CN109563339B - 无氟纤维处理组合物、经处理基底以及处理方法 - Google Patents

无氟纤维处理组合物、经处理基底以及处理方法 Download PDF

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CN109563339B
CN109563339B CN201780049566.5A CN201780049566A CN109563339B CN 109563339 B CN109563339 B CN 109563339B CN 201780049566 A CN201780049566 A CN 201780049566A CN 109563339 B CN109563339 B CN 109563339B
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isocyanate
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group
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CN109563339A (zh
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迪尔克·M·科庞
鲁道夫·J·达姆斯
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3M Innovative Properties Co
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  • Polyurethanes Or Polyureas (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201780049566.5A 2016-08-12 2017-08-08 无氟纤维处理组合物、经处理基底以及处理方法 Active CN109563339B (zh)

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US201662374409P 2016-08-12 2016-08-12
US62/374,409 2016-08-12
PCT/US2017/045876 WO2018031534A1 (en) 2016-08-12 2017-08-08 Fluorine-free fibrous treating compositions, treated substrates, and treating methods

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CN109563339A CN109563339A (zh) 2019-04-02
CN109563339B true CN109563339B (zh) 2022-03-01

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Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019108476A1 (en) * 2017-11-30 2019-06-06 3M Innovative Properties Company Compositions, treating methods, and treated fibrous substrates
TWI682084B (zh) * 2019-01-04 2020-01-11 遠東新世紀股份有限公司 無氟撥水劑的製造方法與撥水織物
AU2020203204B2 (en) * 2019-05-17 2025-09-25 International Textile Group, Inc. Water resistant protective garment
US20220325016A1 (en) * 2019-08-02 2022-10-13 3M Innovative Properties Company Acrylate oligomers, acrylate oligomer emulsions, and fluorine-free stain-release compositions containing the same
TWI718683B (zh) * 2019-09-25 2021-02-11 財團法人紡織產業綜合研究所 疏水紗線的製造方法
JP7555355B2 (ja) * 2019-12-24 2024-09-24 三井化学株式会社 撥水剤組成物、撥水剤組成物の製造方法、および、繊維製品
WO2021132170A1 (ja) 2019-12-24 2021-07-01 三井化学株式会社 ポリウレタン樹脂組成物、撥剤、繊維撥水剤および防汚コート剤
CN111187380A (zh) * 2020-03-11 2020-05-22 桐乡市钜成涂装科技有限公司 一种含氯的无氟防水剂共聚物乳液及其聚合方法
TWI909098B (zh) * 2021-09-30 2025-12-21 日商日油股份有限公司 撥水劑用聚合物、撥水劑組合物及撥水劑處理物
US12577708B2 (en) 2021-11-23 2026-03-17 Safety Components International, Inc. Outdoor fabric having wool-like properties
TW202424310A (zh) 2022-09-14 2024-06-16 日商大金工業股份有限公司 撥液性纖維的製造方法
CN122055821A (zh) 2023-10-19 2026-05-15 3M创新有限公司 包含非氟化疏水性材料的气体扩散层和微孔层
CN119711183B (zh) * 2025-02-25 2025-05-13 浙江技立新材料股份有限公司 一种防水阻燃多功能面料的制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0436327A1 (en) * 1989-12-22 1991-07-10 Minnesota Mining And Manufacturing Company Water- and oil-repellent treatment agent
EP0448399A2 (en) * 1990-03-21 1991-09-25 Minnesota Mining And Manufacturing Company Waterborne acrylic low adhesion backsize and release coating compositions, methods of making the compositions, and sheet materials coated therewith
CN1406259A (zh) * 2000-12-28 2003-03-26 纳托科株式会社 活化能射线可固化的(甲基)丙烯酸聚氨酯和活化能射线可固化的组合物及其用途
CN101094831A (zh) * 2004-11-04 2007-12-26 3M创新有限公司 使基材斥油斥水的碳二亚胺化合物和组合物
JP2010132844A (ja) * 2008-12-08 2010-06-17 Asahi Glass Co Ltd ウレタン／尿素化合物、その製造方法および撥水剤組成物
TW201605999A (zh) * 2014-05-23 2016-02-16 Meisei Chemical Works Ltd 不含氟之撥水劑組成物及撥水加工方法

