CN109629073A - 一种利用富勒烯制备抗菌型纤维布料的方法 - Google Patents
一种利用富勒烯制备抗菌型纤维布料的方法 Download PDFInfo
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- CN109629073A CN109629073A CN201811494565.4A CN201811494565A CN109629073A CN 109629073 A CN109629073 A CN 109629073A CN 201811494565 A CN201811494565 A CN 201811494565A CN 109629073 A CN109629073 A CN 109629073A
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- fullerene
- antibacterial
- fiber
- cloth
- polyacrylonitrile
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- 239000000835 fiber Substances 0.000 title claims abstract description 187
- 239000004744 fabric Substances 0.000 title claims abstract description 74
- 229910003472 fullerene Inorganic materials 0.000 title claims abstract description 54
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title claims abstract description 45
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 23
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 102
- 229920002239 polyacrylonitrile Polymers 0.000 claims abstract description 94
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 28
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 26
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 26
- 241001330002 Bambuseae Species 0.000 claims abstract description 26
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 26
- 239000011425 bamboo Substances 0.000 claims abstract description 26
- 229920000728 polyester Polymers 0.000 claims abstract description 26
- 238000012545 processing Methods 0.000 claims abstract description 25
- 238000007670 refining Methods 0.000 claims abstract description 24
- 238000010521 absorption reaction Methods 0.000 claims abstract description 19
- 238000005406 washing Methods 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 12
- 229920000742 Cotton Polymers 0.000 claims abstract description 8
- 238000007664 blowing Methods 0.000 claims abstract description 8
- 238000009960 carding Methods 0.000 claims abstract description 8
- 239000002759 woven fabric Substances 0.000 claims abstract description 8
