (de) | Verfahren zur Herstellung von Elektroden und deren Verwendung | |
| DE2310638C2 (de) | Verfahren zum Umwandeln hydrophober Oberflächen aus Aluminium, Aluminiumlegierungen, Kupfer oder Kupferlegierungen in hydrophile Oberflächen | |
| DE1052771B (de) | Verfahren zum elektrolytischen Abscheiden von Platin |