DE1080718B - Verfahren zur Entschwefelung von Roherdoelen - Google Patents
Verfahren zur Entschwefelung von RoherdoelenInfo
- Publication number
- DE1080718B DE1080718B DEE14965A DEE0014965A DE1080718B DE 1080718 B DE1080718 B DE 1080718B DE E14965 A DEE14965 A DE E14965A DE E0014965 A DEE0014965 A DE E0014965A DE 1080718 B DE1080718 B DE 1080718B
- Authority
- DE
- Germany
- Prior art keywords
- stage
- hydrogen
- vapors
- diesel oil
- hydrofining
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 17
- 239000000446 fuel Substances 0.000 title description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 20
- 239000001257 hydrogen Substances 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 15
- 239000002283 diesel fuel Substances 0.000 claims description 11
- 239000011787 zinc oxide Substances 0.000 claims description 10
- 238000001704 evaporation Methods 0.000 claims description 8
- 230000008020 evaporation Effects 0.000 claims description 8
- 239000010779 crude oil Substances 0.000 claims description 7
- 238000005194 fractionation Methods 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 239000003350 kerosene Substances 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 239000011593 sulfur Substances 0.000 description 7
- 238000006477 desulfuration reaction Methods 0.000 description 5
- 230000023556 desulfurization Effects 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 239000005083 Zinc sulfide Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910052984 zinc sulfide Inorganic materials 0.000 description 3
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910007541 Zn O Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical class [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US624617A US2959538A (en) | 1956-11-27 | 1956-11-27 | Hydrodesulfurization of whole crudes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1080718B true DE1080718B (de) | 1960-04-28 |
Family
ID=24502666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEE14965A Pending DE1080718B (de) | 1956-11-27 | 1957-11-19 | Verfahren zur Entschwefelung von Roherdoelen |
Country Status (5)
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3063936A (en) * | 1958-08-22 | 1962-11-13 | Ici Ltd | Desulfurization of hydrocarbon oils |
| NL278028A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1961-05-05 | |||
| GB1068588A (en) * | 1963-12-23 | 1967-05-10 | Gas Council | Method of treating gases |
| US3935295A (en) * | 1973-01-23 | 1976-01-27 | Catalysts And Chemicals, Inc. | Process for removing chlorine-containing compounds from hydrocarbon streams |
| US3963604A (en) * | 1973-11-05 | 1976-06-15 | Uop Inc. | Combination process for hydrorefining an asphaltenic hydrocarbonaceous charge stock |
| US3898153A (en) * | 1973-11-23 | 1975-08-05 | Sun Oil Co Pennsylvania | Catalytic reforming process with sulfur removal |
| US4610780A (en) * | 1985-03-18 | 1986-09-09 | Atlantic Richfield Company | Method for removing sulfur-containing impurities from hydrocarbons |
| US4613724A (en) * | 1985-07-09 | 1986-09-23 | Labofina, S.A. | Process for removing carbonyl-sulfide from liquid hydrocarbon feedstocks |
| GB8803767D0 (en) * | 1988-02-18 | 1988-03-16 | Ici Plc | Desulphurisation |
| GB2221221B (en) * | 1988-07-29 | 1992-03-18 | Amoco Corp | Apparatus and method for recovering diesel-quality fuel from produced crude oil |
| US5116485A (en) * | 1988-07-29 | 1992-05-26 | Krisa Thomas E | Apparatus and method for recovering diesel-quality fuel from produced crude oil |
| US5157201A (en) * | 1990-06-22 | 1992-10-20 | Exxon Chemical Patents Inc. | Process for adsorbing sulfur species from propylene/propane using regenerable adsorbent |
