CN1443834A - 含有磷、钼和羟基取代的二硫代氨基甲酸酯的润滑油组合物 - Google Patents
含有磷、钼和羟基取代的二硫代氨基甲酸酯的润滑油组合物 Download PDFInfo
- Publication number
- CN1443834A CN1443834A CN03121785A CN03121785A CN1443834A CN 1443834 A CN1443834 A CN 1443834A CN 03121785 A CN03121785 A CN 03121785A CN 03121785 A CN03121785 A CN 03121785A CN 1443834 A CN1443834 A CN 1443834A
- Authority
- CN
- China
- Prior art keywords
- composition
- amine
- molybdenum
- glycidyl
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title claims description 68
- 239000011733 molybdenum Chemical group 0.000 title claims description 68
- 229910052750 molybdenum Inorganic materials 0.000 title claims description 68
- 229910052698 phosphorus Inorganic materials 0.000 title claims description 48
- 239000011574 phosphorus Substances 0.000 title claims description 48
- 125000002887 hydroxy group Chemical group [H]O* 0.000 title claims description 43
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 39
- 239000010687 lubricating oil Substances 0.000 title claims description 24
- 239000012990 dithiocarbamate Substances 0.000 title abstract description 27
- 150000004659 dithiocarbamates Chemical class 0.000 title abstract description 4
- 239000002131 composite material Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 89
- 239000002199 base oil Substances 0.000 claims abstract description 7
- 239000003921 oil Substances 0.000 claims description 60
- 150000001412 amines Chemical class 0.000 claims description 37
- -1 alkyl phosphite Chemical compound 0.000 claims description 35
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 34
- 239000005864 Sulphur Substances 0.000 claims description 34
- 239000000654 additive Substances 0.000 claims description 25
- 150000002118 epoxides Chemical class 0.000 claims description 23
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 22
- 125000000217 alkyl group Chemical group 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 22
- 230000000996 additive effect Effects 0.000 claims description 21
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 18
- 150000002148 esters Chemical class 0.000 claims description 16
- 239000000314 lubricant Substances 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 14
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 11
- 229910052725 zinc Inorganic materials 0.000 claims description 11
- 239000011701 zinc Substances 0.000 claims description 11
- 230000008859 change Effects 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 150000003335 secondary amines Chemical class 0.000 claims description 7
- WISUILQECWFZCN-UHFFFAOYSA-N 2-(oxiran-2-ylmethylsulfanylmethyl)oxirane Chemical compound C1OC1CSCC1CO1 WISUILQECWFZCN-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 150000003857 carboxamides Chemical class 0.000 claims description 6