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2941988A (en) 1956-04-02 1960-06-21 Olin Mathieson Process for the alkoxylation of polyvinyl alcohol
GB1413051A (en) 1972-03-06 1975-11-05 Minnesota Mining & Mfg Fabric treatment
US3862989A (en) 1973-06-08 1975-01-28 Minnesota Mining & Mfg Carbodiimide catalysts and processes
JPS6024828B2 (ja) 1979-08-24 1985-06-14 積水化学工業株式会社 剥離剤
US4692503A (en) 1980-12-29 1987-09-08 Ppg Industries, Inc. Coating compositions comprising free radical addition polymers with crosslinkable integral isocyanato groups
DE3928149A1 (de) 1989-08-25 1991-02-28 Bayer Ag Verfahren zur herstellung von polyurethanpulvern
US5225480A (en) 1990-03-21 1993-07-06 Minnesota Mining And Manufacturing Company Water-borne low adhesion backsize and release coating compositions, methods of making the compositions, and sheet materials coated therewith
US5276175A (en) 1991-04-02 1994-01-04 Minnesota Mining And Manufacturing Company Isocyanate derivatives comprising flourochemical oligomers
US5604268A (en) 1995-02-22 1997-02-18 Minnesota Mining And Manufacturing Company Glue crayons
JP3461267B2 (ja) 1997-08-11 2003-10-27 大日精化工業株式会社 ポリカルボジイミド化合物、その製造方法、樹脂組成物及び物品の処理方法
DE19858817A1 (de) 1998-12-21 2000-06-29 Bayer Ag Wäßrige reaktive Spachtelmassen (I)
JP3809856B2 (ja) * 2000-08-31 2006-08-16 平岡織染株式会社 防水布
DE10211549B9 (de) 2002-03-15 2004-11-25 Rudolf Gmbh & Co. Kg Chemische Fabrik Zubereitungen auf Basis von Wasser und/oder organischen Lösemitteln und deren Anwendung als Appretur auf Flächengebilden
JP4045827B2 (ja) * 2002-03-27 2008-02-13 大日本インキ化学工業株式会社 水性樹脂組成物
JP4136428B2 (ja) 2002-04-10 2008-08-20 日本ポリウレタン工業株式会社 水性サンディングシーラー及びその製造方法
DE10245099A1 (de) * 2002-09-27 2004-04-08 Goldschmidt Ag Polyurethan-Verdickungsmittel zur Verdickung wässriger Systeme
DE10350786A1 (de) 2003-10-29 2005-06-02 Röhm GmbH & Co. KG Mischungen zur Herstellung von Reaktivschmelzklebstoffen sowie daraus erhältliche Reaktivschmelzklebstoffe
AU2006263574B2 (en) 2005-06-29 2012-01-12 3M Innovative Properties Company Polyurethanes derived from oligomeric fluoroacrylates
DE102006027490A1 (de) * 2006-06-14 2007-12-20 Borchers Gmbh Neue Polyurethane und ihre Verwendung zur Verdickung wässriger Systeme
DE102007020790B4 (de) 2007-05-03 2009-10-01 Rudolf Gmbh & Co. Kg Chemische Fabrik Fluorkohlenstoffpolymer-freie Zubereitungen auf Basis von Wasser und/oder organischen Lösemitteln und deren Anwendung als Appretur auf Flächengebilden sowie danach erhaltene textile Substrate
EP2233633A1 (de) * 2009-03-28 2010-09-29 Huntsman Textile Effects (Germany) GmbH Fluorfreie wässrige Dispersion für die Behandlung von textilen Flächengebilden
JP2012025820A (ja) 2010-07-21 2012-02-09 Kansai Paint Co Ltd 親水化処理剤組成物
JP5667849B2 (ja) 2010-11-19 2015-02-12 株式会社カネカ 水性樹脂組成物
US8742022B2 (en) 2010-12-20 2014-06-03 3M Innovative Properties Company Coating compositions comprising non-ionic surfactant exhibiting reduced fingerprint visibility
EP2581421A1 (en) * 2011-10-12 2013-04-17 Ineos Europe AG Additive
US20150119497A1 (en) 2012-03-29 2015-04-30 Sanyo Chemical Industries, Ltd. Vinyl resin and resin composition
JP6129296B2 (ja) 2012-04-24 2017-05-17 スリーエム イノベイティブ プロパティズ カンパニー フルオロケミカル化合物、組成物、物品、及び方法
US10138392B2 (en) 2013-03-29 2018-11-27 The Chemours Company Fc, Llc Non-fluorinated urethane based coatings
JP2015040365A (ja) * 2013-08-23 2015-03-02 大原パラヂウム化学株式会社 繊維用加工剤ならびにそれを用いて処理した繊維製品
DE102013224140A1 (de) 2013-11-26 2015-05-28 Rudolf Gmbh Ausrüstungsmittel mit blockierten Polyisocyanaten
JP6932081B2 (ja) 2015-02-13 2021-09-08 スリーエム イノベイティブ プロパティズ カンパニー イソシアネートから誘導された（メタ）アクリレート含有ポリマー化合物を含む、フッ素非含有組成物を使用して繊維基材を処理するための方法
JP6735763B2 (ja) 2015-02-13 2020-08-05 スリーエム イノベイティブ プロパティズ カンパニー ポリカルボジイミド及び任意にパラフィンワックスを含むフッ素不含繊維処理組成物、並びに処理方法
JP6741676B2 (ja) 2015-02-13 2020-08-19 スリーエム イノベイティブ プロパティズ カンパニー イソシアネートに由来するエチレン性不飽和モノマーを含むオリゴマーを含む、フッ素不含有の繊維処理組成物、及び処理方法
DE102015204736A1 (de) 2015-03-16 2016-09-22 Cht R. Beitlich Gmbh Fluorfreie Hydrophobierung
JP6949354B2 (ja) 2016-06-08 2021-10-13 明成化学工業株式会社 フッ素を含まないはっ水剤及びはっ水加工方法、はっ水性繊維製品
JP6840385B2 (ja) 2017-04-21 2021-03-10 明成化学工業株式会社 フッ素を含まないはっ水剤及びはっ水加工方法、はっ水性繊維製品

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0436327A1 (en) * 1989-12-22 1991-07-10 Minnesota Mining And Manufacturing Company Water- and oil-repellent treatment agent
EP0448399A2 (en) * 1990-03-21 1991-09-25 Minnesota Mining And Manufacturing Company Waterborne acrylic low adhesion backsize and release coating compositions, methods of making the compositions, and sheet materials coated therewith
CN1406259A (zh) * 2000-12-28 2003-03-26 纳托科株式会社 活化能射线可固化的(甲基)丙烯酸聚氨酯和活化能射线可固化的组合物及其用途
CN101094831A (zh) * 2004-11-04 2007-12-26 3M创新有限公司 使基材斥油斥水的碳二亚胺化合物和组合物
JP2010132844A (ja) * 2008-12-08 2010-06-17 Asahi Glass Co Ltd ウレタン／尿素化合物、その製造方法および撥水剤組成物
TW201605999A (zh) * 2014-05-23 2016-02-16 Meisei Chemical Works Ltd 不含氟之撥水劑組成物及撥水加工方法

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