CS201505B2 - Method of producing purple titanium trichloride - Google Patents
Method of producing purple titanium trichloride Download PDFInfo
- Publication number
- CS201505B2 CS201505B2 CS774623A CS462377A CS201505B2 CS 201505 B2 CS201505 B2 CS 201505B2 CS 774623 A CS774623 A CS 774623A CS 462377 A CS462377 A CS 462377A CS 201505 B2 CS201505 B2 CS 201505B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- dbe
- toluene
- complexing agent
- titanium tetrachloride
- purple
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 23
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 title abstract description 12
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 34
- 239000008139 complexing agent Substances 0.000 claims abstract description 23
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 239000003960 organic solvent Substances 0.000 claims abstract description 9
- 239000011541 reaction mixture Substances 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 150000001924 cycloalkanes Chemical class 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229910010062 TiCl3 Inorganic materials 0.000 abstract description 11
- 229910003074 TiCl4 Inorganic materials 0.000 abstract description 10
- 239000000203 mixture Substances 0.000 abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 abstract description 2
- 238000001556 precipitation Methods 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 183
- 230000000052 comparative effect Effects 0.000 description 32
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 10
- 125000005234 alkyl aluminium group Chemical group 0.000 description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- KTZHUTMWYRHVJB-UHFFFAOYSA-K thallium(3+);trichloride Chemical compound Cl[Tl](Cl)Cl KTZHUTMWYRHVJB-UHFFFAOYSA-K 0.000 description 7
- 239000008096 xylene Substances 0.000 description 7
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 5
- -1 alkyl aluminum compound Chemical class 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000000707 stereoselective effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910010165 TiCu Inorganic materials 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000012721 stereospecific polymerization Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical group CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical group CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 241001676573 Minium Species 0.000 description 1
- 229910010061 TiC13 Inorganic materials 0.000 description 1
- 229910010068 TiCl2 Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Chemical group 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB28897/76A GB1579725A (en) | 1976-07-12 | 1976-07-12 | Preparation of violet tici3 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS201505B2 true CS201505B2 (en) | 1980-11-28 |
Family
ID=10282951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS774623A CS201505B2 (en) | 1976-07-12 | 1977-07-11 | Method of producing purple titanium trichloride |
Country Status (26)
| Country | Link |
|---|---|
| US (1) | US4195069A (OSRAM) |
| JP (1) | JPS539296A (OSRAM) |
| AR (1) | AR216476A1 (OSRAM) |
| AT (1) | AT355298B (OSRAM) |
| AU (1) | AU508618B2 (OSRAM) |
| BE (1) | BE856418A (OSRAM) |
| BR (1) | BR7704536A (OSRAM) |
| CA (1) | CA1095017A (OSRAM) |
| CS (1) | CS201505B2 (OSRAM) |
| DE (1) | DE2731241A1 (OSRAM) |
| DK (1) | DK314677A (OSRAM) |
| ES (2) | ES460624A1 (OSRAM) |
| FR (1) | FR2358360A1 (OSRAM) |
| GB (1) | GB1579725A (OSRAM) |