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 150000003568 thioethers Chemical group 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical compound CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 239000000376 reactant Substances 0.000 claims description 4
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000007810 chemical reaction solvent Substances 0.000 claims description 3
- DSZTYVZOIUIIGA-UHFFFAOYSA-N 1,2-Epoxyhexadecane Chemical compound CCCCCCCCCCCCCCC1CO1 DSZTYVZOIUIIGA-UHFFFAOYSA-N 0.000 claims description 2
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 claims description 2
- JPZYXGPCHFZBHO-UHFFFAOYSA-N 1-aminopentadecane Chemical compound CCCCCCCCCCCCCCCN JPZYXGPCHFZBHO-UHFFFAOYSA-N 0.000 claims description 2
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 claims description 2
- XNJDQHLXEBQMDE-UHFFFAOYSA-N 2-(cyclohexyloxymethyl)oxirane Chemical compound C1OC1COC1CCCCC1 XNJDQHLXEBQMDE-UHFFFAOYSA-N 0.000 claims description 2
- DBGLJLJEKJZHCK-UHFFFAOYSA-N 2-(cyclohexylsulfanylmethyl)oxirane Chemical compound C1OC1CSC1CCCCC1 DBGLJLJEKJZHCK-UHFFFAOYSA-N 0.000 claims description 2
- NPKKFQUHBHQTSH-UHFFFAOYSA-N 2-(decoxymethyl)oxirane Chemical compound CCCCCCCCCCOCC1CO1 NPKKFQUHBHQTSH-UHFFFAOYSA-N 0.000 claims description 2
- BMZQIIUFCUYJRW-UHFFFAOYSA-N 2-(decylsulfanylmethyl)oxirane Chemical compound CCCCCCCCCCSCC1CO1 BMZQIIUFCUYJRW-UHFFFAOYSA-N 0.000 claims description 2
- VMSIYTPWZLSMOH-UHFFFAOYSA-N 2-(dodecoxymethyl)oxirane Chemical compound CCCCCCCCCCCCOCC1CO1 VMSIYTPWZLSMOH-UHFFFAOYSA-N 0.000 claims description 2
- ODEHOIXQVTVIGZ-UHFFFAOYSA-N 2-(dodecylsulfanylmethyl)oxirane Chemical compound CCCCCCCCCCCCSCC1CO1 ODEHOIXQVTVIGZ-UHFFFAOYSA-N 0.000 claims description 2
- KDSVXIGJVLFKOE-UHFFFAOYSA-N 2-(ethylsulfanylmethyl)oxirane Chemical compound CCSCC1CO1 KDSVXIGJVLFKOE-UHFFFAOYSA-N 0.000 claims description 2
- SCURLAWXZMJRRH-UHFFFAOYSA-N 2-(heptadecoxymethyl)oxirane Chemical compound CCCCCCCCCCCCCCCCCOCC1CO1 SCURLAWXZMJRRH-UHFFFAOYSA-N 0.000 claims description 2
- VROQSFFKGTWASA-UHFFFAOYSA-N 2-(heptadecylsulfanylmethyl)oxirane Chemical compound CCCCCCCCCCCCCCCCCSCC1CO1 VROQSFFKGTWASA-UHFFFAOYSA-N 0.000 claims description 2
- INSCMIFABOJDRE-UHFFFAOYSA-N 2-(heptoxymethyl)oxirane Chemical compound CCCCCCCOCC1CO1 INSCMIFABOJDRE-UHFFFAOYSA-N 0.000 claims description 2
- QASBWNKYQKETOW-UHFFFAOYSA-N 2-(heptylsulfanylmethyl)oxirane Chemical compound CCCCCCCSCC1CO1 QASBWNKYQKETOW-UHFFFAOYSA-N 0.000 claims description 2
- YZUMRMCHAJVDRT-UHFFFAOYSA-N 2-(hexadecoxymethyl)oxirane Chemical compound CCCCCCCCCCCCCCCCOCC1CO1 YZUMRMCHAJVDRT-UHFFFAOYSA-N 0.000 claims description 2
- FVEZELMSNOOCSU-UHFFFAOYSA-N 2-(hexadecylsulfanylmethyl)oxirane Chemical compound CCCCCCCCCCCCCCCCSCC1CO1 FVEZELMSNOOCSU-UHFFFAOYSA-N 0.000 claims description 2
- JPEGUDKOYOIOOP-UHFFFAOYSA-N 2-(hexoxymethyl)oxirane Chemical compound CCCCCCOCC1CO1 JPEGUDKOYOIOOP-UHFFFAOYSA-N 0.000 claims description 2
- ZFPBDOPLRSHWHV-UHFFFAOYSA-N 2-(hexylsulfanylmethyl)oxirane Chemical compound CCCCCCSCC1CO1 ZFPBDOPLRSHWHV-UHFFFAOYSA-N 0.000 claims description 2