- 238000009987 spinning Methods 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 238000002360 preparation method Methods 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 17
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
- 239000012530 fluid Substances 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 10
- 150000001413 amino acids Chemical class 0.000 claims description 9
- 239000004902 Softening Agent Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- WNYFTWLTSLCQLO-UHFFFAOYSA-N [As].N1=CC=CC=C1 Chemical compound [As].N1=CC=CC=C1 WNYFTWLTSLCQLO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052908 analcime Inorganic materials 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000001103 potassium chloride Substances 0.000 claims description 7
- 235000011164 potassium chloride Nutrition 0.000 claims description 7
- 235000017550 sodium carbonate Nutrition 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- 239000011780 sodium chloride Substances 0.000 claims description 7
- 235000002639 sodium chloride Nutrition 0.000 claims description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- 125000005323 thioketone group Chemical group 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 5
- -1 alkene nitrile Chemical class 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 235000015424 sodium Nutrition 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 125000003184 C60 fullerene group Chemical group 0.000 claims description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004472 Lysine Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 235000001014 amino acid Nutrition 0.000 claims 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 claims 2
- 239000004475 Arginine Substances 0.000 claims 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 1
- 239000004471 Glycine Substances 0.000 claims 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims 1
- 235000004279 alanine Nutrition 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 239000004599 antimicrobial Substances 0.000 claims 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims 1
