CN112127182A - 一种涤纶面料的雕印印花工艺 - Google Patents
一种涤纶面料的雕印印花工艺 Download PDFInfo
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Abstract
本申请涉及面料印花的领域,公开了一种涤纶面料的雕印印花工艺,将涤纶坯布经过如下步骤进行:S1:染色;将坯布进行染色;S2:初次水洗;将经过S1处理后的坯布进行水洗;S3:烘干定型;将经过S2处理后的坯布进行烘干定型;S4:印花;将经过S3处理后的坯布进行印花,印花时所用的浆料的各化学组成以重量份计包括:氯化亚锡20‑40份、助溶剂4‑8份、淀粉糊100‑140份、还原染料20‑50份以及磺基琥珀酸二乙基己酯钠13‑18份;S5:蒸化;S6:二次水洗;S7:后整理;经过S7后得到印花完成的涤纶面料。浆料中添加了磺基琥珀酸二乙基己酯钠,能够增大还原染料与涤纶面料之间的附着力,从而增强了印在涤纶布料上花型的色牢度。
Description
技术领域
本申请涉及面料印花的领域,尤其是涉及一种涤纶面料的雕印印花工艺。
背景技术
涤纶面料是日常生活中用的非常多的一种化纤服装面料。其最大的优点是抗皱性和保形性很好,因此,适合做外套服装、各类箱包和帐篷等户外用品。
旗帜的材质通常采用涤纶面料中的春亚纺布料,该布料具有涤纶面料的特点,面料轻薄,遇风可飘,用于旗帜的制作材料最合适不过。春亚纺布料制作的国旗颜色鲜艳,具有防水、防晒、不变形、耐高温、遇水即干的特性。特别是当旗帜悬挂在旗杆上的时候,突然遭受雨水天气,旗帜被淋湿后遇到风会自然晾干。商家根据客户实际情况的需求,会在旗帜上印有一些花型、标志、图形等。
现有的印花方式则是采用直印的,但是采用直接印花,难有满意的渗透性,在被印织物的反面往往留有白色和不均匀的色彩,而且正面拉开后也会显露出白色。为了解决这一问题,涤纶织物采用雕印印花可以完全解决上述缺点。但是,旗帜通常使用在室外,亟需提供一种色牢度高的涤纶面料的雕印印花工艺。
发明内容
为了解决涤纶面料上雕印色牢度低问题,本申请提供一种涤纶面料的雕印印花工艺。
本申请提供的一种涤纶面料的雕印印花工艺,采用如下的技术方案:
一种涤纶面料的雕印印花工艺,将涤纶坯布经过如下步骤进行:
S1:染色;将坯布进行染色;
S2:初次水洗;将经过S1处理后的坯布进行水洗;
S3:烘干定型;将经过S2处理后的坯布进行烘干定型;
S4:印花;将经过S3处理后的坯布进行印花,印花时所用的浆料的各化学组成以重量份计包括:氯化亚锡20-40份、助溶剂4-8份、淀粉糊100-140份、还原染料20-50份以及磺基琥珀酸二乙基己酯钠13-18份;
S5:蒸化;
S6:二次水洗;
S7:后整理;
经过S7后得到印花完成的涤纶面料。
通过采用上述技术方案,进行雕印时,选择作为氯化亚锡作为雕印的还原剂,氯化亚锡属于酸性还原剂。涤纶的学名为聚酯纤维,在碱性环境易分解。因此本申请中选用酸性的还原剂,能够降低对于涤纶纤维损伤。淀粉糊的抱水性好,渗透性优良,同时能够保证涤纶面料获得清晰的轮廓。通过选择还原染料,同时由于在浆料中添加了磺基琥珀酸二乙基己酯钠,从而增大还原染料与涤纶面料之间的附着力,从而增强了印在涤纶布料上花型的色牢度。同时,由于还原染料与淀粉糊组合,能够使得浆料较为稳定。
作为本申请的进一步改进,所述步骤S4印花步骤中的助溶剂为尿素。
通过采用上述技术方案,通过将助溶剂选择为尿素,一方面能够起到吸湿的效果,另一方面,能够使得浆料中各个物质之间的相容性更好,起到助溶剂的作用。同时,尿素能够加速蒸化时纤维对染料的吸附和扩散作用,从而进一步的提高坯布上雕印花型的色牢度。
作为本申请的进一步改进,S4中印花时所用的浆料中还包括乙醇酸钠2-5份。
