DE102004051242A1 - Feinteilige wasserabsorbierende Polymerpartikel mit hoher Flüssigkeitstransport- und Absorptionsleistung - Google Patents
Feinteilige wasserabsorbierende Polymerpartikel mit hoher Flüssigkeitstransport- und Absorptionsleistung Download PDFInfo
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- DE102004051242A1 DE102004051242A1 DE102004051242A DE102004051242A DE102004051242A1 DE 102004051242 A1 DE102004051242 A1 DE 102004051242A1 DE 102004051242 A DE102004051242 A DE 102004051242A DE 102004051242 A DE102004051242 A DE 102004051242A DE 102004051242 A1 DE102004051242 A1 DE 102004051242A1
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- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920000247 superabsorbent polymer Polymers 0.000 description 1
- 239000004583 superabsorbent polymers (SAPs) Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical class OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Hematology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Wrappers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004051242A DE102004051242A1 (de) | 2004-10-20 | 2004-10-20 | Feinteilige wasserabsorbierende Polymerpartikel mit hoher Flüssigkeitstransport- und Absorptionsleistung |
| US11/665,883 US7759422B2 (en) | 2004-10-20 | 2005-10-14 | Fine-grained water-absorbent particles with a high fluid transport and absorption capacity |
| PCT/EP2005/011073 WO2006042704A2 (de) | 2004-10-20 | 2005-10-14 | Feinteilige wasserabsorbierende polymerpartikel mit hoher flüssigkeitstransport- und absorptionsleistung |
| EP05798199A EP1804842A2 (de) | 2004-10-20 | 2005-10-14 | Feinteilige wasserabsorbierende polymerpartikel mit hoher flüssigkeitstransport- und absorptionsleistung |
| CN200580043376XA CN101080245B (zh) | 2004-10-20 | 2005-10-14 | 具有高流体输送和吸收能力的细粒状吸水性聚合物颗粒 |
| JP2007537171A JP2008517116A (ja) | 2004-10-20 | 2005-10-14 | 高い液体輸送性および吸水性能を有する微粒子状の吸水性ポリマー粒子 |
| EP10173417A EP2263704A1 (de) | 2004-10-20 | 2005-10-14 | Feinteilige wasserabsorbierende Polymerpartikel mit hoher Flüssigkeitstransport- und Absorptionsleistung |
| EP10173415A EP2258409A1 (de) | 2004-10-20 | 2005-10-14 | Feinteilige wasserabsorbierende Polymerpartikel mit hoher Flüssigkeitstransport- und Absorptionsleistung |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004051242A DE102004051242A1 (de) | 2004-10-20 | 2004-10-20 | Feinteilige wasserabsorbierende Polymerpartikel mit hoher Flüssigkeitstransport- und Absorptionsleistung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102004051242A1 true DE102004051242A1 (de) | 2006-05-04 |
Family
ID=36201597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102004051242A Withdrawn DE102004051242A1 (de) | 2004-10-20 | 2004-10-20 | Feinteilige wasserabsorbierende Polymerpartikel mit hoher Flüssigkeitstransport- und Absorptionsleistung |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7759422B2 (https=) |
| EP (3) | EP2258409A1 (https=) |
| JP (1) | JP2008517116A (https=) |
| CN (1) | CN101080245B (https=) |
| DE (1) | DE102004051242A1 (https=) |
| WO (1) | WO2006042704A2 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008000237A1 (de) | 2007-02-06 | 2008-08-07 | Basf Se | Phenol-Imidazolderivate zur Stabilisierung von polymerisationsfähigen Verbindungen |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004038015A1 (de) * | 2004-08-04 | 2006-03-16 | Basf Ag | Verfahren zur Nachvernetzung wasserabsorbierender Polymere mit zyklischen Carba-maten und/oder zyklischen Harnstoffen |
