CN1484677A - 聚(亚芳基醚)-聚烯烃组合物的制备方法以及按此制备的组合物 - Google Patents
聚(亚芳基醚)-聚烯烃组合物的制备方法以及按此制备的组合物 Download PDFInfo
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- CN1484677A CN1484677A CNA018216072A CN01821607A CN1484677A CN 1484677 A CN1484677 A CN 1484677A CN A018216072 A CNA018216072 A CN A018216072A CN 01821607 A CN01821607 A CN 01821607A CN 1484677 A CN1484677 A CN 1484677A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- B—PERFORMING OPERATIONS; TRANSPORTING
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Abstract
Description
材料缩写 | 说明 | wt% |
PP | 聚丙烯,由MontellPolyolefin公司以PH280购得 | 57.2 |
EPR | 乙丙橡胶,由ExxonMobil化学公司以VISTALON878购得 | 7.3 |
PP-g-PS | 聚丙烯-聚苯乙烯接枝共聚物,由MontellPolyolefin公司以Interloy PH 1045H1购得 | 13.3 |
SEBS G1652 | 苯乙烯-(乙烯-丁二烯)-苯乙烯共聚物,由KratonPolymers以KRATONG1652购得 | 2.7 |
PPE | 聚(2,6-二甲基亚苯基醚),IV=0.40dl/g,由通用电气公司购得 | 6.7 |
SBS | 苯乙烯-丁二烯-苯乙烯嵌段共聚物,由KratonPolymers以KRATOND1101购得 | 5.1 |
xPS | 均聚苯乙烯,亦称晶体聚苯乙烯,由Huntsman化学公司以PP-738购得,MFI=10.5g/10min,200℃,5kg | 7.7 |
实施例1 | 实施例2 | 实施例3 | 对比例1 | 对比例2 | |
工艺变化 | |||||
上游混合 | +1 | +1 | +1 | +1 | +1 |
下游混合 | +1 | +1 | +1 | +1 | +1 |
RPM | 450 | 450 | 450 | 250 | 250 |
挤出量(lb/h) | 55 | 25 | 55 | 55 | 25 |
机筒温度(℃) | 240 | 240 | 290 | 290 | 240 |
PP的上游加入分数(%) | 0 | 0 | 0 | 75 | 75 |
PP-g-PS和SEBS上游加入分数(%) | 100 | 0 | 0 | 0 | 0 |
性能 | |||||
缺口伊佐德,23℃(ft-lb/in) | 7.219 | 2.742 | 2.961 | 3.309 | 4.400 |
标准偏差(ft-lb/in) | 0.391 | 0.091 | 0.195 | 0.103 | 0.186 |
相对标准偏差(%) | 5.4 | 3.3 | 6.6 | 3.1 | 4.2 |
缺口伊佐德,-30℃(ft-lb/in) | 1.385 | 0.723 | 0.851 | 1.183 | 1.257 |
标准偏差(ft-lb/in) | 0.053 | 0.071 | 0.144 | 0.172 | 0.109 |
相对标准偏差(%) | 3.8 | 9.8 | 16.9 | 14.5 | 8.7 |
落镖总能量,5mph,23℃(ft-lb) | 26.23 | 16.98 | 22.03 | 24.77 | 22.27 |
标准偏差(ft-lb) | 0.34 | 5.06 | 3.12 | 1.54 | 4.55 |
相对标准偏差(%) | 1.3 | 29.8 | 14.2 | 6.2 | 20.4 |
落镖总能量,5mph,-30℃(ft-lb) | 13.51 | 0.9 | 3.66 | 12.11 | 3.19 |
标准偏差(ft-lb) | 2.09 | 0.47 | 2.38 | 1.53 | 0.81 |
相对标准偏差(%) | 15.5 | 52.2 | 65.0 | 12.6 | 25.4 |
挠曲模量,23℃,1/8in(psi) | 186,300 | 202,700 | 200,600 | 207,400 | 199,100 |
