DE1148235B - Verfahren zur Herstellung von Acylierungsprodukten der phosphorigen Saeure mit mindestens 2 Phosphoratomen im Molekuel - Google Patents
Verfahren zur Herstellung von Acylierungsprodukten der phosphorigen Saeure mit mindestens 2 Phosphoratomen im MolekuelInfo
- Publication number
- DE1148235B DE1148235B DEH43035A DEH0043035A DE1148235B DE 1148235 B DE1148235 B DE 1148235B DE H43035 A DEH43035 A DE H43035A DE H0043035 A DEH0043035 A DE H0043035A DE 1148235 B DE1148235 B DE 1148235B
- Authority
- DE
- Germany
- Prior art keywords
- water
- acid
- phosphorous acid
- molecule
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 10
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 title claims description 8
- 230000010933 acylation Effects 0.000 title claims description 7
- 238000005917 acylation reaction Methods 0.000 title claims description 7
- 125000004437 phosphorous atom Chemical group 0.000 title claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 8
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 claims description 6
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000000047 product Substances 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 7
- 229910052698 phosphorus Inorganic materials 0.000 description 7
- 239000011574 phosphorus Substances 0.000 description 7
- 239000011541 reaction mixture Substances 0.000 description 7
- 238000001816 cooling Methods 0.000 description 6
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 5
- 239000012346 acetyl chloride Substances 0.000 description 5
- -1 acetic acid Carboxylic acids Chemical class 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000005711 Benzoic acid Substances 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000021736 acetylation Effects 0.000 description 2
- 238000006640 acetylation reaction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3839—Polyphosphonic acids
- C07F9/386—Polyphosphonic acids containing hydroxy substituents in the hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL132375D NL132375C (enrdf_load_stackoverflow) | 1961-07-03 | ||
| NL280425D NL280425A (enrdf_load_stackoverflow) | 1961-07-03 | ||
| DEH43035A DE1148235B (de) | 1961-07-03 | 1961-07-03 | Verfahren zur Herstellung von Acylierungsprodukten der phosphorigen Saeure mit mindestens 2 Phosphoratomen im Molekuel |
| CH478562A CH418332A (de) | 1961-07-03 | 1962-04-19 | Verfahren zur Herstellung von Acylierungsprodukten der phosphorigen Säure mit mindestens 2 Phosphoratomen im Molekül |
| GB2480262A GB981252A (en) | 1961-07-03 | 1962-06-28 | Process for the preparation of acylation products of phosphorous acid |
| BE619620A BE619620A (fr) | 1961-07-03 | 1962-07-02 | Procédé de préparation de produits d'acylation de l'acide phosphoreux avec au moins deux atomes de phosphore dans la molécule |
| FR902850A FR1327618A (fr) | 1961-07-03 | 1962-07-03 | Procédé de préparation de produits d'acylation de l'acide phosphoreux avec au moins deux atomes de phosphore dans la molécule |
| US05/869,437 US4060546A (en) | 1961-07-03 | 1969-09-25 | Process for the manufacture of acylation products of phosphorous acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEH43035A DE1148235B (de) | 1961-07-03 | 1961-07-03 | Verfahren zur Herstellung von Acylierungsprodukten der phosphorigen Saeure mit mindestens 2 Phosphoratomen im Molekuel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1148235B true DE1148235B (de) | 1963-05-09 |
Family
ID=7155064
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEH43035A Pending DE1148235B (de) | 1961-07-03 | 1961-07-03 | Verfahren zur Herstellung von Acylierungsprodukten der phosphorigen Saeure mit mindestens 2 Phosphoratomen im Molekuel |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE619620A (enrdf_load_stackoverflow) |
| CH (1) | CH418332A (enrdf_load_stackoverflow) |
| DE (1) | DE1148235B (enrdf_load_stackoverflow) |
| GB (1) | GB981252A (enrdf_load_stackoverflow) |
| NL (2) | NL132375C (enrdf_load_stackoverflow) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3468935A (en) * | 1964-11-11 | 1969-09-23 | Albright & Wilson Mfg Ltd | Preparation of organophosphonic acids |
| US3484480A (en) * | 1968-02-23 | 1969-12-16 | Procter & Gamble | Process for separating ethane - 1 - hydroxy-1,1-diphosphonic acid from a solution of it in an organic solvent which also contains oxyacids of phosphorus |
| US3504018A (en) * | 1966-12-19 | 1970-03-31 | Monsanto Co | Process for preparing phosphonic acids |
| US4060546A (en) * | 1961-07-03 | 1977-11-29 | Henkel Kommanditgesellschaft Auf Aktien | Process for the manufacture of acylation products of phosphorous acid |
| DE3142517A1 (de) * | 1981-10-27 | 1983-05-05 | Chemische Fabrik Budenheim Rudolf A. Oetker, 6501 Budenheim | Verfahren zur herstellung eines phosphonsaeuregemisches |