| EP1846050A2 (en) * | 2005-02-04 | 2007-10-24 | Basf Aktiengesellschaft | A process for producing a water-absorbing material having a coating of elastic filmforming polymers |
| EP1843796B1 (en) * | 2005-02-04 | 2013-02-27 | The Procter & Gamble Company | Absorbent structure with improved water-absorbing material |
| CA2596864C (en) * | 2005-02-04 | 2012-05-08 | The Procter & Gamble Company | Absorbent structure with improved water-swellable material |
| EP1846047B1 (en) * | 2005-02-04 | 2010-07-14 | Basf Se | A process for producing a water-absorbing material having a coating of elastic filmforming polymers |
| EP1846475A1 (en) * | 2005-02-04 | 2007-10-24 | Basf Aktiengesellschaft | Water swellable material |
| EP1846049B1 (en) * | 2005-02-04 | 2011-08-03 | Basf Se | Water-absorbing material having a coating of elastic film-forming polymers |
| CA2596889A1 (en) * | 2005-02-04 | 2006-08-10 | The Procter & Gamble Company | Absorbent structure with improved water-absorbing material |
| TWI344469B (en) | 2005-04-07 | 2011-07-01 | Nippon Catalytic Chem Ind | Polyacrylic acid (salt) water-absorbent resin, production process thereof, and acrylic acid used in polymerization for production of water-absorbent resin |
| TWI394789B (zh) | 2005-12-22 | 2013-05-01 | Nippon Catalytic Chem Ind | 吸水性樹脂組成物及其製造方法、吸收性物品 |
| EP1965841A1 (en) * | 2005-12-28 | 2008-09-10 | Basf Se | Process for production of a water-absorbing material |
| EP1837348B9 (en) | 2006-03-24 | 2020-01-08 | Nippon Shokubai Co.,Ltd. | Water-absorbing resin and method for manufacturing the same |
| WO2008009612A1 (de) | 2006-07-19 | 2008-01-24 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel mit hoher permeabilität durch polymerisation von tropfen einer monomerlösung |
| CN101489597A (zh) * | 2006-07-19 | 2009-07-22 | 巴斯夫欧洲公司 | 通过聚合单体溶液的微滴而生产吸水性聚合物颗粒的方法 |
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| US8529805B2 (en) | 2006-10-05 | 2013-09-10 | Basf Se | Method for the production of water absorbent polymer particles by polymerizing drops of a monomer solution |
| US7935860B2 (en) * | 2007-03-23 | 2011-05-03 | Kimberly-Clark Worldwide, Inc. | Absorbent articles comprising high permeability superabsorbent polymer compositions |
| EP2018877A1 (en) * | 2007-07-27 | 2009-01-28 | The Procter and Gamble Company | Absorbent article comprising water-absorbing polymeric particles and method for the production thereof |
| US8846565B2 (en) | 2007-07-27 | 2014-09-30 | Basf Se | Water-absorbing polymeric particles and method for the production thereof |
| EP2018876A1 (en) * | 2007-07-27 | 2009-01-28 | The Procter and Gamble Company | Absorbent article comprising water-absorbing polymeric particles and method for the production thereof |
| US20100190932A1 (en) * | 2007-07-27 | 2010-07-29 | Basf Se | Water-Absorbing Polymeric Particles and Method for the Production Thereof |
| JP5591118B2 (ja) * | 2007-12-14 | 2014-09-17 | ビーエーエスエフ ソシエタス・ヨーロピア | 吸水性ポリマー粒子の製造方法 |
| US8318306B2 (en) * | 2008-01-30 | 2012-11-27 | Evonik Stockhausen, Llc | Superabsorbent polymer compositions having a triggering composition |
