CN1997681B - 具有高流动性和高弹性的嵌段共聚物 - Google Patents
具有高流动性和高弹性的嵌段共聚物 Download PDFInfo
- Publication number
- CN1997681B CN1997681B CN2005800117461A CN200580011746A CN1997681B CN 1997681 B CN1997681 B CN 1997681B CN 2005800117461 A CN2005800117461 A CN 2005800117461A CN 200580011746 A CN200580011746 A CN 200580011746A CN 1997681 B CN1997681 B CN 1997681B
- Authority
- CN
- China
- Prior art keywords
- block
- goods
- segmented copolymer
- molecular weight
- hydrogenation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001400 block copolymer Polymers 0.000 title abstract description 101
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 52
- 238000000034 method Methods 0.000 claims abstract description 19
- 239000000654 additive Substances 0.000 claims abstract description 18
- 238000000465 moulding Methods 0.000 claims abstract description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 105
- 229920000642 polymer Polymers 0.000 claims description 59
- 229920001577 copolymer Polymers 0.000 claims description 37
- 239000000203 mixture Substances 0.000 claims description 31
- 239000011347 resin Substances 0.000 claims description 30
- 229920005989 resin Polymers 0.000 claims description 30
- -1 line Substances 0.000 claims description 24
- 239000004793 Polystyrene Substances 0.000 claims description 23
- 229920002223 polystyrene Polymers 0.000 claims description 22
- 239000000155 melt Substances 0.000 claims description 17
- 239000000835 fiber Substances 0.000 claims description 16
- 229920001195 polyisoprene Polymers 0.000 claims description 16
- 239000007822 coupling agent Substances 0.000 claims description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 11
- 239000005977 Ethylene Substances 0.000 claims description 11
- 239000004743 Polypropylene Substances 0.000 claims description 10
- 229920000573 polyethylene Polymers 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- 229920000098 polyolefin Polymers 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 238000001746 injection moulding Methods 0.000 claims description 7
- 238000011084 recovery Methods 0.000 claims description 7
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 238000001175 rotational moulding Methods 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 4
- 229920000034 Plastomer Polymers 0.000 claims description 3
- 229920003247 engineering thermoplastic Polymers 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 2
- 238000005187 foaming Methods 0.000 claims description 2
- 230000036571 hydration Effects 0.000 claims 2
- 238000006703 hydration reaction Methods 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 229920003023 plastic Polymers 0.000 claims 1
- 210000003660 reticulum Anatomy 0.000 claims 1
- 239000012745 toughening agent Substances 0.000 claims 1
- 238000001125 extrusion Methods 0.000 abstract description 12
- 230000008569 process Effects 0.000 abstract description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 54
- 238000005859 coupling reaction Methods 0.000 description 21
- 230000008878 coupling Effects 0.000 description 18
- 238000010168 coupling process Methods 0.000 description 18
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 17
- 229920002554 vinyl polymer Polymers 0.000 description 16
- 239000005062 Polybutadiene Substances 0.000 description 13
- 229920002857 polybutadiene Polymers 0.000 description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 12
- 238000005227 gel permeation chromatography Methods 0.000 description 12
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 10
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 9
- 150000001993 dienes Chemical class 0.000 description 7
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000006057 Non-nutritive feed additive Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 239000013032 Hydrocarbon resin Substances 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 229920006270 hydrocarbon resin Polymers 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229920005629 polypropylene homopolymer Polymers 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- VPBZZPOGZPKYKX-UHFFFAOYSA-N 1,2-diethoxypropane Chemical compound CCOCC(C)OCC VPBZZPOGZPKYKX-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- 241001120493 Arene Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 239000004708 Very-low-density polyethylene Substances 0.000 description 2
- 229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 229940117927 ethylene oxide Drugs 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 229920001179 medium density polyethylene Polymers 0.000 description 2
- 239000004701 medium-density polyethylene Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920005638 polyethylene monopolymer Polymers 0.000 description 2
- 229920001955 polyphenylene ether Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- 229920001866 very low density polyethylene Polymers 0.000 description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- GVLZQVREHWQBJN-UHFFFAOYSA-N 3,5-dimethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound CC1=C(O2)C(C)=CC2=C1 GVLZQVREHWQBJN-UHFFFAOYSA-N 0.000 description 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004412 Bulk moulding compound Substances 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NEAPKZHDYMQZCB-UHFFFAOYSA-N N-[2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]ethyl]-2-oxo-3H-1,3-benzoxazole-6-carboxamide Chemical compound C1CN(CCN1CCNC(=O)C2=CC3=C(C=C2)NC(=O)O3)C4=CN=C(N=C4)NC5CC6=CC=CC=C6C5 NEAPKZHDYMQZCB-UHFFFAOYSA-N 0.000 description 1