| US5866749A (en) * | 1993-05-28 | 1999-02-02 | Exxon Chemical Patents Inc. | Sulfur and thiol removal from reactive hydrocarbons |
| US20040140244A1 (en) * | 2000-05-30 | 2004-07-22 | Sughrue Edward L. | Desulfurization and sorbents for same |
| EP2318484A4 (en) * | 2008-08-11 | 2011-12-21 | Ca Minister Natural Resources | GAS PHASE HYDROTREATING OF MIDDLE STILLILLATE HYDROCARBON INGREDIENTS |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE720002C (de) * | 1928-05-09 | 1942-04-21 | Ig Farbenindustrie Ag | Verfahren zur Reinigung von Kohlenwasserstoffen |
| GB669551A (en) * | 1948-04-19 | 1952-04-02 | Anglo Iranian Oil Co Ltd | Improvements relating to catalytic desulphurisation of petroleum hydrocarbons |
| GB697727A (en) * | 1950-01-17 | 1953-09-30 | Anglo Iranian Oil Co Ltd | Improvements relating to the catalytic desulphurisation of petroleum hydrocarbons |
| FR1043217A (fr) * | 1950-09-07 | 1953-11-06 | Anglo Iranian Oil Co Ltd | Procédé de désulfuration de pétrole brut |
| FR1064400A (fr) * | 1951-10-18 | 1954-05-13 | Anglo Iranian Oil Co Ltd | Procédé de récupération à partir de pétrole brut de produits ayant une teneur en soufre très réduite |
| GB721357A (en) * | 1951-04-06 | 1955-01-05 | Anglo Iranian Oil Co Ltd | Improvements in or relating to the desulphurisation of crude petroleum |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US487119A (en) * | 1892-11-29 | Refining canadian or similar petroleum-oils | ||
| US2357121A (en) * | 1943-03-01 | 1944-08-29 | Shell Dev | Process for desulphurizing a hydrocarbon distillate |
| US2769760A (en) * | 1953-09-11 | 1956-11-06 | Pure Oil Co | Production of sweet naphthas from hydrocarbon mixtures by hydrofining the hydrocarbon mixture followed by contacting the hydrocarbon product with a composition containing cobalt and molybdenum |
| US2775544A (en) * | 1955-02-28 | 1956-12-25 | Exxon Research Engineering Co | Production of catalytic cracking feed stocks |
-
0
- BE BE562617D patent/BE562617A/xx unknown
-
1956
- 1956-11-27 US US624617A patent/US2959538A/en not_active Expired - Lifetime
-
1957
- 1957-11-19 DE DEE14965A patent/DE1080718B/de active Pending
- 1957-11-20 GB GB36153/57A patent/GB822682A/en not_active Expired
- 1957-11-26 ES ES0238790A patent/ES238790A1/es not_active Expired
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE720002C (de) * | 1928-05-09 | 1942-04-21 | Ig Farbenindustrie Ag | Verfahren zur Reinigung von Kohlenwasserstoffen |
| GB669551A (en) * | 1948-04-19 | 1952-04-02 | Anglo Iranian Oil Co Ltd | Improvements relating to catalytic desulphurisation of petroleum hydrocarbons |
| GB697727A (en) * | 1950-01-17 | 1953-09-30 | Anglo Iranian Oil Co Ltd | Improvements relating to the catalytic desulphurisation of petroleum hydrocarbons |
| FR1043217A (fr) * | 1950-09-07 | 1953-11-06 | Anglo Iranian Oil Co Ltd | Procédé de désulfuration de pétrole brut |
| GB710342A (en) * | 1950-09-07 | 1954-06-09 | Anglo Iranian Oil Co Ltd | Improvements in or relating to the treatment of crude petroleum |
| GB721357A (en) * | 1951-04-06 | 1955-01-05 | Anglo Iranian Oil Co Ltd | Improvements in or relating to the desulphurisation of crude petroleum |
| FR1064400A (fr) * | 1951-10-18 | 1954-05-13 | Anglo Iranian Oil Co Ltd | Procédé de récupération à partir de pétrole brut de produits ayant une teneur en soufre très réduite |
| US2755225A (en) * | 1951-10-18 | 1956-07-17 | British Petroleum Co | Treatment of crude petroleum |
Also Published As
| Publication number | Publication date |
|---|---|
| BE562617A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| ES238790A1 (es) | 1958-05-01 |
| US2959538A (en) | 1960-11-08 |
| GB822682A (en) | 1959-10-28 |
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