CN110072907B - 使用取代的巴比妥酸实现环氧稳定化 - Google Patents

使用取代的巴比妥酸实现环氧稳定化 Download PDF

Info

Publication number
CN110072907B
CN110072907B CN201780077373.0A CN201780077373A CN110072907B CN 110072907 B CN110072907 B CN 110072907B CN 201780077373 A CN201780077373 A CN 201780077373A CN 110072907 B CN110072907 B CN 110072907B
Authority
CN
China
Prior art keywords
epoxy
resin composition
curable
thiol
thiol resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201780077373.0A
Other languages
English (en)
Chinese (zh)
Other versions
CN110072907A (zh
Inventor
迈克尔·A·克罗普
马修·J·克里格
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN110072907A publication Critical patent/CN110072907A/zh
Application granted granted Critical
Publication of CN110072907B publication Critical patent/CN110072907B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • C08G59/245—Di-epoxy compounds carbocyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/022—Polycondensates containing more than one epoxy group per molecule characterised by the preparation process or apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/66—Mercaptans
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3462—Six-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201780077373.0A 2016-12-13 2017-12-05 使用取代的巴比妥酸实现环氧稳定化 Active CN110072907B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662433325P 2016-12-13 2016-12-13
US62/433,325 2016-12-13
PCT/IB2017/057663 WO2018109617A1 (en) 2016-12-13 2017-12-05 Epoxy stabilization using substituted barbituric acids

Publications (2)

Publication Number Publication Date
CN110072907A CN110072907A (zh) 2019-07-30
CN110072907B true CN110072907B (zh) 2021-12-14

Family

ID=60782289

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780077373.0A Active CN110072907B (zh) 2016-12-13 2017-12-05 使用取代的巴比妥酸实现环氧稳定化

Country Status (6)

Country Link
US (1) US11584823B2 (enExample)
EP (2) EP3555170B1 (enExample)
JP (1) JP7019715B2 (enExample)
KR (1) KR20190093583A (enExample)
CN (1) CN110072907B (enExample)
WO (1) WO2018109617A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11059967B2 (en) 2016-12-13 2021-07-13 3M Innovative Properties Company Epoxy stabilization using acid-coated nitrogen containing catalysts, particles, and methods
US11053348B2 (en) 2017-02-15 2021-07-06 3M Innovative Properties Company Epoxy stabilization using metal nanoparticles and nitrogen-containing catalysts, and methods
CN111093842B (zh) * 2017-09-15 2023-03-10 3M创新有限公司 包含具有可固化环氧/硫醇树脂组合物的(甲基)丙烯酸酯基质的粘合剂膜、带以及方法
EP3856818A4 (en) 2018-09-25 2022-07-13 3M Innovative Properties Company POLYMERIC MATERIAL WITH AN URETDIONE-CONTAINING MATERIAL AND A THERMALLY ACTIVABLE AMINE, TWO-PART COMPOSITIONS AND PROCESSES
CN117813335A (zh) * 2021-07-30 2024-04-02 3M创新有限公司 可固化单部分双阶段硫醇-烯-环氧液体粘合剂和方法
CN116239720B (zh) * 2023-02-06 2024-05-31 四川大学 具有双重碱基面识别Hg2+的温敏性线性高分子材料及其制备方法
US11911748B1 (en) 2023-03-01 2024-02-27 King Faisal University Modified homogeneous dinuclear transition metal-organic frameworks
US11773124B1 (en) 2023-03-08 2023-10-03 King Faisal University Homoliptic dinuclear complexes of palladium (II) with diaroyldihydrazone succinate ligand as highly effective catalyst for cross coupling reactions
WO2025200154A1 (en) 2024-03-29 2025-10-02 3M Innovative Properties Company Two-part epoxy composition comprising thiol curative, and catalyst