- 229920001744 Polyaldehyde Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002732 Polyanhydride Polymers 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000003677 Sheet moulding compound Substances 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 229920010524 Syndiotactic polystyrene Polymers 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- PKTDPMGQJRSFHE-UHFFFAOYSA-L [Co++].CC[Al](CC)CC.CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O Chemical compound [Co++].CC[Al](CC)CC.CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O PKTDPMGQJRSFHE-UHFFFAOYSA-L 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229920006272 aromatic hydrocarbon resin Polymers 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical class OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 1
- QNRMTGGDHLBXQZ-UHFFFAOYSA-N buta-1,2-diene Chemical compound CC=C=C QNRMTGGDHLBXQZ-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- NZMKIFMOEMHAFW-UHFFFAOYSA-N chlorane Chemical class Cl.Cl.Cl.Cl.Cl.Cl.Cl.Cl NZMKIFMOEMHAFW-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 210000004177 elastic tissue Anatomy 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical compound C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000002454 metastable transfer emission spectrometry Methods 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical class CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002900 organolithium compounds Chemical class 0.000 description 1
- 229920000090 poly(aryl ether) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- MQHSFMJHURNQIE-UHFFFAOYSA-N tetrakis(2-ethylhexyl) silicate Chemical compound CCCCC(CC)CO[Si](OCC(CC)CCCC)(OCC(CC)CCCC)OCC(CC)CCCC MQHSFMJHURNQIE-UHFFFAOYSA-N 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- XFVUECRWXACELC-UHFFFAOYSA-N trimethyl oxiran-2-ylmethyl silicate Chemical compound CO[Si](OC)(OC)OCC1CO1 XFVUECRWXACELC-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4291—Olefin series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4334—Polyamides
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Multicomponent Fibers (AREA)
- Nonwoven Fabrics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Filtering Materials (AREA)
- Woven Fabrics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US54957004P | 2004-03-03 | 2004-03-03 | |
| US60/549,570 | 2004-03-03 | ||
| PCT/US2005/006283 WO2005092936A2 (en) | 2004-03-03 | 2005-03-01 | Block copolymers having high flow and high elasticity |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1997681A CN1997681A (zh) | 2007-07-11 |
| CN1997681B true CN1997681B (zh) | 2010-05-05 |
Family
ID=34961513
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005800117461A Expired - Lifetime CN1997681B (zh) | 2004-03-03 | 2005-03-01 | 具有高流动性和高弹性的嵌段共聚物 |
| CNB2005800109126A Expired - Fee Related CN100569849C (zh) | 2004-03-03 | 2005-03-01 | 包含具有高流动性的嵌段共聚物的弹性体双组分纤维 |
| CNA2005800131242A Pending CN1946798A (zh) | 2004-03-03 | 2005-03-01 | 包含具有高流动性和高弹性的嵌段共聚物的聚合物组合物 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005800109126A Expired - Fee Related CN100569849C (zh) | 2004-03-03 | 2005-03-01 | 包含具有高流动性的嵌段共聚物的弹性体双组分纤维 |
| CNA2005800131242A Pending CN1946798A (zh) | 2004-03-03 | 2005-03-01 | 包含具有高流动性和高弹性的嵌段共聚物的聚合物组合物 |
Country Status (10)
| Country | Link |
|---|---|
| US (4) | US7910208B2 (enExample) |
| EP (4) | EP2586803B1 (enExample) |
| JP (2) | JP5080967B2 (enExample) |
| KR (2) | KR100807917B1 (enExample) |
| CN (3) | CN1997681B (enExample) |
| AU (1) | AU2005226781B2 (enExample) |
| BR (2) | BRPI0508388A (enExample) |
| ES (1) | ES2565410T3 (enExample) |
| TW (2) | TWI288754B (enExample) |
| WO (2) | WO2005092979A1 (enExample) |
Families Citing this family (90)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7517932B2 (en) * | 2003-03-24 | 2009-04-14 | Kraton Polymers U.S. Llc | Poly(styrene-butadiene-styrene)polymers having a high vinyl content in the butadiene block and hot melt adhesive composition comprising said polymers |
| EP1723199A1 (en) * | 2004-03-03 | 2006-11-22 | KRATON Polymers Research B.V. | Polymeric compositions containing block copolymers having high flow and high elasticity |
| BRPI0508388A (pt) * | 2004-03-03 | 2007-08-07 | Kraton Polymers Res Bv | fibra bicomponente, artigo, e, processo para produzir a fibra bicomponente |
| US7819761B2 (en) | 2005-01-26 | 2010-10-26 | Taylor Made Golf Company, Inc. | Golf ball having cross-core hardness differential and method for making it |
| US7569281B2 (en) * | 2005-07-25 | 2009-08-04 | Kraton Polymers U.S. Llc | Flexible packaging laminate films including a block copolymer layer |
| US20070026251A1 (en) * | 2005-07-26 | 2007-02-01 | Kraton Polymers U.S. Llc | Flexible packaging laminate films including a block copolymer layer |
| US20070055015A1 (en) * | 2005-09-02 | 2007-03-08 | Kraton Polymers U.S. Llc | Elastomeric fibers comprising controlled distribution block copolymers |
| JP2007154013A (ja) * | 2005-12-05 | 2007-06-21 | Jsr Corp | 不織布用共重合体、不織布用共重合体組成物、及び不織布 |
| US8030411B2 (en) | 2005-12-21 | 2011-10-04 | Taylor Made Golf Company, Inc. | Polymer compositions comprising peptizers, sports equipment comprising such compositions, and method for their manufacture |
| US9205302B2 (en) * | 2006-04-11 | 2015-12-08 | Taylor Made Golf Company, Inc. | Propylene elastomer compositions and golf balls that include such compositions |
| US20070270546A1 (en) * | 2006-04-24 | 2007-11-22 | Kraton Polymers U.S. Llc | Polymeric compositions and films formed therefrom |
| US7990679B2 (en) * | 2006-07-14 | 2011-08-02 | Dais Analytic Corporation | Nanoparticle ultracapacitor |