标准偏差(ft-lb) | 4848 | 2743 | 2823 | 2832 | 4825 |
相对标准偏差(%) | 2.6 | 1.4 | 1.4 | 1.4 | 2.4 |
实施例4 | 实施例5 | 实施例6 | 实施例7 | 实施例8 | 实施例9 | 实施例10 | |
工艺变化 | |||||||
上游混合 | -1 | -1 | -1 | +1 | +1 | +1 | +1 |
下游混合 | -1 | +1 | +1 | -1 | +1 | +1 | +1 |
RPM | 450 | 350 | 350 | 450 | 450 | 450 | 450 |
挤出量(kg/h) | 40 | 55 | 55 | 55 | 55 | 25 | 25 |
机筒温度(℃) | 290 | 240 | 240 | 240 | 290 | 290 | 240 |
性能 | |||||||
HDT,66psi,1/8in(°F) | 221.7 | 211.1 | 207.9 | 206.4 | 219.8 | 216.0 | 215.8 |
HDT,264psi,1/8in(°F) | 143.6 | 144.0 | 141.1 | 139.1 | 144.1 | 141.5 | 142.3 |
缺口伊佐德,23℃(ft-lb/in) | 2.373 | 3.804 | 4.444 | 7.219 | 2.273 | 1.567 | 2.667 |
标准偏差(ft-lb/in) | 0.104 | 0.200 | 0.079 | 0.391 | 0.077 | 0.081 | 0.101 |
相对标准偏差(%) | 4.4 | 5.3 | 1.8 | 5.4 | 3.4 | 5.2 | 3.8 |
缺口伊佐德,-30℃(ft-lb/in) | 0.896 | 1.273 | 1.037 | 1.385 | 0.827 | 0.638 | 0.933 |
标准偏差(ft-lb/in) | 0.088 | 0.077 | 0.026 | 0.053 | 0.194 | 0.030 | 0.055 |
相对标准偏差(%) | 9.8 | 6.0 | 2.5 | 3.8 | 23.5 | 4.7 | 5.9 |
落镖总能量,7.5mph,23℃(ft-lb) | 10.34 | 15.10 | 16.66 | 27.84 | 19.79 | 13.65 | 24.88 |
标准偏差(ft-lb) | 2.63 | 1.07 | 1.13 | 0.39 | 6.16 | 4.81 | 0.98 |
相对标准偏差(%) | 25.4 | 7.1 | 6.8 | 1.4 | 31.1 | 35.2 | 3.9 |
落镖总能量,5mph,23℃(ft-lb) | 12.32 | 14.22 | 16.93 | 26.23 | 14.57 | 8.56 | 18.67 |
标准偏差(ft-lb) | 5.59 | 2.54 | 0.62 | 0.34 | 6.26 | 3.62 | 5.14 |
相对标准偏差(%) | 45.4 | 17.9 | 3.7 | 1.3 | 43.0 | 42.3 | 27.5 |
落镖总能量,5mph,-30℃(ft-lb) | 1.38 | 1.67 | 1.09 | 13.51 | 2.28 | 1.31 | 6.27 |
标准偏差(ft-lb) | 0.67 | 0.40 | 0.23 | 2.09 | 2.01 | 0.36 | 1.98 |
相对标准偏差(%) | 48.6 | 24.0 | 21.1 | 15.5 | 88.2 | 27.5 | 31.6 |
挠曲模量,23℃,1/8in(psi) | 202,400 | 192,400 | 185,700 | 186,300 | 198,800 | 193,500 | 198,200 |
标准偏差(psi) | 5235 | 2846 | 4341 | 4848 | 853 | 1767 | 1085 |
相对标准偏差(%) | 2.6 | 1.5 | 2.3 | 2.6 | 0.4 | 0.9 | 0.5 |
断裂伸长,23℃(%) | 56.2 | 69.0 | 61.1 | 100.6 | 66.5 | 61.9 | 55.8 |
实施例11 | |
组成 | |
PP | 33.90 |
EPR | 6.20 |
PP-g-PS | 5.90 |
SBS | 11.40 |
SEBS H1043 | 6.30 |
xPS | 20.20 |
PPE | 16.20 |
性能 | |
挠曲模量,23℃,1/8″(psi) | 221,000 |
屈服挠曲强度(psi) | 7300 |
HDT,66psi,1/8″(°F) | 229 |
HDT,264psi,1/8″(°F) | 170 |
