DE1153729B - Verfahren zur Entfernung von Schwefel-wasserstoff aus Gasen, Gasgemischen oder fluessigen Kohlenwasserstoffen durch Umsetzung zu elementarem Schwefel - Google Patents

Verfahren zur Entfernung von Schwefel-wasserstoff aus Gasen, Gasgemischen oder fluessigen Kohlenwasserstoffen durch Umsetzung zu elementarem Schwefel

Info

Publication number
DE1153729B
DE1153729B DEN20638A DEN0020638A DE1153729B DE 1153729 B DE1153729 B DE 1153729B DE N20638 A DEN20638 A DE N20638A DE N0020638 A DEN0020638 A DE N0020638A DE 1153729 B DE1153729 B DE 1153729B
Authority
DE
Germany
Prior art keywords
hydrogen sulfide
washing solution
iron
gas
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEN20638A
Other languages
German (de)
English (en)
Inventor
Thomas Nicklin
Whalley Range
Anthony William Sommerville
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clayton Aniline Co Ltd
North Western Gas Board
Original Assignee
Clayton Aniline Co Ltd
North Western Gas Board
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clayton Aniline Co Ltd, North Western Gas Board filed Critical Clayton Aniline Co Ltd
Publication of DE1153729B publication Critical patent/DE1153729B/de
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/12—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
    • C10K1/128—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors containing organic oxygen transferring compounds, e.g. sulfoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • B01D53/523—Mixtures of hydrogen sulfide and sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/05—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/14875—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Water Supply & Treatment (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
DEN20638A 1960-10-12 1961-10-06 Verfahren zur Entfernung von Schwefel-wasserstoff aus Gasen, Gasgemischen oder fluessigen Kohlenwasserstoffen durch Umsetzung zu elementarem Schwefel Pending DE1153729B (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB3489860A GB948270A (en) 1960-10-12 1960-10-12 Improvements relating to the removal of hydrogen sulphide
GB4331761 1960-12-16

Publications (1)

Publication Number Publication Date
DE1153729B true DE1153729B (de) 1963-09-05

Family

ID=10371278

Family Applications (1)

Application Number Title Priority Date Filing Date
DEN20638A Pending DE1153729B (de) 1960-10-12 1961-10-06 Verfahren zur Entfernung von Schwefel-wasserstoff aus Gasen, Gasgemischen oder fluessigen Kohlenwasserstoffen durch Umsetzung zu elementarem Schwefel

Country Status (8)

Country Link
BE (1) BE609049A (ru)
CH (2) CH414903A (ru)
DE (1) DE1153729B (ru)
DK (1) DK102815C (ru)
ES (1) ES270949A1 (ru)
GB (1) GB948270A (ru)
MY (1) MY6500038A (ru)
NL (2) NL136828C (ru)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1979000516A1 (en) * 1978-01-17 1979-08-09 Murex Ltd Soluble compound of vanadium

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1014929A (en) * 1973-09-11 1977-08-02 David Krofchak Limited Recovery of sodium thiocyanate
US3933993A (en) * 1974-06-28 1976-01-20 General Electric Company Use of concentrated chelated iron reagent for reducing pollutant content of a fluid
GB1505996A (en) * 1974-08-27 1978-04-05 British Gas Corp Gas purification liquors
US4206194A (en) 1975-05-21 1980-06-03 Union Oil Company Of California Reducing the consumption of anthraquinone disulfonate in stretford solutions
US4060594A (en) * 1975-05-21 1977-11-29 Union Oil Company Of California Reducing the consumption of anthraquinone disulfonate in stretford solutions
US4315903A (en) 1975-05-21 1982-02-16 Union Oil Company Of California Reducing the consumption of anthraquinone disulfonate in stretford solutions
US4125597A (en) * 1976-02-04 1978-11-14 Union Oil Company Of California Method of removing hydrogen sulfide from gas
US4251492A (en) 1978-06-07 1981-02-17 Ciba-Geigy Corporation Purification process
US4251493A (en) * 1978-07-21 1981-02-17 Ciba-Geigy Corporation Gas purification process
DE2906056A1 (de) * 1979-02-16 1980-08-28 Linde Ag Verfahren zur rueckgewinnung der salze der anthrachinondisulfonsaeure aus einem waschfluessigkeitsstrom
DE2912115C3 (de) * 1979-03-27 1986-05-28 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zur selektiven Entschwefelung von Gasen
US4325936A (en) 1979-06-20 1982-04-20 Union Oil Company Of California Method for removing hydrogen sulfide from gas streams
US4432962A (en) * 1979-06-20 1984-02-21 Union Oil Company Of California Method for removing hydrogen sulfide from gas streams
US4272291A (en) 1980-01-02 1981-06-09 Shtern Maria A Heat-reflective enamel
US4400361A (en) * 1982-03-30 1983-08-23 Purtec Systems, Inc. Method of removing H2 S from a gas stream utilizing boron-vanadium and iron complexes
GB2125779B (en) * 1982-08-19 1986-01-29 Nippon Shokubai Kagaku Gogyo C Desulfurization of h2s-containing gases
FR2542630B1 (fr) * 1983-03-18 1987-11-13 Inst Francais Du Petrole Procede de preparation d'un catalyseur d'oxydation des mercaptans en disulfures et application de ce catalyseur a l'adoucissement des distillats petroliers
GB2166453B (en) * 1984-08-01 1987-10-28 Ciba Geigy Ag Purification process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1979000516A1 (en) * 1978-01-17 1979-08-09 Murex Ltd Soluble compound of vanadium

Also Published As

Publication number Publication date
ES270949A1 (es) 1962-01-01
MY6500038A (en) 1965-12-31
NL136828C (ru)
DK102815C (da) 1965-10-11
NL270089A (ru)
GB948270A (en) 1964-01-29
CH414903A (de) 1966-06-15
BE609049A (ru)
CH410260A (fr) 1966-03-31

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