| WO2008039779A2 (en) * | 2006-09-25 | 2008-04-03 | Dais Analytic Corporation | Enhanced hvac system and method |
| JP5240477B2 (ja) | 2006-11-13 | 2013-07-17 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | ビチューメンエマルジョン |
| WO2008089484A1 (en) * | 2007-01-20 | 2008-07-24 | Dais Analytic Corporation | Multi-phase selective mass transfer through a membrane |
| WO2008114982A1 (en) * | 2007-03-16 | 2008-09-25 | Lg Electronics Inc. | A method and an apparatus for processing an audio signal |
| US7577433B2 (en) * | 2007-06-18 | 2009-08-18 | Cvon Innovations Limited | Method and system for managing delivery of communications |
| US8586637B2 (en) * | 2007-06-26 | 2013-11-19 | Dais Analytic Corporation | Stable and compatible polymer blends |
| US20090062457A1 (en) * | 2007-09-04 | 2009-03-05 | Kraton Polymers U.S. Llc | Styrenic block copolymers and compositions containing the same |
| US8211976B2 (en) | 2007-12-21 | 2012-07-03 | Taylor Made Golf Company, Inc. | Sports equipment compositions comprising a polyurethane, polyurea or prepolymer thereof and a polyfunctional modifier |
| KR101193772B1 (ko) * | 2007-12-21 | 2012-10-23 | 크레이튼 폴리머즈 유.에스. 엘엘씨 | 연질 탄성중합체 필름 |
| US8096899B2 (en) | 2007-12-28 | 2012-01-17 | Taylor Made Golf Company, Inc. | Golf ball comprising isocyanate-modified composition |
| KR20100126712A (ko) * | 2008-02-29 | 2010-12-02 | 다우 글로벌 테크놀로지스 인크. | 에틸렌/α-올레핀 혼성중합체로부터 제조된 섬유 및 직물 |
| CN101628959A (zh) * | 2008-07-15 | 2010-01-20 | 中国石油化工集团公司 | 一种可发泡苯乙烯属单体-二烯烃共聚物、其制备方法和用途 |
| US9732178B1 (en) | 2008-07-24 | 2017-08-15 | Bridgestone Corporation | Block copolymers including high vinyl segments |
| US9168718B2 (en) | 2009-04-21 | 2015-10-27 | Exxonmobil Chemical Patents Inc. | Method for producing temperature resistant nonwovens |
| US9498932B2 (en) | 2008-09-30 | 2016-11-22 | Exxonmobil Chemical Patents Inc. | Multi-layered meltblown composite and methods for making same |
| US10161063B2 (en) | 2008-09-30 | 2018-12-25 | Exxonmobil Chemical Patents Inc. | Polyolefin-based elastic meltblown fabrics |
| US8664129B2 (en) | 2008-11-14 | 2014-03-04 | Exxonmobil Chemical Patents Inc. | Extensible nonwoven facing layer for elastic multilayer fabrics |
| CN101817911B (zh) * | 2009-02-26 | 2013-09-25 | 中国石油化工股份有限公司 | 由异戊二烯、丁二烯和苯乙烯形成的星型嵌段共聚物及其制备方法和用途 |
| KR101348060B1 (ko) | 2009-02-27 | 2014-01-03 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 다층 부직 동일-공정계 라미네이트 및 이의 제조 방법 |
| JP5311050B2 (ja) * | 2009-09-30 | 2013-10-09 | 日本ゼオン株式会社 | 弾性フィラメント用組成物、弾性フィラメントおよび伸縮性シート |
| US8668975B2 (en) | 2009-11-24 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Fabric with discrete elastic and plastic regions and method for making same |
| US8575278B2 (en) | 2009-12-31 | 2013-11-05 | Taylor Made Golf Company, Inc. | Ionomer compositions for golf balls |
| US8629228B2 (en) | 2009-12-31 | 2014-01-14 | Taylor Made Golf Company, Inc. | Ionomer compositions for golf balls |
| US8674023B2 (en) | 2009-12-31 | 2014-03-18 | Taylor Made Golf Company, Inc. | Ionomer compositions for golf balls |
| US9393557B2 (en) | 2010-01-09 | 2016-07-19 | Dais Analytic Corporation | Anionic exchange electrolyte polymer membranes |
| US9013155B2 (en) | 2010-01-09 | 2015-04-21 | Dais Analytic Corporation | Energy storage devices including a solid multilayer electrolyte |
| CA2817719A1 (en) * | 2010-11-12 | 2012-05-18 | The Procter & Gamble Company | Elastomeric compositions that resist disintegration |
| US9017305B2 (en) * | 2010-11-12 | 2015-04-28 | The Procter Gamble Company | Elastomeric compositions that resist force loss and disintegration |
| US9293269B2 (en) | 2012-02-08 | 2016-03-22 | Dais Analytic Corporation | Ultracapacitor tolerating electric field of sufficient strength |
| US20130225020A1 (en) | 2012-02-24 | 2013-08-29 | Kraton Polymers Us Llc | High flow, hydrogenated styrene-butadiene-styrene block copolymer and applications |
| US9771473B2 (en) * | 2012-02-24 | 2017-09-26 | Kraton Polymers U.S. Llc | High flow, hydrogenated styrene-butadiene-styrene block copolymers and applications |
| CN102617970B (zh) * | 2012-04-26 | 2014-03-05 | 湖南汇中新材料有限公司 | 一种氢化嵌段共聚物弹性体-尼龙6的组合物 |
| WO2014055946A1 (en) * | 2012-10-04 | 2014-04-10 | North Carolina State University | Multicomponent fibers capable of thermally induced shape recovery and the making thereof |
| US10058808B2 (en) | 2012-10-22 | 2018-08-28 | Cummins Filtration Ip, Inc. | Composite filter media utilizing bicomponent fibers |
| JP6188306B2 (ja) * | 2012-11-08 | 2017-08-30 | スリーエム イノベイティブ プロパティズ カンパニー | 不織布及び伸縮性積層体 |
| CN104593895B (zh) * | 2013-11-01 | 2017-04-12 | 林晓 | 一种功能纤维基材及制备方法 |
| US9757901B2 (en) | 2013-11-26 | 2017-09-12 | Kraton Polymers U.S. Llc | Laser sintering powder, laser sintering article, and a method of making a laser sintering article |
| SG11201610385RA (en) | 2014-07-01 | 2017-01-27 | Asahi Chemical Ind | Polyolefin-based resin composition, film, medical bag, and tube |
| US9963585B2 (en) * | 2014-07-30 | 2018-05-08 | Tsrc Corporation | Polymer composition and compound therefrom for isotropic film, extruded and molded article |
| KR102213963B1 (ko) * | 2014-08-26 | 2021-02-08 | 주식회사 쿠라레 | 열가소성 중합체 조성물, 및 성형품 |
| CN104194359B (zh) * | 2014-08-27 | 2016-05-11 | 陕西国础实业有限公司 | 一种热熔胶粘性改性路面沥青 |
| KR20170051432A (ko) | 2014-09-09 | 2017-05-11 | 에이치. 비. 풀러, 컴퍼니 | 적어도 하나의 탄성 접합 영역을 포함하는 일회용 물품 |
| US10150896B2 (en) | 2014-12-19 | 2018-12-11 | Tredegar Film Products Corporation | Surface protection film |
| US10329418B2 (en) * | 2015-02-11 | 2019-06-25 | Polyone Corporation | Damping thermoplastic elastomer articles with low compression set |
| US10457805B2 (en) | 2015-02-11 | 2019-10-29 | Polyone Corporation | Damping thermoplastic elastomers |