| CN102124039B (zh) | 2008-09-16 | 2013-04-24 | 株式会社日本触媒 | 吸水性树脂的制造方法和通液性提高方法 |
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| WO2010130703A2 (de) * | 2009-05-15 | 2010-11-18 | Basf Se | Automatische analyse von feinteiligen feststoffen |
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| JP5801203B2 (ja) | 2009-09-29 | 2015-10-28 | 株式会社日本触媒 | 粒子状吸水剤及びその製造方法 |
| EP2527391B1 (en) | 2010-01-20 | 2023-08-09 | Nippon Shokubai Co., Ltd. | Method for producing water absorbent resin |
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| EP3115382B1 (en) | 2010-04-07 | 2019-07-10 | Nippon Shokubai Co., Ltd. | Method for producing water absorbent polyacrylic acid (salt) resin powder, and water absorbent polyacrylic acid (salt) resin powder |
| KR101989142B1 (ko) | 2010-09-30 | 2019-06-13 | 가부시기가이샤 닛뽕쇼꾸바이 | 입자상 흡수제 및 그 제조 방법 |
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| US8664151B2 (en) | 2011-06-01 | 2014-03-04 | The Procter & Gamble Company | Articles comprising reinforced polyurethane coating agent |
| WO2012164017A1 (en) | 2011-06-01 | 2012-12-06 | Basf Se | Fast water-absorbing material having a coating of elastic film-forming polyurethane with high wicking |
| EP2727953B1 (en) | 2011-06-29 | 2017-03-08 | Nippon Shokubai Co., Ltd. | Polyacrylic acid (salt) water-absorbent resin powder, and method for producing same |
| ES2686023T5 (es) | 2011-10-18 | 2024-11-27 | Basf Se | Artículo absorbente de fluidos |
| KR102125105B1 (ko) | 2012-08-01 | 2020-06-19 | 가부시키가이샤 닛폰 쇼쿠바이 | 폴리아크릴산(염)계 흡수성 수지의 제조 방법 |
| US20150225514A1 (en) | 2012-09-11 | 2015-08-13 | Nippon Shokubai Co., Ltd. | Method for producing polyacrylic acid (salt)-based water absorbing agent, and water absorbing agent |
| CN104640441B (zh) * | 2012-10-09 | 2018-01-19 | 株式会社大贵 | 吸水处理材 |
| KR20150090067A (ko) | 2012-11-27 | 2015-08-05 | 가부시키가이샤 닛폰 쇼쿠바이 | 폴리아크릴산(염)계 흡수성 수지의 제조 방법 |
| CN104684969B (zh) | 2013-04-30 | 2016-03-23 | 株式会社Lg化学 | 高吸水树脂 |
| EP3473655B1 (de) | 2013-10-30 | 2021-06-09 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel durch suspensionspolymerisation |
| CN106132534B (zh) * | 2014-03-31 | 2020-06-19 | 株式会社日本触媒 | 颗粒状吸水剂及其制造方法 |
| JP6805144B2 (ja) * | 2014-12-04 | 2020-12-23 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 吸水性ポリマー粒子を懸濁重合によって製造する方法 |
| JP7014605B2 (ja) * | 2015-02-27 | 2022-02-01 | ビーエーエスエフ ソシエタス・ヨーロピア | 吸水性ポリマー粒子を懸濁重合によって製造する方法 |
| KR101857702B1 (ko) * | 2015-12-23 | 2018-05-14 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| US11198768B2 (en) | 2016-03-11 | 2021-12-14 | Lg Chem, Ltd. | Preparation method of super absorbent polymer |
| KR102637493B1 (ko) | 2018-09-28 | 2024-02-15 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 및 고흡수성 수지 |
| EP4105242A4 (en) | 2020-02-14 | 2024-07-10 | Nippon Shokubai Co., Ltd. | WATER ABSORBING RESIN AND METHOD FOR ITS PRODUCTION |
| CN114929760A (zh) * | 2020-04-13 | 2022-08-19 | 株式会社Lg化学 | 超吸收性聚合物和用于制备其的方法 |
| JP7648287B2 (ja) | 2021-12-10 | 2025-03-18 | エルジー・ケム・リミテッド | 高吸水性樹脂の製造方法 |
| CN115181205A (zh) * | 2022-07-20 | 2022-10-14 | 浙江卫星新材料科技有限公司 | 一种气味轻的高吸收性树脂的制备方法 |
Family Cites Families (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6018690B2 (ja) | 1981-12-30 | 1985-05-11 | 住友精化株式会社 | 吸水性樹脂の吸水性改良方法 |