| US20130286488A1 (en) * | 2012-04-30 | 2013-10-31 | Samsung Electro-Mechanics Co., Ltd. | Optical system for camera |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3400148A (en) * | 1965-09-23 | 1968-09-03 | Procter & Gamble | Phosphonate compounds |
| US3400176A (en) * | 1965-11-15 | 1968-09-03 | Procter & Gamble | Propanepolyphosphonate compounds |
| DE2745083C2 (de) | 1977-10-07 | 1985-05-02 | Henkel KGaA, 4000 Düsseldorf | Hydroxydiphosphonsäuren und Verfahren zu deren Herstellung |
| US9777027B2 (en) | 2013-10-25 | 2017-10-03 | Straitmark Holding Ag | Method for the synthesis of ethane-1-hydroxy-1,1-diphosphonic acid |
| CN105829328B (zh) | 2013-10-25 | 2019-02-19 | 孟山都技术有限责任公司 | 用于合成烷烃-1-羟基-1,1-二膦酸的方法 |
-
0
- NL NL280425D patent/NL280425A/xx unknown
- NL NL132375D patent/NL132375C/xx active
-
1961
- 1961-07-03 DE DEH43035A patent/DE1148235B/de active Pending
-
1962
- 1962-04-19 CH CH478562A patent/CH418332A/de unknown
- 1962-06-28 GB GB2480262A patent/GB981252A/en not_active Expired
- 1962-07-02 BE BE619620A patent/BE619620A/fr unknown
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4060546A (en) * | 1961-07-03 | 1977-11-29 | Henkel Kommanditgesellschaft Auf Aktien | Process for the manufacture of acylation products of phosphorous acid |
| US3468935A (en) * | 1964-11-11 | 1969-09-23 | Albright & Wilson Mfg Ltd | Preparation of organophosphonic acids |
| US3504018A (en) * | 1966-12-19 | 1970-03-31 | Monsanto Co | Process for preparing phosphonic acids |
| US3484480A (en) * | 1968-02-23 | 1969-12-16 | Procter & Gamble | Process for separating ethane - 1 - hydroxy-1,1-diphosphonic acid from a solution of it in an organic solvent which also contains oxyacids of phosphorus |
| DE3142517A1 (de) * | 1981-10-27 | 1983-05-05 | Chemische Fabrik Budenheim Rudolf A. Oetker, 6501 Budenheim | Verfahren zur herstellung eines phosphonsaeuregemisches |
| US20130286488A1 (en) * | 2012-04-30 | 2013-10-31 | Samsung Electro-Mechanics Co., Ltd. | Optical system for camera |
| US20140104704A1 (en) * | 2012-04-30 | 2014-04-17 | Samsung Electro-Mechanics Co., Ltd. | Optical system for camera |
Also Published As
| Publication number | Publication date |
|---|---|
| NL280425A (enrdf_load_stackoverflow) | |
| NL132375C (enrdf_load_stackoverflow) | |
| BE619620A (fr) | 1963-01-02 |
| CH418332A (de) | 1966-08-15 |
| GB981252A (en) | 1965-01-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE734743C (de) | Verfahren zur Herstellung von polyamidartigen Verbindungen | |
| DE1148551B (de) | Verfahren zur Herstellung von Phosphonsaeuren bzw. deren Salzen mit mindestens 2 Phosphoratomen im Molekuel | |
| DE849109C (de) | Verfahren zur Herstellung aliphatischer Azoverbindungen | |
| DE1148235B (de) | Verfahren zur Herstellung von Acylierungsprodukten der phosphorigen Saeure mit mindestens 2 Phosphoratomen im Molekuel | |
| US3855284A (en) | Process for the manufacture of phosphonic acids and phosphonates having at least two phosphorus atoms | |
| DE1232146B (de) | Verfahren zur Herstellung von Metallsalzen der IV. und V. Hauptgruppe des Periodischen Systems von hoehermolekularen Carbonsaeuren | |
| DE2313580C3 (enrdf_load_stackoverflow) | ||
| CH414624A (de) | Verfahren zur Herstellung von Acylierungsprodukten der phosphorigen Säure | |
| DE2518144A1 (de) | Verfahren zur herstellung von carboxyalkan-phosphonsaeuren und carboxy-alkylphosphinsaeuren | |
| DE2852163A1 (de) | Verfahren zur herstellung von m-hydroxy-benzoesaeure | |
| DE2652216A1 (de) | Kristallines aethercarboxylat.monohydrat, verfahren zu seiner herstellung und seine verwendung | |
| DE854264C (de) | Verfahren zur Herstellung von Organosiloxanen durch Hydrolyse hydrolysierbarer Silane und Kondensation der Hydrolysierungsprodukte | |
| DE950289C (de) | Verfahren zur Herstellung von N-Carboxyalkylhexitylaminen | |
| DE2048913B2 (de) | Verfahren zur Herstellung von 1 -Aminoalkan-1,1 -diphosphonsäuren | |
| AT68869B (de) | Verfahren zur Darstellung von Arsen und von Phosphor enthaltenden Fettsäuren. | |
| DE2060329C3 (de) | Verfahren zur Herstellung von substituierten Benzamiden | |
| DE2456274C3 (de) | Verfahren zur Herstellung eines Gemisches von Hydroxyaluminiumnitratpolymeren und Ammoniumnitrat | |
| AT326638B (de) | Verfahren zur herstellung von n(beta-diäthylaminoäthyl) -4-amino-5-chlor-2-methoxybenzamid | |
| DE749643C (de) | Verfahren zur Herstellung ungesaettigter Carbonsaeureamide | |
| DE947370C (de) | Verfahren zur Herstellung von 4-Thionylamino-2-oxy-benzoylchlorid | |
| DE2513952C2 (de) | Verfahren zur herstellung von monochlorbenzoesaeuren | |
| DE2226296A1 (de) | Verfahren zur Herstellung von Antimontrialkoxyden | |
| EP0252244A1 (de) | Verfahren zur Herstellung von Vinyldiphosphonsäure und ihren Salzen | |
| AT308064B (de) | Verfahren zur Herstellung von neuen Sulfoniumverbindungen von α-Hydroxy-γ-alkylmercaptobuttersäuren | |
| DE893949C (de) | Verfahren zur Herstellung von aliphatischen Harnstoffderivaten |