| CN107223148A (zh) * | 2015-02-11 | 2017-09-29 | 普立万公司 | 声音阻尼热塑性弹性体制品 |
| CN107207866A (zh) * | 2015-02-11 | 2017-09-26 | 普立万公司 | 阻尼热塑性弹性体 |
| WO2016149375A1 (en) | 2015-03-16 | 2016-09-22 | H.B. Fuller Company | Low application temperature hot melt adhesive composition |
| EP3271438B1 (en) | 2015-03-16 | 2022-12-21 | H.B. Fuller Company | An elastic adhesive composition and an elastic composite made with the same |
| EP3320027B1 (en) | 2015-06-12 | 2020-08-12 | Kraton Polymers U.S. LLC | Styrenic block copolymers as thermally-activated viscosifiers for oilfield applications |
| TWI604027B (zh) | 2015-06-12 | 2017-11-01 | 科騰聚合物美國有限責任公司 | 用於纜線填充應用之熱活化膠 |
| JP6964578B2 (ja) * | 2015-07-24 | 2021-11-10 | ダイナソル・エラストメロス・エセ・アDynasol Elastomeros S.A. | Tpe組成物における改善された性能を有する水素化ゴム |
| CA3014614A1 (en) | 2016-02-19 | 2017-08-24 | Teknor Apex Company | Fiber forming compositions, fibers and methods for production |
| CN109196049B (zh) | 2016-05-27 | 2019-11-19 | 沙特基础工业全球技术有限公司 | 聚(亚苯基醚)组合物及制品 |
| CN109415475B (zh) * | 2016-06-30 | 2022-04-05 | 科腾聚合物美国有限责任公司 | 性能改进的高乙烯基嵌段共聚物组合物及其用途 |
| WO2018022478A1 (en) | 2016-07-25 | 2018-02-01 | Polyone Corporation | Super-vibration damping thermoplastic elastomer blends and articles made therewith |
| KR102172741B1 (ko) * | 2016-09-09 | 2020-11-03 | 다이나졸 엘라스토메로스 에스에이 데 세베 | 고 비닐 블록 공중합을 위한 극성 개질제 시스템 |
| JP6992470B2 (ja) * | 2016-12-14 | 2022-01-13 | Mcppイノベーション合同会社 | 溶融押出成形用熱可塑性エラストマー組成物、押出成形体及び医療用チューブ |
| US20190104790A1 (en) * | 2017-10-11 | 2019-04-11 | Kai-Hsi Tseng | Reinforcement fiber for protection products |
| KR20200121314A (ko) * | 2018-02-21 | 2020-10-23 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 코어-시스 필라멘트 및 접착제 인쇄 방법 |
| US11279821B2 (en) | 2018-03-23 | 2022-03-22 | Kraton Polymers Llc | Ultrahigh melt flow styrenic block copolymers |
| WO2019183302A1 (en) | 2018-03-23 | 2019-09-26 | Kraton Polymers Llc | Ultrahigh melt flow styrenic block copolymers |
| CN109161095B (zh) * | 2018-07-16 | 2020-12-25 | 中广核俊尔新材料有限公司 | 一种利用改性无纺布再生料制备的阻燃聚丙烯材料及其制备方法 |
| BR112021011661A2 (pt) | 2018-12-18 | 2021-09-08 | Tredegar Surface Protection, Llc | Película de mascaramento para proteger substratos sensíveis |
| CN111424334A (zh) * | 2019-01-10 | 2020-07-17 | 全程兴业股份有限公司 | 双组合弹性纤维复合材料及包含该复合材料的弹性复丝纤维与制法 |
| CN113677772B (zh) * | 2019-02-25 | 2023-07-18 | 3M创新有限公司 | 可挤出的压敏粘合剂 |
| JP7565935B2 (ja) * | 2019-02-25 | 2024-10-11 | スリーエム イノベイティブ プロパティズ カンパニー | フィラメント接着剤ディスペンサシステム |
| CN110092960B (zh) * | 2019-03-29 | 2021-11-12 | 金发科技股份有限公司 | 一种热塑性聚合物组合物及其制备方法 |
| US11413800B2 (en) * | 2019-05-20 | 2022-08-16 | Kraton Polymers Llc | Molding compositions and articles made thereof |
| EP3996916A4 (en) * | 2019-07-09 | 2023-08-23 | Tredegar Surface Protection, LLC | SURFACE PROTECTION FILM |
| EP3766934B1 (en) * | 2019-07-19 | 2024-01-03 | Kraton Polymers Research B.V. | Molding composition and articles formed thereof |
| EP4017930B1 (en) * | 2019-08-21 | 2023-08-16 | 3M Innovative Properties Company | Core-sheath filaments including polyisobutylene compositions and methods of printing the same |
| EP3819315B1 (en) | 2019-11-08 | 2023-01-18 | TSRC Corporation | Polymer composition and pressure sensitive adhesives or films made therefrom |
| CA3161886A1 (en) | 2019-12-20 | 2021-06-24 | Church & Dwight Co., Inc. | Polymer compositions and products formed therewith |
| CN114846103A (zh) * | 2019-12-23 | 2022-08-02 | 3M创新有限公司 | 包含可热交联粘合剂组合物的皮芯长丝 |
| CN111733521B (zh) * | 2020-05-19 | 2022-04-19 | 界首市鑫豪塑胶有限公司 | 利用汽车内饰件边角料和回收料加工地板革基材的工艺 |
| DE102021207504A1 (de) * | 2021-07-14 | 2023-01-19 | Neenah Gessner Gmbh | Filtermedium umfassend ein Meltblownvlies sowie Verwendung davon |
| US20230149839A1 (en) * | 2021-11-18 | 2023-05-18 | Hollingsworth & Vose Company | Filter media including fibers comprising a matrix polymer and impact modifier, and related methods |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003064528A2 (en) * | 2002-01-31 | 2003-08-07 | Kraton Polymers Research B.V. | Block copolymer compositions, having improved mechanical properties and processability |
Family Cites Families (170)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3149182A (en) | 1957-10-28 | 1964-09-15 | Shell Oil Co | Process for preparing block copolymers utilizing organolithium catalysts |
| US3244664A (en) | 1960-10-24 | 1966-04-05 | Phillips Petroleum Co | Silicon-containing polymers |
| US3281383A (en) | 1962-08-09 | 1966-10-25 | Phillips Petroleum Co | Branched polymers prepared from monolithium-terminated polymers and compounds having at least three reactive sites |
| US3431323A (en) | 1964-01-20 | 1969-03-04 | Shell Oil Co | Hydrogenated block copolymers of butadiene and a monovinyl aryl hydrocarbon |
| US3900678A (en) * | 1965-10-23 | 1975-08-19 | Asahi Chemical Ind | Composite filaments and process for the production thereof |
| BE697838A (enExample) | 1966-11-11 | 1967-10-02 | ||
| GB1205281A (en) * | 1967-03-16 | 1970-09-16 | Toray Industries | A method for manufacturing synthetic multicore composite filaments and fabrics made therewith |
| US3594452A (en) * | 1968-02-06 | 1971-07-20 | Shell Oil Co | Polymers prepared from monolithiumterminated block copolymers and certain diesters |
| USRE27145E (en) | 1969-05-20 | 1971-06-22 | Side-chain | |
| US3634594A (en) | 1969-08-05 | 1972-01-11 | Nippon Musical Instruments Mfg | Touch-responsive tone envelope control circuit for electronic musical instruments |
| US3670054A (en) | 1969-10-29 | 1972-06-13 | Shell Oil Co | Block copolymers having reduced solvent sensitivity |
| US3700748A (en) | 1970-05-22 | 1972-10-24 | Shell Oil Co | Selectively hydrogenated block copolymers |