- 239000002054 inoculum Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- 238000001291 vacuum drying Methods 0.000 claims 1
- 230000003115 biocidal effect Effects 0.000 abstract description 12
- 238000005516 engineering process Methods 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000004753 textile Substances 0.000 description 8
- 150000001336 alkenes Chemical class 0.000 description 7
- 238000010998 test method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000009759 skin aging Effects 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 125000003916 ethylene diamine group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 229940032021 tetramune Drugs 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
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- D01F1/00—General methods for the manufacture of artificial filaments or the like
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- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
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- D01F6/54—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated nitriles
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Abstract
本发明涉及抗菌功能纤维技术领域,具体涉及一种利用富勒烯制备抗菌型纤维布料的方法,包括以下步骤:将抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维按照2:3:2:3的质量比分别进行称取,所述抗菌聚丙烯腈纤维中内置有抗菌剂和水溶性富勒烯;分别将上述抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维进行清花、打卷、梳棉处理,将莫代尔纤维、竹纤维、聚酯纤维进行并条、粗纱、细纱处理,得到混纺纱线,再对抗菌聚丙烯腈纤维单独进行并条、粗纱、细纱处理,得到抗菌聚丙烯腈纤维纱线;最后经过精炼处理、织布、洗涤、吸湿整理以及烘干即得到抗菌型纤维布料;本发明长效抗菌、柔软护肤、排汗吸湿以及坚固耐磨的优点。
Description
技术领域
本发明涉及抗菌功能纤维技术领域,具体涉及一种利用富勒烯制备抗菌型纤维布料的方法。
背景技术
具有抗菌功能的纺织布料能杀灭或抑制与其接触的细菌等微生物,从而起到卫生防范的效果,通常是应用纺丝得到抗菌纤维或普通纺织品经过后整理得到的功能性纺织品。在生活水平逐步提高的当今社会,纺织品的舒适卫生性直接影响着人们的生活质量,赋予抗菌抑菌功能是纺织品性能升级的重要手段。纺织品的抗菌性能在军事上也有很大的实用价值,二次世界大战中德军装备了经过抗菌加工的军服而减少了伤员的细菌感染。上世纪六十年代,抗菌后整理的卫生织物开始民用。抗菌后整理通常是使用有机抗菌剂,早起使用安全性较差的氯代酚等抗菌性化学物质,八十年代中期以后多采用季胺盐类抗菌整理剂。
近年来也在后整理技术中开发应用无机抗菌剂,至今对纯天然纤维制成的纺织品而言,后整理技术在耐洗涤性不够是该技术的短处,因此,开发一款不仅能长效抗菌,还能考虑到舒适度与耐用率的布料是人们所期盼的。
发明内容
本发明的目的在于克服现有技术的不足,提供一种利用富勒烯制备抗菌型纤维布料的方法。本发明长效抗菌、柔软护肤、排汗吸湿以及坚固耐磨的优点。
一种利用富勒烯制备抗菌型纤维布料的方法,包括以下步骤:
S1原料准备:将抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维按照2:3:2:3的质量比分别进行称取,所述抗菌聚丙烯腈纤维中内置有抗菌剂和水溶性富勒烯,所述抗菌聚丙烯腈纤维的制备方法为将抗菌剂与水性富勒烯以球型固体颗粒形态加入到聚丙烯腈纺丝原液中,再喷丝制成;