- LKMJVFRMDSNFRT-UHFFFAOYSA-N 2-(methoxymethyl)oxirane Chemical compound COCC1CO1 LKMJVFRMDSNFRT-UHFFFAOYSA-N 0.000 claims description 2
- OSIXFNQHNPOVIA-UHFFFAOYSA-N 2-(methylsulfanylmethyl)oxirane Chemical compound CSCC1CO1 OSIXFNQHNPOVIA-UHFFFAOYSA-N 0.000 claims description 2
- KEKXMAURKVLACV-UHFFFAOYSA-N 2-(nonoxymethyl)oxirane Chemical compound CCCCCCCCCOCC1CO1 KEKXMAURKVLACV-UHFFFAOYSA-N 0.000 claims description 2
- XBJHHKYUHTWRKV-UHFFFAOYSA-N 2-(nonylsulfanylmethyl)oxirane Chemical compound CCCCCCCCCSCC1CO1 XBJHHKYUHTWRKV-UHFFFAOYSA-N 0.000 claims description 2
- ZXJBWUAALADCRI-UHFFFAOYSA-N 2-(octadecoxymethyl)oxirane Chemical compound CCCCCCCCCCCCCCCCCCOCC1CO1 ZXJBWUAALADCRI-UHFFFAOYSA-N 0.000 claims description 2
- YVXUDMCXJUEEED-UHFFFAOYSA-N 2-(octadecylsulfanylmethyl)oxirane Chemical compound CCCCCCCCCCCCCCCCCCSCC1CO1 YVXUDMCXJUEEED-UHFFFAOYSA-N 0.000 claims description 2
- SNALIOQALXUVIF-UHFFFAOYSA-N 2-(pentadecoxymethyl)oxirane Chemical compound CCCCCCCCCCCCCCCOCC1CO1 SNALIOQALXUVIF-UHFFFAOYSA-N 0.000 claims description 2
- JXLUIGCPOOKJQD-UHFFFAOYSA-N 2-(pentadecylsulfanylmethyl)oxirane Chemical compound CCCCCCCCCCCCCCCSCC1CO1 JXLUIGCPOOKJQD-UHFFFAOYSA-N 0.000 claims description 2
- NVKSMKFBUGBIGE-UHFFFAOYSA-N 2-(tetradecoxymethyl)oxirane Chemical compound CCCCCCCCCCCCCCOCC1CO1 NVKSMKFBUGBIGE-UHFFFAOYSA-N 0.000 claims description 2
- NPRJZERJESYSLA-UHFFFAOYSA-N 2-(tetradecylsulfanylmethyl)oxirane Chemical compound CCCCCCCCCCCCCCSCC1CO1 NPRJZERJESYSLA-UHFFFAOYSA-N 0.000 claims description 2
- ZCZCZLVSKGCRTD-UHFFFAOYSA-N 2-(tridecoxymethyl)oxirane Chemical compound CCCCCCCCCCCCCOCC1CO1 ZCZCZLVSKGCRTD-UHFFFAOYSA-N 0.000 claims description 2
- RUZRQYBSXSMGQA-UHFFFAOYSA-N 2-(tridecylsulfanylmethyl)oxirane Chemical compound CCCCCCCCCCCCCSCC1CO1 RUZRQYBSXSMGQA-UHFFFAOYSA-N 0.000 claims description 2
- HNJSJLKMMRCGKX-UHFFFAOYSA-N 2-(undecoxymethyl)oxirane Chemical compound CCCCCCCCCCCOCC1CO1 HNJSJLKMMRCGKX-UHFFFAOYSA-N 0.000 claims description 2
- CZKCQTSDNRFCJW-UHFFFAOYSA-N 2-(undecylsulfanylmethyl)oxirane Chemical compound CCCCCCCCCCCSCC1CO1 CZKCQTSDNRFCJW-UHFFFAOYSA-N 0.000 claims description 2
- WHNBDXQTMPYBAT-UHFFFAOYSA-N 2-butyloxirane Chemical compound CCCCC1CO1 WHNBDXQTMPYBAT-UHFFFAOYSA-N 0.000 claims description 2
- MPGABYXKKCLIRW-UHFFFAOYSA-N 2-decyloxirane Chemical compound CCCCCCCCCCC1CO1 MPGABYXKKCLIRW-UHFFFAOYSA-N 0.000 claims description 2
- GXOYTMXAKFMIRK-UHFFFAOYSA-N 2-heptyloxirane Chemical compound CCCCCCCC1CO1 GXOYTMXAKFMIRK-UHFFFAOYSA-N 0.000 claims description 2
- QBJWYMFTMJFGOL-UHFFFAOYSA-N 2-hexadecyloxirane Chemical compound CCCCCCCCCCCCCCCCC1CO1 QBJWYMFTMJFGOL-UHFFFAOYSA-N 0.000 claims description 2
- LXVAZSIZYQIZCR-UHFFFAOYSA-N 2-nonyloxirane Chemical compound CCCCCCCCCC1CO1 LXVAZSIZYQIZCR-UHFFFAOYSA-N 0.000 claims description 2
