DE1193923B - Verfahren zur Herstellung von Hydroxylamin - Google Patents
Verfahren zur Herstellung von HydroxylaminInfo
- Publication number
- DE1193923B DE1193923B DEJ24035A DEJ0024035A DE1193923B DE 1193923 B DE1193923 B DE 1193923B DE J24035 A DEJ24035 A DE J24035A DE J0024035 A DEJ0024035 A DE J0024035A DE 1193923 B DE1193923 B DE 1193923B
- Authority
- DE
- Germany
- Prior art keywords
- hydroxylamine
- platinum
- solution
- reaction solution
- reduction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 title claims description 15
- 238000000034 method Methods 0.000 title claims description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 30
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 25
- 239000000243 solution Substances 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 17
- 229910052697 platinum Inorganic materials 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 150000002443 hydroxylamines Chemical class 0.000 claims description 4
- 238000006722 reduction reaction Methods 0.000 claims description 4
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 4
- 239000003929 acidic solution Substances 0.000 claims description 3
- 238000010531 catalytic reduction reaction Methods 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 5
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical compound O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910001260 Pt alloy Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229940000488 arsenic acid Drugs 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229910001020 Au alloy Inorganic materials 0.000 description 1
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 1
- 235000010624 Medicago sativa Nutrition 0.000 description 1
- 240000004658 Medicago sativa Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- VGYYSIDKAKXZEE-UHFFFAOYSA-L hydroxylammonium sulfate Chemical compound O[NH3+].O[NH3+].[O-]S([O-])(=O)=O VGYYSIDKAKXZEE-UHFFFAOYSA-L 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/14—Hydroxylamine; Salts thereof
- C01B21/1409—Preparation
- C01B21/1418—Preparation by catalytic reduction of nitrogen oxides or nitrates with hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH845162A CH427758A (de) | 1962-07-13 | 1962-07-13 | Verfahren zur Herstellung von Hydroxylamin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1193923B true DE1193923B (de) | 1965-06-03 |
Family
ID=4340558
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEJ24035A Pending DE1193923B (de) | 1962-07-13 | 1963-07-10 | Verfahren zur Herstellung von Hydroxylamin |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3295925A (enrdf_load_stackoverflow) |
| AT (1) | AT242103B (enrdf_load_stackoverflow) |
| BE (1) | BE634876A (enrdf_load_stackoverflow) |
| CH (1) | CH427758A (enrdf_load_stackoverflow) |
| DE (1) | DE1193923B (enrdf_load_stackoverflow) |
| DK (1) | DK104933C (enrdf_load_stackoverflow) |
| ES (1) | ES288701A1 (enrdf_load_stackoverflow) |
| FI (1) | FI43181B (enrdf_load_stackoverflow) |
| GB (1) | GB1039866A (enrdf_load_stackoverflow) |
| NL (1) | NL295133A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4192856A (en) | 1977-08-16 | 1980-03-11 | Basf Aktiengesellschaft | Manufacture of hydroxylammonium salts |
| EP0059366A1 (de) * | 1981-02-28 | 1982-09-08 | BASF Aktiengesellschaft | Verfahren zur kontinuierlichen Herstellung von Hydroxylammoniumsalzen |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL136781C (enrdf_load_stackoverflow) * | 1965-05-01 | |||
| DE1567513B2 (de) * | 1965-12-28 | 1975-05-28 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Hydroxylammoniumsalzen |
| CH583588A5 (enrdf_load_stackoverflow) * | 1973-10-10 | 1977-01-14 | Inventa Ag | |
| CH585581A5 (enrdf_load_stackoverflow) * | 1974-03-21 | 1977-03-15 | Inventa Ag | |
| US3954946A (en) * | 1974-07-18 | 1976-05-04 | Inventa Ag Fur Forschung Und Patentverwertung, Zurich | Process for reacting nitric oxide with hydrogen |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL74063C (enrdf_load_stackoverflow) * | 1949-08-27 | |||
| US3009779A (en) * | 1953-02-25 | 1961-11-21 | Basf Ag | Production of hydroxylamine |
| DE956038C (de) * | 1954-04-01 | 1957-01-10 | Basf Ag | Verfahren zur Herstellung von Hydroxylammoniumsalzen |
-
0
- NL NL295133D patent/NL295133A/xx unknown
- BE BE634876D patent/BE634876A/xx unknown
-
1962
- 1962-07-13 CH CH845162A patent/CH427758A/de unknown
-
1963
- 1963-06-04 ES ES288701A patent/ES288701A1/es not_active Expired
- 1963-06-21 AT AT498263A patent/AT242103B/de active
- 1963-07-09 US US293609A patent/US3295925A/en not_active Expired - Lifetime
- 1963-07-10 DE DEJ24035A patent/DE1193923B/de active Pending
- 1963-07-12 DK DK333763AA patent/DK104933C/da active
- 1963-07-12 FI FI1383/63A patent/FI43181B/fi active
- 1963-07-12 GB GB27748/63A patent/GB1039866A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4192856A (en) | 1977-08-16 | 1980-03-11 | Basf Aktiengesellschaft | Manufacture of hydroxylammonium salts |
| EP0059366A1 (de) * | 1981-02-28 | 1982-09-08 | BASF Aktiengesellschaft | Verfahren zur kontinuierlichen Herstellung von Hydroxylammoniumsalzen |
| US4477424A (en) * | 1981-02-28 | 1984-10-16 | Basf Aktiengesellschaft | Continuous preparation of hydroxylammonium salts |
Also Published As
| Publication number | Publication date |
|---|---|
| AT242103B (de) | 1965-08-25 |
| FI43181B (enrdf_load_stackoverflow) | 1970-11-02 |
| CH427758A (de) | 1967-01-15 |
| DK104933C (da) | 1966-07-25 |
| GB1039866A (en) | 1966-08-24 |
| BE634876A (enrdf_load_stackoverflow) | |
| US3295925A (en) | 1967-01-03 |
| ES288701A1 (es) | 1963-08-01 |
| NL295133A (enrdf_load_stackoverflow) |
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