缺口伊佐德,23℃,(ft-lb/in) | 8.9 |
缺口伊佐德,-30℃,(ft-lb/in) | 2.5 |
无缺口伊佐德,23℃,(ft-lb/in) | -- |
破坏能量,23℃,7.5mph(ft-lb) | 19.2 |
总能量,23℃,7.5mph(ft-lb) | 32.4 |
破坏能量,-30℃,7.5mph(ft-lb) | 14.7 |
总能量,-30℃,7.5mph(ft-lb) | 17 |
破坏能量,-30℃,5mph(ft-lb) | -- |
总能量,-30℃,5mph(ft-lb) | -- |
屈服抗张强度(psi) | 5,060 |
断裂拉伸应力(psi) | 5,079 |
断裂伸长(%) | 273 |
PPE | 16.14 |
SBS | 11.36 |
xPS | 20.13 |
SEBS H1043 | 6.28 |
PP-g-PS | 5.88 |
PP | 33.76 |
EPR | 6.20 |
热稳定剂 | 0.25 |
实施例No. | 能量输入(kW-hr/kg) | 破坏能量-30℃,5mph(ft-lb) |
12 | 0.228 | 11.83 |
13 | 0.241 | 15.23 |
14 | 0.218 | 11.61 |
15 | 0.234 | 11.32 |
16 | 0.229 | 5.87 |
17 | 0.224 | 10.32 |
18 | 0.211 | 8.99 |
19 | 0.227 | 10.52 |
20 | 0.215 | 12.41 |
21 | 0.247 | 19.36 |
22 | 0.233 | 6.74 |
23 | 0.216 | 10.72 |
24 | 0.227 | 13.46 |
25 | 0.251 | 14.80 |
26 | 0.224 | 11.03 |
27 | 0.226 | 10.10 |
28 | 0.225 | 5.80 |
29 | 0.243 | 18.11 |
30 | 0.246 | 13.30 |
31 | 0.230 | 11.10 |
32 | 0.241 | 16.94 |
33 | 0.223 | 6.74 |
34 | 0.233 | 9.54 |
35 | 0.222 | 3.79 |
36 | 0.224 | 7.74 |
37 | 0.267 | 21.74 |
38 | 0.255 | 21.16 |
39 | 0.245 | 20.29 |
40 | 0.240 | 20.06 |
41 | 0.267 | 14.88 |
42 | 0.245 | 13.29 |
43 | 0.245 | 23.24 |
44 | 0.245 | 21.71 |
45 | 0.245 | 21.41 |
46 | 0.245 | 23.47 |
47 | 0.245 | 22.28 |
实施例48 | 实施例49 | 实施例50 | 实施例51 | 实施例52 | 实施例53 | |
工艺变化 | ||||||
(PP+EPR)下游加入百分率 | 0 | 0 | 100 | 100 | 0 | 0 |
上游混合 | -1 | -1 | -1 | -1 | +1 | +1 |
下游混合 | -1 | -1 | -1 | -1 | -1 | -1 |
性能 | ||||||
HDT,66psi,1/8in(°F) | 223.7 | 225.1 | 227.9 | 228.3 | -- | 230.4 |
标准偏差(°F) | 9.1 | 5.7 | 0.6 | 2.3 | -- | 1.9 |
HDT,264psi,1/8in(°F) | 163.2 | 166.6 | 164.4 | 164.6 | 165.6 | 166.7 |
标准偏差(°F) | 0.9 | 2.4 | 0.6 | 2.4 | 1.3 | 1.4 |
缺口伊佐德,23℃(ft-lb/in) | 8.1 | 8.2 | 7.8 | 8.8 | 7.8 | 7.6 |
标准偏差(ft-lb/in) | 0.1 | 0.3 | 0.3 | 0.4 | 0.3 | 0.2 |
缺口伊佐德,-30℃(ft-lb/in) | 2.3 | 2.9 | 2.6 | 2.6 | 2.4 | 3.0 |
标准偏差(ft-lb/in) | 0.4 | 0.8 | 0.5 | 0.3 | 0.3 | 0.7 |
落镖破坏能量,7.5mph,23℃(ft-lb) | 17.55 | 17.61 | 17.61 | 17.74 | 17.90 | 17.98 |
标准偏差(ft-lb) | 0.46 | 0.24 | 0.59 | 0.54 | 0.23 | 0.51 |
