CN1328153C - 合成气的制备方法和装置 - Google Patents

合成气的制备方法和装置 Download PDF

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Publication number
CN1328153C
CN1328153C CNB031648223A CN03164822A CN1328153C CN 1328153 C CN1328153 C CN 1328153C CN B031648223 A CNB031648223 A CN B031648223A CN 03164822 A CN03164822 A CN 03164822A CN 1328153 C CN1328153 C CN 1328153C
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China
Prior art keywords
steam
steam reforming
catalyst
unit
gas
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Expired - Fee Related
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CNB031648223A
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English (en)
Chinese (zh)
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CN1496956A (zh
Inventor
P·S·克里斯滕森
T·罗斯楚普－尼尔森
N·埃里克斯楚普
K·阿尔斯伯格－彼得森
J·－H·B·汉森
I·迪布杰尔
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Topsoe AS
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Haldor Topsoe AS
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08—Production of synthetic natural gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816—Heating by flames
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1035—Catalyst coated on equipment surfaces, e.g. reactor walls
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
CNB031648223A 2002-09-26 2003-09-26 合成气的制备方法和装置 Expired - Fee Related CN1328153C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA200201431 2002-09-26
DKPA200201431 2002-09-26

Publications (2)

Publication Number Publication Date
CN1496956A CN1496956A (zh) 2004-05-19
CN1328153C true CN1328153C (zh) 2007-07-25

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CNB031648223A Expired - Fee Related CN1328153C (zh) 2002-09-26 2003-09-26 合成气的制备方法和装置

Country Status (11)

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US (2) US7094363B2 (enExample)
EP (1) EP1403215B1 (enExample)
JP (1) JP4959105B2 (enExample)
KR (1) KR101044621B1 (enExample)
CN (1) CN1328153C (enExample)
AU (1) AU2003248394B2 (enExample)
CA (1) CA2442493C (enExample)
ES (1) ES2405587T3 (enExample)
NO (1) NO336969B1 (enExample)
RU (1) RU2354608C2 (enExample)
ZA (1) ZA200307449B (enExample)

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CN102395524A (zh) * 2009-04-15 2012-03-28 气体产品与化学公司 制造含氢产物气体的方法

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US8177868B2 (en) 2002-01-04 2012-05-15 Meggitt (Uk) Limited Reforming apparatus and method
US7377951B2 (en) * 2005-04-15 2008-05-27 Air Products And Chemicals, Inc. Process to utilize low-temperature waste heat for the preparation of synthesis gas
US7504048B2 (en) * 2005-06-14 2009-03-17 Air Products And Chemicals, Inc. Axial convective reformer
EP2049456B1 (en) 2006-01-23 2012-03-14 Saudi Basic Industries Corporation Inc. Process for the production of ethylene from natural gas with heat integration
US20080110801A1 (en) * 2006-11-09 2008-05-15 Leon Yuan Process For Heating A Hydrocarbon Stream Entering A Reaction Zone With A Heater Convection Section
US7740751B2 (en) 2006-11-09 2010-06-22 Uop Llc Process for heating a stream for a hydrocarbon conversion process
US7501078B2 (en) 2007-01-10 2009-03-10 Air Products And Chemicals, Inc. Process for generating synthesis gas using catalyzed structured packing
US7862633B2 (en) 2007-04-13 2011-01-04 Battelle Memorial Institute Method and system for introducing fuel oil into a steam reformer with reduced carbon deposition
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
US7906559B2 (en) * 2007-06-21 2011-03-15 University Of Southern California Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas
US7790059B2 (en) * 2007-10-18 2010-09-07 Air Products And Chemicals, Inc. Staged hydrocarbon/steam reformer apparatus and method
US8282814B2 (en) * 2009-03-31 2012-10-09 Uop Llc Fired heater for a hydrocarbon conversion process
RU2548410C2 (ru) 2011-02-18 2015-04-20 Сергей Александрович Вощинин Способ и устройство для получения синтез-газа
DE102012019382A1 (de) * 2012-10-02 2014-04-03 Linde Aktiengesellschaft Anlage und Verfahren zur Herstellung von Synthesegas
ES2961240T3 (es) 2016-06-10 2024-03-11 Topsoe As Producción de gas de síntesis rico en CO
US10633603B2 (en) 2018-01-04 2020-04-28 Chevron Phillips Chemical Company Lp Optimized reactor configuration for optimal performance of the aromax catalyst for aromatics synthesis
US10537867B2 (en) 2018-01-04 2020-01-21 Chevron Phillips Chemical Company Lp Optimized reactor configuration for optimal performance of the aromax catalyst for aromatics synthesis
RU2677142C1 (ru) * 2018-05-04 2019-01-15 Андрей Владиславович Курочкин Устройство нагрева реакционной зоны каталитического реактора
RU2677146C1 (ru) * 2018-05-04 2019-01-15 Андрей Владиславович Курочкин Установка для получения синтез-газа с каталитическим нагревателем
GB201813431D0 (en) 2018-08-17 2018-10-03 Weedon Geoffrey Gerald Process & apparatus for steam reforming
CN119947980A (zh) 2022-10-03 2025-05-06 埃克森美孚技术与工程公司 高温逆流反应器中的氢气生成
WO2024196340A1 (en) * 2023-03-17 2024-09-26 Jbk Extractions Llc Systems and methods for making syngas

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102395524A (zh) * 2009-04-15 2012-03-28 气体产品与化学公司 制造含氢产物气体的方法
CN102395524B (zh) * 2009-04-15 2015-07-15 气体产品与化学公司 制造含氢产物气体的方法

Also Published As

Publication number Publication date
JP4959105B2 (ja) 2012-06-20
ES2405587T3 (es) 2013-05-31
CA2442493C (en) 2011-05-03
AU2003248394B2 (en) 2010-03-11
US20060143984A1 (en) 2006-07-06
JP2004269345A (ja) 2004-09-30
AU2003248394A1 (en) 2004-04-22
NO20034283L (no) 2004-03-29
KR20040027456A (ko) 2004-04-01
US7547332B2 (en) 2009-06-16
CN1496956A (zh) 2004-05-19
EP1403215B1 (en) 2013-03-13
NO336969B1 (no) 2015-12-07
KR101044621B1 (ko) 2011-06-29
US20040065014A1 (en) 2004-04-08
RU2354608C2 (ru) 2009-05-10
ZA200307449B (en) 2004-07-06
US7094363B2 (en) 2006-08-22
EP1403215A1 (en) 2004-03-31
CA2442493A1 (en) 2004-03-26
NO20034283D0 (no) 2003-09-25
RU2003128598A (ru) 2005-03-27

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