DE1127085B - Verfahren zur Herstellung waessriger stabiler Dispersionen von Mischpolymerisaten aus organischen Vinylestern und AEthylen - Google Patents
Verfahren zur Herstellung waessriger stabiler Dispersionen von Mischpolymerisaten aus organischen Vinylestern und AEthylenInfo
- Publication number
- DE1127085B DE1127085B DEF31915A DEF0031915A DE1127085B DE 1127085 B DE1127085 B DE 1127085B DE F31915 A DEF31915 A DE F31915A DE F0031915 A DEF0031915 A DE F0031915A DE 1127085 B DE1127085 B DE 1127085B
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- vinyl
- copolymers
- activator
- vinyl esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 46
- 239000005977 Ethylene Substances 0.000 title claims description 46
- 239000006185 dispersion Substances 0.000 title claims description 31
- 238000000034 method Methods 0.000 title claims description 20
- 229920001567 vinyl ester resin Polymers 0.000 title claims description 17
- 229920001577 copolymer Polymers 0.000 title claims description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 20
- 239000007787 solid Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000012190 activator Substances 0.000 claims description 10
- 239000008346 aqueous phase Substances 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- -1 vinyl halides Chemical class 0.000 claims description 8
- 239000000084 colloidal system Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- 150000002978 peroxides Chemical class 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- 239000013543 active substance Substances 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 239000001530 fumaric acid Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000003995 emulsifying agent Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 238000013459 approach Methods 0.000 description 6
- 239000012736 aqueous medium Substances 0.000 description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 239000007970 homogeneous dispersion Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 235000002639 sodium chloride Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE607369D BE607369A (en, 2012) | 1960-08-19 | ||
| DEF31915A DE1127085B (de) | 1960-08-19 | 1960-08-19 | Verfahren zur Herstellung waessriger stabiler Dispersionen von Mischpolymerisaten aus organischen Vinylestern und AEthylen |
| FR871143A FR1301103A (fr) | 1960-08-19 | 1961-08-19 | Procédé de préparation de dispersions stables de copolymères d'esters vinyliques organiques et d'éthylène |
| GB3015061A GB991550A (en) | 1960-08-19 | 1961-08-21 | Process for the manufacture of stable aqueous dispersions of copolymers of vinyl esters of organic acids and ethylene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF31915A DE1127085B (de) | 1960-08-19 | 1960-08-19 | Verfahren zur Herstellung waessriger stabiler Dispersionen von Mischpolymerisaten aus organischen Vinylestern und AEthylen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1127085B true DE1127085B (de) | 1962-04-05 |
Family
ID=7094413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF31915A Pending DE1127085B (de) | 1960-08-19 | 1960-08-19 | Verfahren zur Herstellung waessriger stabiler Dispersionen von Mischpolymerisaten aus organischen Vinylestern und AEthylen |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE607369A (en, 2012) |
| DE (1) | DE1127085B (en, 2012) |
| GB (1) | GB991550A (en, 2012) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1237311B (de) * | 1963-05-04 | 1967-03-23 | Bayer Ag | Verfahren zur Herstellung waessriger Dispersionen von AEthylen-Mischpolymerisaten |
| DE1267429B (de) * | 1964-07-18 | 1968-05-02 | Hoechst Ag | Verfahren zur Herstellung waessriger stabiler Dispersionen von Mischpolymerisaten aus Vinylestern und AEthylen |
| DE2718716A1 (de) * | 1976-04-28 | 1977-11-17 | Sumitomo Chemical Co | Dispersionshaftkleber auf der basis eines aethylen-vinylacetat-copolymerisats |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4164489A (en) | 1978-04-24 | 1979-08-14 | Air Products And Chemicals, Inc. | Continuous emulsion polymerization of vinyl acetate and ethylene |
| CA1152669A (en) * | 1979-09-28 | 1983-08-23 | Russell J. Hanna | Latex polymerization process |
| US4332850A (en) * | 1981-05-26 | 1982-06-01 | Air Products And Chemicals, Inc. | Vinyl acetate-ethylene emulsions for nonwoven goods |
-
0
- BE BE607369D patent/BE607369A/xx unknown
-
1960
- 1960-08-19 DE DEF31915A patent/DE1127085B/de active Pending
-
1961
- 1961-08-21 GB GB3015061A patent/GB991550A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1237311B (de) * | 1963-05-04 | 1967-03-23 | Bayer Ag | Verfahren zur Herstellung waessriger Dispersionen von AEthylen-Mischpolymerisaten |
| DE1267429B (de) * | 1964-07-18 | 1968-05-02 | Hoechst Ag | Verfahren zur Herstellung waessriger stabiler Dispersionen von Mischpolymerisaten aus Vinylestern und AEthylen |
| DE2718716A1 (de) * | 1976-04-28 | 1977-11-17 | Sumitomo Chemical Co | Dispersionshaftkleber auf der basis eines aethylen-vinylacetat-copolymerisats |
Also Published As
| Publication number | Publication date |
|---|---|
| GB991550A (en) | 1965-05-12 |
| BE607369A (en, 2012) |
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