CN1213983C - 将烃类催化氧化为羧酸和脱氢产物的气相方法 - Google Patents

将烃类催化氧化为羧酸和脱氢产物的气相方法 Download PDF

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Publication number
CN1213983C
CN1213983C CNB008130280A CN00813028A CN1213983C CN 1213983 C CN1213983 C CN 1213983C CN B008130280 A CNB008130280 A CN B008130280A CN 00813028 A CN00813028 A CN 00813028A CN 1213983 C CN1213983 C CN 1213983C
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China
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catalyst
oxygen
reaction zone
mixture
sulfur
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Expired - Fee Related
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CNB008130280A
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English (en)
Chinese (zh)
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CN1374936A (zh
Inventor
K·卡林
A·坎
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CNB008130280A 1999-09-17 2000-09-11 将烃类催化氧化为羧酸和脱氢产物的气相方法 Expired - Fee Related CN1213983C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/399,275 US6258992B1 (en) 1999-09-17 1999-09-17 Gas phase catalytic oxidation of hydrocarbons to carboxylic acids and dehydrogenated products
US09/399275 1999-09-17

Publications (2)

Publication Number Publication Date
CN1374936A CN1374936A (zh) 2002-10-16
CN1213983C true CN1213983C (zh) 2005-08-10

Family

ID=23578911

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB008130280A Expired - Fee Related CN1213983C (zh) 1999-09-17 2000-09-11 将烃类催化氧化为羧酸和脱氢产物的气相方法

Country Status (10)

Country Link
US (1) US6258992B1 (enExample)
EP (1) EP1212276B1 (enExample)
JP (1) JP4711582B2 (enExample)
KR (1) KR100798183B1 (enExample)
CN (1) CN1213983C (enExample)
AT (1) ATE261925T1 (enExample)
DE (1) DE60009092T2 (enExample)
ES (1) ES2215724T3 (enExample)
SA (1) SA00201005B1 (enExample)
WO (1) WO2001021570A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6841699B2 (en) * 2001-04-25 2005-01-11 Rohm And Haas Company Recalcined catalyst
US6642173B2 (en) * 2001-04-25 2003-11-04 Rohm And Haas Company Catalyst
JP2002322116A (ja) * 2001-04-25 2002-11-08 Nippon Shokubai Co Ltd （メタ）アクリル酸の製造方法
US6656873B2 (en) * 2001-06-14 2003-12-02 Sanjay Chaturvedi Mixed metal oxide catalyst
DE10132526A1 (de) * 2001-07-09 2003-01-30 Ruhrgas Ag Verfahren zum Herstellen eines Alkanderivats
US20040158112A1 (en) * 2003-02-10 2004-08-12 Conocophillips Company Silicon carbide-supported catalysts for oxidative dehydrogenation of hydrocarbons
JP5301110B2 (ja) * 2007-05-15 2013-09-25 三菱レイヨン株式会社 メタクロレインの製造方法
JP2009051816A (ja) * 2007-08-23 2009-03-12 Rohm & Haas Co 不飽和カルボン酸およびニトリルの製造方法
US20100030001A1 (en) * 2008-07-31 2010-02-04 Laiyuan Chen Process for catalytically producing ethylene directly from acetic acid in a single reaction zone
US20100030002A1 (en) * 2008-07-31 2010-02-04 Johnston Victor J Ethylene production from acetic acid utilizing dual reaction zone process
CN103861619A (zh) * 2012-12-11 2014-06-18 江苏省海洋石化股份有限公司 一种烷烃脱氢硫化物催化剂及烷烃脱氢的方法
EP2988864A2 (en) * 2013-04-24 2016-03-02 Saudi Basic Industries Corporation Supported catalyst for production of unsaturated carboxylic acids from alkanes
US12059670B2 (en) 2017-08-01 2024-08-13 Purdue Research Foundation Nickel alloy catalysts for light alkane dehydrogenation
WO2020194228A1 (en) 2019-03-26 2020-10-01 Sabic Global Technologies B.V. Method of reactivating catalyst
CN109939688B (zh) * 2019-04-03 2021-12-14 华东理工大学 铁镓基丙烷脱氢催化剂及其制备方法
CN110504108A (zh) * 2019-08-22 2019-11-26 杭州求实新材料科技有限公司 一种超级电容器用多孔超薄碳膜负载碳化钼量子点的制备方法
EP4059916A1 (de) 2021-03-15 2022-09-21 Linde GmbH Verfahren und anlage zur erzeugung eines produktkohlenwasserstoffs
EP4342873A1 (de) 2022-09-26 2024-03-27 Linde GmbH Verfahren und anlage zur herstellung von ethylen und essigsäure, verfahren und anlage zur herstellung einer zielverbindung unter verwendung von ethylen und essigsäure