| JPS58180233A (ja) | 1982-04-19 | 1983-10-21 | Nippon Shokubai Kagaku Kogyo Co Ltd | 吸収剤 |
| US4734478A (en) | 1984-07-02 | 1988-03-29 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Water absorbing agent |
| DE3817425A1 (de) | 1988-05-21 | 1989-11-23 | Cassella Ag | Alkenyl-phosphon- und -phosphin-saeureester, verfahren zu ihrer herstellung sowie unter deren verwendung hergestellte hydrogele und deren verwendung |
| DE3836968A1 (de) | 1988-10-31 | 1990-05-03 | Basf Ag | Uv-vernetzbare massen auf basis von isoamyl(meth)acrylatcopolymerisaten |
| DE3844444A1 (de) | 1988-12-31 | 1990-08-09 | Basf Ag | Strahlungsempfindliche, ethylenisch ungesaettigte, copolymerisierbare verbindungen und verfahren zu deren herstellung |
| DE3844445A1 (de) | 1988-12-31 | 1990-07-19 | Basf Ag | Uv-vernetzbare massen auf basis von (meth)-acrylesterpolymerisaten |
| WO1990015830A1 (en) | 1989-06-12 | 1990-12-27 | Weyerhaeuser Company | Hydrocolloid polymer |
| DE4007318A1 (de) | 1990-03-08 | 1991-09-12 | Basf Ag | Ethylenisch ungesaettigte verbindungen |
| AU637470B2 (en) | 1990-04-02 | 1993-05-27 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Method for production of fluid stable aggregate |
| DE4020780C1 (https=) | 1990-06-29 | 1991-08-29 | Chemische Fabrik Stockhausen Gmbh, 4150 Krefeld, De | |
| EP0530438B1 (en) | 1991-09-03 | 1997-02-12 | Hoechst Celanese Corporation | A superabsorbent polymer having improved absorbency properties |
| DE4131045C1 (https=) | 1991-09-18 | 1992-11-19 | Cassella Ag, 6000 Frankfurt, De | |
| DE4138408A1 (de) | 1991-11-22 | 1993-05-27 | Cassella Ag | Hydrophile, hochquellfaehige hydrogele |
| JP3045422B2 (ja) | 1991-12-18 | 2000-05-29 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
| EP0559476B1 (en) | 1992-03-05 | 1997-07-16 | Nippon Shokubai Co., Ltd. | Method for the production of absorbent resin |
| GB9208449D0 (en) | 1992-04-16 | 1992-06-03 | Dow Deutschland Inc | Crosslinked hydrophilic resins and method of preparation |
| EP0838483B1 (en) | 1993-06-18 | 2009-09-09 | Nippon Shokubai Co., Ltd. | Process for preparing absorbent resin |
| NZ268535A (en) | 1993-06-30 | 1998-05-27 | Procter & Gamble | Absorbent article comprising layers of superabsorbent material |
| JP3722858B2 (ja) | 1993-11-25 | 2005-11-30 | ビーエーエスエフ アクチェンゲゼルシャフト | ポリアクリレート溶融体から残留揮発分を除去する方法 |
| US5599335A (en) | 1994-03-29 | 1997-02-04 | The Procter & Gamble Company | Absorbent members for body fluids having good wet integrity and relatively high concentrations of hydrogel-forming absorbent polymer |
| US5624967A (en) | 1994-06-08 | 1997-04-29 | Nippon Shokubai Co., Ltd. | Water-absorbing resin and process for producing same |
| DE19543368C2 (de) | 1995-11-21 | 1998-11-26 | Stockhausen Chem Fab Gmbh | Wasserabsorbierende Polymere mit verbesserten Eigenschaften, Verfahren zu deren Herstellung und deren Verwendung |
| DE19646484C2 (de) | 1995-11-21 | 2000-10-19 | Stockhausen Chem Fab Gmbh | Flüssigkeitsabsorbierende Polymere, Verfahren zu deren Herstellung und deren Verwendung |
| DE19807502B4 (de) * | 1998-02-21 | 2004-04-08 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit 2-Oxazolidinonen, daraus hergestellte Hydrogele und deren Verwendung |
| US6265488B1 (en) | 1998-02-24 | 2001-07-24 | Nippon Shokubai Co., Ltd. | Production process for water-absorbing agent |