S2纺纱工序:分别将上述抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维进行清花、打卷、梳棉处理,将莫代尔纤维、竹纤维、聚酯纤维进行并条、粗纱、细纱处理,得到混纺纱线,再对抗菌聚丙烯腈纤维单独进行并条、粗纱、细纱处理,得到抗菌聚丙烯腈纤维纱线;
S3精炼处理:将经过纺纱工序的抗菌聚丙烯腈纤维纺纱和混纺纱线置于65-80℃的精炼液中处理45-55min,浴比为1:35-40;
S4织布工序:将经过精炼处理的纺纱放入无缝针织机上织成布料,所述布料包括经纱和纬纱,所述经纱为所述抗菌聚丙烯腈纤维纱线,纬纱为所述混纺纱线;
S5洗涤工序:将步骤S4得到的布料置于混有洗涤液的水中水洗10-15min,洗涤温度为25-30℃;
S6吸湿整理:将经过洗涤工序后的布料用整理液在25-30℃的温度下处理15-20min,浴比为1:10;
S7烘干:将经过吸湿整理后的布料放入烘干机中于80-90℃下进行烘干,即得到抗菌型纤维布料;
进一步地,所述步骤S1抗菌聚丙烯腈纤维中内置的抗菌剂和水溶性富勒烯的质量比为3:1。
进一步地,所述步骤S1中抗菌剂由砒啶硫酮锌和方沸石按照质量比为3:5混合制成。
进一步地,所述步骤S3精炼液由氯化钠、氯化钾、纯碱以及硫酸钠按照质量比为1:3:2:2混合而成。
进一步地,所述步骤S4中经纱和纬纱的密度比为112:87。
进一步地,所述步骤S6整理液由QC-1476型吸湿排汗整理液与SF-10型柔软剂按照质量比为3:2混合而成。
有益效果
本发明的有益效果如下:
(1)、本发明原料中抗菌聚丙烯腈纤维采用通过内置式设计,将抗菌剂与水溶性富勒烯储存于纤维里,纤维内部形成了抗菌仓库,抗菌剂不断溶出至纤维表面,形成抗菌层和抑菌层,当旧的抗菌层被水洗掉,抗菌剂又能溢出形成新的抗菌层,如此能不断循环,解决了现有技术中仅仅靠面料染整后处理时需要加抑菌除螨助剂来发挥抑菌除螨作用而带来维持时间短,不可持续,抑菌除螨效果不好的技术问题,同时,抗菌聚丙烯腈纤维内储存的水溶性富勒烯能够有效清除和抵抗皮肤中的自由基,预防皮肤衰老及暗沉,其抗氧化性也很强,是维生素C的172倍,使布料增添了延缓皮肤衰老的功效,而原料中的莫代尔纤维具有很好的柔软性和优良的吸湿性,使布料更适合作为与人体直接接触的内衣物制品了。
(2)、本发明将抗菌聚丙烯腈纤维纱线与由莫代尔纤维、竹纤维、聚酯纤维混纺而成的混纺纱线分别作为经纱和纬纱按照经纬密度比为112:87纺织成布,这种经纬密度比的布料不仅厚实坚固,还具有良好的防静电性能,其中,聚酯纤维抗皱性和保形性很好,具有较高的强度与弹性恢复能力,竹纤维具有良好的透气性、瞬间吸水性、较强的耐磨性和良好的染色性等特性,同时具有天然抗菌、抑菌、除螨、防臭和抗紫外线功能,这两种纤维的加入显著提升了布料的品质,使布料不仅具有抗菌、护肤作用,还拥有了舒适的穿着体验以及经久耐磨的优良品质;本发明通过使用由QC-1476型吸湿排汗整理液与SF-10型柔软剂按照质量比为3:2混合而成的整理液,使布料在舒适柔软的同时具有显著的吸湿排汗功能。
具体实施方式
下面结合具体实施例对本发明作进一步详细说明。
实施例1
一种利用富勒烯制备抗菌型纤维布料的方法,包括以下步骤:
S1原料准备:将抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维按照2:3:2:3的质量比分别进行称取,所述抗菌聚丙烯腈纤维中内置有质量比为3:1的抗菌剂和水溶性富勒烯,所述抗菌聚丙烯腈纤维的制备方法为将抗菌剂与水性富勒烯以球型固体颗粒形态加入到聚丙烯腈纺丝原液中,再喷丝制成,其中所述抗菌剂由砒啶硫酮锌和方沸石按照质量比为3:5混合制成;
S2纺纱工序:分别将上述抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维进行清花、打卷、梳棉处理,将莫代尔纤维、竹纤维、聚酯纤维进行并条、粗纱、细纱处理,得到混纺纱线,再对抗菌聚丙烯腈纤维单独进行并条、粗纱、细纱处理,得到抗菌聚丙烯腈纤维纱线;
S3精炼处理:将经过纺纱工序的抗菌聚丙烯腈纤维纺纱和混纺纱线置于65℃的由氯化钠、氯化钾、纯碱以及硫酸钠按照质量比为1:3:2:2混合而成的精炼液中处理45min,浴比为1:35;
S4织布工序:将经过精炼处理的纺纱放入无缝针织机上织成布料,所述布料包括经纱和纬纱,经纱和纬纱的密度比为112:87,所述经纱为所述抗菌聚丙烯腈纤维纱线,纬纱为所述混纺纱线;
S5洗涤工序:将步骤S4得到的布料置于混有洗涤液的水中水洗10min,洗涤温度为25℃;
S6吸湿整理:将经过洗涤工序后的布料用由QC-1476型吸湿排汗整理液与SF-10型柔软剂按照质量比为3:2混合而成的整理液在25℃的温度下处理15min,浴比为1:10;