| HU (1) | HU177378B (OSRAM) |
| IL (1) | IL52500A (OSRAM) |
| IT (1) | IT1126749B (OSRAM) |
| LU (1) | LU77733A1 (OSRAM) |
| NL (1) | NL7707676A (OSRAM) |
| NO (1) | NO141847C (OSRAM) |
| PL (1) | PL109141B1 (OSRAM) |
| PT (1) | PT66790B (OSRAM) |
| SE (1) | SE7708055L (OSRAM) |
| SU (1) | SU664555A3 (OSRAM) |
| TR (1) | TR19723A (OSRAM) |
| ZA (1) | ZA774143B (OSRAM) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1121329A (en) * | 1978-07-25 | 1982-04-06 | Andras G.T.G. Kortbeek | Olefin polymerization catalysts |
| JPS55116626A (en) * | 1979-03-01 | 1980-09-08 | Mitsubishi Chem Ind Ltd | Manufacture of solid titanium trichloride |
| US4366297A (en) * | 1979-10-23 | 1982-12-28 | Japan Ep Rubber Co., Ltd. | Process for producing olefinic copolymer rubber with improved titanium compound containing catalyst system |
| DE3368644D1 (en) * | 1982-07-13 | 1987-02-05 | Mitsubishi Chem Ind | Process for preparing solid titanium trichloride useful for the polymerization of an alpha-olefin |
| JPS61113823A (ja) * | 1984-11-06 | 1986-05-31 | Toyobo Co Ltd | ポリアミド系潜在巻縮性複合繊維 |
| US5315053A (en) * | 1985-06-17 | 1994-05-24 | Chevron Research Company | Normally liquid alpha-olefin oligomers useful as base stocks and viscosity index improvers, and lubricating oils containing same |
| US5177276A (en) * | 1985-06-17 | 1993-01-05 | Chevron Research Company | Alpha-olefin oligomers useful as base stocks and viscosity index improvers, and lubricating oils containing same |
| JP2717306B2 (ja) * | 1989-05-02 | 1998-02-18 | チッソ株式会社 | 複合紡糸口金装置 |
| BE1003968A3 (fr) * | 1990-11-08 | 1992-07-28 | Solvay | Solide catalytique utilisable pour la polymerisation stereospecifique des alpha-olefines, procede pour le preparer et procede pour polymeriser des alpha-olefines en sa presence |
| US6465383B2 (en) | 2000-01-12 | 2002-10-15 | Eastman Chemical Company | Procatalysts, catalyst systems, and use in olefin polymerization |
| BRPI0107604B1 (pt) | 2000-01-12 | 2015-03-31 | Westlake Longview Corp | Pró-catalisador sólido, sistema catalisador, e, processo para a polimerização de pelo menos uma ou mais olefinas |
| US6696380B2 (en) | 2000-01-12 | 2004-02-24 | Darryl Stephen Williams | Procatalysts, catalyst systems, and use in olefin polymerization |
| RU2707362C1 (ru) * | 2019-04-05 | 2019-11-26 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский химико-технологический университет имени Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) | Способ получения треххлористого титана |
| RU2711226C1 (ru) * | 2019-04-05 | 2020-01-15 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский химико-технологический университет имени Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) | Способ получения треххлористого титана |
| US20240018171A1 (en) | 2022-07-15 | 2024-01-18 | Hindustan Petroleum Corporation Limited | Novel titanium complexes as catalysts for alpha olefin polymerization |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1152192A (en) | 1965-07-23 | 1969-05-14 | Sir Soc Italiana Resine Spa | Method of Preparing Catalytically Active TiCI3 |
| US3466140A (en) * | 1967-03-31 | 1969-09-09 | Goodyear Tire & Rubber | Process for producing reduced transition metal halides |
| US3558271A (en) * | 1969-06-25 | 1971-01-26 | Benedetto Calcagno | Method of preparing catalytically active ticl3 |
| IE35231B1 (en) | 1970-03-26 | 1975-12-24 | Solvay | Process for the preparation of a ziegler-natta type catalyst |
| CH543546A (fr) | 1971-03-23 | 1973-10-31 | Solvay | Système catalytique de polymérisation des alpha-oléfines |
