DE1217607B - Vulkanisierbare Formmassen aus Polyaethylen - Google Patents
Vulkanisierbare Formmassen aus PolyaethylenInfo
- Publication number
- DE1217607B DE1217607B DEF38183A DEF0038183A DE1217607B DE 1217607 B DE1217607 B DE 1217607B DE F38183 A DEF38183 A DE F38183A DE F0038183 A DEF0038183 A DE F0038183A DE 1217607 B DE1217607 B DE 1217607B
- Authority
- DE
- Germany
- Prior art keywords
- polyethylene
- nitrite
- tert
- peroxide
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 polyethylene Polymers 0.000 title claims description 40
- 229920000573 polyethylene Polymers 0.000 title claims description 36
- 239000004698 Polyethylene Substances 0.000 title claims description 34
- 238000000465 moulding Methods 0.000 title claims description 7
- 150000001875 compounds Chemical class 0.000 title claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 239000000945 filler Substances 0.000 claims description 8
- 125000000864 peroxy group Chemical group O(O*)* 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- 150000001451 organic peroxides Chemical class 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 description 23
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 19
- 241001441571 Hiodontidae Species 0.000 description 13
- 230000006835 compression Effects 0.000 description 9
- 238000007906 compression Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- OWFXIOWLTKNBAP-UHFFFAOYSA-N isoamyl nitrite Chemical compound CC(C)CCON=O OWFXIOWLTKNBAP-UHFFFAOYSA-N 0.000 description 7
- 150000002826 nitrites Chemical class 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 5
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000004073 vulcanization Methods 0.000 description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- DAQIQPHKWNXNKB-UHFFFAOYSA-N 2-ethylhexyl nitrite Chemical compound CCCCC(CC)CON=O DAQIQPHKWNXNKB-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- YKTNISGZEGZHIS-UHFFFAOYSA-N 2-$l^{1}-oxidanyloxy-2-methylpropane Chemical group CC(C)(C)O[O] YKTNISGZEGZHIS-UHFFFAOYSA-N 0.000 description 2
- KRDXTHSSNCTAGY-UHFFFAOYSA-N 2-cyclohexylpyrrolidine Chemical compound C1CCNC1C1CCCCC1 KRDXTHSSNCTAGY-UHFFFAOYSA-N 0.000 description 2
- JXCNBASKFCBVAN-UHFFFAOYSA-N 2-methylbutan-2-yl nitrite Chemical compound CCC(C)(C)ON=O JXCNBASKFCBVAN-UHFFFAOYSA-N 0.000 description 2
- SGVYKUFIHHTIFL-UHFFFAOYSA-N 2-methylnonane Chemical compound CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 2
- 241000872198 Serjania polyphylla Species 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000002144 chemical decomposition reaction Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- NRCNZCLHYWKEDX-UHFFFAOYSA-N cyclohexyl nitrite Chemical compound O=NOC1CCCCC1 NRCNZCLHYWKEDX-UHFFFAOYSA-N 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- QRUUDTPJSZPUOW-UHFFFAOYSA-N 2,5-dimethyl-1-(2-methylbutan-2-ylperoxy)hexane Chemical compound CCC(C)(C)OOCC(C)CCC(C)C QRUUDTPJSZPUOW-UHFFFAOYSA-N 0.000 description 1
- BWOITHKYQUJGSB-UHFFFAOYSA-N 2-methylbutan-2-ylperoxycyclohexane Chemical compound CCC(C)(C)OOC1CCCCC1 BWOITHKYQUJGSB-UHFFFAOYSA-N 0.000 description 1
- UVTIZRNEWKAOEM-UHFFFAOYSA-N 2-tert-butylperoxy-2-methylbutane Chemical compound CCC(C)(C)OOC(C)(C)C UVTIZRNEWKAOEM-UHFFFAOYSA-N 0.000 description 1
- FGHPXAKHUFZDRY-UHFFFAOYSA-N 3-ethyl-3-(3-ethylpentan-3-ylperoxy)pentane Chemical compound CCC(CC)(CC)OOC(CC)(CC)CC FGHPXAKHUFZDRY-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 229910021386 carbon form Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- SXUKVAAVKCDPPR-UHFFFAOYSA-N decyl nitrite Chemical compound CCCCCCCCCCON=O SXUKVAAVKCDPPR-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- JMAPCNOXSIMIBG-UHFFFAOYSA-N hexadecyl nitrite Chemical compound CCCCCCCCCCCCCCCCON=O JMAPCNOXSIMIBG-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- MYCGLJRATIRCNC-UHFFFAOYSA-N octadecyl nitrite Chemical compound CCCCCCCCCCCCCCCCCCON=O MYCGLJRATIRCNC-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/32—Compounds containing nitrogen bound to oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US150875A US3202648A (en) | 1961-11-08 | 1961-11-08 | Scorch-resistant polyethylene compositions and method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1217607B true DE1217607B (de) | 1966-05-26 |