通过采用上述技术方案,乙醇酸钠作为释酸剂,为浆料提供弱酸性环境,防止不耐碱的染料被破坏,同时对染料具有助溶性,能加速还原染料向纤维内部扩散。
作为本申请的进一步改进,S4中印花时所用的浆料中还包括海藻酸钠30-53份。
通过采用上述技术方案,海藻酸钠印花时给色量高,渗透性良好,印制精细花纹轮廓清晰,块面得色均匀,并且雕印后海藻酸钠易于洗涤,印花织物手感柔软。
作为本申请的进一步改进,S4中印花时所用的浆料中还包括氯酸钠7-15份。
通过采用上述技术方案,通过添加氯化钠,能够防止含有硝基或偶氮基的还原染料在蒸化时被还原而变色。
作为本申请的进一步改进,S4中印花时所用的浆料中还包括乙醇酸钠2-5份、海藻酸钠30-53份以及氯酸钠7-15份。
作为本申请的进一步改进,所述S5蒸化,将所述S4印花后的坯布输送至所述蒸化机内进行蒸化,所述蒸化机的温度调节为170-200℃,车速调节为8-12m/min,蒸化时间为6-10min。
通过采用上述技术方案,涤纶纤维在170-200℃的环境下,分子链段运动加剧,有利于还原染料在纤维内扩散,从而使得还原染料与涤纶纤维之间的分子间的作用力增强,最终使得雕印在涤纶面料上的花型固定在纤维上。
作为本申请的进一步改进,所述S1染色中染料的各化学组成以重量份计包括分散染料15-25份、分散剂13-26份、匀染剂50-70份、苯酚磺酸铝3-8份、氨基乙醇硫酸酯1-5份、醋酸10-15份以及水250-300份。
通过采用上述技术方案,分散染料分子结构简单,相对分子质量小,所以容易扩散进入至涤纶纤维分子之间。通过添加苯酚磺酸铝和氨基乙醇硫酸酯,能够与后续印花的浆料中的磺基琥珀酸二乙基己酯钠互相结合,从而使得雕印在染色完毕后花型与涤纶布料之间的附着力增强,最终增强了花型的色牢度。
作为本申请的进一步改进,所述S1染色,先按重量份计无先后顺序的将分散染料、分散剂、匀染剂、苯酚磺酸铝、氨基乙醇硫酸酯、醋酸以及水添加至染液桶内搅拌20min以配置成染液,浴比1:20,持续搅拌50min,然后将染液输送至染色机内,接着将染色机内染液的温度升温至50℃,保温浸泡10min;然后再将染色液温度升至90℃,保温浸泡5min;然后再将染液温度升至115℃,保温浸泡30min;最后将染色机内染液的温度降至70℃,降温时间为15min,染色结束。
通过采用上述技术方案,现将染液的温度升高至50℃,然后再升高至90℃,最后将温度升高至115℃。一方面能够使得分散染料上染至涤纶坯布上,使得涤纶坯布具有合格的上染率。另一方面,能够防止分散染料与涤纶纤维完全结合,方便后续进行雕印工作。
综上所述,本申请包括以下至少一种有益技术效果:
1、由于在浆料中添加了磺基琥珀酸二乙基己酯钠,从而增大还原染料与涤纶面料之间的附着力,从而增强了印在涤纶布料上花型的色牢度;
2、通过将助溶剂选择为尿素,一方面能够起到吸湿的效果,另一方面,能够使得浆料中各个物质之间的相容性更好,起到助溶剂的作用。同时,尿素能够加速蒸化时纤维对染料的吸附和扩散作用,从而进一步的提高坯布上雕印花型的色牢度;
3、乙醇酸钠作为释酸剂,为浆料提供弱酸性环境,防止不耐碱的染料被破坏,同时对染料具有助溶性,能加速还原染料向纤维内部扩散。
附图说明
图1为本申请一种涤纶面料的雕印印花工艺的工艺流程图。
具体实施方式
以下结合附图以及实施例,对本申请作进一步详细描述。
实施例1:
参照图1,本实施例公开了一种涤纶面料的雕印印花工艺,将涤纶坯布经过如下步骤进行:
S1:染色。先将坯布输送至平幅水洗机内进行水洗,水洗持续10min。然后按重量份计无先后顺序的将分散染料20份、分散剂20份、匀染剂60份、苯酚磺酸铝5份、氨基乙醇硫酸酯3份、醋酸12份以及水275份添加至染液桶内搅拌20min,浴比1:20,持续搅拌50min。然后将染液输送至染色机内,接着将染色机内染液的温度升温至50℃,保温浸泡10min。然后再将染色液温度升至90℃,保温浸泡5min。然后再将染色液温度升至115℃,保温浸泡30min。最后将染色机内染液的温度降至70℃,降温时间为15min,染色结束。
S2:初次水洗。将经过S1处理后的坯布输送至绳状水洗机内进行水洗15min。
S3:烘干定型。将经过S2处理后的坯布输送至定型机内,进行烘干定型。
S4:印花。先将经过S3处理后的坯布放入已经制网完成的平网印花机内,再将平网印花机的车速调节为50m/min,烘干温度调节为135℃,然后将配置好的浆料放置浆料添加处,启动平网印花机开始印花。
浆料的配置过程为:先将还原染料用冷水调匀,然后加入淀粉糊搅拌均匀,再加入助溶剂和磺基琥珀酸二乙基己酯钠搅拌均匀,最后再加氯化亚锡搅拌均匀即可,助溶剂选用尿素。
浆料各物质的组成配比以重量份计为:还原染料35份、助溶剂6份、淀粉糊120份、氯化亚锡30份以及磺基琥珀酸二乙基己酯钠15份。使用的平网印花机为日本东伸生产、型号为RSX-1。
S5:蒸化。先将蒸化机调试正常,然后将经过S4处理后的坯布输送至蒸化机内,然后将蒸化机内的温度调节至185℃,车速调节为10m/min,持续蒸化时间为8min。使用的蒸化机为武汉中大生产、型号为YXLM1818。
S6:二次水洗。将经过S5处理后的坯布输送至冲洗池内,再使用含有固色剂的固色液持续浸泡20min,然后使用清水持续冲洗10min。固色剂为三乙烯四胺,用量为1.5g/L。
S7:后整理。将经过S6处理后的坯布输送只定型机内进行定型工作。定型工作时,定型机内的温度调节至190℃,定型8min;定型结束后,将坯布冷却至室温。
经过S7后得到印花完成的涤纶面料。
实施例2:
一种涤纶面料的雕印印花工艺,将涤纶坯布经过如下步骤进行:
S1:染色。先将坯布输送至平幅水洗机内进行水洗,水洗持续10min。然后按重量份计无先后顺序的将分散染料20份、分散剂20份、匀染剂60份、苯酚磺酸铝5份、氨基乙醇硫酸酯3份、醋酸12份以及水275份添加至染液桶内搅拌20min,浴比1:20,持续搅拌50min。然后将染液输送至染色机内,接着将染色机内染液的温度升温至50℃,保温浸泡10min。然后再将染色液温度升至90℃,保温浸泡5min。然后再将染色液温度升至115℃,保温浸泡30min。最后将染色机内染液的温度降至70℃,降温时间为15min,染色结束。分散剂为分散剂MF;匀染剂为烷基苯酚聚氧乙烯醚。
S2:初次水洗。将经过S1处理后的坯布输送至绳状水洗机内进行水洗15min。
S3:烘干定型。将经过S2处理后的坯布输送至定型机内,进行烘干定型。
S4:印花。先将经过S3处理后的坯布放入已经制网完成的平网印花机内,再将平网印花机的车速调节为50m/min,烘干温度调节为135℃,然后将配置好的浆料放置浆料添加处,启动平网印花机开始印花。
浆料的配置过程为:先将还原染料用冷水调匀,然后加入淀粉糊和乙醇酸钠搅拌均匀,再加入助溶剂和磺基琥珀酸二乙基己酯钠搅拌均匀,最后再加氯化亚锡搅拌均匀即可,助溶剂选用尿素。
浆料各物质的组成配比以重量份计为:还原染料35份、助溶剂6份、淀粉糊120份、乙醇酸钠3份、氯化亚锡30份以及磺基琥珀酸二乙基己酯钠15份。使用的平网印花机为日本东伸生产、型号为RSX-1。
S5:蒸化。先将蒸化机调试正常,然后将经过S4处理后的坯布输送至蒸化机内,然后将蒸化机内的温度调节至185℃,车速调节为10m/min,持续蒸化时间为8min。使用的蒸化机为武汉中大生产、型号为YXLM1818。
S6:二次水洗。将经过S5处理后的坯布输送至冲洗池内,再使用含有固色剂的固色液持续浸泡20min,然后使用清水持续冲洗10min。固色剂为三乙烯四胺,用量为1.5g/L。
S7:后整理。将经过S6处理后的坯布输送只定型机内进行定型工作。定型工作时,定型机内的温度调节至190℃,定型8min;定型结束后,将坯布冷却至室温。
经过S7后得到印花完成的涤纶面料。
实施例3:
与实施例1的区别在于,S4:印花。先将经过S3处理后的坯布放入已经制网完成的平网印花机内,再将平网印花机的车速调节为50m/min,烘干温度调节为135℃,然后将配置好的浆料放置浆料添加处,启动平网印花机开始印花。
浆料的配置过程为:先将还原染料用冷水调匀,然后加入淀粉糊和海藻酸钠搅拌均匀,再加入助溶剂和磺基琥珀酸二乙基己酯钠搅拌均匀,最后再加氯化亚锡搅拌均匀即可,助溶剂选用尿素。
浆料各物质的组成配比以重量份计为:还原染料35份、助溶剂6份、淀粉糊120份、海藻酸钠42份、氯化亚锡30份以及磺基琥珀酸二乙基己酯钠15份。使用的平网印花机为日本东伸生产、型号为RSX-1。
实施例4:
与实施例1的区别在于,S4:印花。先将经过S3处理后的坯布放入已经制网完成的平网印花机内,再将平网印花机的车速调节为50m/min,烘干温度调节为135℃,然后将配置好的浆料放置浆料添加处,启动平网印花机开始印花。
浆料的配置过程为:先将还原染料用冷水调匀,然后加入淀粉糊和氯酸钠搅拌均匀,再加入助溶剂和磺基琥珀酸二乙基己酯钠搅拌均匀,最后再加氯化亚锡搅拌均匀即可,助溶剂选用尿素。
浆料各物质的组成配比以重量份计为:还原染料35份、助溶剂6份、淀粉糊120份、氯酸钠11份、氯化亚锡30份以及磺基琥珀酸二乙基己酯钠15份。使用的平网印花机为日本东伸生产、型号为RSX-1。
实施例5:
与实施例1的区别在于,S4:印花。先将经过S3处理后的坯布放入已经制网完成的平网印花机内,再将平网印花机的车速调节为50m/min,烘干温度调节为135℃,然后将配置好的浆料放置浆料添加处,启动平网印花机开始印花。
浆料的配置过程为:先将还原染料用冷水调匀,然后加入乙醇酸钠、海藻酸钠、淀粉糊和氯酸钠搅拌均匀,再加入助溶剂和磺基琥珀酸二乙基己酯钠搅拌均匀,最后再加氯化亚锡搅拌均匀即可,助溶剂选用尿素。
浆料各物质的组成配比以重量份计为:还原染料35份、助溶剂6份、淀粉糊120份、乙醇酸钠3份、海藻酸钠42份、氯酸钠11份、氯化亚锡30份以及磺基琥珀酸二乙基己酯钠15份。使用的平网印花机为日本东伸生产、型号为RSX-1。
实施例6-9与实施例5的区别在于,S1染色中染料的各化学组成以重量份计如表1所示:单位:份;S4印花中浆料各物质的组成配比以重量份计如表1所示:单位:份
表1
实施例6-9与实施例5的区别在于,S5蒸化中蒸化的温度调节至如表2所示,单位:℃;车速调节至如表2所示:单位:m/min;蒸化时间如表2所示,单位:min
表2
实施例 | 实施例6 | 实施例7 | 实施例8 | 实施例9 |
温度 | 170 | 200 | 530 | 580 |
车速 | 8 | 12 | 9 | 11 |
时间 | 6 | 10 | 7 | 9 |
对比例1:与实施例1的区别在于,S4印花中的浆料中无磺基琥珀酸二乙基己酯钠。
对比例2:与实施例1的区别在于,S4印花中的浆料中将还原染料替换为分散染料。
性能检测:
采用实施例1-9中得到的涤纶面料作为试验样品1-9,采用对比例1-2中获得的涤纶面料作为对照样品1-2。
检测方法:采用下述的标准测试标准检测试验样品1-9和对照样品1-2的摩擦牢度和耐洗牢度,并且将检测数据记录至表3中。色牢度测试的方法为:耐洗牢度GB/T3921.1-1997;耐摩擦牢度(干摩、湿摩)GB3920-83;耐汗渍牢度GB/T3922-1995。
表3
试验样品1-9和对比样品1-2的检测结果得知,采用实施例1-9记载的技术方案得到的涤纶布料的耐洗牢度、耐摩擦牢度、耐汗渍牢度以及上染率逐级递增,因此,采用采用实施例5-9记载的技术方案能够得到雕印色牢度高的涤纶面料。
以上均为本申请的较佳实施例,并非依此限制本申请的保护范围,故:凡依本申请的结构、形状、原理所做的等效变化,均应涵盖于本申请的保护范围之内。
Claims (9)
1.一种涤纶面料的雕印印花工艺,其特征在于:将涤纶坯布经过如下步骤进行:
S1:染色;将坯布进行染色;
S2:初次水洗;将经过S1处理后的坯布进行水洗;
S3:烘干定型;将经过S2处理后的坯布进行烘干定型;
S4:印花;将经过S3处理后的坯布进行印花,印花时所用的浆料的各化学组成以重量份计包括:氯化亚锡20-40份、助溶剂4-8份、淀粉糊100-140份、还原染料20-50份以及磺基琥珀酸二乙基己酯钠13-18份;
S5:蒸化;
S6:二次水洗;
S7:后整理;
经过S7后得到印花完成的涤纶面料。
2.根据权利要求1所述的一种涤纶面料的雕印印花工艺,其特征在于:所述步骤S4印花步骤中的助溶剂为尿素。
3.根据权利要求1所述的一种涤纶面料的雕印印花工艺,其特征在于:S4中印花时所用的浆料中还包括乙醇酸钠2-5份。
4.根据权利要求1所述的一种涤纶面料的雕印印花工艺,其特征在于:S4中印花时所用的浆料中还包括海藻酸钠30-53份。
5.根据权利要求1所述的一种涤纶面料的雕印印花工艺,其特征在于:S4中印花时所用的浆料中还包括氯酸钠7-15份。
6.根据权利要求1所述的一种涤纶面料的雕印印花工艺,其特征在于:S4中印花时所用的浆料中还包括乙醇酸钠2-5份、海藻酸钠30-53份以及氯酸钠7-15份。
7.根据权利要求1所述的一种涤纶面料的雕印印花工艺,其特征在于:所述S5蒸化,将所述S4印花后的坯布输送至所述蒸化机内进行蒸化,所述蒸化机的温度调节为170-200℃,车速调节为8-12m/min,蒸化时间为6-10min。
8.根据权利要求1所述的一种涤纶面料的雕印印花工艺,其特征在于:所述S1染色中染料的各化学组成以重量份计包括分散染料15-25份、分散剂13-26份、匀染剂50-70份、苯酚磺酸铝3-8份、氨基乙醇硫酸酯1-5份、醋酸10-15份以及水250-300份。
9.根据权利要求8所述的一种涤纶面料的雕印印花工艺,其特征在于:所述S1染色,先按重量份计无先后顺序的将分散染料、分散剂、匀染剂、苯酚磺酸铝、氨基乙醇硫酸酯、醋酸以及水添加至染液桶内搅拌20min以配置成染液,浴比1:20,持续搅拌50min,然后将染液输送至染色机内,接着将染色机内染液的温度升温至50℃,保温浸泡10min;然后再将染色液温度升至90℃,保温浸泡5min;然后再将染液温度升至115℃,保温浸泡30min;最后将染色机内染液的温度降至70℃,降温时间为15min,染色结束。
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113089340A (zh) * | 2021-04-08 | 2021-07-09 | 绍兴盛鑫印染有限公司 | 一种涤纶面料的印花工艺 |
CN114411432A (zh) * | 2021-12-31 | 2022-04-29 | 绍兴柯桥育达纺染有限公司 | 一种针织服装面料的染印一体工艺 |
CN114559731A (zh) * | 2022-02-25 | 2022-05-31 | 诸暨市华都德胜印花有限公司 | 一种印花工艺 |
CN115584608A (zh) * | 2022-10-31 | 2023-01-10 | 诸暨市欣邦纺织有限公司 | 一种无水雕印服装面料生产工艺及面料 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101191305A (zh) * | 2006-12-01 | 2008-06-04 | 上海和晓印花有限公司 | 聚丙烯睛针织物的雕印印花工艺 |