| US6503979B1 (en) | 1998-02-26 | 2003-01-07 | Basf Aktiengesellschaft | Method for cross-linking hydrogels with bis- and poly-2-oxazolidinones |
| KR100476170B1 (ko) | 1998-04-28 | 2005-03-10 | 니폰 쇼쿠바이 컴파니 리미티드 | 흡수성수지 함수겔상물의 제조방법 |
| DE19854573A1 (de) | 1998-11-26 | 2000-05-31 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit 2-Oxo-tetrahydro-1,3-oxazinen |
| DE19854574A1 (de) | 1998-11-26 | 2000-05-31 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit N-Acyl-2-Oxazolidinonen |
| DE19909653A1 (de) * | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19909838A1 (de) * | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19941423A1 (de) | 1999-08-30 | 2001-03-01 | Stockhausen Chem Fab Gmbh | Polymerzusammensetzung und ein Verfahren zu dessen Herstellung |
| US6239230B1 (en) | 1999-09-07 | 2001-05-29 | Bask Aktiengesellschaft | Surface-treated superabsorbent polymer particles |
| DE19955861A1 (de) | 1999-11-20 | 2001-05-23 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von vernetzten feinteiligen gelförmigen Polymerisaten |
| EP1244474A1 (en) | 1999-12-23 | 2002-10-02 | The Dow Chemical Company | High permeability, low absorption capacity polymers |
| US6720389B2 (en) | 2000-09-20 | 2004-04-13 | Nippon Shokubai Co., Ltd. | Water-absorbent resin and production process therefor |
| US6809158B2 (en) | 2000-10-20 | 2004-10-26 | Nippon Shokubai Co., Ltd. | Water-absorbing agent and process for producing the same |
| AU2002230831A1 (en) | 2000-10-20 | 2002-04-29 | Millennium Pharmaceuticals, Inc. | Compositions of human proteins and method of use thereof |
| WO2002053199A1 (de) * | 2000-12-29 | 2002-07-11 | Basf Aktiengesellschaft | Hydrogele mit sterischen oder elektrostatischen abstandhaltern beschichtet |
| US6831122B2 (en) | 2001-01-19 | 2004-12-14 | Basf Aktiengesellschaft | Water-absorbing agent, method for the production and the utilization thereof |
| US6766807B2 (en) * | 2001-03-05 | 2004-07-27 | Snow Ellen Piccolo | Combination floss dispenser and toothbrush |
| US6766817B2 (en) | 2001-07-25 | 2004-07-27 | Tubarc Technologies, Llc | Fluid conduction utilizing a reversible unsaturated siphon with tubarc porosity action |
| US8426670B2 (en) | 2001-09-19 | 2013-04-23 | Nippon Shokubai Co., Ltd. | Absorbent structure, absorbent article, water-absorbent resin, and its production process and evaluation method |
| BR0212952A (pt) | 2001-10-05 | 2004-10-13 | Basf Ag | Processos para a reticulação e pós-reticulação superficial de polìmeros iniciais, composição de matéria, polìmero, e, usos de polìmeros e de uma composição de matéria |
| WO2003065958A1 (en) | 2002-02-04 | 2003-08-14 | Nippon Shokubai Co., Ltd. | Absorptive material, method for producing the same and absorptive article using the same |
| DE10204937A1 (de) | 2002-02-07 | 2003-08-21 | Stockhausen Chem Fab Gmbh | Verfahren zur Nachvernetzung im Bereich der Oberfläche von wasserabsorbierenden Polymeren mit Harnstoffderivaten |
| DE10204938A1 (de) | 2002-02-07 | 2003-08-21 | Stockhausen Chem Fab Gmbh | Verfahren zur Nachvernetzung im Bereich der Oberfläche von wasserabsorbierenden Polymeren mit beta-Hydroxyalkylamiden |
| DE10225943A1 (de) | 2002-06-11 | 2004-01-08 | Basf Ag | Verfahren zur Herstellung von Estern von Polyalkoholen |