S7烘干:将经过吸湿整理后的布料放入烘干机中于80℃下进行烘干,即得到抗菌型纤维布料;
实施例2
一种利用富勒烯制备抗菌型纤维布料的方法,包括以下步骤:
S1原料准备:将抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维按照2:3:2:3的质量比分别进行称取,所述抗菌聚丙烯腈纤维中内置有质量比为3:1的抗菌剂和水溶性富勒烯,所述抗菌聚丙烯腈纤维的制备方法为将抗菌剂与水性富勒烯以球型固体颗粒形态加入到聚丙烯腈纺丝原液中,再喷丝制成,其中所述抗菌剂由砒啶硫酮锌和方沸石按照质量比为3:5混合制成;
S2纺纱工序:分别将上述抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维进行清花、打卷、梳棉处理,将莫代尔纤维、竹纤维、聚酯纤维进行并条、粗纱、细纱处理,得到混纺纱线,再对抗菌聚丙烯腈纤维单独进行并条、粗纱、细纱处理,得到抗菌聚丙烯腈纤维纱线;
S3精炼处理:将经过纺纱工序的抗菌聚丙烯腈纤维纺纱和混纺纱线置于72℃的由氯化钠、氯化钾、纯碱以及硫酸钠按照质量比为1:3:2:2混合而成的精炼液中处理50min,浴比为1:37;
S4织布工序:将经过精炼处理的纺纱放入无缝针织机上织成布料,所述布料包括经纱和纬纱,经纱和纬纱的密度比为112:87,所述经纱为所述抗菌聚丙烯腈纤维纱线,纬纱为所述混纺纱线;
S5洗涤工序:将步骤S4得到的布料置于混有洗涤液的水中水洗13min,洗涤温度为28℃;
S6吸湿整理:将经过洗涤工序后的布料用由QC-1476型吸湿排汗整理液与SF-10型柔软剂按照质量比为3:2混合而成的整理液在27℃的温度下处理17min,浴比为1:10;
S7烘干:将经过吸湿整理后的布料放入烘干机中于85℃下进行烘干,即得到抗菌型纤维布料;
实施例3
一种利用富勒烯制备抗菌型纤维布料的方法,包括以下步骤:
S1原料准备:将抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维按照2:3:2:3的质量比分别进行称取,所述抗菌聚丙烯腈纤维中内置有质量比为3:1的抗菌剂和水溶性富勒烯,所述抗菌聚丙烯腈纤维的制备方法为将抗菌剂与水性富勒烯以球型固体颗粒形态加入到聚丙烯腈纺丝原液中,再喷丝制成,其中所述抗菌剂由砒啶硫酮锌和方沸石按照质量比为3:5混合制成;
S2纺纱工序:分别将上述抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维进行清花、打卷、梳棉处理,将莫代尔纤维、竹纤维、聚酯纤维进行并条、粗纱、细纱处理,得到混纺纱线,再对抗菌聚丙烯腈纤维单独进行并条、粗纱、细纱处理,得到抗菌聚丙烯腈纤维纱线;
S3精炼处理:将经过纺纱工序的抗菌聚丙烯腈纤维纺纱和混纺纱线置于80℃的由氯化钠、氯化钾、纯碱以及硫酸钠按照质量比为1:3:2:2混合而成的精炼液中处理55min,浴比为1:40;
S4织布工序:将经过精炼处理的纺纱放入无缝针织机上织成布料,所述布料包括经纱和纬纱,经纱和纬纱的密度比为112:87,所述经纱为所述抗菌聚丙烯腈纤维纱线,纬纱为所述混纺纱线;
S5洗涤工序:将步骤S4得到的布料置于混有洗涤液的水中水洗15min,洗涤温度为30℃;
S6吸湿整理:将经过洗涤工序后的布料用由QC-1476型吸湿排汗整理液与SF-10型柔软剂按照质量比为3:2混合而成的整理液在30℃的温度下处理20min,浴比为1:10;
S7烘干:将经过吸湿整理后的布料放入烘干机中于90℃下进行烘干,即得到抗菌型纤维布料;
实施例4
一种利用富勒烯制备抗菌型纤维布料的方法,包括以下步骤:
S1原料准备:将抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维按照2:3:2:3的质量比分别进行称取,所述抗菌聚丙烯腈纤维中内置有质量比为3:1的抗菌剂和水溶性富勒烯,所述抗菌聚丙烯腈纤维的制备方法为:1)聚丙烯腈纺丝原液的准备:将通过溶液聚合法所制得的聚丙烯腈聚合液经过脱单体、混合、脱泡、过滤,得到聚丙烯腈纺丝原液,其中,所述聚丙烯腈纺丝原液包括如下组成:聚丙烯腈15重量份,硫氢酸钠40重量份,去离子水40重量份,10重量份抗菌剂,15重量份水性富勒烯;2)纺丝:聚丙烯腈纺丝原液由喷丝板挤出,进入纺丝甬道,固化成型,经干燥,收集得到耐久性抗菌聚丙烯腈纤维,其中所述抗菌剂由砒啶硫酮锌和方沸石按照质量比为3:5混合制成;
S2纺纱工序:分别将上述抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维进行清花、打卷、梳棉处理,将莫代尔纤维、竹纤维、聚酯纤维进行并条、粗纱、细纱处理,得到混纺纱线,再对抗菌聚丙烯腈纤维单独进行并条、粗纱、细纱处理,得到抗菌聚丙烯腈纤维纱线;
S3精炼处理:将经过纺纱工序的抗菌聚丙烯腈纤维纺纱和混纺纱线置于80℃的由氯化钠、氯化钾、纯碱以及硫酸钠按照质量比为1:3:2:2混合而成的精炼液中处理55min,浴比为1:40;