- ILPBINAXDRFYPL-UHFFFAOYSA-N 2-octene Chemical group CCCCCC=CC ILPBINAXDRFYPL-UHFFFAOYSA-N 0.000 claims description 2
- AAMHBRRZYSORSH-UHFFFAOYSA-N 2-octyloxirane Chemical compound CCCCCCCCC1CO1 AAMHBRRZYSORSH-UHFFFAOYSA-N 0.000 claims description 2
- XSNXNMMWBCZUSS-UHFFFAOYSA-N 2-pentadecyloxirane Chemical compound CCCCCCCCCCCCCCCC1CO1 XSNXNMMWBCZUSS-UHFFFAOYSA-N 0.000 claims description 2
- NMOFYYYCFRVWBK-UHFFFAOYSA-N 2-pentyloxirane Chemical compound CCCCCC1CO1 NMOFYYYCFRVWBK-UHFFFAOYSA-N 0.000 claims description 2
- SYURNNNQIFDVCA-UHFFFAOYSA-N 2-propyloxirane Chemical compound CCCC1CO1 SYURNNNQIFDVCA-UHFFFAOYSA-N 0.000 claims description 2
- QMIBIXKZPBEGTE-UHFFFAOYSA-N 2-tridecyloxirane Chemical compound CCCCCCCCCCCCCC1CO1 QMIBIXKZPBEGTE-UHFFFAOYSA-N 0.000 claims description 2
- ZKAPVLMBPUYKKP-UHFFFAOYSA-N 2-undecyloxirane Chemical compound CCCCCCCCCCCC1CO1 ZKAPVLMBPUYKKP-UHFFFAOYSA-N 0.000 claims description 2
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 2
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 claims description 2
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 239000010775 animal oil Substances 0.000 claims description 2
- 150000007860 aryl ester derivatives Chemical class 0.000 claims description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 2
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims description 2
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 claims description 2
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- KAJZYANLDWUIES-UHFFFAOYSA-N heptadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCN KAJZYANLDWUIES-UHFFFAOYSA-N 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 239000010688 mineral lubricating oil Substances 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- GMTCPFCMAHMEMT-UHFFFAOYSA-N n-decyldecan-1-amine Chemical compound CCCCCCCCCCNCCCCCCCCCC GMTCPFCMAHMEMT-UHFFFAOYSA-N 0.000 claims description 2
- PXSXRABJBXYMFT-UHFFFAOYSA-N n-hexylhexan-1-amine Chemical compound CCCCCCNCCCCCC PXSXRABJBXYMFT-UHFFFAOYSA-N 0.000 claims description 2
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 claims description 2
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 claims description 2
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 2
- DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical compound CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- ADXGNEYLLLSOAR-UHFFFAOYSA-N tasosartan Chemical compound C12=NC(C)=NC(C)=C2CCC(=O)N1CC(C=C1)=CC=C1C1=CC=CC=C1C=1N=NNN=1 ADXGNEYLLLSOAR-UHFFFAOYSA-N 0.000 claims description 2
- ABVVEAHYODGCLZ-UHFFFAOYSA-N tridecan-1-amine Chemical compound CCCCCCCCCCCCCN ABVVEAHYODGCLZ-UHFFFAOYSA-N 0.000 claims description 2
- QFKMMXYLAPZKIB-UHFFFAOYSA-N undecan-1-amine Chemical compound CCCCCCCCCCCN QFKMMXYLAPZKIB-UHFFFAOYSA-N 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- YZKRIHZCXGPZGB-UHFFFAOYSA-L zinc;oxido-propan-2-yloxy-propan-2-ylsulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound [Zn+2].CC(C)OP([O-])(=S)SC(C)C.CC(C)OP([O-])(=S)SC(C)C YZKRIHZCXGPZGB-UHFFFAOYSA-L 0.000 claims description 2
