CN1123561C - 乙烷催化氧化选择性生产乙酸的方法 - Google Patents

乙烷催化氧化选择性生产乙酸的方法 Download PDF

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Publication number
CN1123561C
CN1123561C CN98810193A CN98810193A CN1123561C CN 1123561 C CN1123561 C CN 1123561C CN 98810193 A CN98810193 A CN 98810193A CN 98810193 A CN98810193 A CN 98810193A CN 1123561 C CN1123561 C CN 1123561C
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CN
China
Prior art keywords
ethane
catalyst
acetic acid
ethylene
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN98810193A
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English (en)
Chinese (zh)
Other versions
CN1275971A (zh
Inventor
H·伯彻特
U·丁格迪森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Department Of Nutrition And Food Ingredient Novi Co ltd
Celanese Sales Germany GmbH
Original Assignee
Celanese Chemicals Europe GmbH
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Publication date
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Publication of CN1275971A publication Critical patent/CN1275971A/zh
Application granted granted Critical
Publication of CN1123561C publication Critical patent/CN1123561C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN98810193A 1997-10-17 1998-10-09 乙烷催化氧化选择性生产乙酸的方法 Expired - Lifetime CN1123561C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19745902A DE19745902A1 (de) 1997-10-17 1997-10-17 Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan
DE19745902.1 1997-10-17

Publications (2)

Publication Number Publication Date
CN1275971A CN1275971A (zh) 2000-12-06
CN1123561C true CN1123561C (zh) 2003-10-08

Family

ID=7845827

Family Applications (1)

Application Number Title Priority Date Filing Date
CN98810193A Expired - Lifetime CN1123561C (zh) 1997-10-17 1998-10-09 乙烷催化氧化选择性生产乙酸的方法

Country Status (12)

Country Link
US (1) US6399816B1 (enExample)
EP (1) EP1025075B1 (enExample)
JP (1) JP4377051B2 (enExample)
CN (1) CN1123561C (enExample)
AT (1) ATE234804T1 (enExample)
CA (1) CA2307337C (enExample)
DE (2) DE19745902A1 (enExample)
ES (1) ES2193582T3 (enExample)
MY (1) MY117146A (enExample)
NO (1) NO325592B1 (enExample)
SA (1) SA98190861B1 (enExample)
WO (1) WO1999020592A1 (enExample)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9807142D0 (en) 1998-04-02 1998-06-03 Bp Chem Int Ltd Catalyst and process utilising the catalyst
GB9819221D0 (en) 1998-09-04 1998-10-28 Bp Chem Int Ltd Process for the production of acetic acid
US6114278A (en) * 1998-11-16 2000-09-05 Saudi Basic Industries Corporation Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same
GB9907704D0 (en) * 1999-04-01 1999-05-26 Bp Chem Int Ltd Catalyst and process utilising the catalyst
US6143921A (en) 1999-05-14 2000-11-07 Saudi Basic Industries Corporation Method for producing vinyl acetate monomer from ethane or ethylene oxidation
JP4486751B2 (ja) * 1999-06-25 2010-06-23 サウディ ベーシック インダストリーズ コーポレイション エチレンからの酢酸の一段気相製造用触媒システム
JP4809532B2 (ja) * 1999-11-15 2011-11-09 サウディ ベーシック インダストリーズ コーポレイション プロパンのアクリル酸への接触酸化用触媒、その製造法及び使用法
US6531631B1 (en) 2000-04-28 2003-03-11 Saudi Basic Industries Corporation Oxidation of ethane to acetic acid and ethylene using molybdenum and vanadium based catalysts
DE10024437A1 (de) 2000-05-19 2001-11-29 Aventis Res & Tech Gmbh & Co Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan
CA2411000C (en) 2000-05-19 2006-11-14 Sabine Zeyss Process for the production of vinyl acetate
CA2410999C (en) * 2000-05-19 2007-04-10 Sabine Zeyss Integrated process for the production of vinyl acetate
US6841699B2 (en) * 2001-04-25 2005-01-11 Rohm And Haas Company Recalcined catalyst
EP1266688A3 (en) * 2001-06-14 2003-07-09 Rohm And Haas Company Mixed metal oxide catalyst doped by vapor depositing a metal and mixed metal oxide catalyst prepared by depositing a plurality of films of different elements using physical vapor deposition
US20050020856A1 (en) * 2003-07-24 2005-01-27 The Regents Of The University Of Califorinia Process for production of acetyl anhydrides and optionally acetic acid from methane and carbon dioxide
WO2005092495A1 (en) 2004-03-29 2005-10-06 Showa Denko K.K. Palladium, tungsten and zirconium-based catalyst for production of oxygen-containing compound, production process of the catalyst, and production process of oxygen-containing compound using the catalyst
US7009074B2 (en) * 2004-07-28 2006-03-07 The Regents Of The University Of California Process for direct oxidation of methane to acetic acid
JP2009526052A (ja) * 2006-02-07 2009-07-16 セラニーズ・インターナショナル・コーポレーション 酢酸を製造するためのエタンをベースとするプロセスにおいてエタンからエチレンを分離するための化学反応の使用
CN101432254B (zh) * 2006-02-07 2012-12-19 塞拉尼斯国际公司 一种制备醋酸和醋酸乙烯酯的综合方法
US20080132723A1 (en) * 2006-12-04 2008-06-05 Celanese International Corporation Process for the production of ethylene, acetic acid and carbon monoxide from ethane
US7786006B2 (en) * 2007-02-26 2010-08-31 Tokyo Electron Limited Interconnect structures with a metal nitride diffusion barrier containing ruthenium and method of forming
KR20100017604A (ko) * 2007-05-04 2010-02-16 비피 코포레이션 노쓰 아메리카 인코포레이티드 방향족 화합물의 산화를 위한 방법 및 촉매
WO2008136857A1 (en) * 2007-05-04 2008-11-13 Bp Corporation North America Inc. Process for the production of non-aromatic carboxylic acids
JP5136017B2 (ja) * 2007-11-21 2013-02-06 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
DE102010001399A1 (de) 2010-01-29 2011-08-04 Wacker Chemie AG, 81737 Verfahren zur Herstellung von Carbonsäuren mit 1-3 Kohlenstoff-atomen aus nachwachsenden Rohstoffen
US20140275619A1 (en) 2013-03-15 2014-09-18 Celanese International Corporation Process for Producing Acetic Acid and/or Ethanol By Methane Oxidation
KR102368345B1 (ko) 2016-09-13 2022-03-02 아사히 가세이 가부시키가이샤 산화물 촉매의 제조 방법, 및 불포화 니트릴의 제조 방법
CN111644210B (zh) * 2020-06-22 2022-11-15 新疆兵团现代绿色氯碱化工工程研究中心(有限公司) 一种复合载体钌基催化剂在乙炔氢氯化反应中的应用
CN116408061A (zh) * 2021-12-31 2023-07-11 中国石油天然气股份有限公司 乙烷选择氧化制乙酸和乙烯的催化剂及其制备方法与应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0294845A1 (en) * 1987-06-12 1988-12-14 Union Carbide Corporation Acetic acid from ethane, ethylene and oxygen
EP0620205A1 (en) * 1993-04-06 1994-10-19 Showa Denko Kabushiki Kaisha Process for producing acetic acid