落镖总能量,7.5mph,23℃(ft-lb) | 28.57 | 26.69 | 25.38 | 27.02 | 29.16 | 30.39 |
标准偏差(ft-lb) | 1.78 | 2.97 | 3.19 | 2.64 | 2.44 | 1.03 |
落镖破坏能量,7.5mph,-30℃(ft-lb) | 11.13 | 7.83 | 6.41 | 8.22 | 10.03 | 10.73 |
标准偏差(ft-lb) | 4.17 | 3.42 | 2.30 | 4.42 | 5.26 | 5.40 |
落镖总能量,7.5mph,-30℃(ft-lb) | 12.51 | 8.32 | 7.08 | 8.64 | 10.52 | 11.22 |
标准偏差(ft-lb) | 5.67 | 3.43 | 2.68 | 4.54 | 5.42 | 5.55 |
落镖破坏能量,5mph,-30℃(ft-lb) | 15.04 | 15.11 | 9.82 | 10.14 | 17.87 | 17.93 |
标准偏差(ft-lb) | 4.11 | 5.46 | 3.97 | 4.63 | 3.08 | 4.35 |
落镖总能量,5mph,-30℃(ft-lb) | 15.50 | 15.54 | 10.16 | 10.49 | 19.06 | 19.69 |
标准偏差(ft-lb) | 4.23 | 5.58 | 4.04 | 4.74 | 4.13 | 6.52 |
挠曲模量,23℃,1/8in(psi) | 203,900 | 210,300 | 209,800 | 214,000 | 213,100 | 212,200 |
标准偏差(psi) | 980 | 755 | 3936 | 2612 | 3368 | 1532 |
屈服挠曲强度,23℃,1/8in(psi) | 6,704 | 6,830 | 6,878 | 6,994 | 6,888 | 6,875 |
标准偏差(psi) | 21 | 17 | 32 | 32 | 22 | 23 |
屈服抗张强度,23℃,1/8in(psi) | 4,693 | 4,721 | 4,809 | 4,818 | 4,703 | 4,693 |
标准偏差(psi) | 27.4 | 5.8 | 19.4 | 10.8 | 6.0 | 27.3 |
断裂抗张强度,23℃,1/8in(psi) | 4,216 | 4,454 | 4,358 | 4,508 | 4,588 | 4,216 |
标准偏差(psi) | 182.6 | 105.3 | 89.8 | 108.8 | 32.4 | 182.6 |
断裂伸长,23℃(%) | 137.42 | 203.69 | 171.06 | 205.44 | 248.66 | 137.6 |
标准偏差(%) | 64.02 | 30.87 | 19.52 | 32.55 | 10.74 | 64.07 |
实施例54 | 实施例55 | 实施例56 | 实施例57 | 实施例58 | 实施例59 | |
工艺变化 | ||||||
(PP+EPR)下游加入百分率 | 100 | 100 | 100 | 100 | 0 | 0 |
上游混合 | +1 | +1 | +1 | +1 | +1 | +1 |
下游混合 | -1 | -1 | +1 | +1 | +1 | +1 |
性能 | ||||||
HDT,66psi,1/8in(°F) | 225.5 | 230.4 | 238.1 | 233.6 | 235.4 | 234.6 |
标准偏差(°F) | 8.1 | 0.9 | 0.8 | 1.9 | 2.3 | 3.0 |
HDT,264psi,1/8in(°F) | 165.5 | 168.7 | 171.4 | 170.3 | 169.7 | 169.0 |
标准偏差(°F) | 1.7 | 0.9 | 2.3 | 0.8 | 0.8 | 2.6 |
缺口伊佐德,23℃(ft-lb/in) | 8.4 | 8.5 | 7.5 | 7.8 | 7.2 | 7.5 |
标准偏差(ft-lb/in) | 0.4 | 0.2 | 0.3 | 0.4 | 0.2 | 0.3 |
缺口伊佐德,-30℃(ft-lb/in) | 2.7 | 2.7 | 2.2 | 2.1 | 2.1 | 2.1 |
标准偏差(ft-lb/in) | 0.3 | 0.3 | 0.2 | 0.1 | 0.2 | 0.2 |
落镖破坏能量,7.5mph,23℃(ft-lb) | 17.77 | 17.75 | 17.52 | 17.5 | 16.83 | 17.52 |
标准偏差(ft-lb) | 0.40 | 0.17 | 0.5 | 0.52 | 0.28 | 0.13 |