| US3692874A (en) | 1970-09-02 | 1972-09-19 | Ralph C Farrar | Process of coupling alkali metal-terminated polymers with silicic compound in presence of conjugated dienes |
| US3700633A (en) | 1971-05-05 | 1972-10-24 | Shell Oil Co | Selectively hydrogenated block copolymers |
| US3766301A (en) | 1971-05-21 | 1973-10-16 | Shell Oil Co | Preparation of polymers of increased average molecular weight from mono lithium terminated block co polymers coupled with certain aryl monoesters |
| US3783072A (en) | 1971-11-02 | 1974-01-01 | Johnson & Johnson | Extrusion process for pressure-sensitive adhesive sheets and tapes |
| US3772196A (en) | 1971-12-03 | 1973-11-13 | Shell Oil Co | Lubricating compositions |
| US4039593A (en) * | 1973-05-18 | 1977-08-02 | Lithium Corporation Of America | Preparation of hydroxy-terminated conjugated diene polymers |
| US3880954A (en) * | 1973-08-22 | 1975-04-29 | Phillips Petroleum Co | Methoxy silane coupling of block copolymer formed in cyclohexane |
| US3985830B1 (en) | 1974-07-15 | 1998-03-03 | Univ Akron | Star polymers and process for the preparation thereof |
| US4039633A (en) | 1976-04-19 | 1977-08-02 | Phillips Petroleum Company | Coupling of alkali metal-terminated polymers |
| US4107131A (en) * | 1976-06-07 | 1978-08-15 | Shell Oil Company | Multicomponent polyurethane-block copolymer-polymer blends |
| US4076915A (en) | 1976-06-08 | 1978-02-28 | Phillips Petroleum Company | Treatment of coupled polymers prior to hydrogenation |
| GB1597500A (en) | 1977-12-29 | 1981-09-09 | Shell Int Research | Polymers |
| US4188432A (en) | 1978-03-30 | 1980-02-12 | Shell Oil Company | Articles resistant to attack by fatty substances, made from polystyrene blends, and compositions |
| US4273946A (en) | 1978-10-30 | 1981-06-16 | Basf Wyandotte Corporation | Fiber lubricants derived from the oxyalkylation of a glycerol-1,3-dialkylether |
| US4294936A (en) | 1979-07-05 | 1981-10-13 | Permacel | Adhesive compositions |
| US4286077A (en) | 1980-04-21 | 1981-08-25 | Shell Oil Company | Weather resistant adhesive composition |
| US4296008A (en) | 1980-04-21 | 1981-10-20 | Shell Oil Company | Sealant composition |
| US4405297A (en) | 1980-05-05 | 1983-09-20 | Kimberly-Clark Corporation | Apparatus for forming nonwoven webs |
| US4379891A (en) | 1981-06-15 | 1983-04-12 | Shell Oil Company | Multifunctional coupling agent |
| JPS61194221A (ja) | 1985-02-18 | 1986-08-28 | Chisso Corp | 弾性複合繊維およびこれを用いた布 |
| JPS61194247A (ja) * | 1985-02-18 | 1986-08-28 | 株式会社クラレ | 複合繊維布帛 |
| US4663220A (en) * | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
| JPH0735607B2 (ja) | 1986-02-03 | 1995-04-19 | チッソ株式会社 | 弾性複合繊維およびその製造方法 |
| US4892903A (en) | 1986-07-07 | 1990-01-09 | Shell Oil Company | Elastomeric fibers, structures fashioned therefrom and elastomeric films |
| US4789699A (en) | 1986-10-15 | 1988-12-06 | Kimberly-Clark Corporation | Ambient temperature bondable elastomeric nonwoven web |
| US5272214A (en) | 1986-12-01 | 1993-12-21 | Enichem Elastomeri S.P.A. | Radial and branched block copolymers, compositions which contain them, their preparation and their use in bituminous compositions |
| US4874447A (en) * | 1987-01-27 | 1989-10-17 | Exxon Chemical Patents, Inc. | Melt blown nonwoven web from fiber comprising an elastomer |
| DE3713861A1 (de) * | 1987-04-25 | 1988-11-10 | Reifenhaeuser Masch | Verfahren und spinnvliesanlage zur herstellung eines spinnvlieses aus synthetischem endlosfilament |
| JPH0655772B2 (ja) | 1988-01-12 | 1994-07-27 | 旭化成工業株式会社 | 重合体を取得する方法 |
| JPH0688608B2 (ja) * | 1988-08-08 | 1994-11-09 | 日本クラウンコルク株式会社 | 耐熱性ライナー付容器蓋及びその製法 |
| US5191024A (en) | 1989-05-19 | 1993-03-02 | Japan Synthetic Rubber Co., Ltd. | Hydrogenated diene block copolymer and composition comprising the same |
| JPH0798890B2 (ja) | 1989-06-23 | 1995-10-25 | 日本ゼオン株式会社 | 粘着剤用ブロック共重合体組成物及び粘着剤組成物 |
| DE69029849T2 (de) * | 1989-10-03 | 1997-06-12 | Kanebo Ltd | Elastisches verbundgarn sowie dessen herstellungsverfahren |
| US5260126A (en) * | 1990-01-10 | 1993-11-09 | Kimberly-Clark Corporation | Low stress relaxation elastomeric nonwoven webs and fibers |
| US5093422A (en) * | 1990-04-23 | 1992-03-03 | Shell Oil Company | Low stress relaxation extrudable elastomeric composition |
| US6552109B1 (en) * | 1994-04-19 | 2003-04-22 | Applied Elastomerics, Inc. | Gelatinous elastomer compositions and articles |
| US6333374B1 (en) | 1990-05-21 | 2001-12-25 | Applied Elastomerics, Inc. | Fluffy, strong, solid elastic gels, articles and method of making same |
| JPH04228617A (ja) * | 1990-06-14 | 1992-08-18 | Shell Internatl Res Maatschappij Bv | 二成分弾性繊維 |
| US5352518A (en) * | 1990-06-22 | 1994-10-04 | Kanebo, Ltd. | Composite elastic filament with rough surface, production thereof, and textile structure comprising the same |
| JPH0678376B2 (ja) | 1990-07-31 | 1994-10-05 | 旭化成工業株式会社 | ブロック共重合体の製造方法 |
| EP0498672A3 (en) | 1991-02-07 | 1993-06-23 | Chisso Corporation | Microfiber-generating fibers and woven or non-woven fabrics produced therefrom |
| JP2721599B2 (ja) | 1991-07-22 | 1998-03-04 | 株式会社クラレ | 複合繊維 |
| TW224494B (enExample) * | 1991-07-25 | 1994-06-01 | Kuraray Co | |
| JP2957775B2 (ja) | 1991-08-22 | 1999-10-06 | 株式会社クラレ | 制振性能を有する芯鞘型複合繊維 |
| DE4229008A1 (de) * | 1991-08-30 | 1993-03-04 | Mazda Motor | Zuendeinrichtung fuer eine brennkraftmaschine |
| US5266648A (en) * | 1991-09-27 | 1993-11-30 | Shell Oil Company | One phase melt radial polymer |
| EP0541180A3 (en) * | 1991-11-08 | 1993-11-18 | Shell Int Research | Star polymers, a process for their preparation and lubricating oil compositions and concentrates containing them |
