CN1339516A - 生产聚酯多元醇的方法和装置,聚酯多元醇和聚氨酯泡沫体 - Google Patents
生产聚酯多元醇的方法和装置,聚酯多元醇和聚氨酯泡沫体 Download PDFInfo
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- CN1339516A CN1339516A CN01132895A CN01132895A CN1339516A CN 1339516 A CN1339516 A CN 1339516A CN 01132895 A CN01132895 A CN 01132895A CN 01132895 A CN01132895 A CN 01132895A CN 1339516 A CN1339516 A CN 1339516A
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- ethylene glycol
- polyester polyol
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
- C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
- C08G18/4252—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/785—Preparation processes characterised by the apparatus used
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/916—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
聚酯多元醇 | 实施例1 | 实施例3 | Actcol ES-40 | |
环戊烷 | 溶解的份数 | 10 | ||
分离的份数 | 5 | 20 | 5 | |
HFC-245fa | 溶解的份数 | 30 | 150 | |
分离的份数 | 40 | 160 | 5 | |
HFC-365mfc | 溶解的份数 | 5 | 70 | |
分离的份数 | 10 | 80 | 5 |
表述 | 生产实施例1 | 生产实施例2 | 生产实施例3 | 生产对比实施例1 |
Actcol GR-36B | 90 | 90 | 90 | 100 |
实施例1的聚酯多元醇 | 10 | |||
实施例2的聚酯多元醇 | 10 | |||
实施例3的聚酯多元醇 | 10 | |||
DMCHA | 3.0 | 3.0 | 4.0 | 2.9 |
PMDETA | 0.3 | 0.3 | 0.4 | 0.3 |
H2O | 1.5 | 1.5 | 1.5 | 1.5 |
CP | 16 | 16 | 16 | 18 |
B-8462 | 2.0 | 2.0 | 2.0 | 2.0 |
4040MC(Index 110) | 128 | 129 | 128 | 132 |
CT(sec) | 4 | 4 | 4 | 4 |
GT(sec) | 30 | 29 | 32 | 31 |
RT(sec) | 49 | 48 | 52 | 50 |
Df(kg/m3) | 25.6 | 25.6 | 25.9 | 25.5 |
Kf(W/mK) | 0.0181 | 0.0180 | 0.0182 | 0.0186 |
表述 | 生产实施例4 | 生产实施例5 | 生产对比例2 | 生产实施例6 | 生产实施例7 | 生产对比例3 |
Actcol IR-45 | 30 | 30 | 30 | 30 | 30 | 30 |
实施例1的聚酯多元醇 | 70 | 70 | ||||
实施例3的聚酯多元醇 | 70 | 70 | ||||
Actcol ES-40 | 70 | 70 | ||||
TMHDA | 0.5 | 0.6 | 0.5 | 0.5 | 0.6 | 0.5 |
K-13 | 3.0 | 3.6 | 3.0 | 3.0 | 3.6 | 3.0 |
H2O | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
HFC-245fa | 35 | 35 | 35 | |||
HFC-365mfc | 35 | 35 | 35 | |||
SH-193 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 |
互溶性 | 良好 | 良好 | 不好 | 良好 | 良好 | 不好 |
M-200(Index 150) | 155 | 155 | 155 | 155 | 155 | 155 |
CT(sec) | 7 | 9 | 7 | 18 | 20 | 19 |
GT(sec) | 42 | 44 | 43 | 45 | 46 | 46 |
Df(kg/m3) | 28.3 | 28.8 | 32.0 | 33.2 | 34.1 | 36.7 |
泡孔的粗糙度 | 无 | 无 | 观察到 | 无 | 无 | 观察到 |
Claims (7)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000230534 | 2000-07-31 | ||
JP230534/2000 | 2000-07-31 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1339516A true CN1339516A (zh) | 2002-03-13 |
CN1221588C CN1221588C (zh) | 2005-10-05 |
Family
ID=18723480
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011328959A Expired - Fee Related CN1221588C (zh) | 2000-07-31 | 2001-07-31 | 生产聚酯多元醇的方法和装置,聚酯多元醇和聚氨酯泡沫体 |
Country Status (8)
Country | Link |
---|---|
US (1) | US6667416B2 (zh) |
EP (1) | EP1178062B1 (zh) |
KR (1) | KR20020011118A (zh) |
CN (1) | CN1221588C (zh) |
AT (1) | ATE402966T1 (zh) |