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3597410A (en) * 1968-04-29 1971-08-03 Henkel & Cie Gmbh Process for retarding the hardening of epoxide resins using a barbituric retarder and retarding compositions
US5439746A (en) * 1991-09-09 1995-08-08 Kabushiki Kaisha Toshiba Epoxy resin-basin composite material
CN1288481A (zh) * 1998-01-16 2001-03-21 洛克泰特(R&D)有限公司 可固化的环氧基组合物
US6359039B1 (en) * 1998-04-28 2002-03-19 Industrial Technology Research Institute Mixing barbituric acid-modified BMI with MEK solution of epoxy resin and elastomer
TW538318B (en) * 2000-11-03 2003-06-21 Ind Tech Res Inst Photo-sensitive composition
CN101210077A (zh) * 2006-12-28 2008-07-02 财团法人工业技术研究院 无卤耐高温组合物
CN103189412A (zh) * 2010-11-05 2013-07-03 汉高爱尔兰有限公司 具有改善的稳定性的环氧-硫醇组合物
CN103228696A (zh) * 2010-11-19 2013-07-31 汉高公司 单组分环氧树脂组合物
CN105440658A (zh) * 2014-09-23 2016-03-30 费希尔厂有限责任两合公司 具有细分填料的固定体系
CN106062030A (zh) * 2014-03-17 2016-10-26 纳美仕有限公司 树脂组合物

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1593791A1 (de) 1966-05-04 1970-10-01 Ciba Geigy Latente Haerter und stabile hitzegehaertete Epoxydmassen
US3496250A (en) 1967-02-21 1970-02-17 Borg Warner Blends of epoxy resins and acrylonitrile butadiene-styrene graft copolymers
JPS5657820A (en) 1979-10-18 1981-05-20 Semedain Kk Curable epoxy resin composition
JPS6072917A (ja) 1983-09-30 1985-04-25 Ajinomoto Co Inc エポキシ樹脂用潜在性硬化剤
JPS61159417A (ja) 1984-12-29 1986-07-19 Semedain Kk 硬化性エポキシ樹脂組成物
EP0193068A1 (en) 1985-02-18 1986-09-03 Asahi Kasei Kogyo Kabushiki Kaisha One liquid type epoxy resin composition
EP0257640B1 (en) * 1986-08-29 1994-03-16 Nippon Zeon Co., Ltd. Vulcanizable elastomer composition
JPH0794588B2 (ja) * 1987-03-07 1995-10-11 日本ゼオン株式会社 アクリレ−ト系エラストマ−加硫組成物
IE891601L (en) 1989-05-18 1990-11-18 Loctite Ireland Ltd Latent hardeners for epoxy resin compositions
EP0594133B1 (en) 1992-10-22 1998-05-06 Ajinomoto Co., Inc. Polythiol epoxy resin composition with extended working life
US5464910A (en) 1993-12-22 1995-11-07 Shikoku Chemicals Corporation Epoxy resin adduct combined with a borate ester and phenolic compound
US6653371B1 (en) 1998-01-16 2003-11-25 Barry E. Burns One-part curable composition of polyepoxide, polythiol, latent hardener and solid organic acid
JP3882374B2 (ja) 1999-02-12 2007-02-14 味の素株式会社 導電性樹脂組成物
CA2413180A1 (en) 2000-05-29 2002-11-26 Ajinomoto Co., Inc. A conductive resin composition
US6872762B2 (en) 2000-07-13 2005-03-29 Loctite (R&D) Limited Epoxy resin composition with solid organic acid
CN1934158B (zh) * 2004-01-22 2010-06-09 味之素株式会社 单组分环氧树脂组合物
WO2006083344A2 (en) * 2005-02-01 2006-08-10 Henkel Corporation Liquid stable thiol-acrylate/vinyl ether compositions
CN102227457B (zh) 2008-11-07 2012-10-31 横滨橡胶株式会社 1液型热固化性环氧树脂组合物
EP2412361A1 (en) 2010-07-29 2012-02-01 3M Innovative Properties Company Kit of parts, method of producing and use thereof
WO2012093510A1 (ja) 2011-01-05 2012-07-12 ナミックス株式会社 樹脂組成物
JP6715853B2 (ja) 2015-02-13 2020-07-01 スリーエム イノベイティブ プロパティズ カンパニー 耐寒性シーラント及びその構成成分
CN111093842B (zh) * 2017-09-15 2023-03-10 3M创新有限公司 包含具有可固化环氧/硫醇树脂组合物的(甲基)丙烯酸酯基质的粘合剂膜、带以及方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3597410A (en) * 1968-04-29 1971-08-03 Henkel & Cie Gmbh Process for retarding the hardening of epoxide resins using a barbituric retarder and retarding compositions
US5439746A (en) * 1991-09-09 1995-08-08 Kabushiki Kaisha Toshiba Epoxy resin-basin composite material
CN1288481A (zh) * 1998-01-16 2001-03-21 洛克泰特(R&D)有限公司 可固化的环氧基组合物
US6359039B1 (en) * 1998-04-28 2002-03-19 Industrial Technology Research Institute Mixing barbituric acid-modified BMI with MEK solution of epoxy resin and elastomer
TW538318B (en) * 2000-11-03 2003-06-21 Ind Tech Res Inst Photo-sensitive composition
CN101210077A (zh) * 2006-12-28 2008-07-02 财团法人工业技术研究院 无卤耐高温组合物
CN103189412A (zh) * 2010-11-05 2013-07-03 汉高爱尔兰有限公司 具有改善的稳定性的环氧-硫醇组合物
CN103228696A (zh) * 2010-11-19 2013-07-31 汉高公司 单组分环氧树脂组合物
CN106062030A (zh) * 2014-03-17 2016-10-26 纳美仕有限公司 树脂组合物
CN105440658A (zh) * 2014-09-23 2016-03-30 费希尔厂有限责任两合公司 具有细分填料的固定体系

