CN1188382C - 用受到促进的铱催化剂的汽相羰基化方法 - Google Patents

用受到促进的铱催化剂的汽相羰基化方法 Download PDF

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Publication number
CN1188382C
CN1188382C CNB008120153A CN00812015A CN1188382C CN 1188382 C CN1188382 C CN 1188382C CN B008120153 A CNB008120153 A CN B008120153A CN 00812015 A CN00812015 A CN 00812015A CN 1188382 C CN1188382 C CN 1188382C
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CN
China
Prior art keywords
catalyst
iridium
carbonylation
metal
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB008120153A
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English (en)
Chinese (zh)
Other versions
CN1371350A (zh
Inventor
J·R·佐勒
A·H·辛格勒顿
G·C·图斯廷
D·L·卡弗
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Eastman Chemical Co
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Eastman Chemical Co
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Publication date
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Publication of CN1371350A publication Critical patent/CN1371350A/zh
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Publication of CN1188382C publication Critical patent/CN1188382C/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CNB008120153A 1999-08-25 2000-08-11 用受到促进的铱催化剂的汽相羰基化方法 Expired - Fee Related CN1188382C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/383,049 US6353132B1 (en) 1999-08-25 1999-08-25 Vapor phase carbonylation process using group 5 metal promoted iridium catalyst
US09/383,049 1999-08-25

Publications (2)

Publication Number Publication Date
CN1371350A CN1371350A (zh) 2002-09-25
CN1188382C true CN1188382C (zh) 2005-02-09

Family

ID=23511488

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB008120153A Expired - Fee Related CN1188382C (zh) 1999-08-25 2000-08-11 用受到促进的铱催化剂的汽相羰基化方法

Country Status (7)

Country Link
US (1) US6353132B1 (enExample)
EP (1) EP1206433B1 (enExample)
JP (1) JP2003507445A (enExample)
CN (1) CN1188382C (enExample)
BR (1) BR0013528A (enExample)
DE (1) DE60008118T2 (enExample)
WO (1) WO2001014305A1 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6617471B2 (en) * 2001-06-20 2003-09-09 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using tin promoted iridium catalyst
CA2496839A1 (en) 2004-07-19 2006-01-19 Woodland Chemical Systems Inc. Process for producing ethanol from synthesis gas rich in carbon monoxide
US20060252959A1 (en) * 2005-05-05 2006-11-09 The Regents Of The University Of California Process for carbonylation of alkyl ethers
US7465822B2 (en) 2005-05-05 2008-12-16 Bp Chemicals Ltd. Process for carbonylation of alkyl ethers
GB0601863D0 (en) 2006-01-30 2006-03-08 Bp Chem Int Ltd Process
KR20080108605A (ko) * 2006-04-05 2008-12-15 우드랜드 바이오퓨엘스 인크. 합성 가스에 의해 바이오매스를 에탄올로 전환시키는 시스템 및 방법
US7507855B2 (en) * 2006-12-15 2009-03-24 The Regents Of The University Of California Process for carbonylation of aliphatic alcohols and/or ester derivatives thereof
EP1985607A1 (en) * 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
US9421522B2 (en) * 2011-12-28 2016-08-23 Eastman Chemical Company Iridium catalysts for carbonylation
US10512902B2 (en) * 2015-12-18 2019-12-24 Bp Chemicals Limited Carbonylation process using a pretreated zeolite catalyst
CN106111191A (zh) * 2016-06-29 2016-11-16 兖矿水煤浆气化及煤化工国家工程研究中心有限公司 一种碳纳米管负载铑催化剂体系及其应用
CN108067222B (zh) * 2016-11-15 2020-09-22 中国科学院大连化学物理研究所 活性炭载体负载的硫促进的铱基催化剂及其制备和应用
CN111195530B (zh) * 2018-11-20 2021-04-23 中国科学院大连化学物理研究所 一种原子级单分散的铱基催化剂其制备方法与应用

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3717670A (en) 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
US3772380A (en) 1970-03-12 1973-11-13 Monsanto Co Production of carboxylic acids and esters
US3689533A (en) 1971-03-15 1972-09-05 Monsanto Co Production of carboxylic acids and esters
US4417077A (en) 1980-10-01 1983-11-22 University Of Illinois Foundation Heterogeneous anionic transition metal catalysts
US4612387A (en) 1982-01-04 1986-09-16 Air Products And Chemicals, Inc. Production of carboxylic acids and esters
DE3463257D1 (en) 1983-03-25 1987-05-27 Texaco Development Corp A process for producing carboxylic acids by carbonylation of alkanols over a carbon catalyst
US4625050A (en) 1983-06-23 1986-11-25 Chevron Research Company Ether homologation to esters and alcohols using a heterogeneous sulfided catalyst
DE3323654A1 (de) 1983-07-01 1985-01-03 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von essigsaeure und methylacetat
US5144068A (en) 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
EP0203286B1 (de) 1985-03-27 1988-09-14 Hoechst Aktiengesellschaft Trägerkatalysator und Verfahren zur Herstellung von Monocarbonsäureanhydriden
DE3643894A1 (de) 1986-12-22 1988-06-23 Degussa Rhodium-haltige organopolysiloxan-ammoniumverbindungen, verfahren zu ihrer herstellung und verwendung
US5185462A (en) 1987-01-08 1993-02-09 Bp Chemicals Limited Production of carboxylic acids and esters thereof
GB8807284D0 (en) 1988-03-26 1988-04-27 Bp Chem Int Ltd Chemical process
US5218140A (en) 1988-08-02 1993-06-08 Union Carbide Chemicals & Plastics Technology Corporation Carbonylation reaction and catalyst therefor
GB9013116D0 (en) 1990-06-12 1990-08-01 British Petroleum Co Plc Carbonylation of methanol
US5488143A (en) 1992-06-30 1996-01-30 Korea Institute Of Science And Technology Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride
GB9223170D0 (en) 1992-11-05 1992-12-16 British Petroleum Co Plc Process for preparing carboxylic acids
WO1995031426A1 (fr) * 1994-05-13 1995-11-23 Pardies Acetiques Procede de preparation d'acides carboxyliques ou des esters correspondants en presence d'un catalyseur a base d'iridium et d'iodures sous forme soluble
US5510524A (en) 1995-02-21 1996-04-23 Bp Chemicals Limited Process for the production of a carboxylic acid
US5696284A (en) 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
GB9517184D0 (en) 1995-08-22 1995-10-25 Bp Chem Int Ltd Process
US5900505A (en) 1997-02-04 1999-05-04 Eastman Chemical Company Heterogeneous vapor phase carbonylation process

Also Published As

Publication number Publication date
DE60008118T2 (de) 2004-07-08
CN1371350A (zh) 2002-09-25
BR0013528A (pt) 2002-04-30
US6353132B1 (en) 2002-03-05
EP1206433B1 (en) 2004-02-04
WO2001014305A1 (en) 2001-03-01
JP2003507445A (ja) 2003-02-25
EP1206433A1 (en) 2002-05-22
DE60008118D1 (de) 2004-03-11

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Owner name: EASTMAN CHEMICAL COMPANY

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Granted publication date: 20050209

Termination date: 20170811

CF01 Termination of patent right due to non-payment of annual fee