CN1562473A - 一种1,4-丁二醇脱氢制备γ-丁内酯催化剂及其用途 - Google Patents
一种1,4-丁二醇脱氢制备γ-丁内酯催化剂及其用途 Download PDFInfo
- Publication number
- CN1562473A CN1562473A CN 200410012188 CN200410012188A CN1562473A CN 1562473 A CN1562473 A CN 1562473A CN 200410012188 CN200410012188 CN 200410012188 CN 200410012188 A CN200410012188 A CN 200410012188A CN 1562473 A CN1562473 A CN 1562473A
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- Prior art keywords
- butyrolactone
- gamma
- catalyzer
- butanediol
- dehydrogenating
- Prior art date
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- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 title claims abstract description 53
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 title abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 230000004913 activation Effects 0.000 claims abstract description 3
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 230000009467 reduction Effects 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000003054 catalyst Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 229910000421 cerium(III) oxide Inorganic materials 0.000 abstract 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 9
- 230000009466 transformation Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 6
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229910052684 Cerium Inorganic materials 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000000247 postprecipitation Methods 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Furan Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410012188 CN1247303C (zh) | 2004-03-16 | 2004-03-16 | 一种1,4-丁二醇脱氢制备γ-丁内酯催化剂及其用途 |
Applications Claiming Priority (1)
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---|---|---|---|
CN 200410012188 CN1247303C (zh) | 2004-03-16 | 2004-03-16 | 一种1,4-丁二醇脱氢制备γ-丁内酯催化剂及其用途 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1562473A true CN1562473A (zh) | 2005-01-12 |
CN1247303C CN1247303C (zh) | 2006-03-29 |
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CN 200410012188 Expired - Lifetime CN1247303C (zh) | 2004-03-16 | 2004-03-16 | 一种1,4-丁二醇脱氢制备γ-丁内酯催化剂及其用途 |
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CN (1) | CN1247303C (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102029156A (zh) * | 2009-10-07 | 2011-04-27 | Sk能源株式会社 | 由1,4-丁二醇制备γ-丁内酯和N-甲基吡咯烷酮的方法 |
CN101157677B (zh) * | 2007-09-27 | 2011-05-04 | 复旦大学 | 一种用负载型纳米金催化剂制备δ-戊内酯的方法 |
CN105797734A (zh) * | 2014-12-29 | 2016-07-27 | 神华集团有限责任公司 | 短链脂肪酸酯加氢制低碳醇的催化剂、制法、用途和短链脂肪酸酯加氢制低碳醇的方法 |
CN110526849A (zh) * | 2019-09-29 | 2019-12-03 | 迈奇化学股份有限公司 | 一种1,4-丁二醇胺化制备烷基吡咯烷酮的方法 |
CN116173977A (zh) * | 2023-03-30 | 2023-05-30 | 重庆中润新材料股份有限公司 | 一种脱氢催化剂及其制备方法和应用 |
-
2004
- 2004-03-16 CN CN 200410012188 patent/CN1247303C/zh not_active Expired - Lifetime
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101157677B (zh) * | 2007-09-27 | 2011-05-04 | 复旦大学 | 一种用负载型纳米金催化剂制备δ-戊内酯的方法 |
CN102029156A (zh) * | 2009-10-07 | 2011-04-27 | Sk能源株式会社 | 由1,4-丁二醇制备γ-丁内酯和N-甲基吡咯烷酮的方法 |
CN102029156B (zh) * | 2009-10-07 | 2013-02-27 | Sk新技术株式会社 | 由1,4-丁二醇制备γ-丁内酯和N-甲基吡咯烷酮的方法 |
CN105797734A (zh) * | 2014-12-29 | 2016-07-27 | 神华集团有限责任公司 | 短链脂肪酸酯加氢制低碳醇的催化剂、制法、用途和短链脂肪酸酯加氢制低碳醇的方法 |
CN105797734B (zh) * | 2014-12-29 | 2019-09-03 | 国家能源投资集团有限责任公司 | 短链脂肪酸酯加氢制低碳醇的催化剂、制法、用途和短链脂肪酸酯加氢制低碳醇的方法 |
CN110526849A (zh) * | 2019-09-29 | 2019-12-03 | 迈奇化学股份有限公司 | 一种1,4-丁二醇胺化制备烷基吡咯烷酮的方法 |
CN110526849B (zh) * | 2019-09-29 | 2021-05-11 | 迈奇化学股份有限公司 | 一种1,4-丁二醇胺化制备烷基吡咯烷酮的方法 |
CN116173977A (zh) * | 2023-03-30 | 2023-05-30 | 重庆中润新材料股份有限公司 | 一种脱氢催化剂及其制备方法和应用 |
CN116173977B (zh) * | 2023-03-30 | 2023-12-12 | 重庆中润新材料股份有限公司 | 一种脱氢催化剂及其制备方法和应用 |
Also Published As
Publication number | Publication date |
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CN1247303C (zh) | 2006-03-29 |
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Owner name: ZHONGKE OIL PROJECT CO., LTD. Free format text: FORMER OWNER: SHANXI INST. OF COAL CHEMISTRY, CHINESE ACADEMY OF SCIENCES Effective date: 20081017 |
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Effective date of registration: 20081017 Address after: 3, building 1, Tsinghua Science and Technology Park, No. 609, Zhongguancun East Road, Beijing, Haidian District Patentee after: SYNEFUELS CHINA Inc. Address before: 165 mailbox, Taiyuan City, Shanxi Province Patentee before: INSTITUTE OF COAL CHEMISTRY, CHINESE ACADEMY OF SCIENCES |
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Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee after: Synefuels China Inc. Address before: 100195, Haidian District Zhongguancun East Road, No. 1, building 3, Tsinghua Science and Technology Park, pioneering building, 609, Beijing Patentee before: Synefuels China Inc. |
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Owner name: SYNEFUELS CHINA CO., LTD. Free format text: FORMER NAME: SYNEFUELS CHINA INC. |
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Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee after: SYNFUELS CHINA Address before: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee before: Synefuels China Inc. |
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Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone Park south two Street No. 1 Patentee after: SYNEFUELS CHINA Inc. Address before: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee before: SYNFUELS CHINA |
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Granted publication date: 20060329 |