DE112020001517T5 - Feststoffelektrolyt und gassensor - Google Patents
Feststoffelektrolyt und gassensor Download PDFInfo
- Publication number
- DE112020001517T5 DE112020001517T5 DE112020001517.3T DE112020001517T DE112020001517T5 DE 112020001517 T5 DE112020001517 T5 DE 112020001517T5 DE 112020001517 T DE112020001517 T DE 112020001517T DE 112020001517 T5 DE112020001517 T5 DE 112020001517T5
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- DE
- Germany
- Prior art keywords
- solid electrolyte
- phase
- gas
- temperature
- rate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000007784 solid electrolyte Substances 0.000 title claims abstract description 130
- 239000013078 crystal Substances 0.000 claims abstract description 47
- 230000008859 change Effects 0.000 claims abstract description 31
- 239000002245 particle Substances 0.000 claims abstract description 28
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 11
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims abstract description 4
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims description 15
- 239000007789 gas Substances 0.000 description 108
- 238000000137 annealing Methods 0.000 description 43
- 230000007704 transition Effects 0.000 description 33
- 230000027311 M phase Effects 0.000 description 29
- 239000000446 fuel Substances 0.000 description 24
- 239000010410 layer Substances 0.000 description 24
- 238000005259 measurement Methods 0.000 description 24
- 230000035882 stress Effects 0.000 description 23
- 230000007423 decrease Effects 0.000 description 22
- 238000010586 diagram Methods 0.000 description 22
- 230000035939 shock Effects 0.000 description 14
- 238000010304 firing Methods 0.000 description 13
- 230000009467 reduction Effects 0.000 description 10
- 238000009792 diffusion process Methods 0.000 description 9
- 239000011810 insulating material Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000003381 stabilizer Substances 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 8
- 239000011812 mixed powder Substances 0.000 description 8
- 230000002093 peripheral effect Effects 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 230000003247 decreasing effect Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000010587 phase diagram Methods 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 239000011241 protective layer Substances 0.000 description 5
- 239000006104 solid solution Substances 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 238000009499 grossing Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 229910052596 spinel Inorganic materials 0.000 description 4
- 239000011029 spinel Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000008247 solid mixture Substances 0.000 description 3
- 229910020068 MgAl Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 238000013001 point bending Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 229910002483 Cu Ka Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000009429 electrical wiring Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 description 1
- UZLYXNNZYFBAQO-UHFFFAOYSA-N oxygen(2-);ytterbium(3+) Chemical compound [O-2].[O-2].[O-2].[Yb+3].[Yb+3] UZLYXNNZYFBAQO-UHFFFAOYSA-N 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium oxide Chemical compound O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229940075624 ytterbium oxide Drugs 0.000 description 1