- DBIJGSRXWPQTLH-UHFFFAOYSA-N n-butyloctan-1-amine Chemical compound CCCCCCCCNCCCC DBIJGSRXWPQTLH-UHFFFAOYSA-N 0.000 claims 1
- 239000005078 molybdenum compound Substances 0.000 abstract description 7
- 230000001050 lubricating effect Effects 0.000 abstract description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract description 2
- 235000016768 molybdenum Nutrition 0.000 description 50
- 238000006243 chemical reaction Methods 0.000 description 48
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 36
- 239000000047 product Substances 0.000 description 28
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 25
- 239000010721 machine oil Substances 0.000 description 25
- PDEDQSAFHNADLV-UHFFFAOYSA-M potassium;disodium;dinitrate;nitrite Chemical compound [Na+].[Na+].[K+].[O-]N=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PDEDQSAFHNADLV-UHFFFAOYSA-M 0.000 description 19
- 229910052757 nitrogen Inorganic materials 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 230000003647 oxidation Effects 0.000 description 15
- 238000007254 oxidation reaction Methods 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 238000010992 reflux Methods 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- 239000010705 motor oil Substances 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 8
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 7
- 238000005160 1H NMR spectroscopy Methods 0.000 description 7
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 7
- 239000002075 main ingredient Substances 0.000 description 7
- 239000011541 reaction mixture Substances 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
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- 150000002752 molybdenum compounds Chemical class 0.000 description 6
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- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000008427 organic disulfides Chemical class 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
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- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
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- 238000002411 thermogravimetry Methods 0.000 description 1
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- JGSUMMPGKPITGK-UHFFFAOYSA-L zinc;n,n-dipentylcarbamodithioate Chemical compound [Zn+2].CCCCCN(C([S-])=S)CCCCC.CCCCCN(C([S-])=S)CCCCC JGSUMMPGKPITGK-UHFFFAOYSA-L 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C333/14—Dithiocarbamic acids; Derivatives thereof
- C07C333/18—Esters of dithiocarbamic acids
- C07C333/20—Esters of dithiocarbamic acids having nitrogen atoms of dithiocarbamate groups bound to hydrogen atoms or to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/08—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/142—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/12—Groups 6 or 16
