CN1293677A - 桥连金属茂的制备和在催化体系中的应用 - Google Patents

桥连金属茂的制备和在催化体系中的应用 Download PDF

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Publication number
CN1293677A
CN1293677A CN99804086A CN99804086A CN1293677A CN 1293677 A CN1293677 A CN 1293677A CN 99804086 A CN99804086 A CN 99804086A CN 99804086 A CN99804086 A CN 99804086A CN 1293677 A CN1293677 A CN 1293677A
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CN
China
Prior art keywords
compound
formula
indenyl
dimethyl
metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN99804086A
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English (en)
Chinese (zh)
Inventor
T·达尔奥科
V·A·当
L·C·于
L·雷斯科尼
D·巴尔波尼
A·波斯卡拉托
C·J·沙维里恩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Publication of CN1293677A publication Critical patent/CN1293677A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465—Indenes; Completely or partially hydrogenated indenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN99804086A 1998-11-20 1999-11-03 桥连金属茂的制备和在催化体系中的应用 Pending CN1293677A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98203912.5 1998-11-20
EP98203912 1998-11-20

Publications (1)

Publication Number Publication Date
CN1293677A true CN1293677A (zh) 2001-05-02

Family

ID=8234360

Family Applications (1)

Application Number Title Priority Date Filing Date
CN99804086A Pending CN1293677A (zh) 1998-11-20 1999-11-03 桥连金属茂的制备和在催化体系中的应用

Country Status (15)

Country Link
US (1) US6433203B1 (https=)
EP (1) EP1049704B1 (https=)
JP (1) JP4658326B2 (https=)
KR (1) KR20010034199A (https=)
CN (1) CN1293677A (https=)
AR (1) AR021294A1 (https=)
AT (1) ATE300549T1 (https=)
AU (1) AU6476799A (https=)
BR (1) BR9909744A (https=)
CA (1) CA2317485A1 (https=)
DE (1) DE69926339T2 (https=)
HU (1) HUP0101144A2 (https=)
IL (1) IL137158A0 (https=)
WO (1) WO2000031088A1 (https=)
ZA (1) ZA200003797B (https=)

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* Cited by examiner, † Cited by third party
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US6242545B1 (en) * 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US20060293470A1 (en) * 2005-06-28 2006-12-28 Cao Phuong A Polymerization process using spray-dried catalyst
US8497330B2 (en) * 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
JP2002256012A (ja) * 2001-02-28 2002-09-11 Inst Of Physical & Chemical Res 重合用触媒
AU2002320633B2 (en) 2001-07-19 2005-08-25 Univation Technologies, Llc Polyethylene films with improved physical properties
JP4020862B2 (ja) 2001-07-19 2007-12-12 ユニベーション・テクノロジーズ・エルエルシー コモノマー少量組込み触媒とコモノマー多量組込み触媒を含有する混合メタロセン触媒系
US6936675B2 (en) 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
CA2454060A1 (en) 2001-07-19 2003-01-30 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
CA2412488C (en) * 2001-12-11 2009-09-08 Crompton Gmbh Process for preparing partial hydrolysates of organometallic compounds or transition metal catalysts immobilized on inert support materials
US6884748B2 (en) 2002-09-04 2005-04-26 Univation Technologies, Llc Process for producing fluorinated catalysts
US6753390B2 (en) 2002-09-04 2004-06-22 Univation Technologies, Llc Gas phase polymerization process
US6875828B2 (en) 2002-09-04 2005-04-05 Univation Technologies, Llc Bimodal polyolefin production process and films therefrom
US6812183B1 (en) * 2003-04-23 2004-11-02 Equistar Chemicals, Lp Triple-decker catalysts based on delocalized dianionic ligands
US7838611B2 (en) 2005-12-19 2010-11-23 Tosoh Corporation Ethylene polymer, catalyst for ethylene polymer production, and method for producing ethylene polymer
JP4940649B2 (ja) * 2005-12-19 2012-05-30 東ソー株式会社 エチレン系重合体製造用触媒およびエチレン系重合体の製造方法
KR100864313B1 (ko) * 2007-05-21 2008-10-20 한국화학연구원 불포화 금속자리를 갖는 다공성 유-무기 혼성체 또는메조세공체의 표면 기능화 및 그의 응용
CN101815727B (zh) * 2007-08-27 2013-05-15 保瑞利斯科技公司 催化剂
ATE547439T1 (de) * 2007-10-25 2012-03-15 Lummus Novolen Technology Gmbh Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere
US8435911B2 (en) 2008-10-16 2013-05-07 Basell Polyolefine Gmbh Hybrid catalyst composition for polymerization of olefins
KR101549206B1 (ko) 2012-05-08 2015-09-02 주식회사 엘지화학 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법

Family Cites Families (14)

* Cited by examiner, † Cited by third party
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ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
JPH0745543B2 (ja) 1987-07-31 1995-05-17 チッソ株式会社 オレフィン重合体の製造方法
JPH0725821B2 (ja) 1987-08-03 1995-03-22 チッソ株式会社 ポリオレフィンの製造方法
DE3836059A1 (de) 1988-10-22 1990-05-03 Hoechst Ag Verfahren zur herstellung eines ethylen-propylen-copolymers
DE3916555A1 (de) 1989-05-20 1990-11-22 Hoechst Ag Verfahren zur herstellung von ethylenpolymeren
FR2666142B2 (fr) 1989-10-30 1994-09-16 Lacroix E Tous Artifices Perfectionnements aux sytemes d'arme munis d'un dispositif d'amortissement.
DE4017331A1 (de) * 1990-05-30 1991-12-05 Hoechst Ag Verfahren zur herstellung eines polyolefins
IT1270253B (it) 1994-06-20 1997-04-29 Spherilene Srl Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
IT1275777B1 (it) * 1995-07-06 1997-10-17 Enichem Spa Catalizzatore metallocenico per la (co)polimerizzazione delle olefine
US5744415A (en) * 1995-12-28 1998-04-28 Union Carbide Chemicals & Plastics Technology Corporation Rare earth metal catalyst for olefin polymerization
IT1283630B1 (it) * 1996-05-09 1998-04-23 Enichem Spa Procedimento per la preparazione di copolimeri elastomerici ep(d)m
BR9804807A (pt) * 1997-03-29 1999-08-17 Montell Technology Company Bv Compostos metalocenos e catalisadores para a polimeraza-Æo de olefinas
IT1298616B1 (it) * 1998-03-10 2000-01-12 Enichem Spa Complesso metallocenico pontato per la (co) polimerizzazione delle olefine
DE19823168A1 (de) * 1998-05-23 1999-11-25 Aventis Res & Tech Gmbh & Co Katalysatorsystem

Also Published As

Publication number Publication date
JP2002530413A (ja) 2002-09-17
ATE300549T1 (de) 2005-08-15
WO2000031088A1 (en) 2000-06-02
US6433203B1 (en) 2002-08-13
HUP0101144A2 (hu) 2001-07-30
DE69926339D1 (de) 2005-09-01
BR9909744A (pt) 2002-03-26
ZA200003797B (en) 2001-02-07
JP4658326B2 (ja) 2011-03-23
CA2317485A1 (en) 2000-06-02
EP1049704A1 (en) 2000-11-08
KR20010034199A (ko) 2001-04-25
IL137158A0 (en) 2001-07-24
AU6476799A (en) 2000-06-13
DE69926339T2 (de) 2006-01-26
EP1049704B1 (en) 2005-07-27
AR021294A1 (es) 2002-07-03

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