- 229910003454 ytterbium oxide Inorganic materials 0.000 description 1
Images
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4073—Composition or fabrication of the solid electrolyte
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/486—Fine ceramics
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
- G01M15/00—Testing of engines
- G01M15/04—Testing internal-combustion engines
- G01M15/10—Testing internal-combustion engines by monitoring exhaust gases or combustion flame
- G01M15/102—Testing internal-combustion engines by monitoring exhaust gases or combustion flame by monitoring exhaust gases
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
- C04B2235/3246—Stabilised zirconias, e.g. YSZ or cerium stabilised zirconia
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4071—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/409—Oxygen concentration cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2019059103A JP7215284B2 (ja) | 2019-03-26 | 2019-03-26 | 固体電解質、ガスセンサ |
| JP2019-059103 | 2019-03-26 | ||
| PCT/JP2020/006214 WO2020195346A1 (ja) | 2019-03-26 | 2020-02-18 | 固体電解質、ガスセンサ |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE112020001517T5 true DE112020001517T5 (de) | 2021-12-16 |
Family
ID=72610445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE112020001517.3T Pending DE112020001517T5 (de) | 2019-03-26 | 2020-02-18 | Feststoffelektrolyt und gassensor |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US12111282B2 (https=) |
| JP (1) | JP7215284B2 (https=) |
| CN (1) | CN113631530B (https=) |
| DE (1) | DE112020001517T5 (https=) |
| WO (1) | WO2020195346A1 (https=) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7329960B2 (ja) * | 2019-05-14 | 2023-08-21 | 東京エレクトロン株式会社 | 載置台およびプラズマ処理装置 |
| JP2025183070A (ja) * | 2024-06-04 | 2025-12-16 | 株式会社デンソー | ガスセンサ素子 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63210063A (ja) | 1987-02-25 | 1988-08-31 | 株式会社日立製作所 | ジルコニア酸素センサ素子 |
| JP2019059103A (ja) | 2017-09-26 | 2019-04-18 | 富士ゼロックス株式会社 | 積層造形用粉末、三次元造形用材料セット、三次元造形装置及び三次元造形物 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5642909A (en) * | 1979-09-18 | 1981-04-21 | Ngk Insulators Ltd | Solid electrolyte |
| JPS591232B2 (ja) * | 1979-09-28 | 1984-01-11 | 住友アルミニウム製錬株式会社 | ジルコニア焼結体の製造方法 |
| JPS56111455A (en) * | 1980-02-07 | 1981-09-03 | Nippon Denso Co Ltd | Solid electrolyte body for oxygen sensor |
| JPS59114455A (ja) * | 1982-12-21 | 1984-07-02 | Nippon Kagaku Togyo Kk | 酸素濃度測定用ジルコニア固体電解質の製造方法 |
| JPS62191466A (ja) * | 1986-02-19 | 1987-08-21 | 加藤 悦朗 | ジルコニア多結晶独立薄膜及びその製造方法 |
| JPH0650297B2 (ja) * | 1986-12-27 | 1994-06-29 | 日本碍子株式会社 | 酸素センサ素子の製造方法 |
| JP2617204B2 (ja) * | 1988-04-27 | 1997-06-04 | 日本特殊陶業株式会社 | 固体電解質の製造方法 |
| JPH01261267A (ja) | 1988-11-05 | 1989-10-18 | Ngk Insulators Ltd | 固体電解質およびその製造法 |
| DE4238688A1 (de) | 1992-11-17 | 1994-05-19 | Bosch Gmbh Robert | Gesinterter Festelektrolyt mit hoher Sauerstoffionenleitfähigkeit |
| JP3274330B2 (ja) | 1994-10-19 | 2002-04-15 | 日本碍子株式会社 | セラミックス成形体の焼成収縮を制御する方法 |
| US6258233B1 (en) * | 1995-07-13 | 2001-07-10 | Denso Corporation | Multilayered air-fuel ratio sensing element |