Family
ID=22536378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF38183A Pending DE1217607B (de) | 1961-11-08 | 1962-10-29 | Vulkanisierbare Formmassen aus Polyaethylen |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3202648A (enExample) |
| DE (1) | DE1217607B (enExample) |
| GB (1) | GB1007818A (enExample) |
| NL (2) | NL285276A (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3449191A (en) * | 1964-02-03 | 1969-06-10 | Boeing Co | Polymer bonding process and product |
| US3891597A (en) * | 1970-12-21 | 1975-06-24 | Phillips Petroleum Co | Rotational molding of crosslinkable polymers |
| JPS5148196B2 (enExample) * | 1972-03-11 | 1976-12-18 | ||
| US4015058A (en) * | 1974-11-27 | 1977-03-29 | Union Carbide Corporation | Composition with dicumyl peroxide and process for avoiding scorching of ethylene polymer composition |
| JP2855875B2 (ja) * | 1990-04-16 | 1999-02-10 | 日本油脂株式会社 | エチレン系ポリマーの架橋可能な組成物及び架橋方法 |
| CA2063478A1 (en) | 1991-03-22 | 1992-09-23 | Michael F. Novits | Scorch extending curing/crosslinking compositions |
| US5272213A (en) * | 1992-05-14 | 1993-12-21 | Air Products And Chemicals, Inc. | Scorch retardant polyacrylate elastomers |
| US20040198920A1 (en) * | 2003-04-03 | 2004-10-07 | Atofina | Scorch-retardant composition |
| FR2875502B1 (fr) * | 2004-09-22 | 2007-01-05 | Arkema Sa | Composition retardant le grillage |
| EP2070127B2 (en) | 2006-09-20 | 2015-09-02 | Dow Global Technologies LLC | Electronic device module comprising an ethylene multi-block copolymer |
| US20080115825A1 (en) | 2006-09-20 | 2008-05-22 | Patel Rajen M | Electronic Device Module Comprising an Ethylene Multi-Block Copolymer |
| US8581094B2 (en) * | 2006-09-20 | 2013-11-12 | Dow Global Technologies, Llc | Electronic device module comprising polyolefin copolymer |
| US7465769B2 (en) * | 2006-10-09 | 2008-12-16 | Dow Global Technologies Inc. | Nitroxide compounds for minimizing scorch in crosslinkable compositions |
| US20100120955A1 (en) * | 2007-03-14 | 2010-05-13 | Chaudhary Bharat I | Isocyanate, Diisocyanate and (Meth) Acrylate Compounds for Minimizing Scorch and Diisocyanate Compounds for Promoting Cure in Crosslinkable Compositions |
| CN101778896A (zh) * | 2007-06-08 | 2010-07-14 | 联合碳化化学及塑料技术有限责任公司 | 抑焦剂迁移低的可交联组合物,降低这种迁移的方法,以及由该组合物制成的制品 |
| US20110290317A1 (en) | 2010-05-26 | 2011-12-01 | John Naumovitz | Electronic device module comprising polyolefin copolymer with low unsaturation and optional vinyl silane |
| EP2576686A1 (en) | 2010-06-04 | 2013-04-10 | Dow Global Technologies LLC | Electronic device module comprising film of homogeneous polyolefin copolymer and adhesive property enhancing graft polymer |
| EP2576639A1 (en) | 2010-06-04 | 2013-04-10 | Dow Global Technologies LLC | Electronic device module comprising film of homogeneous polyolefin copolymer and grafted silane |
| WO2011163025A1 (en) | 2010-06-24 | 2011-12-29 | Dow Global Technologies Llc | Electronic device module comprising heterogeneous polyolefin copolymer and optionally silane |
| JP2013539596A (ja) | 2010-06-24 | 2013-10-24 | ダウ グローバル テクノロジーズ エルエルシー | エチレンの長鎖分岐した（ｌｃｂ）、ブロック、または相互接続されたコポリマー、および場合によってはシランを含む電子素子モジュール |
| CN108384033B (zh) | 2012-02-03 | 2021-11-12 | 陶氏环球技术有限责任公司 | 包括含硅烷乙烯互聚物配方的膜和包括其的电子设备模块 |
| EP3048649A1 (en) | 2015-01-23 | 2016-07-27 | Yparex B.V. | Electronic device module |
-
0
- NL NL124035D patent/NL124035C/xx active
- NL NL285276D patent/NL285276A/xx unknown
-
1961
- 1961-11-08 US US150875A patent/US3202648A/en not_active Expired - Lifetime
-
1962
- 1962-10-08 GB GB37936/62A patent/GB1007818A/en not_active Expired
- 1962-10-29 DE DEF38183A patent/DE1217607B/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US3202648A (en) | 1965-08-24 |
| NL124035C (enExample) | |
| NL285276A (enExample) | |
| GB1007818A (en) | 1965-10-22 |
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