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2423418A (en) 1943-08-14 1947-07-01 Texas Co Process for producing alkadienes by dehydrogenating alkenes
US2720550A (en) 1952-08-09 1955-10-11 Trustees Of Iowa College Dehydrogenation of naphthenes by means of sulfur dioxide
US2867677A (en) 1956-05-15 1959-01-06 Sun Oil Co Dehydrogenation of hydrocarbons
US3403192A (en) * 1965-03-29 1968-09-24 Exxon Research Engineering Co Sulfur-promoted oxidative dehydrogenation process
US3456026A (en) * 1967-11-01 1969-07-15 Exxon Research Engineering Co Sulfur dehydrogenation of organic compounds
US3585250A (en) * 1968-12-02 1971-06-15 Exxon Research Engineering Co Sulfur promoted dehydrogenation of organic compounds
US3585249A (en) * 1968-12-02 1971-06-15 Exxon Research Engineering Co Sulfur promoted oxidative dehydrogenation of organic compounds
US3585248A (en) * 1968-12-02 1971-06-15 Exxon Research Engineering Co Sulfur oxide dehydrogenation of organic compounds
BE755817A (fr) * 1969-09-19 1971-03-08 Petro Tex Chem Corp Procede de deshydrogenation oxydante favorisee par le soufre
US3970697A (en) 1974-07-01 1976-07-20 National Distillers And Chemical Corporation Oxidation of ethylene to acetic acid
US4339355A (en) 1975-10-09 1982-07-13 Union Carbide Corporation Catalytic oxide of molybdenum, vanadium, niobium and optional 4th metal
US4188490A (en) 1977-05-27 1980-02-12 National Distillers And Chemical Corporation Catalytic oxidation of ethylene to mixtures of acetic acid and vinyl acetate
US4148757A (en) 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
DE2811115A1 (de) 1978-03-15 1979-09-27 Hoechst Ag Traeger-katalysator fuer die herstellung von vinylacetat aus ethylen, essigsaeure und sauerstoff in der gasphase
US4250346A (en) 1980-04-14 1981-02-10 Union Carbide Corporation Low temperature oxydehydrogenation of ethane to ethylene
US4524236A (en) 1984-06-28 1985-06-18 Union Carbide Corporation Process for oxydehydrogenation of ethane to ethylene
US4568790A (en) 1984-06-28 1986-02-04 Union Carbide Corporation Process for oxydehydrogenation of ethane to ethylene
US4596787A (en) 1985-04-11 1986-06-24 Union Carbide Corporation Process for preparing a supported catalyst for the oxydehydrogenation of ethane to ethylene
US4899003A (en) 1985-07-11 1990-02-06 Union Carbide Chemicals And Plastics Company Inc. Process for oxydehydrogenation of ethane to ethylene
DE3803900A1 (de) 1988-02-09 1989-08-17 Hoechst Ag Verfahren zur herstellung von vinylacetat
US5185308A (en) 1991-05-06 1993-02-09 Bp Chemicals Limited Catalysts and processes for the manufacture of vinyl acetate
TW295579B (enExample) * 1993-04-06 1997-01-11 Showa Denko Kk
FR2705668B1 (fr) 1993-05-28 1995-08-25 Rhone Poulenc Chimie Procédé de préparation d'acide acétique par oxydation ménagée de l'éthane.
GB9616573D0 (en) * 1996-08-07 1996-09-25 Bp Chem Int Ltd Process
US6013597A (en) 1997-09-17 2000-01-11 Saudi Basic Industries Corporation Catalysts for the oxidation of ethane to acetic acid processes of making same and, processes of using same
US6087297A (en) * 1998-06-29 2000-07-11 Saudi Basic Industries Corporation Catalysts for gas phase production of acetic acid from ethane, processes of making the same and methods of using same
US6028221A (en) * 1998-06-29 2000-02-22 Saudi Basic Industries Corporation Catalyst systems for the one step gas phase production of acetic acid from ethylene and methods of making and using the same
US6060421A (en) * 1998-12-23 2000-05-09 Saudi Basic Industries Corporation Catalysts for the oxidation of ethane to acetic acid, methods of making and using the same
US6143921A (en) * 1999-05-14 2000-11-07 Saudi Basic Industries Corporation Method for producing vinyl acetate monomer from ethane or ethylene oxidation

Also Published As

Publication number Publication date
KR20020029132A (ko) 2002-04-17
SA00201005B1 (ar) 2006-08-01
DE60009092T2 (de) 2005-01-20
EP1212276B1 (en) 2004-03-17
US6258992B1 (en) 2001-07-10
JP2003520202A (ja) 2003-07-02
WO2001021570A1 (en) 2001-03-29
KR100798183B1 (ko) 2008-01-24
EP1212276A1 (en) 2002-06-12
ES2215724T3 (es) 2004-10-16
CN1374936A (zh) 2002-10-16
JP4711582B2 (ja) 2011-06-29
DE60009092D1 (de) 2004-04-22
ATE261925T1 (de) 2004-04-15

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Granted publication date: 20050810

Termination date: 20180911