| JPH11316211A (ja) * | 1998-03-05 | 1999-11-16 | Denso Corp | 積層型空燃比センサ素子 |
| JP4062768B2 (ja) * | 1998-02-25 | 2008-03-19 | 株式会社デンソー | 酸素センサ素子の製造方法 |
| US6174489B1 (en) * | 1995-09-01 | 2001-01-16 | Denso Corporation | Method for manufacturing a gas sensor unit |
| JP3525601B2 (ja) | 1995-11-27 | 2004-05-10 | 東陶機器株式会社 | セラミック緻密薄膜の形成方法 |
| FR2744220B1 (fr) * | 1996-01-31 | 1999-09-10 | Denso Corp | Dispositif de detection de la concentration en oxygene et son procede de fabrication |
| JP3605984B2 (ja) * | 1997-01-23 | 2004-12-22 | 株式会社デンソー | 酸素センサ素子の製造方法及び製造装置 |
| US6168745B1 (en) * | 1998-11-28 | 2001-01-02 | Materials And Systems Research, Inc. | Method for forming t'-phase zirconia for high temperature applications |
| JP2000310610A (ja) * | 1999-02-25 | 2000-11-07 | Denso Corp | ガスセンサ素子及びその製造方法 |
| KR20010021013A (ko) * | 1999-06-22 | 2001-03-15 | 오카무라 가네오 | 절연성 세라믹 입자를 포함하는 가스 센서용 고체 전해질및 그 제조방법 |
| JP4595264B2 (ja) * | 2000-10-05 | 2010-12-08 | 株式会社デンソー | 酸素センサ素子及びその製造方法 |
| KR100544628B1 (ko) | 2003-03-07 | 2006-01-23 | 한국화학연구원 | 지르코니아 수화물 나노입자 졸의 연속 제조방법 |
| JP4548020B2 (ja) * | 2004-07-06 | 2010-09-22 | 株式会社デンソー | ジルコニア構造体およびその製造方法 |
| US20090081101A1 (en) * | 2007-09-20 | 2009-03-26 | Daiichi Kigenso Kagaku Kogyo Co., Ltd. | Yttria-stabilized zirconia sintered body and method for producing the same |
| JP4724772B2 (ja) * | 2009-02-06 | 2011-07-13 | 株式会社日本自動車部品総合研究所 | ガスセンサ用固体電解質、その製造方法、及びそれを用いたガスセンサ |
| KR101665155B1 (ko) * | 2009-08-21 | 2016-10-11 | 가부시키가이샤 노리타께 캄파니 리미티드 | 지르코니아 소결체, 및 지르코니아 소결체의 소결용 혼합체, 소결 전 성형체, 및 소결 전 가소체 |
| JP5333527B2 (ja) * | 2011-06-20 | 2013-11-06 | トヨタ自動車株式会社 | 酸素センサの製造方法 |
| JP6131166B2 (ja) * | 2012-11-22 | 2017-05-17 | 株式会社デンソー | ガスセンサ用の電極及びそれを用いたガスセンサ素子 |
| US10347929B2 (en) * | 2014-09-19 | 2019-07-09 | Osaka Gas Co., Ltd. | Electrochemical element, solid oxide fuel cell, and methods for producing the same |
| US10273191B2 (en) | 2015-01-15 | 2019-04-30 | Tosoh Corporation | Translucent zirconia sintered body, method for manufacturing same, and use thereof |
| FR3034569B1 (fr) * | 2015-04-02 | 2021-10-22 | Soitec Silicon On Insulator | Electrolyte solide avance et sa methode de fabrication |
| JP6669045B2 (ja) | 2016-11-15 | 2020-03-18 | 株式会社デンソー | ガスセンサ素子用固体電解質体とその製造方法及びガスセンサ素子 |
| JP6182286B1 (ja) | 2017-03-16 | 2017-08-16 | 日本碍子株式会社 | 燃料電池 |
-
2019
- 2019-03-26 JP JP2019059103A patent/JP7215284B2/ja active Active
-
2020
- 2020-02-18 DE DE112020001517.3T patent/DE112020001517T5/de active Pending
- 2020-02-18 WO PCT/JP2020/006214 patent/WO2020195346A1/ja not_active Ceased
- 2020-02-18 CN CN202080023851.1A patent/CN113631530B/zh active Active
-
2021
- 2021-09-24 US US17/448,733 patent/US12111282B2/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63210063A (ja) | 1987-02-25 | 1988-08-31 | 株式会社日立製作所 | ジルコニア酸素センサ素子 |
| JP2019059103A (ja) | 2017-09-26 | 2019-04-18 | 富士ゼロックス株式会社 | 積層造形用粉末、三次元造形用材料セット、三次元造形装置及び三次元造形物 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2020195346A1 (ja) | 2020-10-01 |
| JP7215284B2 (ja) | 2023-01-31 |
| CN113631530B (zh) | 2023-12-12 |
| JP2020158342A (ja) | 2020-10-01 |
| CN113631530A (zh) | 2021-11-09 |
| US12111282B2 (en) | 2024-10-08 |
| US20220011259A1 (en) | 2022-01-13 |
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