落镖总能量,7.5mph,23℃(ft-lb) | 28.84 | 29.89 | 28.07 | 27.07 | 25.59 | 28.47 |
标准偏差(ft-lb) | 3.20 | 1.57 | 1.13 | 3.22 | 2.56 | 1.41 |
落镖破坏能量,7.5mph,-30℃(ft-lb) | 15.62 | 15.83 | 17.18 | 16.61 | 13.39 | 16.56 |
标准偏差(ft-lb) | 5.38 | 6.89 | 6.80 | 6.12 | 7.66 | 5.44 |
落镖总能量,7.5mph,-30℃(ft-lb) | 17.88 | 20.65 | 18.26 | 19.21 | 14.45 | 18.05 |
标准偏差(ft-lb) | 7.80 | 12.27 | 7.37 | 8.76 | 8.49 | 6.66 |
落镖破坏能量,5mph,-30℃(ft-lb) | 17.09 | 20.81 | 15.17 | 18.22 | 12.13 | 16.05 |
标准偏差(ft-lb) | 6.56 | 3.49 | 6.13 | 3.80 | 6.45 | 6.95 |
落镖总能量,5mph,-30℃(ft-lb) | 20.63 | 27.63 | 17.73 | 19.85 | 13.33 | 18.84 |
标准偏差(ft-lb) | 9.48 | 8.10 | 9.08 | 5.06 | 8.09 | 9.37 |
挠曲模量,23℃,1/8in(psi) | 215,700 | 218,400 | 225,100 | 220,400 | 220,900 | 220,600 |
标准偏差(psi) | 997 | 2,298 | 2,172 | 1,398 | 1,373 | 728 |
屈服挠曲强度,23℃,1/8in(psi) | 7,052 | 7,098 | 7,307 | 7,195 | 7,075 | 7,099 |
标准偏差(psi) | 23 | 35 | 35 | 44 | 29 | 50 |
屈服抗张强度,23℃,1/8in(psi) | 4,826 | 4,867 | 4,936 | 4,910 | 4,824 | 4,814 |
标准偏差(psi) | 13.0 | 11.4 | 25.8 | 19.4 | 19.7 | 32.5 |
断裂抗张强度,23℃,1/8in(psi) | 4,541 | 4,472 | 4,601 | 4,665 | 4,607 | 4,575 |
标准偏差(psi) | 67.4 | 105.8 | 88.7 | 62.0 | 60.2 | 153.4 |
断裂伸长,23℃(%) | 215.86 | 212.81 | 196.47 | 232.73 | 216.67 | 206.02 |
标准偏差(%) | 26.76 | 33.25 | 33.81 | 9.92 | 18.80 | 80.46 |
Claims (32)
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US25889400P | 2000-12-28 | 2000-12-28 | |
US60/258,894 | 2000-12-28 | ||
US09/682,929 US6627701B2 (en) | 2000-12-28 | 2001-11-01 | Method for the preparation of a poly(arylene ether)-polyolefin composition, and composition prepared thereby |
US09/682,929 | 2001-11-01 |
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- 2001-11-01 US US09/682,929 patent/US6627701B2/en not_active Expired - Lifetime
- 2001-12-03 WO PCT/US2001/046389 patent/WO2002053644A2/en active IP Right Grant
- 2001-12-03 CN CN018216072A patent/CN1217994C/zh not_active Expired - Lifetime
- 2001-12-03 AU AU2002225906A patent/AU2002225906A1/en not_active Abandoned
- 2001-12-03 ES ES01995348T patent/ES2240561T3/es not_active Expired - Lifetime