| US5470639A (en) | 1992-02-03 | 1995-11-28 | Fiberweb North America, Inc. | Elastic nonwoven webs and method of making same |
| US5997989A (en) * | 1992-02-03 | 1999-12-07 | Bba Nonwovens Simpsonville, Inc. | Elastic nonwoven webs and method of making same |
| TW307801B (enExample) * | 1992-03-19 | 1997-06-11 | Minnesota Mining & Mfg | |
| JP3145796B2 (ja) * | 1992-06-18 | 2001-03-12 | 株式会社クラレ | 芯鞘型複合繊維 |
| JP3104888B2 (ja) | 1992-07-03 | 2000-10-30 | 株式会社クラレ | 制振機能を有する複合繊維 |
| US5405682A (en) * | 1992-08-26 | 1995-04-11 | Kimberly Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material |
| GB9219663D0 (en) | 1992-09-17 | 1992-10-28 | Rca Thomson Licensing Corp | Switch mode power supply with low input current distortion |
| FI955107L (fi) | 1993-04-27 | 1995-10-26 | Dow Chemical Co | Joustavia kuituja, kankaita ja niistä valmistettuja tuotteita |
| US5589542A (en) | 1993-11-03 | 1996-12-31 | Shell Oil Company | Multiblock hydrogenated polymers for adhesives |
| US20010000258A1 (en) * | 1994-05-24 | 2001-04-12 | Exxon Chemical Patents Inc. | Articles made from polypropylene, higher alpha-olefin copolymers |
| US5498468A (en) * | 1994-09-23 | 1996-03-12 | Kimberly-Clark Corporation | Fabrics composed of ribbon-like fibrous material and method to make the same |
| US6420285B1 (en) * | 1994-11-23 | 2002-07-16 | Bba Nonwovens Simpsonville, Inc. | Multicomponent fibers and fabrics made using the same |
| US6417122B1 (en) * | 1994-11-23 | 2002-07-09 | Bba Nonwovens Simpsonville, Inc. | Multicomponent fibers and fabrics made using the same |
| EP0821699B1 (en) * | 1995-04-19 | 1999-03-10 | Shell Internationale Researchmaatschappij B.V. | Coupling of anionic polymers with trialkoxysilanes having silicon-hydrogen bonds |
| US6113825A (en) | 1995-05-08 | 2000-09-05 | Shell Oil Company | Process for preparing poly(trimethylene terephthalate) carpet yarn |
| CA2219237C (en) * | 1995-05-25 | 2006-02-28 | Minnesota Mining And Manufacturing Company | Undrawn, tough, durably melt-bondable, macrodenier, thermoplastic, multicomponent filaments |
| US6027592A (en) * | 1995-06-06 | 2000-02-22 | Gillette Canada Inc. | Dental floss |
| US5875797A (en) * | 1995-06-06 | 1999-03-02 | Gillette Canada Inc. | Dental floss |
| JP3498107B2 (ja) | 1995-06-20 | 2004-02-16 | 三菱レイヨン株式会社 | 高摩擦抵抗繊維織編物及びそれに用いる高摩擦抵抗繊維の製造方法 |
| US6045883A (en) | 1995-06-29 | 2000-04-04 | Asahi Kasei Kogyo Kabushiki Kaisha | Resin composition and resin composition for secondary battery jar |
| CA2223630C (en) | 1995-07-04 | 2001-08-07 | Teijin Limited | Process for preparing cushioning structure using fiber assembly and apparatus therefor |
| JP3475225B2 (ja) * | 1995-09-29 | 2003-12-08 | 株式会社クラレ | バインダー用芯鞘型複合繊維 |
| US5705556A (en) | 1996-03-05 | 1998-01-06 | Shell Oil Company | Modified styrenic block copolymer compounds having improved elastic performance |
| US5792766A (en) * | 1996-03-13 | 1998-08-11 | Neurogen Corporation | Imidazo 1,5-c! quinazolines; a new class of GABA brain receptor ligands |
| US5665300A (en) * | 1996-03-27 | 1997-09-09 | Reemay Inc. | Production of spun-bonded web |
| JP4251380B2 (ja) | 1996-04-19 | 2009-04-08 | 花王株式会社 | 伸縮弾性不織布 |
| US6054002A (en) | 1996-06-27 | 2000-04-25 | Kimberly-Clark Worldwide, Inc. | Method of making a seamless tubular band |
| EP0909294B1 (en) | 1996-07-03 | 2000-03-08 | Shell Internationale Researchmaatschappij B.V. | High 1,2-content thermoplastic elastomer oil polyolefin composition |
| DE69712211T2 (de) | 1996-08-15 | 2002-11-28 | Gillette Canada Co | Zahnseide |
| JP3159653B2 (ja) | 1996-08-27 | 2001-04-23 | 大和紡績株式会社 | 高摩擦性繊維及び高摩擦性布帛 |
| US5762734A (en) * | 1996-08-30 | 1998-06-09 | Kimberly-Clark Worldwide, Inc. | Process of making fibers |
| US5891957A (en) * | 1996-10-24 | 1999-04-06 | Shell Oil Company | Adhesive composition for skin adhesion and bandage applications |
| US5733825A (en) * | 1996-11-27 | 1998-03-31 | Minnesota Mining And Manufacturing Company | Undrawn tough durably melt-bondable macrodenier thermoplastic multicomponent filaments |
| ES2182142T3 (es) * | 1996-12-31 | 2003-03-01 | Quantum Group Inc | Hilos elastomeros compuestos. |
| US20020088501A1 (en) * | 1996-12-31 | 2002-07-11 | Jeffrey W. Bruner | Composite elastomeric yarns and fabric |
| US5777043A (en) | 1997-03-05 | 1998-07-07 | Shell Oil Company | Sealant formulations containing high vinyl content hydrogenated styrene-butadiene-styrene block copolymers |
| JP3994230B2 (ja) * | 1997-04-04 | 2007-10-17 | Jsr株式会社 | 水添ブロック共重合体組成物 |
| DE19815895C2 (de) | 1997-04-09 | 2000-04-13 | Asahi Chemical Ind | Hydrierte Blockcopolymere, diese enthaltende Zusammensetzungen und Formkörper |
| JP4093595B2 (ja) * | 1997-05-02 | 2008-06-04 | カーギル インコーポレイテッド | 分解性ポリマー繊維の製造方法、製品、及び使用法 |
| JP3683409B2 (ja) * | 1997-05-28 | 2005-08-17 | 三井化学株式会社 | 自動車内外装用ポリプロピレン樹脂組成物 |
| USH1956H1 (en) | 1997-07-23 | 2001-04-03 | Shell Oil Company | Enhanced hydrogenation catalyst removal from block copolymers by reduction in polymer cement viscosity by increasing the vinyl content of the block copolymers |
| US5925707A (en) | 1997-07-30 | 1999-07-20 | Shell Oil Company | Oil gel formulations containing high vinyl content hydrogenated styrene-butadiene-styrene block copolymers |
| WO1999046327A1 (en) * | 1998-03-11 | 1999-09-16 | The Dow Chemical Company | STRUCTURES AND FABRICATED ARTICLES HAVING SHAPE MEMORY MADE FROM α-OLEFIN/VINYL OR VINYLIDENE AROMATIC AND/OR HINDERED ALIPHATIC VINYL OR VINYLIDENE INTERPOLYMERS |
| KR100551782B1 (ko) * | 1998-03-11 | 2006-02-13 | 다우 글로벌 테크놀로지스 인크. | 알파-올레핀/비닐 또는 비닐리덴 방향족 및/또는 장애 지환족 또는 지방족 비닐 또는 비닐리덴 인터폴리머로부터 제조된 섬유 |