CA (1) | CA2354252C (zh) |
DE (1) | DE60135069D1 (zh) |
TW (1) | TWI290933B (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1302035C (zh) * | 2005-02-24 | 2007-02-28 | 烟台万华聚氨酯股份有限公司 | 一种聚合物聚酯多元醇、其生产工艺及其应用 |
CN101184808B (zh) * | 2005-04-27 | 2010-12-22 | 金斯潘控股有限公司 | 用于酚醛泡沫体的增塑剂,以及制备酚醛泡沫体的方法 |
CN102159613A (zh) * | 2008-08-06 | 2011-08-17 | 陶氏环球技术有限责任公司 | 芳族聚酯、包含其的多元醇共混物以及由该共混物得到的产品 |
CN103059283A (zh) * | 2013-01-23 | 2013-04-24 | 常熟理工学院 | 一种以废旧聚酯瓶为主要原料制备聚酯多元醇的方法 |
CN107513149A (zh) * | 2017-08-31 | 2017-12-26 | 苏州市苏真床垫有限公司 | 一种涤纶发泡床垫的制备方法 |
CN110387032A (zh) * | 2019-07-25 | 2019-10-29 | 万华化学集团股份有限公司 | 一种聚醚酯多元醇、其制备方法及其制备的聚氨酯弹性体 |
CN114276516A (zh) * | 2022-01-14 | 2022-04-05 | 浙江佳人新材料有限公司 | 一种以废旧纺织品化学法再生工艺的副产物制备硬质聚氨酯泡沫的方法 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100850995B1 (ko) * | 2002-01-04 | 2008-08-12 | 주식회사 엘지이아이 | 경질 폴리우레탄 발포체 제조용 조성물 및 그로부터제조된 경질 폴리우레탄 발포체 |
US6784150B2 (en) | 2002-04-16 | 2004-08-31 | Honeywell International Inc. | Composition of pentafluoropropane, pentafluoropropane and water |
CN104937003B (zh) | 2013-01-25 | 2019-05-10 | 汉高股份有限及两合公司 | 包含可持续生产的原料的湿气固化聚氨酯组合物 |
CN103881074B (zh) * | 2014-01-23 | 2016-01-06 | 单成敏 | 一种生物质聚酯多元醇的制备方法 |
WO2015171433A1 (en) | 2014-05-05 | 2015-11-12 | Resinate Materials Group, Inc. | Polyester polyols from thermoplastic polyesters and dimer fatty acids |
CA2979277C (en) | 2015-03-13 | 2023-09-12 | Basf Se | Method of forming a polyurethane foam article |
EP3283545A1 (en) * | 2015-04-14 | 2018-02-21 | Resinate Materials Group, Inc. | Polyester polyols with increased clarity |
CN106496533B (zh) * | 2016-10-20 | 2019-01-29 | 中国石油化工股份有限公司 | 由pta残渣及环氧乙烷/乙二醇装置釜残液制备聚酯多元醇的方法 |
PL233298B1 (pl) * | 2017-11-17 | 2019-09-30 | Gor Stal Spolka Z Ograniczona Odpowiedzialnoscia | Ekologiczny niskohydroksylowy poliol i sposób wytwarzania poliolu |
US11845863B2 (en) | 2020-05-04 | 2023-12-19 | Carlisle Construction Materials, LLC | Polyurethane dispersions and their use to produce coatings and adhesives |
EP3957665A1 (de) | 2020-08-20 | 2022-02-23 | Covestro Deutschland AG | Lagerstabile polyolformulierungen |
EP4230670A1 (de) | 2022-02-18 | 2023-08-23 | Covestro Deutschland AG | Lagerstabile polyolformulierungen |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4439549A (en) | 1982-11-22 | 1984-03-27 | Texaco Inc. | Novel aromatic polyester polyol mixtures made from polyethylene terephthalate residues and alkylene oxides |
US4469824A (en) | 1983-11-18 | 1984-09-04 | Texaco, Inc. | Liquid terephthalic ester polyols and polyisocyanurate foams therefrom |
JPH0211625A (ja) | 1988-06-28 | 1990-01-16 | Nippon Ester Co Ltd | 改質ポリエステルの製造法 |
US5360900A (en) | 1993-08-12 | 1994-11-01 | Oxid, Inc. | Aromatic polyester polyol |
JP2000017058A (ja) | 1998-07-04 | 2000-01-18 | Hokoku Seiyu Kk | ポリウレタン用ポリオール |
JP3690930B2 (ja) | 1998-12-24 | 2005-08-31 | 三井化学株式会社 | 芳香族ポリエステルポリオールの製造方法 |