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
油样 | MO重量% | MOMolyvan855重量% | 羟基二硫代氨基甲酸酯的类型 | 羟基二硫代氨基甲酸酯的处理量重量%(ppmS) | 硫化烯烃HiTEC7084重量% | 四球磨损疤痕(mm) | 在油1上的提高(>/=0.05磨损降低) | 在油2上的提高(>/=0.05磨损降低) | 在油3上的提高(>/=0.05磨损降低) |
基准 | 0 | 0 | 无 | 0 | 0 | 0.69 |
1 | 0 | 0 | 无 | 0 | 0 | 0.63 |
2 | 0.40 | 0 | 无 | 0 | 0 | 0.72 | |||
3 | 0 | 0.40 | 无 | 0 | 0 | 0.58 | × |
4 | 0 | 0 | Ex.9 | 0.37(750) | 0 | 0.54 | × | ||
5 | 0 | 0 | Ex.9 | 0.73(1500) | 0 | 0.58 | × | ||
6 | 0 | 0 | Ex.9 | 1.10(2250) | 0 | 0.62 | |||
7 | 0.40 | 0 | Ex.9 | 0.37(750) | 0 | 0.63 | × | ||
8 | 0.40 | 0 | Ex.9 | 0.73(1500) | 0 | 0.52 | × | × | |
9 | 0.40 | 0 | Ex.9 | 1.10(2250) | 0 | 0.46 | × | × | |
10 | 0 | 0.40 | Ex.9 | 0.37(750) | 0 | 0.51 | × | × | |
11 | 0 | 0.40 | Ex.9 | 0.73(1500) | 0 | 0.44 | × | × | |
12 | 0 | 0.40 | Ex.9 | 1.10(2250) | 0 | 0.44 | × | × |
13 | 0 | 0 | Ex.10 | 0.38(750) | 0 | 0.60 | |||
14 | 0 | 0 | Ex.10 | 0.77(1500) | 0 | 0.65 | |||
15 | 0 | 0 | Ex.10 | 1.15(2250) | 0 | 0.63 | |||
16 | 0.40 | 0 | Ex.10 | 0.38(750) | 0 | 0.51 | × | × | |
17 | 0.40 | 0 | Ex.10 | 0.77(1500) | 0 | 0.48 | × | × | |
18 | 0.40 | 0 | Ex.10 | 1.15(2250) | 0 | 0.46 | × | × | |
19 | 0 | 0.40 | Ex10 | 0.38(750) | 0 | 0.32 | × | × | |
20 | 0 | 0.40 | Ex.10 | 0.77(1500) | 0 | 0.33 | × | × | |
21 | 0 | 0.40 | Ex.10 | 1.15(2250) | 0 | 0.44 | × | × |
22 | 0 | 0 | Ex.11 | 0.38(750) | 0 | 0.52 | × | ||
23 | 0 | 0 | Ex.11 | 0.77(1500) | 0 | 0.66 |
24 | 0 | 0 | Ex.11 | 1.15(2250) | 0 | 0.60 | |||
25 | 0.40 | 0 | Ex.11 | 0.38(750) | 0 | 0.52 | × | × | |
26 | 0.40 | 0 | Ex.11 | 0.77(1500) | 0 | 0.52 | × | × | |
27 | 0.40 | 0 | Ex.11 | 1.15(2250) | 0 | 0.47 | × | × | |
28 | 0 | 0.40 | Ex.11 | 0.38(750) | 0 | 0.47 | × | × | |
29 | 0 | 0.40 | Ex.11 | 0.77(1500) | 0 | 0.46 | × | × | |
30 | 0 | 0.40 | Ex.11 | 1.15(2250) | 0 | 0.67 |
31 | 0 | 0 | Ex.2 | 0.45(750) | 0 | 0.70 | |||
32 | 0 | 0 | Ex.2 | 0.90(1500) | 0 | 0.64 | |||
33 | 0 | 0 | Ex.2 | 1.35(2250) | 0 | 0.61 | |||
34 | 0.40 | 0 | Ex.2 | 0.45(750) | 0 | 0.62 | × | × | |
35 | 0.40 | 0 | Ex.2 | 0.90(1500) | 0 | 0.55 | × | × | |
36 | 0.40 | 0 | Ex.2 | 1.35(2250) | 0 | 0.56 | × | × | |
37 | 0 | 0.40 | Ex.2 | 0.45(750) | 0 | 0.58 | × | ||
38 | 0 | 0.40 | Ex.2 | 0.90(1500) | 0 | 0.50 | × | × | |
39 | 0 | 0.40 | Ex.2 | 1.35(2250) | 0 | 0.51 | × | × |
40 | 0 | 0 | 无 | 0 | 0.38 | 0.63 | |||
41 | 0 | 0 | 无 | 0 | 0.75 | 0.65 | |||
42 | 0 | 0 | 无 | 0 | 1.12 | 0.63 | |||
43 | 0 | 0.40 | 无 | 0 | 0.38 | 0.72 | |||
44 | 0 | 0.40 | 无 | 0 | 0.75 | 0.56 | × | ||
45 | 0 | 0.40 | 无 | 0 | 1.12 | 0.56 | × |
油样 | 钼处理量Mdyvan(R)855重量% | 羟基二硫代氨基甲酸酯类型 | 羟基二硫代氨基甲酸酯处理量重量%(ppm硫) | 油中总ZDDPHiTEC(R)7169重量%(ppm P) | PDSC开始温度(C) |
参考例1 | 0 | 无 | 0 | 120(1000) | 207.8 |
参考例2 | 0.4 | 无 | 0 | 1.20(1000) | 220.0 |
1 | 0 | 无 | 0 | 0.6(500) | 199.1 |
3 | 0.40 | 无 | 0 | 0.6(500) | 211.7 |
4 | 0 | 实施例9 | 0.37(750) | 0.6(500) | 200.1 |