| US6709742B2 (en) * | 1998-05-18 | 2004-03-23 | Dow Global Technologies Inc. | Crosslinked elastic fibers |
| EP1002813B1 (en) * | 1998-06-05 | 2009-09-09 | Asahi Kasei Kabushiki Kaisha | Hydrogenated block copolymer and polypropylene resin composition containing the same |
| JP2000008225A (ja) * | 1998-06-16 | 2000-01-11 | Toyobo Co Ltd | 難燃性に優れた弾性複合フィラメント |
| CA2336343A1 (en) | 1998-06-30 | 2000-01-06 | Kevin Mckay | Hot melt adhesive composition comprising homogeneous ethylene interpolymer and block copolymer |
| US6225243B1 (en) | 1998-08-03 | 2001-05-01 | Bba Nonwovens Simpsonville, Inc. | Elastic nonwoven fabric prepared from bi-component filaments |
| EP1029876B1 (en) | 1998-09-14 | 2011-03-09 | Asahi Kasei Kabushiki Kaisha | Hydrogenated block copolymer |
| EP1031586B1 (en) | 1998-09-14 | 2018-12-26 | Asahi Kasei Kabushiki Kaisha | Hydrogenated block copolymer |
| US6184292B1 (en) | 1998-10-05 | 2001-02-06 | Bridgestone Corporation | Soft gel polymers for high temperature use |
| EP1149195B1 (en) * | 1998-10-06 | 2007-01-17 | Hills, Inc. | Splittable multicomponent elastomeric fibers |
| US6362389B1 (en) * | 1998-11-20 | 2002-03-26 | Kimberly-Clark Worldwide, Inc. | Elastic absorbent structures |
| US6368609B1 (en) * | 1999-04-12 | 2002-04-09 | Kimberly-Clark Worldwide, Inc. | Absorbent structure including a thin, calendered airlaid composite and a process for making the composite |
| JP2000178833A (ja) * | 1998-12-14 | 2000-06-27 | Pilot Ink Co Ltd | 感温変形性複合フィラメント |
| JP3816688B2 (ja) | 1999-03-31 | 2006-08-30 | 株式会社クラレ | 海島型複合ステープル繊維 |
| US6667038B1 (en) * | 1999-04-21 | 2003-12-23 | Boston Medical Center Corp. | Prevention, diagnosis and treatment of lyme disease |
| US6465557B1 (en) | 1999-06-25 | 2002-10-15 | Kraton Polymers U.S. Llc | Hot melt pressure sensitive positioning adhesive |
| JP3550052B2 (ja) * | 1999-06-28 | 2004-08-04 | ユニ・チャーム株式会社 | 伸縮性不織布およびその製造方法 |
| US6777082B2 (en) * | 1999-07-28 | 2004-08-17 | The Dow Chemical Company | Hydrogenated block copolymers having elasticity and articles made therefrom |
| US6451913B1 (en) * | 1999-09-01 | 2002-09-17 | Kraton Polymers U.S. Llc | Radial hydrogenated block copolymers showing one phase melt behavior |
| KR100709049B1 (ko) * | 1999-09-30 | 2007-04-18 | 세키스이가가쿠 고교가부시키가이샤 | 열가소성 엘라스토머, 그 용도 및 제조 방법 |
| FR2801612B1 (fr) * | 1999-11-29 | 2002-08-30 | Aplix Sa | Fibre a ame elastique et tissu non tisse elastique |
| US6267252B1 (en) | 1999-12-08 | 2001-07-31 | Kimberly-Clark Worldwide, Inc. | Fine particle filtration medium including an airlaid composite |
| JP4350258B2 (ja) * | 2000-03-14 | 2009-10-21 | 株式会社クラレ | 染色性に優れた軽量繊維 |
| EP1275891B1 (en) * | 2000-04-21 | 2006-01-25 | Kuraray Co., Ltd. | Multilayered tube and medical supply comprising multilayered tube |
| CA2406666A1 (en) * | 2000-05-11 | 2001-11-15 | The Dow Chemical Company | Method of making elastic articles having improved heat-resistance |
| JP2001329431A (ja) * | 2000-05-18 | 2001-11-27 | Kuraray Co Ltd | 複合繊維 |
| EP1307509B1 (en) | 2000-06-07 | 2005-02-16 | KRATON Polymers Research B.V. | Kink resistant medical tubes |
| US6914094B2 (en) * | 2000-09-29 | 2005-07-05 | Solvay Engineered Polymers, Inc. | Engineered polyolefin materials with enhanced surface durability |
| US6548166B2 (en) * | 2000-09-29 | 2003-04-15 | E. I. Du Pont De Nemours And Company | Stretchable fibers of polymers, spinnerets useful to form the fibers, and articles produced therefrom |
| JP2004518828A (ja) | 2000-09-29 | 2004-06-24 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 伸張可能なポリマー繊維およびそれから生産される物品 |
| EP1322707A1 (en) | 2000-10-04 | 2003-07-02 | Kraton Polymers Research B.V. | An elastomeric film and fiber grade thermoplastic elastomer composition |
| EP1197971B1 (en) * | 2000-10-10 | 2003-09-17 | Dynasol Elastomeros, S.A. | Composition for cables filling |
| US20020104548A1 (en) * | 2000-12-01 | 2002-08-08 | Vipul Bhupendra Dave | Monofilament tape |
| WO2002074855A1 (en) | 2001-03-15 | 2002-09-26 | Mitsui Chemicals, Inc. | Automotive part made of polypropylene resin composition |
| US7182086B2 (en) * | 2001-06-01 | 2007-02-27 | Kuraray Co., Ltd. | Mouth guard and sheet for mouth guard |
| CN1555432B (zh) * | 2001-07-17 | 2010-10-13 | 陶氏环球技术公司 | 弹性、耐热和耐湿的双组分和双成分纤维 |
| DK1412566T3 (da) * | 2001-07-17 | 2007-02-05 | Dow Global Technologies Inc | Elastiske bikomponent- og bikonstituentfibre og fremgangsmåder til fremstilling af cellulosestrukturer ud fra samme |
| MXPA04002719A (es) * | 2001-09-28 | 2004-07-05 | Du Pont | Hebra hetero-compuesta, telas de la misma y metodos de fabricacion. |
| WO2003027366A1 (en) * | 2001-09-28 | 2003-04-03 | E. I. Du Pont De Nemours And Company | Stretchable nonwoven web and method therefor |
| EP1333058A1 (en) * | 2002-01-31 | 2003-08-06 | KRATON Polymers Research B.V. | Modified styrenic block copolymer and compounds thereof having improved mechanical properties and processability |
| CN1286903C (zh) * | 2002-01-31 | 2006-11-29 | 克拉通聚合物研究有限公司 | 具有改善机械性能和加工性能的嵌段共聚物组合物 |
| JP4259023B2 (ja) | 2002-02-05 | 2009-04-30 | 富士ゼロックス株式会社 | カーボンナノチューブデバイスの作製方法、およびカーボンナノチューブデバイス |
| US20030181584A1 (en) * | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
| US6987142B2 (en) * | 2002-02-07 | 2006-01-17 | Kraton Polymers U.S. Llc | Adhesives and sealants from controlled distribution block copolymers |
| JP4155042B2 (ja) * | 2002-02-20 | 2008-09-24 | チッソ株式会社 | 弾性長繊維不織布及びこれを用いた繊維製品 |
| DE60330851D1 (de) * | 2002-03-28 | 2010-02-25 | Kraton Polymers Res Bv | Zusammensetzungen |
| BR0311537B1 (pt) | 2002-06-04 | 2013-09-17 | processo para a obtenção de uma composição de copolímero em bloco, e, composição de copolímero em bloco | |