| DE2533511C2 (de) | 1974-07-31 | 1984-11-29 | Mitsubishi Chemical Industries Ltd., Tokio/Tokyo | Verfahren zur Herstellung von festem purpurfarbenem feingranuliertem Titantrichlorid und seine Verwendung zur Polymerisation von α-Olefinen |
| US4060593A (en) * | 1974-07-31 | 1977-11-29 | Mitsubishi Chemical Industries | Preparation of titanium trichloride |
| NL7606139A (nl) | 1975-06-11 | 1976-12-14 | Shell Int Research | Werkwijze ter bereiding van violet tic13. |
| US4085064A (en) * | 1975-12-12 | 1978-04-18 | Exxon Research & Engineering Co. | Purple TiCl3 by direct low temperature reduction |
-
1976
- 1976-07-12 GB GB28897/76A patent/GB1579725A/en not_active Expired
-
1977
- 1977-06-10 CA CA000280290A patent/CA1095017A/en not_active Expired
- 1977-06-17 US US05/807,696 patent/US4195069A/en not_active Expired - Lifetime
- 1977-07-04 BE BE1008252A patent/BE856418A/xx unknown
- 1977-07-11 SU SU772500805A patent/SU664555A3/ru active
- 1977-07-11 HU HU77SE1862A patent/HU177378B/hu unknown
- 1977-07-11 PL PL1977199533A patent/PL109141B1/pl not_active IP Right Cessation
- 1977-07-11 AT AT496177A patent/AT355298B/de not_active IP Right Cessation
- 1977-07-11 DK DK314677A patent/DK314677A/da unknown
- 1977-07-11 DE DE19772731241 patent/DE2731241A1/de not_active Withdrawn
- 1977-07-11 IL IL52500A patent/IL52500A/xx unknown
- 1977-07-11 ES ES460624A patent/ES460624A1/es not_active Expired
- 1977-07-11 TR TR19723A patent/TR19723A/xx unknown
- 1977-07-11 IT IT50215/77A patent/IT1126749B/it active
- 1977-07-11 SE SE7708055A patent/SE7708055L/xx unknown
- 1977-07-11 FR FR7721279A patent/FR2358360A1/fr active Pending
- 1977-07-11 ES ES460610A patent/ES460610A1/es not_active Expired
- 1977-07-11 BR BR7704536A patent/BR7704536A/pt unknown
- 1977-07-11 ZA ZA00774143A patent/ZA774143B/xx unknown
- 1977-07-11 PT PT66790A patent/PT66790B/pt unknown
- 1977-07-11 AU AU26904/77A patent/AU508618B2/en not_active Expired
- 1977-07-11 CS CS774623A patent/CS201505B2/cs unknown
- 1977-07-11 NL NL7707676A patent/NL7707676A/xx not_active Application Discontinuation
- 1977-07-11 JP JP8209277A patent/JPS539296A/ja active Pending
- 1977-07-11 AR AR268392A patent/AR216476A1/es active
- 1977-07-11 NO NO772440A patent/NO141847C/no unknown
- 1977-07-11 LU LU77733A patent/LU77733A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO141847B (no) | 1980-02-11 |
| NO772440L (no) | 1978-01-13 |
| AR216476A1 (es) | 1979-12-28 |
| ZA774143B (en) | 1978-05-30 |
| DE2731241A1 (de) | 1978-01-19 |
| PL109141B1 (en) | 1980-05-31 |
| BR7704536A (pt) | 1978-06-06 |
| IL52500A0 (en) | 1977-10-31 |
| SU664555A3 (ru) | 1979-05-25 |
| NO141847C (no) | 1980-05-21 |
| GB1579725A (en) | 1980-11-26 |
| JPS539296A (en) | 1978-01-27 |
| HU177378B (en) | 1981-09-28 |
| IT1126749B (it) | 1986-05-21 |
| BE856418A (nl) | 1978-01-04 |
| ATA496177A (de) | 1979-07-15 |
| LU77733A1 (OSRAM) | 1978-02-02 |
| TR19723A (tr) | 1979-10-16 |
| PT66790B (en) | 1978-12-19 |
| AU508618B2 (en) | 1980-03-27 |
| ES460610A1 (es) | 1978-05-01 |
| ES460624A1 (es) | 1978-05-01 |
| CA1095017A (en) | 1981-02-03 |
| PT66790A (en) | 1977-08-01 |
| SE7708055L (sv) | 1978-01-13 |
| AT355298B (de) | 1980-02-25 |
| NL7707676A (nl) | 1978-01-16 |
| IL52500A (en) | 1980-01-31 |
| FR2358360A1 (fr) | 1978-02-10 |
| PL199533A1 (pl) | 1978-04-10 |
| US4195069A (en) | 1980-03-25 |
| AU2690477A (en) | 1979-01-18 |
| DK314677A (da) | 1978-01-13 |
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