-
2001
- 2001-07-25 TW TW090118117A patent/TWI290933B/zh not_active IP Right Cessation
- 2001-07-26 US US09/912,312 patent/US6667416B2/en not_active Expired - Lifetime
- 2001-07-27 CA CA2354252A patent/CA2354252C/en not_active Expired - Fee Related
- 2001-07-28 AT AT01118206T patent/ATE402966T1/de not_active IP Right Cessation
- 2001-07-28 DE DE60135069T patent/DE60135069D1/de not_active Expired - Lifetime
- 2001-07-28 EP EP01118206A patent/EP1178062B1/en not_active Expired - Lifetime
- 2001-07-31 KR KR1020010046203A patent/KR20020011118A/ko not_active Application Discontinuation
- 2001-07-31 CN CNB011328959A patent/CN1221588C/zh not_active Expired - Fee Related
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1302035C (zh) * | 2005-02-24 | 2007-02-28 | 烟台万华聚氨酯股份有限公司 | 一种聚合物聚酯多元醇、其生产工艺及其应用 |
CN101184808B (zh) * | 2005-04-27 | 2010-12-22 | 金斯潘控股有限公司 | 用于酚醛泡沫体的增塑剂,以及制备酚醛泡沫体的方法 |
CN102159613A (zh) * | 2008-08-06 | 2011-08-17 | 陶氏环球技术有限责任公司 | 芳族聚酯、包含其的多元醇共混物以及由该共混物得到的产品 |
CN103059283A (zh) * | 2013-01-23 | 2013-04-24 | 常熟理工学院 | 一种以废旧聚酯瓶为主要原料制备聚酯多元醇的方法 |
CN107513149A (zh) * | 2017-08-31 | 2017-12-26 | 苏州市苏真床垫有限公司 | 一种涤纶发泡床垫的制备方法 |
CN110387032A (zh) * | 2019-07-25 | 2019-10-29 | 万华化学集团股份有限公司 | 一种聚醚酯多元醇、其制备方法及其制备的聚氨酯弹性体 |
CN110387032B (zh) * | 2019-07-25 | 2021-07-23 | 万华化学集团股份有限公司 | 一种聚醚酯多元醇、其制备方法及其制备的聚氨酯弹性体 |
CN114276516A (zh) * | 2022-01-14 | 2022-04-05 | 浙江佳人新材料有限公司 | 一种以废旧纺织品化学法再生工艺的副产物制备硬质聚氨酯泡沫的方法 |
Also Published As
Publication number | Publication date |
---|---|
ATE402966T1 (de) | 2008-08-15 |
EP1178062A1 (en) | 2002-02-06 |
CN1221588C (zh) | 2005-10-05 |
CA2354252A1 (en) | 2002-01-31 |
US6667416B2 (en) | 2003-12-23 |
KR20020011118A (ko) | 2002-02-07 |
EP1178062B1 (en) | 2008-07-30 |
US20020035166A1 (en) | 2002-03-21 |
CA2354252C (en) | 2010-05-25 |
DE60135069D1 (de) | 2008-09-11 |
TWI290933B (en) | 2007-12-11 |
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Address after: 1-5-2, East Xinqiao, Tokyo, Japan Patentee after: MITSUI CHEMICALS POLYURETHANES, Inc. Address before: Tokyo, Japan Patentee before: MITSUI TAKEDA CHEMICALS, Inc. |
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TR01 | Transfer of patent right |
Effective date of registration: 20160408 Address after: 1-5-2, East Xinqiao, Tokyo, Japan Patentee after: Mitsui Chemicals SKC Polyurethane Co.,Ltd. Address before: 1-5-2, East Xinqiao, Tokyo, Japan Patentee before: MITSUI CHEMICALS, Inc. Effective date of registration: 20160408 Address after: 1-5-2, East Xinqiao, Tokyo, Japan Patentee after: MITSUI CHEMICALS, Inc. Address before: 1-5-2, East Xinqiao, Tokyo, Japan Patentee before: MITSUI CHEMICALS POLYURETHANES, Inc. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20051005 Termination date: 20190731 |
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CF01 | Termination of patent right due to non-payment of annual fee |