5 | 0 | 实施例9 | 0.73(1500) | 0.6(500) | 199.3 |
6 | 0 | 实施例9 | 1.10(2250) | 0.6(500) | 201.6 |
10 | 0.40 | 实施例9 | 0.37(750) | 0.6(500) | 215.2 |
11 | 0.40 | 实施例9 | 0.73(1500) | 0.6(500) | 217.5 |
12 | 0.40 | 实施例9 | 1.10(2250) | 0.6(500) | 219.2 |
13 | 0 | 实施例10 | 0.38(750) | 0.6(500) | 200.1 |
14 | 0 | 实施例10 | 0.77(1500) | 0.6(500) | 197.7 |
15 | 0 | 实施例10 | 1.15(2250) | 0.6(500) | 200.4 |
19 | 0.40 | 实施例10 | 0.38(750) | 0.6(500) | 215.4 |
20 | 0.40 | 实施例10 | 0.77(1500) | 0.6(500) | 220.8 |
21 | 0.40 | 实施例10 | 1.15(2250) | 0.6(500) | 222.6 |
22 | 0 | 实施例11 | 0.38(750) | 0.6(500) | 200.9 |
23 | 0 | 实施例11 | 0.77(1500) | 0.6(500) | 201.9 |
24 | 0 | 实施例11 | 1.15(2250) | 0.6(500) | 201.4 |
28 | 0.40 | 实施例11 | 0.38(750) | 0.6(500) | 220.8 |
29 | 0.40 | 实施例11 | 0.77(1500) | 0.6(500) | 220.8 |
30 | 0.40 | 实施例11 | 1.15(2250) | 0.6(500) | 224.6 |
31 | 0 | 实施例2 | 0.45(750) | 0.6(500) | 196.9 |
32 | 0 | 实施例2 | 0.90(1500) | 0.6(500) | 197.3 |
33 | 0 | 实施例2 | 1.35(2250) | 0.6(500) | 193.8 |
37 | 0.40 | 实施例2 | 0.45(750) | 0.6(500) | 217.3 |
38 | 0.40 | 实施例2 | 0.90(1500) | 0.6(500) | 217.2 |
39 | 0.40 | 实施例2 | 1.35(2250) | 0.6(500) | 219.0 |
Claims (49)
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US10/067978 | 2002-02-08 | ||
US10/067,978 US7112558B2 (en) | 2002-02-08 | 2002-02-08 | Lubricant composition containing phosphorous, molybdenum, and hydroxy-substituted dithiocarbamates |
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CN1443834A true CN1443834A (zh) | 2003-09-24 |
CN100519713C CN100519713C (zh) | 2009-07-29 |
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US (1) | US7112558B2 (zh) |
EP (1) | EP1338590B1 (zh) |
JP (1) | JP3920784B2 (zh) |
CN (1) | CN100519713C (zh) |
AT (1) | ATE492531T1 (zh) |
AU (1) | AU2003200476B2 (zh) |
DE (1) | DE60335430D1 (zh) |
SG (1) | SG110020A1 (zh) |
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- 2003-02-06 AU AU2003200476A patent/AU2003200476B2/en not_active Ceased
- 2003-02-07 EP EP03250785A patent/EP1338590B1/en not_active Expired - Lifetime
- 2003-02-07 DE DE60335430T patent/DE60335430D1/de not_active Expired - Lifetime
- 2003-02-07 SG SG200300487A patent/SG110020A1/en unknown
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CN101065467B (zh) * | 2004-11-23 | 2010-06-09 | 科聚亚公司 | 作为润滑剂和燃料用添加剂的二硫代氨基甲酰基β-羟基脂肪酸酯 |
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Also Published As
Publication number | Publication date |
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CN100519713C (zh) | 2009-07-29 |
AU2003200476A1 (en) | 2003-08-28 |
SG110020A1 (en) | 2005-04-28 |
ATE492531T1 (de) | 2011-01-15 |
JP2003238979A (ja) | 2003-08-27 |
JP3920784B2 (ja) | 2007-05-30 |
EP1338590B1 (en) | 2010-12-22 |
US20030211951A1 (en) | 2003-11-13 |
DE60335430D1 (de) | 2011-02-03 |
US7112558B2 (en) | 2006-09-26 |
EP1338590A1 (en) | 2003-08-27 |
AU2003200476B2 (en) | 2007-12-13 |
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