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4499301A (en) 1979-04-20 1985-02-12 National Distillers And Chemical Corporation Process for the preparation of unsaturated aldehydes and carboxylic acids
US5260250A (en) * 1989-07-05 1993-11-09 Bp Chemicals Limited Catalyst for the production of ethylene and acetic acid
DE19630832A1 (de) 1996-07-31 1998-02-05 Hoechst Ag Verfahren zur selektiven Herstellung von Essigsäure

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0294845A1 (en) * 1987-06-12 1988-12-14 Union Carbide Corporation Acetic acid from ethane, ethylene and oxygen
EP0620205A1 (en) * 1993-04-06 1994-10-19 Showa Denko Kabushiki Kaisha Process for producing acetic acid

Also Published As

Publication number Publication date
NO20001947L (no) 2000-05-29
ATE234804T1 (de) 2003-04-15
MY117146A (en) 2004-05-31
EP1025075B1 (de) 2003-03-19
ES2193582T3 (es) 2003-11-01
NO20001947D0 (no) 2000-04-13
SA98190861B1 (ar) 2006-10-11
DE59807577D1 (de) 2003-04-24
CA2307337A1 (en) 1999-04-29
CA2307337C (en) 2009-12-01
JP4377051B2 (ja) 2009-12-02
EP1025075A1 (en) 2000-08-09
JP2001520976A (ja) 2001-11-06
DE19745902A1 (de) 1999-04-22
CN1275971A (zh) 2000-12-06
WO1999020592A1 (de) 1999-04-29
US6399816B1 (en) 2002-06-04
NO325592B1 (no) 2008-06-23

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C06 Publication
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SE01 Entry into force of request for substantive examination
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C56 Change in the name or address of the patentee
CP01 Change in the name or title of a patent holder

Address after: German Sur F Bach

Patentee after: CELANESE SALES GERMANY GmbH

Address before: German Sur F Bach

Patentee before: Department of nutrition and food ingredient Novi Co.,Ltd.

TR01 Transfer of patent right

Effective date of registration: 20160415

Address after: German Sur F Bach

Patentee after: Department of nutrition and food ingredient Novi Co.,Ltd.

Address before: Frankfurt, Germany

Patentee before: CELANESE CHEMICALS EUROPE GmbH

C56 Change in the name or address of the patentee
CP02 Change in the address of a patent holder

Address after: German Sur F Bach (Taunus)

Patentee after: CELANESE SALES GERMANY GMBH

Address before: German Sur F Bach

Patentee before: CELANESE SALES GERMANY GMBH

CX01 Expiry of patent term

Granted publication date: 20031008

CX01 Expiry of patent term