| CA2488226A1 (en) | 2002-06-11 | 2003-12-18 | Basf Aktiengesellschaft | (meth)acrylic esters of polyalkoxylated trimethylolpropane |
| CA2487030A1 (en) | 2002-06-11 | 2003-12-18 | Basf Aktiengesellschaft | (meth)acrylic esters of polyalkoxylated glycerine |
| DE10239074A1 (de) * | 2002-08-26 | 2004-03-11 | Basf Ag | Wasserabsorbierendes Mittel und Verfahren zu seiner Herstellung |
| DE10257449A1 (de) * | 2002-12-09 | 2003-11-06 | Basf Ag | Verfahren zur Herstellung geruchsarmer Hydrogel-bildender Polymerisate |
| EP1594557B1 (en) | 2003-02-10 | 2019-05-01 | Nippon Shokubai Co., Ltd. | Water-absorbent resin composition and its production process |
| CN100346843C (zh) | 2003-02-10 | 2007-11-07 | 株式会社日本触媒 | 吸水剂 |
| JP4739682B2 (ja) * | 2003-02-10 | 2011-08-03 | 株式会社日本触媒 | 吸水剤 |
| EP1594608B1 (en) | 2003-02-10 | 2013-07-17 | Nippon Shokubai Co., Ltd. | Particulate water absorbent containing water absorbent resin as a main component |
| DE10331450A1 (de) | 2003-07-10 | 2005-01-27 | Basf Ag | (Meth)acrylsäureester monoalkoxilierter Polyole und deren Herstellung |
| DE10331456A1 (de) | 2003-07-10 | 2005-02-24 | Basf Ag | (Meth)acrylsäureester alkoxilierter ungesättigter Polyolether und deren Herstellung |
| DE10334584A1 (de) | 2003-07-28 | 2005-02-24 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit bicyclischen Amidacetalen |
| JP4695370B2 (ja) * | 2003-09-19 | 2011-06-08 | 株式会社日本触媒 | 表面処理された吸水性樹脂の製造方法 |
| DE10355401A1 (de) | 2003-11-25 | 2005-06-30 | Basf Ag | (Meth)acrylsäureester ungesättigter Aminoalkohole und deren Herstellung |
| DE102004009438A1 (de) | 2004-02-24 | 2005-09-15 | Basf Ag | Verfahren zur Oberflächennachvernetzung wasserabsorbierender Polymere |
| DE102004015686A1 (de) | 2004-03-29 | 2005-10-27 | Basf Ag | Quellbare hydrogelbildende Polymere mit hoher Permeabilität |
| DE102004038015A1 (de) * | 2004-08-04 | 2006-03-16 | Basf Ag | Verfahren zur Nachvernetzung wasserabsorbierender Polymere mit zyklischen Carba-maten und/oder zyklischen Harnstoffen |
-
2004
- 2004-10-20 DE DE102004051242A patent/DE102004051242A1/de not_active Withdrawn
-
2005
- 2005-10-14 US US11/665,883 patent/US7759422B2/en active Active
- 2005-10-14 EP EP10173415A patent/EP2258409A1/de not_active Withdrawn
- 2005-10-14 JP JP2007537171A patent/JP2008517116A/ja active Pending
- 2005-10-14 CN CN200580043376XA patent/CN101080245B/zh not_active Expired - Lifetime
- 2005-10-14 EP EP05798199A patent/EP1804842A2/de not_active Ceased
- 2005-10-14 EP EP10173417A patent/EP2263704A1/de not_active Withdrawn
- 2005-10-14 WO PCT/EP2005/011073 patent/WO2006042704A2/de not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008000237A1 (de) | 2007-02-06 | 2008-08-07 | Basf Se | Phenol-Imidazolderivate zur Stabilisierung von polymerisationsfähigen Verbindungen |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008517116A (ja) | 2008-05-22 |
| CN101080245B (zh) | 2012-06-06 |
| EP2258409A1 (de) | 2010-12-08 |
| WO2006042704A3 (de) | 2006-08-10 |
| US20080125533A1 (en) | 2008-05-29 |
| EP2263704A1 (de) | 2010-12-22 |
| WO2006042704A2 (de) | 2006-04-27 |
| CN101080245A (zh) | 2007-11-28 |
| EP1804842A2 (de) | 2007-07-11 |
| US7759422B2 (en) | 2010-07-20 |
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