CN1183079C - 用于低级脂肪醇的羰基化的铱催化剂 - Google Patents

用于低级脂肪醇的羰基化的铱催化剂 Download PDF

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Publication number
CN1183079C
CN1183079C CNB998161632A CN99816163A CN1183079C CN 1183079 C CN1183079 C CN 1183079C CN B998161632 A CNB998161632 A CN B998161632A CN 99816163 A CN99816163 A CN 99816163A CN 1183079 C CN1183079 C CN 1183079C
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CN
China
Prior art keywords
catalyst
iridium
metal
weight
iodide
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Expired - Fee Related
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CNB998161632A
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English (en)
Chinese (zh)
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CN1334790A (zh
Inventor
Jr
J·R·佐伊勒
A·H·辛莱顿
G·C·图斯丁
ά
D·L·卡维尔
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Eastman Chemical Co
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Eastman Chemical Co
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Publication of CN1334790A publication Critical patent/CN1334790A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB998161632A 1999-02-16 1999-12-31 用于低级脂肪醇的羰基化的铱催化剂 Expired - Fee Related CN1183079C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/250,665 US6159896A (en) 1999-02-16 1999-02-16 Iridium catalyst for carbonylation of lower aliphatic alcohols
US09/250,665 1999-02-16
US09/250665 1999-02-16

Publications (2)

Publication Number Publication Date
CN1334790A CN1334790A (zh) 2002-02-06
CN1183079C true CN1183079C (zh) 2005-01-05

Family

ID=22948674

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998161632A Expired - Fee Related CN1183079C (zh) 1999-02-16 1999-12-31 用于低级脂肪醇的羰基化的铱催化剂

Country Status (6)

Country Link
US (1) US6159896A (enExample)
EP (1) EP1153007B1 (enExample)
JP (1) JP2003517914A (enExample)
CN (1) CN1183079C (enExample)
DE (1) DE69936542T2 (enExample)
WO (1) WO2000048976A1 (enExample)

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KR100451646B1 (ko) * 2000-01-05 2004-10-08 니폰 쇼쿠바이 컴파니 리미티드 배수처리용 촉매, 그의 제조방법 및 배수의 처리방법
US6235673B1 (en) * 2000-04-05 2001-05-22 Eastman Chemical Company Carbonylation catalyst supported on a carbonized polysulfonated divinylbenzene-styrene copolymer
US6509293B1 (en) * 2000-05-22 2003-01-21 Eastman Chemical Company Gold based heterogeneous carbonylation catalysts
US6586650B2 (en) * 2000-07-21 2003-07-01 Exxonmobil Research And Engineering Company Ring opening with group VIII metal catalysts supported on modified substrate
US6964936B1 (en) * 2003-03-06 2005-11-15 Sandia Corporation Method of making maximally dispersed heterogeneous catalysts
KR100712637B1 (ko) * 2005-12-23 2007-04-30 한국항공우주연구원 보오크사이트를 이용한 고강도 특성을 지닌 우주비행체추력기용 하이드라진 분해용 이리듐 촉매의 제조방법 및그로부터 수득되는 이리듐 촉매
CN103084214B (zh) * 2011-11-02 2014-11-05 中国石油化工股份有限公司 一种铱催化剂体系
TWI560178B (en) * 2011-12-08 2016-12-01 Celanese Int Corp Rhodium-catalyzed low water methanol carbonylation process with lanthanide metal co-catalyst stabilization and reduced inorganic iodide levels
CN106140156A (zh) * 2015-04-20 2016-11-23 中国科学院大连化学物理研究所 一种活性炭负载的铑基催化剂及其制备方法和应用
EA202193241A1 (ru) 2019-05-28 2022-03-18 Инеркем Инк. Катализатор газофазного карбонилирования метанола

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BE790861A (fr) * 1971-11-19 1973-04-30 Catalyse Soc Prod Francais Nouveau catalyseur de conversion d'hydrocarbures
US3856856A (en) * 1973-01-08 1974-12-24 Shell Oil Co Production of carboxylic acids and esters
US3897328A (en) * 1973-10-29 1975-07-29 Exxon Research Engineering Co Iridium-containing reforming catalyst and use thereof
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US4024052A (en) * 1975-11-20 1977-05-17 Uop Inc. Hydrocarbon conversion with an acidic multimetallic catalytic composite
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US4625050A (en) * 1983-06-23 1986-11-25 Chevron Research Company Ether homologation to esters and alcohols using a heterogeneous sulfided catalyst
DE3323654A1 (de) * 1983-07-01 1985-01-03 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von essigsaeure und methylacetat
US5144068A (en) * 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
US4831191A (en) * 1984-12-12 1989-05-16 Texaco Inc. Catalytic conversion of allyl formate to carboxylic acids
EP0203286B1 (de) * 1985-03-27 1988-09-14 Hoechst Aktiengesellschaft Trägerkatalysator und Verfahren zur Herstellung von Monocarbonsäureanhydriden
DE3544765C2 (de) * 1985-12-18 1994-04-07 Roehm Gmbh Verfahren zur Herstellung von ungesättigten aliphatischen Carbonsäureanhydriden
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JPH08277244A (ja) * 1995-04-05 1996-10-22 Daicel Chem Ind Ltd カルボン酸の製造方法及びカルボニル化反応用触媒系
JPH08309185A (ja) * 1995-05-18 1996-11-26 N E Chemcat Corp 排気ガス浄化用触媒および排気ガスの浄化方法
US5696284A (en) * 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
GB9517184D0 (en) * 1995-08-22 1995-10-25 Bp Chem Int Ltd Process
WO1998033590A1 (en) * 1997-02-04 1998-08-06 Eastman Chemical Company Carbonylation catalyst
US5900505A (en) * 1997-02-04 1999-05-04 Eastman Chemical Company Heterogeneous vapor phase carbonylation process
GB9715402D0 (en) * 1997-07-22 1997-09-24 Bp Chem Int Ltd Process
US6137000A (en) * 1999-02-16 2000-10-24 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using a supported iridium and lanthanide series catalyst

Also Published As

Publication number Publication date
WO2000048976A1 (en) 2000-08-24
JP2003517914A (ja) 2003-06-03
DE69936542D1 (de) 2007-08-23
US6159896A (en) 2000-12-12
EP1153007B1 (en) 2007-07-11
DE69936542T2 (de) 2008-03-13
EP1153007A1 (en) 2001-11-14
CN1334790A (zh) 2002-02-06

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Owner name: EASTMAN CHEMICAL COMPANY

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