DE1132337B - Verfahren zur Blockpolymerisation von Vinylchlorid - Google Patents
Verfahren zur Blockpolymerisation von VinylchloridInfo
- Publication number
- DE1132337B DE1132337B DEW28264A DEW0028264A DE1132337B DE 1132337 B DE1132337 B DE 1132337B DE W28264 A DEW28264 A DE W28264A DE W0028264 A DEW0028264 A DE W0028264A DE 1132337 B DE1132337 B DE 1132337B
- Authority
- DE
- Germany
- Prior art keywords
- vinyl chloride
- percent
- polymerization
- weight
- hydroxides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 13
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 11
- 238000012662 bulk polymerization Methods 0.000 title description 2
- 239000000178 monomer Substances 0.000 claims description 12
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 11
- 150000004679 hydroxides Chemical class 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- -1 methanol Chemical class 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- DHZSIQDUYCWNSB-UHFFFAOYSA-N chloroethene;1,1-dichloroethene Chemical compound ClC=C.ClC(Cl)=C DHZSIQDUYCWNSB-UHFFFAOYSA-N 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE606717D BE606717A (en, 2012) | 1960-07-28 | ||
| DEW28264A DE1132337B (de) | 1960-07-28 | 1960-07-28 | Verfahren zur Blockpolymerisation von Vinylchlorid |
| US126515A US3151103A (en) | 1960-07-28 | 1961-07-25 | Bulk polymerization of vinyl chloride with metallic oxides and hydroxides |
| FR869430A FR1296361A (fr) | 1960-07-28 | 1961-07-28 | Procédé de préparation de polymères du chlorure de vinyle |
| GB27516/61A GB986615A (en) | 1960-07-28 | 1961-07-28 | Process for the manufacture of vinyl chloride polymers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEW28264A DE1132337B (de) | 1960-07-28 | 1960-07-28 | Verfahren zur Blockpolymerisation von Vinylchlorid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1132337B true DE1132337B (de) | 1962-06-28 |
Family
ID=7598887
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEW28264A Pending DE1132337B (de) | 1960-07-28 | 1960-07-28 | Verfahren zur Blockpolymerisation von Vinylchlorid |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3151103A (en, 2012) |
| BE (1) | BE606717A (en, 2012) |
| DE (1) | DE1132337B (en, 2012) |
| GB (1) | GB986615A (en, 2012) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3717607A (en) * | 1970-09-21 | 1973-02-20 | Hooker Chemical Corp | Stabilization of poly(vinyl halide) |
| US4029863A (en) * | 1971-08-06 | 1977-06-14 | Hooker Chemicals & Plastics Corporation | Method of obtaining small particle size polymers and copolymers of vinyl chloride by bulk polymerization |
| US3899473A (en) * | 1972-03-10 | 1975-08-12 | Kema Nord Ab | Method of incorporating solid additives into vinyl chloride polymers |
| US3933771A (en) * | 1973-07-16 | 1976-01-20 | Hooker Chemicals & Plastics Corporation | Composition of and method of obtaining small particle size polymers and copolymers of vinyl chloride having a fused surface |
| IT1007803B (it) * | 1974-04-09 | 1976-10-30 | Montedison Spa | Composizioni polimeriche plastifi cate a base di polimeri del cloru ro di vinile con buone caratteri stiche fisico meccaniche e con ec cellenti caratteristiche di isola mento elettrico anche a temperatu ra elevata |
| US4028329A (en) * | 1974-07-24 | 1977-06-07 | Hooker Chemicals & Plastics Corporation | Process for the bulk polymerization of vinyl halide polymers showing reduced reactor scale formation |
| DE2837173A1 (de) * | 1978-08-25 | 1980-02-28 | Dynamit Nobel Ag | Verfahren zur massepolymerisation von vinylchlorid |
| US4574138A (en) * | 1984-01-09 | 1986-03-04 | Moran Jr James P | Rapid cure acrylic monomer systems containing elemental aluminum metal |
| US4722960A (en) * | 1983-01-18 | 1988-02-02 | Loctite Corporation | Aluminum filled compositions |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2483960A (en) * | 1948-02-26 | 1949-10-04 | Monsanto Chemicals | Polymerization of vinyl halides in an aqueous dispersion |
| FR1079772A (fr) * | 1952-07-29 | 1954-12-02 | Saint Gobain | Perfectionnement à la polymérisation en masse |
| US3057831A (en) * | 1957-11-29 | 1962-10-09 | Escambia Chem Corp | Suspension polymerization of vinyl chloride and product thereof |
-
0
- BE BE606717D patent/BE606717A/xx unknown
-
1960
- 1960-07-28 DE DEW28264A patent/DE1132337B/de active Pending
-
1961
- 1961-07-25 US US126515A patent/US3151103A/en not_active Expired - Lifetime
- 1961-07-28 GB GB27516/61A patent/GB986615A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB986615A (en) | 1965-03-17 |
| BE606717A (en, 2012) | |
| US3151103A (en) | 1964-09-29 |
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