S4织布工序:将经过精炼处理的纺纱放入无缝针织机上织成布料,所述布料包括经纱和纬纱,经纱和纬纱的密度比为112:87,所述经纱为所述抗菌聚丙烯腈纤维纱线,纬纱为所述混纺纱线;
S5洗涤工序:将步骤S4得到的布料置于混有洗涤液的水中水洗15min,洗涤温度为30℃;
S6吸湿整理:将经过洗涤工序后的布料用由QC-1476型吸湿排汗整理液与SF-10型柔软剂按照质量比为3:2混合而成的整理液在30℃的温度下处理20min,浴比为1:10;
S7烘干:将经过吸湿整理后的布料放入烘干机中于90℃下进行烘干,即得到抗菌型纤维布料;
实施例5
一种利用富勒烯制备抗菌型纤维布料的方法,包括以下步骤:
S1原料准备:将抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维按照2:3:2:3的质量比分别进行称取,所述抗菌聚丙烯腈纤维中内置有质量比为3:1的抗菌剂和水溶性富勒烯,所述抗菌聚丙烯腈纤维的制备方法为:1)聚丙烯腈纺丝原液的准备:将通过溶液聚合法所制得的聚丙烯腈聚合液经过脱单体、混合、脱泡、过滤,得到聚丙烯腈纺丝原液,其中,所述聚丙烯腈纺丝原液包括如下组成:聚丙烯腈15重量份,硫氢酸钠40重量份,去离子水40重量份,10重量份抗菌剂,15重量份水性富勒烯;2)纺丝:聚丙烯腈纺丝原液由喷丝板挤出,进入纺丝甬道,固化成型,经干燥,收集得到耐久性抗菌聚丙烯腈纤维,其中所述抗菌剂由砒啶硫酮锌和方沸石按照质量比为3:5混合制成;其中,
该水性富勒烯是在富勒烯分子上通过化学键连接水溶性氨基酸制成,水溶性氨基酸和富勒烯的质量比为0.5:1,所述的富勒烯为C60富勒烯,所述水溶性氨基酸为赖氨酸,其中,包括以下步骤:1)将氨化试剂30mL和氢氧化钠2g混合,搅拌均匀后,逐滴加入含有富勒烯的有机溶液50mL,加入反应釜中,在60℃条件下进行反应12小时,然后在60℃下,真空干燥72h,得氨基富勒烯;所述的氨化试剂为乙二胺;所述的含有富勒烯的有机溶液由富勒烯和有机溶剂组成,每1mL的有机溶液中含富勒烯1mg;所述的有机溶剂为甲苯;2)称取上述得到的氨基富勒烯20mg与水溶性氨基酸50mg、40mL甲酰胺中混合均匀,加入反应釜中,在60℃条件条件下进行反应12小时,然后在60℃下,真空干燥72h,得富勒烯-水溶性氨基酸聚合物,即水性富勒烯;
S2纺纱工序:分别将上述抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维进行清花、打卷、梳棉处理,将莫代尔纤维、竹纤维、聚酯纤维进行并条、粗纱、细纱处理,得到混纺纱线,再对抗菌聚丙烯腈纤维单独进行并条、粗纱、细纱处理,得到抗菌聚丙烯腈纤维纱线;
S3精炼处理:将经过纺纱工序的抗菌聚丙烯腈纤维纺纱和混纺纱线置于80℃的由氯化钠、氯化钾、纯碱以及硫酸钠按照质量比为1:3:2:2混合而成的精炼液中处理55min,浴比为1:40;
S4织布工序:将经过精炼处理的纺纱放入无缝针织机上织成布料,所述布料包括经纱和纬纱,经纱和纬纱的密度比为112:87,所述经纱为所述抗菌聚丙烯腈纤维纱线,纬纱为所述混纺纱线;
S5洗涤工序:将步骤S4得到的布料置于混有洗涤液的水中水洗15min,洗涤温度为30℃;
S6吸湿整理:将经过洗涤工序后的布料用由QC-1476型吸湿排汗整理液与SF-10型柔软剂按照质量比为3:2混合而成的整理液在30℃的温度下处理20min,浴比为1:10;
S7烘干:将经过吸湿整理后的布料放入烘干机中于90℃下进行烘干,即得到抗菌型纤维布料;
对比例1
对比例1与实施例2的不同之处在于对比例1原料中不含有抗菌聚丙烯腈纤维。
通过对实施例1-实施例3和对比例1制得的布料进行断裂强度、抗菌效果、抗菌耐久度、保水率以及回潮率的测试,测试结果如下表所示:
项目 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 对比例1 |
断裂强度cN·dtex<sup>-1</sup> | 2.24 | 2.31 | 2.28 | 2.41 | 2.45 | 2.25 |
回潮率% | 1.06 | 1.2 | 1.18 | 1.01 | 1.03 | 1.12 |
保水率% | 3.24 | 3.32 | 3.26 | 3.31 | 3.34 | 3.27 |
抗菌效果% | 82 | 84 | 82 | 88 | 89 | 64 |
抗菌耐久度% | 32.4 | 34.6 | 33.2 | 35.2 | 35.0 | 12.4 |
其中,断裂强度的测试方法为:GB/T 13835.5-2009《单纤维断裂强度测试》;
回潮率的测试方法为:采用箱内热称法测试。称取(50±0.01)g的试样,在(105±3)℃烘箱烘燥1h后称重,根据烘燥前后质量差计算。
保水率的测试方法为:将开松纤维浸没于水,使纤维充分吸水平衡后,用离心罐脱水,纤维所保持的各种水分总量的百分数即为所测保水率。