Also Published As

Publication number Publication date
US11584823B2 (en) 2023-02-21
US20210403634A1 (en) 2021-12-30
JP2020503426A (ja) 2020-01-30
WO2018109617A1 (en) 2018-06-21
EP3822298A1 (en) 2021-05-19
JP7019715B2 (ja) 2022-02-15
EP3555170B1 (en) 2021-05-05
KR20190093583A (ko) 2019-08-09
EP3555170A1 (en) 2019-10-23
CN110072907A (zh) 2019-07-30

Similar Documents

Publication Publication Date Title
CN110072907B (zh) 使用取代的巴比妥酸实现环氧稳定化
KR102585184B1 (ko) 경화성 에폭시/티올 수지 조성물을 포함하는 (메트)아크릴레이트 매트릭스를 포함하는 접착제 필름, 테이프 및 방법
CN101910238B (zh) 用于复合材料应用的高Tg环氧体系
WO2020065466A1 (en) Polymeric material including a uretdione-containing material and a thermally activatable amine, two-part compositions, and methods
JP2013108011A (ja) エポキシ樹脂溶液、エポキシ樹脂組成物、硬化物及び接着剤
JP3253919B2 (ja) 接着剤組成物
JP2006022146A (ja) 硬化性樹脂組成物
CN110392709B (zh) 使用金属纳米粒子和含氮催化剂的环氧树脂稳定以及方法
KR102589546B1 (ko) 산 무수물기반 에폭시 화합물, 이를 포함하는 에폭시 수지 조성물 및 이로부터 제조된 경화물
JP7202136B2 (ja) Ｎ－アルキル置換アミノピリジン・フタル酸塩及びそれを含むエポキシ樹脂組成物
EP4377373B1 (en) Curable, one-part, dual-stage thiol-ene-epoxy liquid adhesives and methods
WO2016093253A1 (ja) 熱硬化性樹脂組成物
WO2025176980A1 (en) Adhesive formulation
WO2024149555A1 (en) One component liquid epoxy resin composition
WO2025249317A1 (ja) 硬化剤、硬化性組成物、硬化物及び硬化物の製造方法
CN118834371A (zh) 一种高Tg值可降解的热固性复合材料及其制备的可降解井下封堵工具
JP2006241268A (ja) 熱硬化性樹脂組成物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant