CN1867704B - 用于磷酸盐化金属表面的电解方法和由此磷酸盐化的金属层 - Google Patents
用于磷酸盐化金属表面的电解方法和由此磷酸盐化的金属层 Download PDFInfo
- Publication number
- CN1867704B CN1867704B CN200480030171.3A CN200480030171A CN1867704B CN 1867704 B CN1867704 B CN 1867704B CN 200480030171 A CN200480030171 A CN 200480030171A CN 1867704 B CN1867704 B CN 1867704B
- Authority
- CN
- China
- Prior art keywords
- electrolytic solution
- salt
- layer
- alloy
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 45
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 18
- 239000002184 metal Substances 0.000 title claims abstract description 18
- 239000011701 zinc Substances 0.000 claims abstract description 24
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 230000008021 deposition Effects 0.000 claims abstract description 8
- 230000002378 acidificating effect Effects 0.000 claims abstract description 6
- 239000007864 aqueous solution Substances 0.000 claims abstract description 5
- 239000008151 electrolyte solution Substances 0.000 claims description 16
- 150000002500 ions Chemical class 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 11
- 229910019142 PO4 Inorganic materials 0.000 claims description 10
- 239000010452 phosphate Substances 0.000 claims description 10
- 238000005868 electrolysis reaction Methods 0.000 claims description 7
- -1 phosphate anion Chemical class 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 3
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 229910000838 Al alloy Inorganic materials 0.000 claims description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 2
- SYNHCENRCUAUNM-UHFFFAOYSA-N Nitrogen mustard N-oxide hydrochloride Chemical compound Cl.ClCC[N+]([O-])(C)CCCl SYNHCENRCUAUNM-UHFFFAOYSA-N 0.000 claims description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims description 2
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 claims description 2
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 239000002105 nanoparticle Substances 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 2
- 239000011574 phosphorus Substances 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 9
- 238000000151 deposition Methods 0.000 abstract description 5
- 239000003792 electrolyte Substances 0.000 abstract description 2
- 238000004070 electrodeposition Methods 0.000 abstract 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 239000010953 base metal Substances 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 229910001297 Zn alloy Inorganic materials 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229910000851 Alloy steel Inorganic materials 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 230000005012 migration Effects 0.000 description 4
- 238000013508 migration Methods 0.000 description 4
- 238000005554 pickling Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000007743 anodising Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- OXHXATNDTXVKAU-UHFFFAOYSA-N phosphoric acid zinc Chemical compound [Zn].OP(O)(O)=O OXHXATNDTXVKAU-UHFFFAOYSA-N 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- DBPRUZCKPFOVDV-UHFFFAOYSA-N Clorprenaline hydrochloride Chemical compound O.Cl.CC(C)NCC(O)C1=CC=CC=C1Cl DBPRUZCKPFOVDV-UHFFFAOYSA-N 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 230000002520 cambial effect Effects 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000000574 ganglionic effect Effects 0.000 description 1
- 150000002327 glycerophospholipids Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910001463 metal phosphate Inorganic materials 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000010129 solution processing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910002058 ternary alloy Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
- SPDJAIKMJHJYAV-UHFFFAOYSA-H trizinc;diphosphate;tetrahydrate Chemical compound O.O.O.O.[Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O SPDJAIKMJHJYAV-UHFFFAOYSA-H 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/36—Phosphatising
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Chemical Treatment Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10348251.2 | 2003-10-16 | ||
| DE10348251A DE10348251A1 (de) | 2003-10-16 | 2003-10-16 | Elektrolytisches Verfahren zum Phosphatieren von Metalloberflächen und damit phosphatierte Metallschicht |
| PCT/EP2004/052269 WO2005038095A2 (de) | 2003-10-16 | 2004-09-22 | Elektrolytisches verfahren zum phosphatieren von metalloberflächen und damit phosphatierte metallschicht |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1867704A CN1867704A (zh) | 2006-11-22 |
| CN1867704B true CN1867704B (zh) | 2012-03-14 |
Family