- 2001-12-03 JP JP2002555162A patent/JP2004517188A/ja active Pending
- 2001-12-03 EP EP01995348A patent/EP1352029B1/en not_active Expired - Lifetime
- 2001-12-03 DE DE60110641T patent/DE60110641T2/de not_active Expired - Lifetime
- 2001-12-17 TW TW090131242A patent/TW555810B/zh active
-
2003
- 2003-07-10 US US10/617,849 patent/US6908964B2/en not_active Expired - Fee Related
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2004
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CN101506304B (zh) * | 2006-08-18 | 2012-04-18 | 沙伯基础创新塑料知识产权有限公司 | 聚(亚芳基醚)组合物、方法和制品 |
CN101563420B (zh) * | 2006-11-13 | 2011-08-31 | 沙伯基础创新塑料知识产权有限公司 | 聚(亚芳基醚)/聚烯烃组合物,方法,和制品 |
CN102066481A (zh) * | 2008-06-17 | 2011-05-18 | 普立万公司 | 具有优异耐磨性的热塑性弹性体 |
CN102719014A (zh) * | 2012-07-03 | 2012-10-10 | 上海锦湖日丽塑料有限公司 | 聚苯醚聚丙烯树脂组合物及其制备方法 |
CN102719014B (zh) * | 2012-07-03 | 2014-09-17 | 上海锦湖日丽塑料有限公司 | 聚苯醚聚丙烯树脂组合物及其制备方法 |
CN108026365A (zh) * | 2015-08-20 | 2018-05-11 | 沙特基础工业全球技术公司 | 用于高频电子组件的树脂组合物 |
US10557035B2 (en) | 2015-08-20 | 2020-02-11 | Sabic Global Technologies B.V. | Resin composition for high frequency electronic components |
CN105128311A (zh) * | 2015-09-10 | 2015-12-09 | 泉州市昶鸿化工贸易有限公司 | 用于eva/pe交联发泡物料加工的双螺杆挤出机 |
CN105128311B (zh) * | 2015-09-10 | 2018-04-24 | 泉州市昶鸿化工贸易有限公司 | 用于eva/pe交联发泡物料加工的双螺杆挤出机 |
CN115667400A (zh) * | 2020-06-05 | 2023-01-31 | 高新特殊工程塑料全球技术有限公司 | 组合物、用于制备其的方法及由其制成的制品 |
Also Published As
Publication number | Publication date |
---|---|
DE60110641T2 (de) | 2006-01-19 |
WO2002053644A2 (en) | 2002-07-11 |
DE60110641D1 (de) | 2005-06-09 |
EP1352029A2 (en) | 2003-10-15 |
HK1064400A1 (en) | 2005-01-28 |
CN1217994C (zh) | 2005-09-07 |
ES2240561T3 (es) | 2005-10-16 |
US20020156185A1 (en) | 2002-10-24 |
WO2002053644A3 (en) | 2003-01-30 |
US6908964B2 (en) | 2005-06-21 |
AU2002225906A1 (en) | 2002-07-16 |
US20040082719A1 (en) | 2004-04-29 |
EP1352029B1 (en) | 2005-05-04 |
US6627701B2 (en) | 2003-09-30 |
TW555810B (en) | 2003-10-01 |
JP2004517188A (ja) | 2004-06-10 |
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