| US7001956B2 (en) * | 2002-06-04 | 2006-02-21 | Kraton Polymers U.S. Llc | Articles prepared from hydrogenated block copolymers |
| US7316842B2 (en) * | 2002-07-02 | 2008-01-08 | Kimberly-Clark Worldwide, Inc. | High-viscosity elastomeric adhesive composition |
| US20050031865A1 (en) | 2002-07-23 | 2005-02-10 | Sauer Bryan B. | Fibers, tapes and films prepared from olefinic and segmented elastomers |
| US6881375B2 (en) * | 2002-08-30 | 2005-04-19 | Kimberly-Clark Worldwide, Inc. | Method of forming a 3-dimensional fiber into a web |
| US20040110442A1 (en) * | 2002-08-30 | 2004-06-10 | Hannong Rhim | Stretchable nonwoven materials with controlled retraction force and methods of making same |
| US6677038B1 (en) | 2002-08-30 | 2004-01-13 | Kimberly-Clark Worldwide, Inc. | 3-dimensional fiber and a web made therefrom |
| EP1573107B1 (en) * | 2002-10-24 | 2009-12-02 | Dow Global Technologies Inc. | Elastomeric multicomponent fibers, nonwoven webs and nonwoven fabrics |
| JP3800536B2 (ja) * | 2002-12-06 | 2006-07-26 | Tdk株式会社 | モジュラジャック |
| US6866945B2 (en) * | 2003-01-06 | 2005-03-15 | General Motors Corporation | Magnesium containing aluminum alloys and anodizing process |
| JP4069389B2 (ja) * | 2003-03-07 | 2008-04-02 | ジェイエスアール クレイトン エラストマー株式会社 | アスファルト改質用ブロック共重合体組成物、その製造方法、およびアスファルト組成物 |
| WO2005005701A2 (en) * | 2003-07-09 | 2005-01-20 | Advanced Design Concept Gmbh | Fibers made from block copolymer |
| BRPI0413214A (pt) | 2003-08-22 | 2006-10-03 | Advanced Design Concept Gmbh | composto de filme não tecido, totalmente elástico |
| US20050106982A1 (en) * | 2003-11-17 | 2005-05-19 | 3M Innovative Properties Company | Nonwoven elastic fibrous webs and methods for making them |
| US20050130544A1 (en) * | 2003-11-18 | 2005-06-16 | Cheng Chia Y. | Elastic nonwoven fabrics made from blends of polyolefins and processes for making the same |
| US7601657B2 (en) * | 2003-12-31 | 2009-10-13 | Kimberly-Clark Worldwide, Inc. | Single sided stretch bonded laminates, and methods of making same |
| BRPI0508388A (pt) * | 2004-03-03 | 2007-08-07 | Kraton Polymers Res Bv | fibra bicomponente, artigo, e, processo para produzir a fibra bicomponente |
| EP1723199A1 (en) * | 2004-03-03 | 2006-11-22 | KRATON Polymers Research B.V. | Polymeric compositions containing block copolymers having high flow and high elasticity |
| US7101623B2 (en) * | 2004-03-19 | 2006-09-05 | Dow Global Technologies Inc. | Extensible and elastic conjugate fibers and webs having a nontacky feel |
| US8182456B2 (en) * | 2004-03-29 | 2012-05-22 | The Procter & Gamble Company | Disposable absorbent articles with components having both plastic and elastic properties |
| US7348376B2 (en) * | 2004-04-13 | 2008-03-25 | Kraton Polymers U.S. Llc | Adhesive composition |
| WO2006031625A2 (en) * | 2004-09-10 | 2006-03-23 | Invista Technologies S.A.R.L. | Extensible fibers, method for their production and use |
-
2005
- 2005-03-01 BR BRPI0508388-5A patent/BRPI0508388A/pt not_active Application Discontinuation
- 2005-03-01 EP EP13152385.4A patent/EP2586803B1/en not_active Expired - Lifetime
- 2005-03-01 JP JP2007501871A patent/JP5080967B2/ja not_active Expired - Lifetime
- 2005-03-01 ES ES05723937.8T patent/ES2565410T3/es not_active Expired - Lifetime
- 2005-03-01 KR KR1020067020180A patent/KR100807917B1/ko not_active Expired - Fee Related
- 2005-03-01 US US11/069,268 patent/US7910208B2/en active Active
- 2005-03-01 EP EP11186474A patent/EP2428534A1/en not_active Withdrawn
- 2005-03-01 EP EP05724074A patent/EP1723200A1/en not_active Withdrawn
- 2005-03-01 EP EP05723937.8A patent/EP1730201B1/en not_active Expired - Lifetime
- 2005-03-01 CN CN2005800117461A patent/CN1997681B/zh not_active Expired - Lifetime
- 2005-03-01 JP JP2007501884A patent/JP4733108B2/ja not_active Expired - Fee Related
- 2005-03-01 CN CNB2005800109126A patent/CN100569849C/zh not_active Expired - Fee Related
- 2005-03-01 BR BRPI0508355-9A patent/BRPI0508355A/pt not_active Application Discontinuation
- 2005-03-01 CN CNA2005800131242A patent/CN1946798A/zh active Pending
- 2005-03-01 KR KR1020067020176A patent/KR100830024B1/ko not_active Expired - Lifetime
- 2005-03-01 WO PCT/US2005/006456 patent/WO2005092979A1/en not_active Ceased
- 2005-03-01 WO PCT/US2005/006283 patent/WO2005092936A2/en not_active Ceased
- 2005-03-01 US US11/069,487 patent/US7439301B2/en active Active
- 2005-03-01 AU AU2005226781A patent/AU2005226781B2/en not_active Ceased
- 2005-03-02 TW TW094106285A patent/TWI288754B/zh not_active IP Right Cessation
- 2005-03-02 TW TW094106286A patent/TWI310391B/zh not_active IP Right Cessation
-
2006
- 2006-09-01 US US11/515,513 patent/US8003209B2/en not_active Expired - Fee Related
-
2008
- 2008-08-13 US US12/190,900 patent/US7662323B1/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003064528A2 (en) * | 2002-01-31 | 2003-08-07 | Kraton Polymers Research B.V. | Block copolymer compositions, having improved mechanical properties and processability |
Non-Patent Citations (2)
| Title |
|---|
| 实施例4 |
| 权利要求1-3. |
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1997681B (zh) | 具有高流动性和高弹性的嵌段共聚物 | |
| KR100788123B1 (ko) | 흐름성 및 탄성이 높은 블록 공중합체를 함유하는 중합체조성물 | |
| US7001956B2 (en) | Articles prepared from hydrogenated block copolymers | |
| CN1643015B (zh) | 由氢化的控制分布嵌段共聚物制备的制品 | |
| US8188192B2 (en) | Soft elastomeric films | |
| EP3740515B1 (en) | Ultrahigh melt flow styrenic block copolymers | |
| US20100056721A1 (en) | Articles prepared from certain hydrogenated block copolymers | |
| US7262248B2 (en) | Articles prepared from high molecular weight tetrablock copolymers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20100505 |