抗菌性的测试方法为:GB T 20944.3-2008《纺织品抗菌性能的评价》中对金黄色葡萄球菌的抑菌率以及对白色念珠菌抑菌率的测试方法;
抗菌耐久度的测试方法为:将布料放入洗衣机中重复洗涤10次后,在对其抗菌性进行测试,得到的结果与之洗涤之前的抗菌率结果的比值即为抗菌耐久度。
从以上表格数据可以看出抗菌聚丙烯腈纤维对抗菌性和抗菌耐久度的重要影响,且实施例4和5的各项数据最好,为最优实施方案。
最后应说明的是:以上所述仅为本发明的优选实施例而已,并不用于限制本发明,尽管参照前述实施例对本发明进行了详细的说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (8)
1.一种利用富勒烯制备抗菌型纤维布料的方法,其特征在于,包括以下步骤:
S1原料准备:将抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维按照2:3:2:3的质量比分别进行称取,所述抗菌聚丙烯腈纤维中内置有抗菌剂和水溶性富勒烯,所述抗菌聚丙烯腈纤维的制备方法为将抗菌剂与水性富勒烯以固体颗粒形态加入到聚丙烯腈纺丝原液中,再喷丝制成;
S2纺纱工序:分别将上述抗菌聚丙烯腈纤维、莫代尔纤维、竹纤维、聚酯纤维进行清花、打卷、梳棉处理,将莫代尔纤维、竹纤维、聚酯纤维进行并条、粗纱、细纱处理,得到混纺纱线,再对抗菌聚丙烯腈纤维单独进行并条、粗纱、细纱处理,得到抗菌聚丙烯腈纤维纱线;
S3精炼处理:将经过纺纱工序的抗菌聚丙烯腈纤维纺纱和混纺纱线置于65-80℃的精炼液中处理45-55min,浴比为1:35-40;
S4织布工序:将经过精炼处理的纺纱放入无缝针织机上织成布料,所述布料包括经纱和纬纱,所述经纱为所述抗菌聚丙烯腈纤维纱线,纬纱为所述混纺纱线;
S5洗涤工序:将步骤S4得到的布料置于混有洗涤液的水中水洗10-15min,洗涤温度为25-30℃;
S6吸湿整理:将经过洗涤工序后的布料用整理液在25-30℃的温度下处理15-20min,浴比为1:10;
S7烘干:将经过吸湿整理后的布料放入烘干机中于80-90℃下进行烘干,即得到抗菌型纤维布料。
2.根据权利要求1所述的一种利用富勒烯制备抗菌型纤维布料的方法,其特征在于,所述步骤S1抗菌聚丙烯腈纤维中内置的抗菌剂和水溶性富勒烯的质量比为3:1。
3.根据权利要求1所述的一种利用富勒烯制备抗菌型纤维布料的方法,其特征在于,所述步骤S1中抗菌剂由砒啶硫酮锌和方沸石按照质量比为3:5混合制成。
4.根据权利要求1所述的一种利用富勒烯制备抗菌型纤维布料的方法,其特征在于,所述步骤S3精炼液由氯化钠、氯化钾、纯碱以及硫酸钠按照质量比为1:3:2:2混合而成。
5.根据权利要求1所述的一种利用富勒烯制备抗菌型纤维布料的方法,其特征在于,所述步骤S4中经纱和纬纱的密度比为112:87。
6.根据权利要求1所述的一种利用富勒烯制备抗菌型纤维布料的方法,其特征在于,所述步骤S6整理液由QC-1476型吸湿排汗整理液与SF-10型柔软剂按照质量比为3:2混合而成。
7.根据权利要求1所述的一种利用富勒烯制备抗菌型纤维布料的方法,其特征在于,所述抗菌聚丙烯腈纤维的制备方法为:
1)聚丙烯腈纺丝原液的准备:将通过溶液聚合法所制得的聚丙烯腈聚合液经过脱单体、混合、脱泡、过滤,得到聚丙烯腈纺丝原液,其中,所述聚丙烯腈纺丝原液包括如下组成:聚丙烯腈13~15重量份,硫氢酸钠40~45重量份,去离子水40~47重量份,5~10重量份抗菌剂,10~15重量份水性富勒烯;2)纺丝:聚丙烯腈纺丝原液由喷丝板挤出,进入纺丝甬道,固化成型,经干燥,收集得到耐久性抗菌聚丙烯腈纤维。
8.根据权利要求1所述的一种利用富勒烯制备抗菌型纤维布料的方法,其特征在于,水性富勒烯是在富勒烯分子上通过化学键连接水溶性氨基酸制成,水溶性氨基酸和富勒烯的质量比为0.3-0.5:1,所述的富勒烯为C60富勒烯,所述水溶性氨基酸为丙氨酸、甘氨酸、丝氨酸、精氨酸、赖氨酸和天门氨酸中的至少一种,其中,包括以下步骤:1)将氨化试剂10-30mL和氢氧化钠0.5-2g混合,搅拌均匀后,逐滴加入含有富勒烯的有机溶液50mL,加入反应釜中,在60-70℃条件条件下进行反应10-12小时,然后在20-60℃下,真空干燥24-72h,得氨基富勒烯;所述的氨化试剂为乙二胺、1,3-丙二胺、1,6-己二胺中的一种;所述的含有富勒烯的有机溶液由富勒烯和有机溶剂组成,每1mL的有机溶液中含富勒烯1mg;所述的有机溶剂为甲苯、苯、四氢呋喃中的一种或两种以上的混合物;2)称取上述得到的氨基富勒烯10-20mg与水溶性氨基酸40-50mg、20-40mL甲酰胺中混合均匀,加入反应釜中,在60-70℃条件条件下进行反应10-12小时,然后在20-60℃下,真空干燥24-72h,得富勒烯-水溶性氨基酸聚合物,即水性富勒烯。
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