CN102418295A (zh) * | 2010-09-28 | 2012-04-18 | 大丰市海隆化工有限公司 | 牛仔布拔染印花色浆及其制备方法 |
CN104532628A (zh) * | 2015-01-06 | 2015-04-22 | 江苏樱竹恋纺织科技发展有限公司 | 一种兼具雕印和烂花风格的经编绒类面料及其加工方法 |
CN108330607A (zh) * | 2017-01-20 | 2018-07-27 | 江苏双山集团股份有限公司 | 一种涤纶经编绒拔染印花织物的生产方法 |
CN110541315A (zh) * | 2019-09-11 | 2019-12-06 | 广州市盛勤实业有限公司 | 涤纶织物的拔染助剂、印花浆和拔染印花方法 |
-
2020
- 2020-09-26 CN CN202011027919.1A patent/CN112127182A/zh active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101191305A (zh) * | 2006-12-01 | 2008-06-04 | 上海和晓印花有限公司 | 聚丙烯睛针织物的雕印印花工艺 |
CN102418295A (zh) * | 2010-09-28 | 2012-04-18 | 大丰市海隆化工有限公司 | 牛仔布拔染印花色浆及其制备方法 |
CN104532628A (zh) * | 2015-01-06 | 2015-04-22 | 江苏樱竹恋纺织科技发展有限公司 | 一种兼具雕印和烂花风格的经编绒类面料及其加工方法 |
CN108330607A (zh) * | 2017-01-20 | 2018-07-27 | 江苏双山集团股份有限公司 | 一种涤纶经编绒拔染印花织物的生产方法 |
CN110541315A (zh) * | 2019-09-11 | 2019-12-06 | 广州市盛勤实业有限公司 | 涤纶织物的拔染助剂、印花浆和拔染印花方法 |
Non-Patent Citations (3)
Title |
---|
朱传方: "《有机精细化工选论》", 31 December 1991, 华中师范大学出版社 * |
莫寅: "涤纶绸拔染印花工艺的选择", 《丝绸》 * |
赵涛: "《染整工艺与原理 下册》", 31 January 2020, 中国纺织出版社 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113089340A (zh) * | 2021-04-08 | 2021-07-09 | 绍兴盛鑫印染有限公司 | 一种涤纶面料的印花工艺 |
CN113089340B (zh) * | 2021-04-08 | 2022-04-12 | 绍兴盛鑫印染有限公司 | 一种涤纶面料的印花工艺 |
CN114411432A (zh) * | 2021-12-31 | 2022-04-29 | 绍兴柯桥育达纺染有限公司 | 一种针织服装面料的染印一体工艺 |
CN114559731A (zh) * | 2022-02-25 | 2022-05-31 | 诸暨市华都德胜印花有限公司 | 一种印花工艺 |
CN115584608A (zh) * | 2022-10-31 | 2023-01-10 | 诸暨市欣邦纺织有限公司 | 一种无水雕印服装面料生产工艺及面料 |
CN115584608B (zh) * | 2022-10-31 | 2023-08-04 | 诸暨市欣邦纺织有限公司 | 一种无水雕印服装面料生产工艺及面料 |
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