ID=34428451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200480030171.3A Expired - Fee Related CN1867704B (zh) | 2003-10-16 | 2004-09-22 | 用于磷酸盐化金属表面的电解方法和由此磷酸盐化的金属层 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20070295608A1 (xx) |
| EP (1) | EP1675975A2 (xx) |
| JP (1) | JP2007508457A (xx) |
| CN (1) | CN1867704B (xx) |
| BR (1) | BRPI0415520A (xx) |
| DE (1) | DE10348251A1 (xx) |
| TR (1) | TR200601814T1 (xx) |
| WO (1) | WO2005038095A2 (xx) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006035974A1 (de) * | 2006-08-02 | 2008-02-07 | Robert Bosch Gmbh | Verfahren zur Phosphatierung einer Metallschicht |
| MX2010014396A (es) * | 2008-06-18 | 2011-06-17 | Massachusetts Inst Technology | Materiales cataliticos, electrodos y sistemas para la electrolisis de agua y otras tecnicas electroquimicas. |
| CN101643928B (zh) * | 2009-09-09 | 2011-01-05 | 重庆科技学院 | 镁合金表面阴极电沉积磷酸盐/金属复合膜的方法 |
| DE102010030465B4 (de) | 2010-06-24 | 2023-12-07 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zum Herstellen eines Blechformteils aus einem höherfesten Stahlblechmaterial mit einer elektrolytisch aufgebrachten Zink-Nickel-Beschichtung |
| DE102011100974A1 (de) * | 2011-05-09 | 2012-11-15 | Knorr-Bremse Systeme für Schienenfahrzeuge GmbH | Schienenrad und Verfahren zur Herstellung eines Schienenrades |
| CN102212864A (zh) * | 2011-06-10 | 2011-10-12 | 沈阳理工大学 | 修饰电解磷化膜的方法 |
| US9393759B2 (en) * | 2013-10-24 | 2016-07-19 | General Electric Company | Metal laminate structures with systems and methods for treating |
| DE102016100245A1 (de) | 2016-01-08 | 2017-07-13 | Staku Anlagenbau Gmbh | Selbstschmierende elektrolytisch abgeschiedene Phosphatierungsbeschichtung |
| CN105951155B (zh) * | 2016-06-01 | 2017-12-29 | 中钢集团郑州金属制品研究院有限公司 | 一种钢丝在线双磷化方法及其连续生产设备 |
| CN107630243B (zh) * | 2017-10-16 | 2019-07-02 | 浙江五源科技股份有限公司 | 一种复合磷化膜的电解制备方法 |
| CN114824263B (zh) * | 2021-01-29 | 2024-03-19 | 中南大学 | 一种Zn@Zn-E复合负极及其制备和在水系锌离子电池中的应用 |
| CN114883560B (zh) * | 2021-02-05 | 2024-03-19 | 中南大学 | 一种三维集流体/Zn/Zn-E复合负极及其制备和在水系锌离子电池中的应用 |
| CN114737179B (zh) * | 2022-05-05 | 2024-05-24 | 东南大学 | 一种高温合金耐热磷化膜、其制备方法及应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3449222A (en) * | 1964-08-13 | 1969-06-10 | Hooker Chemical Corp | Metal coating process |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2540314A (en) * | 1947-07-24 | 1951-02-06 | Parker Rust Proof Co | Process and compositions for applying phosphate coatings |
| US3449229A (en) * | 1966-08-08 | 1969-06-10 | Hooker Chemical Corp | Electrophoretic deposition on zinc enriched metal surface |
| JP2534280B2 (ja) * | 1987-02-05 | 1996-09-11 | 日本パーカライジング株式会社 | 亜鉛系複合めっき金属材料およびめっき方法 |
| US5232523A (en) * | 1989-03-02 | 1993-08-03 | Nippon Paint Co., Ltd. | Phosphate coatings for metal surfaces |
| JPH0336296A (ja) * | 1989-06-29 | 1991-02-15 | Nippon Parkerizing Co Ltd | ステンレス鋼の表面処理方法 |
| JPH0436498A (ja) * | 1990-06-01 | 1992-02-06 | Nippon Parkerizing Co Ltd | 鉄鋼線材の表面処理方法 |
| US5645706A (en) * | 1992-04-30 | 1997-07-08 | Nippondenso Co., Ltd. | Phosphate chemical treatment method |
| JP2000144494A (ja) * | 1998-09-11 | 2000-05-26 | Nippon Parkerizing Co Ltd | 冷間圧造用の潤滑皮膜を形成する方法 |
| JP2000160394A (ja) * | 1998-12-01 | 2000-06-13 | Nippon Parkerizing Co Ltd | 鉄系金属材料の短時間りん酸塩処理方法 |
| JP4870872B2 (ja) * | 2001-02-23 | 2012-02-08 | 株式会社キリウ | 車両用ブレーキ装置の回転ブレーキ部材およびその防錆処理方法 |
-
2003
- 2003-10-16 DE DE10348251A patent/DE10348251A1/de not_active Withdrawn
-
2004
- 2004-09-22 TR TR2006/01814T patent/TR200601814T1/xx unknown
- 2004-09-22 CN CN200480030171.3A patent/CN1867704B/zh not_active Expired - Fee Related
- 2004-09-22 EP EP04787187A patent/EP1675975A2/de not_active Withdrawn
- 2004-09-22 US US10/575,907 patent/US20070295608A1/en not_active Abandoned
- 2004-09-22 JP JP2006534745A patent/JP2007508457A/ja not_active Withdrawn
- 2004-09-22 BR BRPI0415520-3A patent/BRPI0415520A/pt not_active Application Discontinuation
- 2004-09-22 WO PCT/EP2004/052269 patent/WO2005038095A2/de active Application Filing
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3449222A (en) * | 1964-08-13 | 1969-06-10 | Hooker Chemical Corp | Metal coating process |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2005038095A3 (de) | 2005-07-14 |
| DE10348251A1 (de) | 2005-05-12 |
| EP1675975A2 (de) | 2006-07-05 |
| TR200601814T1 (tr) | 2007-01-22 |
| US20070295608A1 (en) | 2007-12-27 |
| JP2007508457A (ja) | 2007-04-05 |
| BRPI0415520A (pt) | 2006-12-26 |
| WO2005038095A2 (de) | 2005-04-28 |
| CN1867704A (zh) | 2006-11-22 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120314 Termination date: 20160922 |
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